CN105778172A - High-anti-slippery abrasion-resistant material for shoes and preparation method thereof - Google Patents
High-anti-slippery abrasion-resistant material for shoes and preparation method thereof Download PDFInfo
- Publication number
- CN105778172A CN105778172A CN201610216765.8A CN201610216765A CN105778172A CN 105778172 A CN105778172 A CN 105778172A CN 201610216765 A CN201610216765 A CN 201610216765A CN 105778172 A CN105778172 A CN 105778172A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber
- abrasive material
- footwear
- slip preventing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-anti-slippery abrasion-resistant material for shoes and a preparation method thereof.The high-anti-slippery abrasion-resistant material is prepared from, by weight, 20-40 parts of natural rubber, 20-40 parts of styrene-butadiene rubber, 20-40 parts of butadiene rubber, 15-25 parts of halogenated butyl rubber, 20-30 parts of nanometer calcium carbonate, 10-20 parts of rubber oil, 10-20 parts of white carbon black, 3-8 parts of an activator, 3-5 parts of silicon carbide, 2-4 parts of organic siloxane, 1-5 parts of an accelerant, 1-3 parts of an antiager, 1-3 parts of sulfur and 0.5-1.5 parts of stearic acid.The raw materials required by the prepared high-anti-slippery abrasion-resistant material for the shoes are low in price and easy to obtain, the preparation process is simple, the strength is high, the anti-slippery performance is good, the abrasion-resistant performance and processing performance are excellent, the friction coefficient is 1.4-1.6, the friction volume is 304-315/mm<3>, and the material can be used for production of high-anti-slippery abrasion-resistant shoe soles and other auxiliary materials.
Description
Technical field
The invention belongs to footwear field, especially relate to a kind of footwear high slip preventing high-abrasive material and preparation method thereof.
Background technology
Ordinary rubber material its on-slip (dryness) effect under normal conditions is mostly good, but indivedual industries then need higher anti-slip effect, needed for being satisfied with operation under severe operating conditions, such as it is used in the footware etc. that wet ground environment (submersible or kitchen) is dressed.High slip preventing footwear manufacturing process in the market is complicated, and material price is expensive, and its price is often tens times even tens times of common footwear, and suitable environment situation is comparatively limited to.
Present Research according to current footwear industry, weight at the bottom of the injection moulded shoes such as plate footwear, injection moulded shoes and hard, affect snugness of fit, the non-skid property at the bottom of the injection moulded shoes of common plastics is poor；From base rubber, main or use natural rubber is the making that material of main part carries out on-slip shoe body.Although natural rubber possesses good non-skid property and quality is soft, elastic splendid, but not wear-resisting.Chinese patent CN103483634 discloses a kind of Antiskid rubber shoe sole material, adds TDI modified Nano SiO2With other auxiliary agents, improve coefficient of friction, but due to SiO2Extra modified technique need to be carried out prepare, improve manufacture difficulty, therefore urgently a kind of high slip preventing wear-resistant rubber sole material.Halogenated butyl rubber has stronger viscosity because possessing halogen atom, and its strand internal resistance is big, makes to act on the fast of ground amplitude decay, applies to and have stronger earth-grasping force on material for sole of shoe.Adding the carborundum of certain proportioning, nano-calcium carbonate and organosiloxane in gum filler, carborundum can effectively change wearability and wet-sliding resistant performance, and nano-calcium carbonate can be effectively improved or regulate firm, toughness, fineness and the bending strength of material.Improve processing characteristics, improve the rheological property of material, dimensional stability, heat-resistant stability have filling and strengthen, toughness reinforcing effect, the expensive inserts of part and auxiliary agent can be replaced, reduce the consumption of rubber, thus reducing production cost, improving the market competitiveness, organosiloxane can the mechanical property of reinforcing material, also being good coupling agent, its addition can strengthen the switching performance of raw material and wearability and wet-sliding resistant performance are greatly improved.
Summary of the invention
It is an object of the invention to provide a kind of footwear high slip preventing high-abrasive material and preparation method thereof.The footwear high slip preventing high-abrasive material of preparation adopts natural rubber, nitrile rubber and halogenated butyl rubber to carry out composite, and add the carborundum of certain proportioning, nano-calcium carbonate and organosiloxane and other auxiliary agents are modified, can either strengthen, toughening rubber material, improve its anti-skid antiwear performance and also can replace the expensive inserts of part and auxiliary agent, reduce the consumption of rubber, thus reducing production cost, improve the market competitiveness.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of footwear high slip preventing high-abrasive material, counts by weight, and its raw material consists of:
Natural rubber 20 ~ 40 parts, 20 ~ 40 parts of butadiene-styrene rubber, butadiene rubber 20 ~ 40 parts, 15 ~ 25 parts of halogenated butyl rubbers, nano-calcium carbonate 20 ~ 30 parts, rubber oil 10 ~ 20 parts, white carbon 10 ~ 20 parts, 3 ~ 8 parts of activator, carborundum 3 ~ 5 parts, organosiloxane 2 ~ 4 parts, accelerator 1 ~ 5 part, 1 ~ 3 part of age resistor, 1 ~ 3 part of sulfur, stearic acid 0.5 ~ 1.5 part；Its preparation method specifically includes following steps:
(1) refining is opened: natural rubber, butadiene-styrene rubber, prepare feeding mill along rubber and halogenated butyl rubber by weight and carry out out refining, mill roll spacing 1mm, thin logical 10 times；
(2) banburying: the blend glue stuff after step (1) is opened refining puts into banbury banburying together with the activator prepared by weight, accelerator, age resistor, rubber oil, stearic acid, white carbon and nano-calcium carbonate, banbury temperature is 95-135 DEG C, discharge after banburying 3-7 minute；
(3) cooling: the epoxy glue that step (2) obtains is entered in appointment mould, cool down 20-26 hour；
(4) sulfuration: add sulfur, carborundum and organosiloxane in the material that step (3) has cooled down, sends into vulcanizer sulfuration, curing temperature 145 ~ 155 DEG C, 400 ~ 450 seconds time, board pressure 15 ~ 16Mpa.
Described halogenated butyl rubber is the one in chlorinated scoline, brombutyl and iodate butyl rubber three.
Described activator is the one in zinc oxide, zinc carbonate and titanium dioxide three.
Described accelerator is tetramethylthiuram monosulfide, dibenzothiazyl disulfide, N, N'-bis-cyclohexyls-2-[4-morpholinodithio sulfenamide and N, N ' one in-diphenylguanidine.
Described age resistor is the one in N-phenyl-1-naphthylamine, N-phenyl-N'-isopropyl p-phenylenediamine, 2-mercaptobenzimidazole and styrenated phenol.
Described organosiloxane is the one in organo-silicone peroxide coupling agent, alpha-functional group silane coupler, long chain alkyl silane coupling agent and dialkoxy silicane coupling agent.
The beneficial effects of the present invention is:
(1) halogenated butyl rubber has stronger viscosity because possessing halogen atom, and its strand internal resistance is big, makes to act on the fast of ground amplitude decay, applies to and have stronger earth-grasping force on material for sole of shoe；
(2) certain carborundum of proportioning, nano-calcium carbonate and organosiloxane can the mechanical property of reinforcing material, wearability and wet-sliding resistant performance are greatly improved, coefficient of friction is 1.2 ~ 1.5, and friction volume is 304 ~ 330/mm3。
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1:
First 30 parts of natural rubbers, 20 parts of butadiene-styrene rubber, 25 parts of butadiene rubbers and 25 weight portion brombutyls are sent into mill and carry out out refining, mill roll spacing 1mm, thin logical 10 times；After the blend glue stuff after opening refining and 8 part by weight of zinc oxide, 1 weight portion tetramethylthiuram monosulfide, 1 weight portion N-phenyl-1-naphthylamine, 15 parts by weight of rubber oil, 0.5 weight portion stearic acid, 13 weight portion white carbons and 27 weight portion nano-calcium carbonates are put into banbury banburying together, banbury temperature is 125 DEG C, discharge after banburying 4 minutes；Above-mentioned epoxy glue is entered in appointment mould, cool down 24 hours；Add 1 weight portion sulfur, 4.5 weight portion carborundums and 4 weight portion organo-silicone peroxide coupling agents after cooling is good, send into vulcanizer sulfuration, curing temperature 145 DEG C, 450 seconds time, board pressure 16Mpa.
Embodiment 2:
First 40 parts of natural rubbers, 25 parts of butadiene-styrene rubber, 20 parts of butadiene rubbers and 23 weight portion chlorinated scolines are carried out out refining by preparing feeding mill, mill roll spacing 1mm, thin logical 10 times；After the blend glue stuff after opening refining and 4 weight portion zinc carbonates, 3 weight portion dibenzothiazyl disulfides, 3 weight portion N-phenyl-N'-isopropyl p-phenylenediamine, 20 parts by weight of rubber oil, 1 weight portion stearic acid, 17 weight portion white carbons and 23 weight portion nano-calcium carbonates are put into banbury banburying together, banbury temperature is 110 DEG C, discharge after banburying 4 minutes；Above-mentioned epoxy glue is entered in appointment mould, cool down 24 hours；Add 2 weight portion sulfur, 3.5 weight portion carborundums and 3 weight portion alpha-functional group silane couplers after cooling is good, send into vulcanizer sulfuration, curing temperature 150 DEG C, 420 seconds time, board pressure 15.5Mpa.
Embodiment 3:
First 30 parts of natural rubbers, 40 parts of butadiene-styrene rubber, 25 parts of butadiene rubbers and 15 parts by weight of iodinated butyl rubbers are carried out out refining by preparing feeding mill, mill roll spacing 1mm, thin logical 10 times；After will open the blend glue stuff after refining and 3 weight portion titanium dioxides, 2 weight portion N, N'-bis-cyclohexyls-2-[4-morpholinodithio sulfenamide, 2 weight portion 2-mercaptobenzimidazoles, 15 parts by weight of rubber oil, 1.5 weight portion stearic acid, 20 weight portion white carbons and 20 weight portion nano-calcium carbonates put into banbury banburying together, banbury temperature is 100 DEG C, discharge after banburying 5 minutes；Above-mentioned epoxy glue is entered in appointment mould, cool down 24 hours；Add 2 weight portion sulfur, 3 weight portion carborundums and 2 weight portion long chain alkyl silane coupling agents after cooling is good, send into vulcanizer sulfuration, curing temperature 155 DEG C, 400 seconds time, board pressure 15Mpa.
Embodiment 4:
First 20 parts of natural rubbers, 30 parts of butadiene-styrene rubber, 40 parts of butadiene rubbers and 25 weight portion brombutyls are sent into mill and carry out out refining, mill roll spacing 1mm, thin logical 10 times；After will open the blend glue stuff after refining and 4 part by weight of zinc oxide, 5 weight portion N, N '-diphenylguanidine, 1 parts by weight of styrene phenol, 10 parts by weight of rubber oil, 1.2 weight portion stearic acid, 10 weight portion white carbons and 30 weight portion nano-calcium carbonates put into banbury banburying together, banbury temperature is 120 DEG C, discharge after banburying 5 minutes；Above-mentioned epoxy glue is entered in appointment mould, cool down 24 hours；Add 3 weight portion sulfur, 5 weight portion carborundums and 4 weight portion dialkoxy silicane coupling agents after cooling is good, send into vulcanizer sulfuration, curing temperature 150 DEG C, 420 seconds time, board pressure 16Mpa.
Performance test:
(1) coefficient of friction of elastomeric material that non-skid property test People's Republic of China (PRC) chemical industry standard HG/T2729-1995 testing example 1-4 and comparative example prepare, adopts Labthink Instruments Co., Ltd.'s MXD-01A friction coefficient instrument test sheet rubber kinematics and static friction coefficient under dry, wet condition.Sample length × wide × height is of a size of 63mm × 63mm × 2mm, and draw speed is 150mm/min, and test sliding distance is 140mm.Test and average for 5 times.
(2) the GX-5028-DIN abrasiometer that wear hardness test employing Gao Xin detecting instrument company limited produces is tested, wear test specimen is cylindric, its diameter is 16.0mm ± 0.2mm, it is highly 8mm, test wear stroke is that 40.0m ± 0.2m(is equivalent to 84r), take four measurements and average.Record result as shown in table 1
Table 1 above-described embodiment test result such as following table
Showing by testing, the indices of embodiment 1～4 is all far superior to the index of existing product.
The foregoing is only presently preferred embodiments of the present invention, all equalizations done according to the present patent application the scope of the claims change and modify, and all should belong to the covering scope of the present invention.
Claims (7)
1. a footwear high slip preventing high-abrasive material, it is characterised in that: counting by weight, the raw material of described footwear high slip preventing high-abrasive material consists of: natural rubber 20 ~ 40 parts; 20 ~ 40 parts of butadiene-styrene rubber, butadiene rubber 20 ~ 40 parts, halogenated butyl rubber 15 ~ 25 parts; nano-calcium carbonate 20 ~ 30 parts, rubber oil 10 ~ 20 parts, white carbon 10 ~ 20 parts; 3 ~ 8 parts of activator, carborundum 3 ~ 5 parts, organosiloxane 2 ~ 4 parts; accelerator 1 ~ 5 part; 1 ~ 3 part of age resistor, 1 ~ 3 part of sulfur, stearic acid 0.5 ~ 1.5 part.
2. footwear high slip preventing high-abrasive material according to claim 1, it is characterised in that: described halogenated butyl rubber is the one in chlorinated scoline, brombutyl and iodate butyl rubber three.
3. footwear high slip preventing high-abrasive material according to claim 1, it is characterised in that: described activator is the one in zinc oxide, zinc carbonate and titanium dioxide three.
4. footwear high slip preventing high-abrasive material according to claim 1, it is characterised in that: described accelerator is tetramethylthiuram monosulfide, dibenzothiazyl disulfide, N, N'-bis-cyclohexyls-2-[4-morpholinodithio sulfenamide and N, N ' one in-diphenylguanidine.
5. footwear high slip preventing high-abrasive material according to claim 1, it is characterised in that: described age resistor is the one in N-phenyl-1-naphthylamine, N-phenyl-N'-isopropyl p-phenylenediamine, 2-mercaptobenzimidazole and styrenated phenol.
6. footwear high slip preventing high-abrasive material according to claim 1, it is characterised in that: described organosiloxane is the one in organo-silicone peroxide coupling agent, alpha-functional group silane coupler, long chain alkyl silane coupling agent and dialkoxy silicane.
7. prepare footwear high slip preventing high-abrasive material as claimed in claim 1 for one kind, it is characterised in that: specifically include following steps:
(1) refining is opened: natural rubber, butadiene-styrene rubber, butadiene rubber and halogenated butyl rubber are prepared by weight feeding mill and carries out out refining, mill roll spacing 1mm, thin logical 10 times；
(2) banburying: the blend glue stuff after step (1) is opened refining puts into banbury banburying together with activator, accelerator, age resistor, rubber oil, stearic acid, white carbon and nano-calcium carbonate, and banbury temperature is 95-135 DEG C, 3-7 minute discharge of banburying；
(3) cooling: the epoxy glue that step (2) obtains is entered in appointment mould, cool down 20-26 hour；
(4) sulfuration: add sulfur, carborundum and organosiloxane in the material that step (3) has cooled down, sends into vulcanizer sulfuration, curing temperature 145 ~ 155 DEG C, 400 ~ 450 seconds time, board pressure 15 ~ 16Mpa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610216765.8A CN105778172B (en) | 2016-04-11 | 2016-04-11 | A kind of shoes high slip preventing wear-resistant material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610216765.8A CN105778172B (en) | 2016-04-11 | 2016-04-11 | A kind of shoes high slip preventing wear-resistant material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105778172A true CN105778172A (en) | 2016-07-20 |
| CN105778172B CN105778172B (en) | 2018-08-31 |
Family
ID=56396080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610216765.8A Active CN105778172B (en) | 2016-04-11 | 2016-04-11 | A kind of shoes high slip preventing wear-resistant material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105778172B (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107216503A (en) * | 2017-07-21 | 2017-09-29 | 肇庆骏鸿实业有限公司 | A kind of tread rubber of environment-friendly type four seasons tire |
| CN107337816A (en) * | 2017-07-29 | 2017-11-10 | 合肥梵清电子商务有限公司 | A kind of sole of insulation and preparation method thereof |
| CN107417998A (en) * | 2017-04-28 | 2017-12-01 | 黎明职业大学 | A kind of modification bamboo charcoal fiber rubber composite sole material and preparation method, application |
| CN107629341A (en) * | 2017-10-20 | 2018-01-26 | 诚展（清远）鞋业有限公司 | A kind of low bullet Antiskid rubber and preparation method thereof |
| CN107759859A (en) * | 2017-10-18 | 2018-03-06 | 诚展（清远）鞋业有限公司 | A kind of wear-resisting Antiskid rubber and preparation method thereof |
| CN109134959A (en) * | 2018-08-06 | 2019-01-04 | 广州维桢化工科技有限公司 | A kind of foaming sole material and preparation method thereof |
| CN109456515A (en) * | 2018-11-19 | 2019-03-12 | 陶伟珍 | A kind of wearability sole rubber material and preparation method thereof |
| CN109912898A (en) * | 2019-04-02 | 2019-06-21 | 晋江市鑫铭鞋材科技有限公司 | A kind of dry and wet ground Anti-skidding rubber sole formula and its manufacture craft |
| CN110144066A (en) * | 2019-05-29 | 2019-08-20 | 李宁（中国）体育用品有限公司 | A kind of water swelling rubber and preparation method thereof, sole and shoes |
| CN110643084A (en) * | 2019-10-22 | 2020-01-03 | 温州职业技术学院 | Enhancement mode antiskid sole and antiskid shoes |
| CN110698733A (en) * | 2019-10-14 | 2020-01-17 | 福建五持恒科技发展有限公司 | Graphene natural rubber polymer ice top-slip mixed foam material and preparation method thereof |
| CN111171401A (en) * | 2018-11-12 | 2020-05-19 | 固特异轮胎和橡胶公司 | Footwear and rubber sole comprising dual silica portions |
| CN112480560A (en) * | 2020-10-29 | 2021-03-12 | 晋江康凯鞋材有限公司 | High-strength sole material and preparation method thereof |
| CN114456454A (en) * | 2022-02-14 | 2022-05-10 | 上海汇平化工有限公司 | Wear-resistant shoe material and preparation method thereof |
| CN114702737A (en) * | 2022-04-12 | 2022-07-05 | 达州市嘉源体育用品有限公司 | Wear-resistant shoe outsole and preparation method thereof |
| CN115028930A (en) * | 2021-03-06 | 2022-09-09 | 福建中宏新材料科技有限公司 | Process for producing wear-resistant high-elasticity chlorinated butyl reclaimed rubber |
| CN110144066B (en) * | 2019-05-29 | 2024-05-10 | 李宁（中国）体育用品有限公司 | Water-absorbing expansion rubber and preparation method thereof, sole and shoe |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
| CN103483634A (en) * | 2013-10-11 | 2014-01-01 | 昆山纯柏精密五金有限公司 | Antiskid rubber shoe sole material |
| CN104277274A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Oil-proof antiskid rubber sole and preparation method thereof |
-
2016
- 2016-04-11 CN CN201610216765.8A patent/CN105778172B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN103483634A (en) * | 2013-10-11 | 2014-01-01 | 昆山纯柏精密五金有限公司 | Antiskid rubber shoe sole material |
| CN104277274A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Oil-proof antiskid rubber sole and preparation method thereof |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107417998A (en) * | 2017-04-28 | 2017-12-01 | 黎明职业大学 | A kind of modification bamboo charcoal fiber rubber composite sole material and preparation method, application |
| CN107216503A (en) * | 2017-07-21 | 2017-09-29 | 肇庆骏鸿实业有限公司 | A kind of tread rubber of environment-friendly type four seasons tire |
| CN107216503B (en) * | 2017-07-21 | 2018-04-03 | 肇庆骏鸿实业有限公司 | A kind of tread rubber of environment-friendly type four seasons tire |
| CN107337816A (en) * | 2017-07-29 | 2017-11-10 | 合肥梵清电子商务有限公司 | A kind of sole of insulation and preparation method thereof |
| CN107759859A (en) * | 2017-10-18 | 2018-03-06 | 诚展（清远）鞋业有限公司 | A kind of wear-resisting Antiskid rubber and preparation method thereof |
| CN107629341A (en) * | 2017-10-20 | 2018-01-26 | 诚展（清远）鞋业有限公司 | A kind of low bullet Antiskid rubber and preparation method thereof |
| CN109134959A (en) * | 2018-08-06 | 2019-01-04 | 广州维桢化工科技有限公司 | A kind of foaming sole material and preparation method thereof |
| US11547174B2 (en) | 2018-11-12 | 2023-01-10 | The Goodyear Tire & Rubber Company | Footwear and rubber sole containing dual silica moieties |
| CN111171401A (en) * | 2018-11-12 | 2020-05-19 | 固特异轮胎和橡胶公司 | Footwear and rubber sole comprising dual silica portions |
| CN109456515A (en) * | 2018-11-19 | 2019-03-12 | 陶伟珍 | A kind of wearability sole rubber material and preparation method thereof |
| CN109912898A (en) * | 2019-04-02 | 2019-06-21 | 晋江市鑫铭鞋材科技有限公司 | A kind of dry and wet ground Anti-skidding rubber sole formula and its manufacture craft |
| CN110144066A (en) * | 2019-05-29 | 2019-08-20 | 李宁（中国）体育用品有限公司 | A kind of water swelling rubber and preparation method thereof, sole and shoes |
| CN110144066B (en) * | 2019-05-29 | 2024-05-10 | 李宁（中国）体育用品有限公司 | Water-absorbing expansion rubber and preparation method thereof, sole and shoe |
| CN110698733A (en) * | 2019-10-14 | 2020-01-17 | 福建五持恒科技发展有限公司 | Graphene natural rubber polymer ice top-slip mixed foam material and preparation method thereof |
| CN110698733B (en) * | 2019-10-14 | 2021-10-01 | 福建五持恒科技发展有限公司 | Graphene natural rubber polymer ice top-slip mixed foam material and preparation method thereof |
| CN110643084A (en) * | 2019-10-22 | 2020-01-03 | 温州职业技术学院 | Enhancement mode antiskid sole and antiskid shoes |
| CN112480560A (en) * | 2020-10-29 | 2021-03-12 | 晋江康凯鞋材有限公司 | High-strength sole material and preparation method thereof |
| CN115028930A (en) * | 2021-03-06 | 2022-09-09 | 福建中宏新材料科技有限公司 | Process for producing wear-resistant high-elasticity chlorinated butyl reclaimed rubber |
| CN114456454A (en) * | 2022-02-14 | 2022-05-10 | 上海汇平化工有限公司 | Wear-resistant shoe material and preparation method thereof |
| CN114702737A (en) * | 2022-04-12 | 2022-07-05 | 达州市嘉源体育用品有限公司 | Wear-resistant shoe outsole and preparation method thereof |
| CN114702737B (en) * | 2022-04-12 | 2023-10-31 | 达州市嘉源体育用品有限公司 | Wear-resistant shoe outsole and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105778172B (en) | 2018-08-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105778172A (en) | High-anti-slippery abrasion-resistant material for shoes and preparation method thereof | |
| CN106459516B (en) | Rubber composition for tire tread | |
| US9150712B2 (en) | Rubber composition for tire tread | |
| US9969865B2 (en) | Rubber composition for tire | |
| NO319094B1 (en) | Pneumatic tire for use on ice | |
| CN101649073A (en) | Rubber material with damping capacity | |
| CN105694149B (en) | A kind of sole oil resistant low-temperature resistance material and preparation method thereof | |
| US20150259515A1 (en) | Rubber Composition for Use in Tire Treads | |
| JP2004217817A (en) | Rubber composition and pneumatic tire using the same | |
| JP2013185091A (en) | Rubber composition for tire tread | |
| CN103483677A (en) | Wear resistant sole material | |
| TW201904754A (en) | Tread Rubbers and Formulations for Producing Tread Rubbers | |
| CN105175807A (en) | High-abrasion-resistance antistatic shoe sole rubber material and preparation method thereof | |
| CN104151650A (en) | Rubber composition containing modified rubber | |
| CN106832447A (en) | The material for sole of shoe and preparation method of a kind of anti-skid wearable sport footwear | |
| JP2016030789A (en) | Pneumatic tire | |
| CN117222703A (en) | Rubber composition for tire | |
| JP5992747B2 (en) | High performance tire tread rubber composition and high performance tire | |
| JP2017082130A (en) | Rubber composition for tire | |
| JP6701671B2 (en) | Rubber composition for tires | |
| CN110157057B (en) | High-tensile high-modulus anti-slip rubber sports shoe material and manufacturing method thereof | |
| KR102622060B1 (en) | A rubber composition for shoe outsole with excellent abrasion resistance and slip resistance | |
| CN107337816A (en) | A kind of sole of insulation and preparation method thereof | |
| JP2014080549A (en) | Rubber composition for tread of motocross tire, and motocross tire | |
| KR100879138B1 (en) | Rubber composition for tire innerliner |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |