CN114456636A - Toner fading agent and use method thereof - Google Patents

Toner fading agent and use method thereof Download PDF

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Publication number
CN114456636A
CN114456636A CN202210158909.4A CN202210158909A CN114456636A CN 114456636 A CN114456636 A CN 114456636A CN 202210158909 A CN202210158909 A CN 202210158909A CN 114456636 A CN114456636 A CN 114456636A
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parts
fading
ink
powder
sodium
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CN202210158909.4A
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CN114456636B (en
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沈福根
杜青
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Shenzhen Ruiou Optics Co ltd
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Shenzhen Ruiou Optics Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/04Chemical paint or ink removers with surface-active agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
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Abstract

The invention belongs to the technical field of optical lenses, and particularly relates to a toner fading powder and a use method thereof, wherein the toner fading powder comprises the following components in parts by weight: 28-42 parts of a surfactant, 20-36 parts of dibutyl maleate, 18-30 parts of a stripping agent, 3-6 parts of an activating agent and 7-11 parts of a composite additive. In the ink fading powder disclosed by the embodiment of the invention, the surfactant, the dibutyl maleate, the stripping agent, the activating agent and the composite additive are compounded into the ink fading powder according to a reasonable proportion, so that the ink can fall off from the surface of the optical glass, no ink residue exists after the ink fading, the loss caused by defective products is reduced, and the production benefit is improved.

Description

Toner fading agent and use method thereof
Technical Field
The invention belongs to the technical field of optical lenses, and particularly relates to a toner fading agent and a using method thereof.
Background
The optical glass camera lens belongs to a structural component of a mobile phone product, and has relatively complex process and high manufacturing cost.
The optical camera lens is finished by a series of complex processes such as cutting, laser, etching, tempering, silk-screen printing, coating and full inspection of glass raw materials, in the process of processing of each process, a part of defective products can be generated inevitably, no remedial measure is provided, the defective products can only be scrapped, and with the existing lens product processing flow, a large number of defective products can be detected only when the finished products are checked completely, the value of the finished lens product at the time is close to the selling price, the scrapping loss ratio is high, and serious loss is caused.
When defective products are repaired, a common oil removing film solvent is not clean in oil removing film, oil film residue still exists after the oil removing film, the defective proportion is high, the repair cost ratio is ultrahigh, and the repair ink removing process loses significance.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: aiming at the problems that the existing optical lens has incomplete oil film removing during repair, has residual oil film and higher bad proportion, and causes overhigh repair cost ratio, the ink removing powder and the use method thereof are provided.
In order to solve the technical problem, an embodiment of the present invention provides an ink fading powder, which includes the following components by weight: 28-42 parts of a surfactant, 20-36 parts of dibutyl maleate, 18-30 parts of a stripping agent, 3-6 parts of an activating agent and 7-11 parts of a composite additive.
Optionally, 32-38 parts of a surfactant, 25-32 parts of dibutyl maleate, 20-26 parts of a stripping agent, 3-5 parts of an activating agent and 8-10 parts of a composite additive.
Optionally, the surfactant is selected from one or more of citric acid fatty acid glyceride, trialkyl citramide, tri-n-butyl citramide, fatty alcohol polyoxyethylene ether and fatty acid glyceride.
Optionally, the activating agent is selected from one or more of sodium silicate, sodium carbonate and sodium phosphate.
Optionally, the composite additive is selected from one or more of sodium glutamate, sodium lactate and sodium sarcosinate.
Optionally, the stripping agent is selected from one or more of sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate.
On the other hand, the embodiment of the invention provides a use method of the ink fading powder, which comprises the steps of preparing the ink fading powder; 5-15 parts of the ink fading powder and 85-95 parts of deionized water are mixed in an ink fading groove, and the pH value of the mixed liquid is 11-13.
Optionally, the temperature in the ink fading groove is 60-80 ℃, and the ink fading time is 3-10 min.
In the ink fading powder provided by the embodiment of the invention, the surfactant, the dibutyl maleate, the stripping agent, the activating agent and the composite additive are compounded into the ink fading powder according to a reasonable proportion, so that the surfactant can reduce the surface tension during ink fading, has good balance and dynamic surface tension performance, enables the surface of the base material to have excellent wettability and can soften the ink. The stripping agent is strong alkali and has a stripping effect on the ink, and the dibutyl maleate is cooperated with the surfactant, so that the surfactant is migrated to an ink/substrate interface to provide wettability, the stripping force on the ink is enhanced, the ink is stripped from the surface of the optical glass, and no ink residue exists after ink stripping.
Detailed Description
In order to make the technical problems, technical solutions and advantageous effects solved by the present invention more apparent, the present invention is further described in detail below with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
An embodiment of the invention provides an ink fading powder, which comprises the following components in parts by weight: 28-42 parts of surfactant, 20-36 parts of dibutyl maleate, 18-30 parts of pH regulator, 3-6 parts of activating agent and 7-11 parts of composite additive.
In the invention, defective products can appear in the process of processing optical glass into finished products and semi-finished products, in the process of repairing the defective products, deplating, ink removing and ultrasonic cleaning are required to be carried out in sequence, the conventional deplating process and formula are adopted during deplating, the ink mainly comprises pigments and connecting materials, wherein the pigments mainly comprise pigments and dyes, and the connecting materials play a role of a medium for dispersing the pigments and auxiliary materials and generally comprise a small amount of organic polymer components such as natural resin, synthetic resin, cellulose, rubber derivatives and the like. The auxiliary materials mainly comprise a filling agent, a diluting agent, an anti-skinning agent, an anti-offset agent, a slip agent and the like. Wherein the filler is mainly inorganic substances such as talcum powder and calcium carbonate, the diluent is mainly oligomeric linseed oil, mineral oil and the like, the main components of the anti-skinning agent are organic reducing agent and organic antioxidant, the anti-reprinting agent is most commonly corn starch, and the slip agent is microcrystalline wax, synthetic wax and the like.
In the ink fading powder disclosed by the embodiment of the invention, the surfactant, the dibutyl maleate, the stripping agent, the activating agent and the composite additive are compounded into the ink fading powder according to a reasonable proportion, so that the surfactant can reduce the surface tension when the ink fading is carried out, and the ink fading powder has good balance and dynamic surface tension performance, so that the surface of the base material has excellent wettability and can soften the ink. The stripping agent is strong alkali and has a stripping effect on the ink, and the dibutyl maleate is cooperated with the surfactant, so that the surfactant is migrated to an ink/substrate interface to provide wettability, the stripping force on the ink is enhanced, the ink is stripped from the surface of the optical glass, and no ink residue exists after ink stripping.
In addition, the activating agent can promote the synergistic effect of the surfactant and the dibutyl maleate, and the compound additive has a certain corrosion inhibition effect, so that no corrosion inhibitor is required to be added into the ink fading powder. The invention does not corrode the surface of the optical glass, can perform tempering, silk-screen printing and film coating again after ink fading is clean to obtain a finished product, reduces the loss caused by defective products, and improves the production benefit.
In one embodiment, preferably, the surfactant is 32-38 parts, the dibutyl maleate is 25-32 parts, the peeling agent is 20-26 parts, the activating agent is 3-5 parts, and the composite additive is 8-10 parts.
In one embodiment, the surfactant is selected from one or more of citric acid fatty acid glyceride, trialkyl citramide, tri-n-butyl citramide, fatty alcohol polyoxyethylene ether and fatty acid glyceride. Preferably, the builder is citric acid fatty acid glyceride.
In one embodiment, the activator is selected from one or more of sodium silicate, sodium carbonate, and sodium phosphate. Preferably, the activator is sodium phosphate.
In one embodiment, the compound additive is selected from one or more of sodium glutamate, sodium lactate and sodium sarcosinate. Preferably, the compound additive is sodium glutamate.
In one embodiment, the stripping agent is selected from one or more of sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate, and preferably, the stripping agent is sodium hydroxide. The stripping agent is strong alkali, has good stripping capability, and can completely remove the printing ink on the optical glass without residue.
In another aspect, the present invention provides a method for using the powder for fading ink, comprising the steps of the powder for fading ink as described above; and mixing 5-15 parts of the ink fading powder and 85-95 parts of deionized water in an ink fading groove to obtain the ink fading agent, wherein the pH value of the mixed liquid is 11-13.
In one embodiment, a method for using the ink-fading powder further comprises: the temperature in the ink fading groove is 60-80 ℃, and the ink fading time is 3-10 min.
The optical glass repair process comprises the steps of inserting defective optical glass into a tempering frame, placing the optical glass into a deplating groove, soaking the optical glass in the deplating solution, heating the deplating solution, placing the optical glass into a deplating groove after the product is completely deplated, heating a deplating agent to maintain the temperature of the optical glass within the range of 60-80 ℃, completing ink deplating treatment after the product is soaked for 3-10 min, and then sequentially performing ultrasonic cleaning, tempering, ultrasonic cleaning, screen printing and film coating to obtain the repaired optical glass.
Compared with the prior art that the ink layer and the coating are removed through a mechanical flat grinding process, or the repair cost is offset due to the fact that the repair process yield is too low, in the invention, the ink removing powder is used for repairing the finished or semi-finished optical lens, so that the ink on the optical lens can be completely removed, the surface of the glass cannot be corroded or damaged, the optical lens is repaired after tempering, screen printing and coating, and the optical lens can be taken as a good product for shipment, the product cost is reduced, the comprehensive yield is improved, and the loss is reduced.
The following is a description of specific examples:
example 1
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of sodium hydroxide, 4 parts of sodium phosphate and 9 parts of sodium glutamate.
10Kg of fading powder and 90Kg of deionized water are mixed in a fading tank and soaked for 4min at 70 ℃.
Example 2
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of trialkyl citramide, 24 parts of sodium hydroxide, 4 parts of sodium phosphate and 9 parts of sodium glutamate. The usage of the fading powder was the same as in example 1.
Example 3
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of fatty glyceride, 24 parts of sodium hydroxide, 4 parts of sodium phosphate and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Example 4
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of potassium hydroxide, 4 parts of sodium phosphate and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Example 5
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of sodium carbonate, 4 parts of sodium phosphate and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Example 6
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of sodium hydroxide, 4 parts of sodium silicate and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Example 7
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of sodium hydroxide, 4 parts of sodium carbonate and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Example 8
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of sodium hydroxide, 4 parts of sodium phosphate and 9 parts of sodium lactate. The application method of the ink fading powder is the same as that in example 1.
Example 9
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of sodium hydroxide, 4 parts of sodium phosphate and 9 parts of sodium sarcosinate. The application method of the ink fading powder is the same as that in example 1.
Example 10
The toner fading agent comprises the following components in parts by weight: 22 parts of dibutyl maleate, 36 parts of citric acid fatty glyceride, 25 parts of sodium hydroxide, 5 parts of sodium phosphate and 11 parts of sodium glutamate. 15Kg of fading powder and 85Kg of deionized water are mixed in a fading tank and soaked for 3min at 75 ℃.
Example 11
The toner fading agent comprises the following components in parts by weight: 32 parts of dibutyl maleate, 32 parts of citric acid fatty glyceride, 19 parts of sodium hydroxide, 6 parts of sodium phosphate and 7 parts of sodium glutamate. 5Kg of fading powder and 95Kg of deionized water are mixed in a fading tank and soaked for 10min at 65 ℃.
Example 12
The toner fading agent comprises the following components in parts by weight: 30 parts of dibutyl maleate, 40 parts of citric acid fatty glyceride, 22 parts of sodium hydroxide, 4 parts of sodium phosphate and 10 parts of sodium glutamate. 8Kg of fading powder and 92Kg of deionized water are mixed in a fading tank and soaked for 8min at 70 ℃.
Example 13
The toner fading agent comprises the following components in parts by weight: 34 parts of dibutyl maleate, 30 parts of citric acid fatty glyceride, 28 parts of sodium hydroxide, 3 parts of sodium phosphate and 8 parts of sodium glutamate. 5Kg of fading powder and 95Kg of deionized water were mixed in a fading tank and soaked at 60 ℃ for 9 min.
Comparative example 1
The toner fading agent comprises the following components in parts by weight: 35 parts of citric acid fatty glyceride, 24 parts of sodium hydroxide, 4 parts of sodium phosphate and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Comparative example 2
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 24 parts of sodium hydroxide, 4 parts of sodium phosphate and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Comparative example 3
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 4 parts of sodium phosphate and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Comparative example 4
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of sodium hydroxide and 9 parts of sodium glutamate. The application method of the ink fading powder is the same as that in example 1.
Comparative example 5
The toner fading agent comprises the following components in parts by weight: 28 parts of dibutyl maleate, 35 parts of citric acid fatty glyceride, 24 parts of sodium hydroxide and 4 parts of sodium phosphate. The application method of the ink fading powder is the same as that in example 1.
By using the optical lenses obtained in the embodiments 1 to 13 to perform the ink removing treatment on the defective optical lens, the optical lens has a good ink removing effect, and the optical lens after ink removing has no ink residue on the surface and no corrosion, and does not cause secondary damage to the optical glass and chemical corrosion.
When the optical lens is subjected to ink fading, the optical lens after the ink fading powder in the embodiment 2 to the embodiment 9 is used has no ink residue and no corrosion, but the cleaning powder in the embodiment 1, the embodiment 10 to the embodiment 13 is an optimal embodiment when the cleaning powder is compared with the embodiment 1, wherein the cleaning powder has the advantages of optimal ink fading effect, high ink clearing speed, good ink fading effect and high efficiency.
By comparing example 1 with comparative example 1 and comparative example 2, it is found that the synergistic effect of dibutyl maleate and the surfactant cannot be completed in comparative example 1 and comparative example 2, the migration capability of the surfactant to an ink/substrate interface is reduced, the stripping effect of the ink is influenced, and the ink on the surface of the optical glass has residue after stripping.
It was found by comparing example 1 with comparative example 3 that in comparative example 3, the peeling of the ink could not be completed without the peeling agent.
Comparison of example 1 with comparative example 4 shows that the absence of the activator in comparative example 4 reduces the synergistic effect of the surfactant and dibutyl maleate, resulting in slower ink peeling with slight residue.
Compared with the comparative example 5, the comparative example 5 does not contain the composite additive, so that the stripping solution does not have a corrosion inhibition effect, and after stripping is finished, the surface of the optical glass has chemical corrosion and an atomization phenomenon.
In the embodiment 1 of the invention, the surface active agent, the dibutyl maleate, the stripping agent, the activating agent and the composite additive are compounded into the ink fading powder according to a reasonable proportion, so that the ink drops from the surface of the optical glass, no ink residue exists after the ink fading, the surface of the optical glass is not corroded, and the stripping effect is good.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.

Claims (8)

1. The ink fading powder is characterized by comprising the following components in parts by weight: 28-42 parts of a surfactant, 20-36 parts of dibutyl maleate, 18-30 parts of a stripping agent, 3-6 parts of an activating agent and 7-11 parts of a composite additive.
2. The fading powder of claim 1, wherein the surfactant comprises 32-38 parts, the dibutyl maleate comprises 25-32 parts, the stripping agent comprises 20-26 parts, the activating agent comprises 3-5 parts, and the composite additive comprises 8-10 parts.
3. The fading powder of claim 1 wherein said surfactant is selected from one or more of citric acid glycerol esters, trialkyl citramides, tri-n-butyl citramides, fatty alcohol polyoxyethylene ethers, and fatty acid glycerol esters.
4. The fading powder of claim 1 wherein said activator is selected from the group consisting of sodium silicate, sodium carbonate, and sodium phosphate.
5. The powder of claim 1 wherein the compound additive is selected from one or more of sodium glutamate, sodium lactate and sodium sarcosinate.
6. The fading powder of claim 1 wherein said release agent is selected from the group consisting of one or more of sodium hydroxide, potassium hydroxide, sodium carbonate, and potassium carbonate.
7. A method of using a powder for fading inks, comprising the powder for fading inks according to any one of claims 1 to 6; 5-15 parts of the ink fading powder and 85-95 parts of deionized water are mixed in an ink fading groove, and the pH value of the mixed liquid is 11-13.
8. The use method of the powder for fading ink as claimed in claim 7, wherein the temperature in the fading tank is 60 to 80 ℃ and the fading time is 3 to 10 min.
CN202210158909.4A 2022-02-21 2022-02-21 Toner fading agent and use method thereof Active CN114456636B (en)

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GB1457577A (en) * 1973-04-12 1976-12-08 Fossati C G Composition and method for removing water-insoluble coat9ngs applied to a substrate
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JPH05263383A (en) * 1991-08-22 1993-10-12 Takeda Chem Ind Ltd Ink-removing agent
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CN104804511A (en) * 2015-03-31 2015-07-29 安徽省嘉信包装印务有限公司 Environment-friendly detergent for printing ink
CN106398374A (en) * 2016-08-30 2017-02-15 广东山之风环保科技有限公司 Deinking method for glass workpiece and water-based deinking agent used by deinking method as well as preparation method of water-based deinking agent
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Publication number Priority date Publication date Assignee Title
GB1457577A (en) * 1973-04-12 1976-12-08 Fossati C G Composition and method for removing water-insoluble coat9ngs applied to a substrate
GB8312264D0 (en) * 1982-05-05 1983-06-08 Wilcot Parent Co Ltd Paint remover
JPH05263383A (en) * 1991-08-22 1993-10-12 Takeda Chem Ind Ltd Ink-removing agent
US20050003979A1 (en) * 2003-07-02 2005-01-06 Ecolab Inc. Warewashing composition for use in automatic dishwashing machines, comprising a mixture of aluminum and zinc ions
CN103013221A (en) * 2012-12-14 2013-04-03 广东工业大学 Preparation and application method of water-based paint remover
CN104804511A (en) * 2015-03-31 2015-07-29 安徽省嘉信包装印务有限公司 Environment-friendly detergent for printing ink
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