CN114456454A - Wear-resistant shoe material and preparation method thereof - Google Patents
Wear-resistant shoe material and preparation method thereof Download PDFInfo
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- CN114456454A CN114456454A CN202210131861.8A CN202210131861A CN114456454A CN 114456454 A CN114456454 A CN 114456454A CN 202210131861 A CN202210131861 A CN 202210131861A CN 114456454 A CN114456454 A CN 114456454A
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- 239000000463 material Substances 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 35
- 238000004073 vulcanization Methods 0.000 claims abstract description 28
- 229920001971 elastomer Polymers 0.000 claims abstract description 23
- 239000005060 rubber Substances 0.000 claims abstract description 23
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims abstract description 22
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920001195 polyisoprene Polymers 0.000 claims abstract description 17
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 13
- 239000011593 sulfur Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 229910000077 silane Inorganic materials 0.000 claims abstract description 11
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 11
- 239000011787 zinc oxide Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 10
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 claims description 18
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 229960002447 thiram Drugs 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 238000003801 milling Methods 0.000 claims description 8
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical group C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 7
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical group C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 7
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract description 7
- 238000013016 damping Methods 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 description 7
- 229920003051 synthetic elastomer Polymers 0.000 description 4
- 239000005061 synthetic rubber Substances 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920003052 natural elastomer Polymers 0.000 description 3
- 229920001194 natural rubber Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241001441571 Hiodontidae Species 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000006081 fluorescent whitening agent Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/10—Footwear characterised by the material made of rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/14—Footwear characterised by the material made of plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention is suitable for the field of shoe materials, and provides a wear-resistant shoe material which comprises the following raw materials in parts by weight: 20-80 parts of styrene butadiene rubber, 20-80 parts of polyisoprene, 50-60 parts of reinforcing filler, 2-5 parts of silane, 8-20 parts of coumarone resin, 2-5 parts of vulcanization anti-aging agent, 0.5-1 part of antioxidant, 3-10 parts of zinc oxide, 2-5 parts of vulcanization accelerator, 3-5 parts of ethylene glycol, 0.1-0.3 part of rubber accelerator and 1-5 parts of sulfur; according to the embodiment of the invention, the polyisoprene is added into the raw material of the shoe material, so that the obtained shoe material has very good damping performance and the best grip in a humid environment, and the shoe material has higher wear resistance; the added precipitated silica can endow the shoe material with high Shore hardness, tensile strength, tear resistance and wear resistance; meanwhile, the rubber can be matched with added glycol to obtain the optimal rubber technical data.
Description
Technical Field
The invention belongs to the field of shoe materials, and particularly relates to a wear-resistant shoe material and a preparation method thereof.
Background
Shoes are essential articles for daily use for people to go on a journey, and except having traditional convenient and practical characteristics, more and more pay attention to comfortable, pleasing to the eye and functional development, in the life of working as, under different occasions, different conditions, the kind diverse of shoes that people wore. Inevitably, the shoes are diversified.
With the development of the times, people have higher requirements on shoes, and sports shoes such as running shoes, ball shoes, football shoes and the like have higher sports comfort and wear resistance.
Traditional shoes wear resistance is poor, therefore the antiskid effect is poor, receives the threat at the in-process security performance that uses, has the short problem of life.
Disclosure of Invention
The embodiment of the invention aims to provide a wear-resistant shoe material and a preparation method thereof, and aims to solve the problems that the traditional shoe is poor in wear resistance, poor in anti-skid effect, threatened in safety performance in the using process and short in service life.
The embodiment of the invention is realized in such a way that the wear-resistant shoe material comprises the following raw materials in parts by weight: 20-80 parts of styrene butadiene rubber, 20-80 parts of polyisoprene, 50-60 parts of reinforcing filler, 2-5 parts of silane, 8-20 parts of coumarone resin, 2-5 parts of vulcanization anti-aging agent, 0.5-1 part of antioxidant, 3-10 parts of zinc oxide, 2-5 parts of vulcanization accelerator, 3-5 parts of ethylene glycol, 0.1-0.3 part of rubber accelerator and 1-5 parts of sulfur.
Preferably, the feed comprises the following raw materials in parts by weight: 20 parts of styrene butadiene rubber, 80 parts of polyisoprene, 50 parts of reinforcing filler, 3 parts of silane, 10 parts of coumarone resin, 3 parts of vulcanization anti-aging agent, 0.8 part of antioxidant, 5 parts of zinc oxide, 2 parts of vulcanization accelerator, 4 parts of ethylene glycol, 1 part of rubber accelerator and 2 parts of sulfur.
Preferably, the composite material also comprises 20-80 parts of polyisoprene.
Preferably, the reinforcing filler comprises precipitated silica.
Preferably, the vulcanization antioxidant comprises 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer and tetramethylthiuram disulfide.
Preferably, the ratio of the 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer to the tetramethylthiuram disulfide is 2: 1.
Preferably, the antioxidant is 2-mercaptobenzimidazole.
Preferably, the vulcanization accelerator is stearic acid.
Preferably, the rubber accelerator is dibenzothiazyl disulfide.
The invention also provides a preparation method of the wear-resistant shoe material, which comprises the following steps:
the method comprises the following steps: adding styrene butadiene rubber, polyisoprene, zinc oxide, coumarone resin and reinforcing filler into an internal mixer according to the parts by weight, and mixing for 20-30 min;
step two: putting the mixed mixture into an open mill, then putting silane, an antioxidant and ethylene glycol according to the parts, and open milling for 20-30min at the temperature of 130-150 ℃;
step three: adding the vulcanization anti-aging agent, the vulcanization accelerator, the rubber accelerator and the sulfur according to the parts, continuously open-milling for 10-30min, and obtaining the shoe material under the pressure of 10-15 MPa in the vulcanization process.
1. According to the embodiment of the invention, the polyisoprene is added into the raw material of the shoe material, so that the obtained shoe material has very good damping performance and the best grip in a humid environment, and the shoe material has higher wear resistance; the problem of traditional shoes wear resistance poor, consequently the antiskid effect is poor, receives the threat at the in-process security performance of use, has life weak point is solved.
2. The added precipitated silica can endow the shoe material with high Shore hardness, tensile strength, tear resistance and wear resistance; meanwhile, the rubber can be matched with added glycol to obtain the optimal rubber technical data.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Specific implementations of the present invention are described in detail below with reference to specific embodiments.
Example 1
Step one (mixing): 20 parts of styrene butadiene rubber, 80 parts of polyisoprene, 5 parts of zinc oxide, 10 parts of coumarone resin and 50 parts of precipitated silica are put into an internal mixer for mixing for 30 min;
step two (open mill): putting the mixed mixture into an open mill, then putting 3 parts of silane, 0.8 part of 2-mercaptobenzimidazole and 4 parts of glycol, and open milling for 30min at the temperature of 150 ℃;
step three (vulcanization): 2 parts of 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer, 1 part of tetramethylthiuram disulfide, 2 parts of stearic acid, 0.1 part of dibenzothiazyl disulfide and 2 parts of sulfur are added, and the mixture is vulcanized for 20min at the temperature of 150 ℃ and the pressure in the vulcanization process is 15MPa, so that the shoe material is obtained.
Example 2
Step one (mixing): putting 60 parts of styrene butadiene rubber, 40 parts of polyisoprene, 5 parts of zinc oxide, 10 parts of coumarone resin and 50 parts of precipitated silica into an internal mixer for mixing for 30 min;
step two (open mill): putting the mixed mixture into an open mill, then putting 3 parts of silane, 0.8 part of 2-mercaptobenzimidazole and 4 parts of glycol, and open milling for 30min at the temperature of 150 ℃;
step three: 2 parts of 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer, 1 part of tetramethylthiuram disulfide, 2 parts of stearic acid, 0.1 part of dibenzothiazyl disulfide and 2 parts of sulfur are added, and the mixture is vulcanized for 20min at the temperature of 150 ℃ and the pressure in the vulcanization process is 15MPa, so that the shoe material is obtained.
Example 3
Step one (mixing): 40 parts of styrene butadiene rubber, 60 parts of polyisoprene, 5 parts of zinc oxide, 10 parts of coumarone resin and 50 parts of precipitated silica are put into an internal mixer for mixing for 30 min;
step two (open mill): putting the mixed mixture into an open mill, then putting 3 parts of silane, 0.8 part of 2-mercaptobenzimidazole and 4 parts of glycol, and open milling for 30min at the temperature of 150 ℃;
step three (vulcanization): 2 parts of 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer, 1 part of tetramethylthiuram disulfide, 2 parts of stearic acid, 0.1 part of dibenzothiazyl disulfide and 2 parts of sulfur are added, and the mixture is vulcanized for 20min at the temperature of 150 ℃ and the pressure in the vulcanization process is 15MPa, so that the shoe material is obtained.
Example 4
Step one (mixing): 20 parts of styrene butadiene rubber, 80 parts of polyisoprene, 5 parts of zinc oxide, 10 parts of coumarone resin and 50 parts of precipitated silica are put into an internal mixer for mixing for 30 min;
step two (open mill): putting the mixed mixture into an open mill, then putting 3 parts of silane, 0.8 part of 2-mercaptobenzimidazole and 4 parts of glycol, and open milling for 30min at the temperature of 150 ℃;
step three (vulcanization): 2 parts of 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer, 1 part of tetramethylthiuram disulfide, 2 parts of stearic acid, 0.1 part of dibenzothiazyl disulfide and 2 parts of sulfur are added, and the mixture is vulcanized for 20min at the temperature of 150 ℃ and the pressure in the vulcanization process is 15MPa, so that the shoe material is obtained.
Example 5
In this example, the shoe materials obtained in examples 1 to 4 were tested in an experimental manner of preheating for 1 minute and testing for 4 minutes with a large rotor at 100 ℃, the mooney viscosities of the shoe materials obtained in five examples were respectively tested, and the test results were compared, and the test data are shown in the following table:
mooney viscosity can reflect the processability of rubber, and the molecular weight is high or low and the distribution range is wide or narrow: the rubber material with high Mooney viscosity is not easy to be mixed uniformly and extruded and processed, and has high molecular weight and wide distribution range; the rubber material with low Mooney viscosity is easy to stick to the roller, the molecular weight is low, the distribution range is narrow, and the tensile strength of the vulcanized product is low if the Mooney viscosity is too low; the larger the Mooney value, the larger the viscosity, and the lower the plasticity.
Example 6
In this example, the viscoelasticity of the shoe materials obtained in examples 1 to 4 was measured at 150 ℃ by a rheometer, and the measurement results were compared, and the measurement data are shown in the following table:
rheological properties are the dual properties of elasticity and viscosity, i.e., viscoelasticity, exhibited by a substance to external forces. Wherein, viscosity corresponds to the flow of the substance, and is related to the inherent property of the substance; when pressure is applied to an object, the shape and volume of each part inside the object are changed into elasticity.
Example 7
In this example, the physical properties of the shoe materials obtained in examples 1 to 4 were measured by vulcanizing the rubber at 150 ℃ for 20min, and the test results were compared, and the test data are shown in the following table:
example 8
In this example, the shoe materials obtained in examples 1 to 4 were tested for their highest wear resistance rating using a Dunlop portable side-slip tester at 22 ℃ on a rough glass plate surface and in a humid environment, and the test results are shown in the following table:
example 9
Properties of the selected raw materials in this exampleIllustratively, the polyisoprenes described in examples 1-4 were selected
3 company, adding polyisoprene into the raw material of the shoe material. The shoe material has very good damping performance and optimal grip in a wet environment, so that the shoe material has high wear resistance.
The 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer is used as a vulcanization anti-aging agent, has particularly excellent anti-thermal oxidation performance, and is suitable for an anti-aging agent which is commonly used in rubber products made of synthetic rubber.
The 2-mercaptobenzimidazole can be used as an antioxidant of natural rubber, diene synthetic rubber and latex, can also be used for polyethylene, has protective effects on oxygen, atmospheric aging, static aging and the like, and has good thermal-oxidative stability. Is easily dispersed in rubber.
The tetramethylthiuram disulfide is Rhenogran TMTD 80 in the model number, can be used as an overspeed vulcanization accelerator for natural rubber and synthetic rubber, and can reduce the consumption of vulcanizing agent sulfur or use low-content sulfur.
The dibenzothiazyl disulfide can be used as a universal accelerator for natural rubber, synthetic rubber and reclaimed rubber.
The reinforcing filler is precipitated silica, or Ultrasil VN 2 or
VN 3GR, a precipitated silica with very high reinforcement, imparts high Shore hardness, tensile strength, tear resistance and abrasion resistance to the rubber compound; in order to obtain the best rubber technical data, the rubber is reacted with added glycol; due to the high surface area, a vulcanizate of excellent transparency can be provided.
And a fluorescent whitening agent can be added, and the fluorescent whitening agent has excellent chlorine bleaching resistance, acid and alkali resistance and sunlight resistance, can improve the service performance of the product, and can improve the internal quality and the appearance quality of the product.
The test results of the examples 5 to 8 are combined, and the numerical values in the example 8 show that the shoe material obtained in the example 4 has the highest wear resistance, the polyisoprene added in the example 4 has the largest amount, but the shoe material obtained in the example 4 has the lowest plasticity from the examples 5 to 7, the numerical value in the example 4 can be selected when the shoe material mainly having the wear resistance is needed, and the numerical value in the example 3 can be selected to prepare the shoe material when the shoe material is required to have the plasticity and have the better wear resistance.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.
Claims (9)
1. The wear-resistant shoe material is characterized by comprising the following raw materials in parts by weight: 20-80 parts of styrene butadiene rubber, 20-80 parts of polyisoprene, 50-60 parts of reinforcing filler, 2-5 parts of silane, 8-20 parts of coumarone resin, 2-5 parts of vulcanization anti-aging agent, 0.5-1 part of antioxidant, 3-10 parts of zinc oxide, 2-5 parts of vulcanization accelerator, 3-5 parts of ethylene glycol, 0.1-0.3 part of rubber accelerator and 1-5 parts of sulfur.
2. The wear-resistant shoe material of claim 1, which comprises the following raw materials in parts by weight: 20 parts of styrene butadiene rubber, 80 parts of polyisoprene, 50 parts of reinforcing filler, 3 parts of silane, 10 parts of coumarone resin, 3 parts of vulcanization anti-aging agent, 0.8 part of antioxidant, 5 parts of zinc oxide, 2 parts of vulcanization accelerator, 4 parts of ethylene glycol, 1 part of rubber accelerator and 2 parts of sulfur.
3. A wear resistant footwear material in accordance with claim 1, wherein said reinforcing filler comprises precipitated silica.
4. The wear resistant footwear material of claim 1, wherein said vulcanization antioxidant comprises 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer and tetramethylthiuram disulfide.
5. The wear-resistant shoe material of claim 4, wherein the ratio of 2, 2, 4-trimethyl-1, 2-dihydroquinoline polymer to tetramethylthiuram disulfide is 2: 1.
6. The wear-resistant shoe material of claim 1, wherein the antioxidant is 2-mercaptobenzimidazole.
7. The wear-resistant shoe material of claim 1, wherein the vulcanization accelerator is stearic acid.
8. The wear-resistant shoe material of claim 1, wherein the rubber accelerator is dibenzothiazyl disulfide.
9. A method for manufacturing the wear-resistant shoe material according to any one of claims 1 to 8, comprising the steps of:
the method comprises the following steps: adding styrene butadiene rubber, polyisoprene, zinc oxide, coumarone resin and reinforcing filler into an internal mixer according to the parts by weight, and mixing for 20-30 min;
step two: putting the mixed mixture into an open mill, then adding silane, an antioxidant and ethylene glycol according to the parts, and open milling for 20-30min at the temperature of 130-;
step three: adding the vulcanization anti-aging agent, the vulcanization accelerator, the rubber accelerator and the sulfur according to the parts by weight, and continuously open-milling for 10-30min to obtain the shoe material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210131861.8A CN114456454A (en) | 2022-02-14 | 2022-02-14 | Wear-resistant shoe material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202210131861.8A CN114456454A (en) | 2022-02-14 | 2022-02-14 | Wear-resistant shoe material and preparation method thereof |
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| CN114456454A true CN114456454A (en) | 2022-05-10 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011160334A1 (en) * | 2010-06-25 | 2011-12-29 | Wan Xianneng | Environmental protection sole and manufacture method of body layer thereof |
| CN102504362A (en) * | 2011-11-30 | 2012-06-20 | 际华三五一四制革制鞋有限公司 | Sizing material for rubber shoe sole and preparation method thereof |
| CN105778172A (en) * | 2016-04-11 | 2016-07-20 | 泉州集友鞋业有限公司 | High-anti-slippery abrasion-resistant material for shoes and preparation method thereof |
| CN105860172A (en) * | 2016-05-25 | 2016-08-17 | 泉州集友鞋业有限公司 | Wear-resistant sole material and preparing method thereof |
| CN111533967A (en) * | 2020-06-16 | 2020-08-14 | 广东石油化工学院 | Rubber sole and preparation method thereof |
-
2022
- 2022-02-14 CN CN202210131861.8A patent/CN114456454A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011160334A1 (en) * | 2010-06-25 | 2011-12-29 | Wan Xianneng | Environmental protection sole and manufacture method of body layer thereof |
| CN102504362A (en) * | 2011-11-30 | 2012-06-20 | 际华三五一四制革制鞋有限公司 | Sizing material for rubber shoe sole and preparation method thereof |
| CN105778172A (en) * | 2016-04-11 | 2016-07-20 | 泉州集友鞋业有限公司 | High-anti-slippery abrasion-resistant material for shoes and preparation method thereof |
| CN105860172A (en) * | 2016-05-25 | 2016-08-17 | 泉州集友鞋业有限公司 | Wear-resistant sole material and preparing method thereof |
| CN111533967A (en) * | 2020-06-16 | 2020-08-14 | 广东石油化工学院 | Rubber sole and preparation method thereof |
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Application publication date: 20220510 |