CN107629341A - A kind of low bullet Antiskid rubber and preparation method thereof - Google Patents
A kind of low bullet Antiskid rubber and preparation method thereof Download PDFInfo
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- CN107629341A CN107629341A CN201710984546.9A CN201710984546A CN107629341A CN 107629341 A CN107629341 A CN 107629341A CN 201710984546 A CN201710984546 A CN 201710984546A CN 107629341 A CN107629341 A CN 107629341A
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Abstract
The invention belongs to rubber soles Material Field, is specifically a kind of low bullet Antiskid rubber, including following parts by weight of component：The main parts by weight of glue 100；The parts by weight of coupling agent 24；The parts by weight of softening oil 5 10；The parts by weight of white carbon 50 65；The parts by weight of zinc oxide 35；The parts by weight of stearic acid 12；The parts by weight of microwax 0.5 1；The parts by weight of uniform resin 5 10；And appropriate age resistor, activating agent, accelerator and sulphur；Described main glue by the natural gum of 10 15 parts by weight, the brombutyl of 45 65 parts by weight, the butadiene-styrene rubber of 5 15 parts by weight, 15 25 parts by weight butadiene rubber, advantages of the present invention is flexible ultralow for its, the characteristics of on-slip ability is excellent, climbing rocks, mountain-climbing, wait had a extensive future in outdoor exercises on foot；The invention also discloses the preparation method of the elastomeric material simultaneously.
Description
Technical field
The present invention relates to rubber soles Material Field, particularly a kind of low bullet Antiskid rubber and preparation method thereof.
Background technology
With the improvement of living standards, people increasingly focus on for the feature of shoes, the occasion used also there is no
Very strict differentiation, sports events, the common rubber such as be possibly used for climbing the mountain with a pair of shoes, play basketball, running can only meet
In on-slip or it is wear-resisting among one, and can not have the function of wear-resisting on-slip simultaneously.
CN201510351548.5 discloses a kind of cold-resistant Antiskid rubber motion footwear material, the cold-resistant Antiskid rubber sport footwear
The raw material composition of material, which includes component A and component B, the component A, includes following raw material：Butadiene rubber, natural rubber, brominated butyl
Rubber, butadiene-styrene rubber, white carbon, naphthenic oil, stearic acid, zinc oxide, the first age resistor, the second age resistor, microwax, white cigarette are lived
Property agent, silane coupler, rosin resin；The component B includes following raw material：Insoluble sulfur, the first accelerator and second promote
Enter agent.Butadiene rubber 25%~35%, natural rubber 10%~20%, brombutyl 10%~15%, butadiene-styrene rubber 3%
~6%, white carbon 18%~25%, naphthenic oil 4%~6%, stearic acid 0.3%~0.5%, zinc oxide 3%~5%, first
Age resistor 0.4%~0.6%, the second age resistor 0.6%~1.0%, microwax 0.3%~0.5%, white smoke active agent 1.8%
~2.5%, silane coupler 1.2%~2%, rosin resin 0.3%~0.6%；Its effect is that dry type on-slip coefficient is 1
Left and right, wet type on-slip coefficient are 0.5 or so.
CN 201610216765.8 discloses a kind of footwear high slip preventing high-abrasive material and preparation method thereof, in parts by weight
Meter, its raw material composition are：20~40 parts of natural rubber, 20~40 parts of butadiene-styrene rubber, 20~40 parts of butadiene rubber, butyl rubber bromide
15~25 parts of glue, 20~30 parts of nano-calcium carbonate, 10~20 parts of rubber oil, 10~20 parts of white carbon, 3~8 parts of activator, carbonization
3~5 parts of silicon, 2~4 parts of organosiloxane, 1~5 part of accelerator, 1~3 part of age resistor, 1~3 part of sulphur, stearic acid 0.5~1.5
Part.It can not accomplish wear-resisting and low elasticity unified raising.
The content of the invention
It is an object of the invention to provide a kind of low bullet Antiskid rubber and preparation method thereof.
To achieve these goals, the solution of the present invention is as follows：A kind of low bullet Antiskid rubber, including following parts by weight group
Point：
The main parts by weight of glue 100；
Coupling agent 2-4 parts by weight；
Softening oil 5-10 parts by weight；
White carbon 50-65 parts by weight；
Zinc oxide 3-5 parts by weight；
Stearic acid 1-2 parts by weight；
Microwax 0.5-1 parts by weight；
Uniform resin 5-10 parts by weight；
And appropriate age resistor, activating agent, accelerator and sulphur；
Described main glue is by the natural gum of 10-15 parts by weight, the brombutyl of 45-65 parts by weight, 5-15 parts by weight
Butadiene-styrene rubber, the butadiene rubber of 15-25 parts by weight.
In above-mentioned low bullet Antiskid rubber, described coupling agent is 3- thiocyanatopropyltriethoxysilanes, 3- mercaptos third
One or more in ethyl triethoxy silicane alkane, vinyl three (2- methoxy ethoxies) silane.
In above-mentioned low bullet Antiskid rubber, described age resistor is 1-3 parts by weight；It is 2,6- di-t-butyls to methyl
One or more combinations in phenol, age resistor CPL, age resistor 1076.
In above-mentioned low bullet Antiskid rubber, described activating agent is 3-5 parts by weight；It is activating agent polyethylene glycol, work
Property agent KETTLITZ AKTIOL, activating agent R1987 in one or more combinations.
In above-mentioned low bullet Antiskid rubber, dibenzothiazyl disulfide, 0.5- of the described accelerator by 1-3 parts by weight
The 2- benzothiazolyl mercaptans of 1 parts by weight, the tetra-benzyl thiram disulfide composition of 0.1-0.5 parts by weight.
In above-mentioned low bullet Antiskid rubber, described sulphur is 2-3 parts by weight, is insoluble sulfur.
Meanwhile the invention also discloses a kind of low preparation method for playing Antiskid rubber as described above, sulphur will be removed, promoted
Then other raw materials outside agent add sulphur and accelerator carry out mixing and is well mixed material, Ran Houjing by mixing, mill
Sulfidization molding produces.
In the preparation method of above-mentioned low bullet Antiskid rubber rubber, described mixing temperature is no more than 80 DEG C.
In the preparation method of above-mentioned low bullet Antiskid rubber rubber, during sulfidization molding, mold temperature is 155 ± 2
℃。
Beneficial effect：
What the present invention was made up of by a certain percentage various special high molecular polymers and some industrial chemicals, and pass through ten thousand horses
Power high-temperature mixing, a kind of high molecular polymer rubber obtained by the manufacturing process such as the calendering of cryogenic freezing board and normal temperature maturation are big
Bottom, it is provided simultaneously with the characteristics of elasticity is ultralow, and on-slip ability is excellent.
Embodiment
Embodiment 1-3
The present embodiment 1-3 low bullet Antiskid rubber preparation process is as follows：
1. ten thousand horsepowers of machines operate (material composition A automatic mixings program)
1.1 first open dust catcher, can just be put into sizing material and resin is kneaded 40 "
1.2 pour into 2/3 white cigarette amount and oils, can just be pressed into hammer and be kneaded 60 "
1.3 are all put into 1/3 white cigarette and medicine class, after hammer press-in is kneaded into 50 ", are cleaned
1.4 be kneaded OK after just can discharging, discharge temp control below 130 DEG C
2. mill operates slice:
2.1 will carry out unloading piece one-stop operation from the sizing material that ten thousand horsepowers of machines unload, and be turned on upender
Expect operation 2 minutes, then coiled strip slice is subcooled, and sizing material temperature control, can below 40 DEG C
Sizing material is put into storeroom maturation, minimum more than 8 hours of maturation time, can be used
2.2 mills may not exceed 80 DEG C of
3. mill adds sulphur：
3.1st, mill power switch is opened, allows machine to dally 1 minute, whether the operating that minds the machine is normal；Check brakes system
Whether system is sensitive
3.2nd, during refining glue by roller spacing adjustment between 6-8MM, after sizing material beat it is soft after addition coloring agent, sulphur, accelerator, enter
Unloading piece one-stop operation is carried out, stirring operation 8 minutes is then carried out on upender, coiled strip after being kneaded uniformly, by required thickness
Spend slabbing.
3.3 are cut into required shape with cut-off knife.
4. vulcanization：
4.1 mold temperature:155+2℃
4.2 oil pressure:150kg/cm2-160kg/cm2
4.3 molding time：300 seconds
4.4 add sulphur by setting time, and sulphur to be added finishes, and open mould and take out footwear material, produce footwear material sample.
Embodiment 1-3 formula table such as table 1 below
The embodiment 1-3 of table 1 formula table
Embodiment 1-3 coupling agent is respectively 3- thiocyanatopropyltriethoxysilanes (embodiment 1), the second of 3- mercaptos propyl group three
TMOS (embodiment 2), vinyl three (2- methoxy ethoxies) silane (embodiment 3)；Embodiment 1-3 age resistor difference
For 2,6- di-tert-butyl methyl phenols (embodiment 1), age resistor CPL (embodiment 2), age resistor 1076 (embodiment 3)；Implement
Example 1-3 activating agent is polyethylene glycol (embodiment 1), activating agent KETTLITZ AKTIOL (embodiment 2), activating agent R1987
(embodiment 3).
Embodiment 1-3 the performance test results such as table 2 below：
The embodiment 1-3 of table 2 the performance test results
Embodiments of the invention 1-3 is to pass through high-temperature mixing by a series of high-molecular compounds, various resins and oils, is made
A kind of while elastic ultralow, the excellent rubber of on-slip ability obtained by various physical and chemical reactions occurs in it, and this rubber should
For sole, by with lower rebound effect, climbing rocks, climbing the mountain, waiting being had a extensive future in outdoor exercises on foot.Develop
Product not only there are a variety of color matchings, while accomplish that dnockout is more environmentally friendly, reduce energy consumption, beneficial to enterprise employee health.It is formulated by adjusting
Ratio, makes that the anti-wear performance of product is more preferable, and service life is longer.
Above-described is only presently preferred embodiments of the present invention, all timess made in the range of the spirit and principles in the present invention
What modifications, equivalent substitutions and improvements etc., should be included in the scope of the protection.
Claims (9)
1. a kind of low bullet Antiskid rubber, it is characterised in that including following parts by weight of component：
The main parts by weight of glue 100；
Coupling agent 2-4 parts by weight；
Softening oil 5-10 parts by weight；
White carbon 50-65 parts by weight；
Zinc oxide 3-5 parts by weight；
Stearic acid 1-2 parts by weight；
Microwax 0.5-1 parts by weight；
Uniform resin 5-10 parts by weight；
And appropriate age resistor, activating agent, accelerator and sulphur；
Described main glue by the natural gum of 10-15 parts by weight, the brombutyl of 45-65 parts by weight, 5-15 parts by weight fourth
The butadiene rubber of benzene rubber, 15-25 parts by weight.
2. low bullet Antiskid rubber according to claim 1, it is characterised in that described coupling agent is 3- thiocyanogens propyl group three
One or more in Ethoxysilane, 3- mercaptopropyltriethoxysilanes, vinyl three (2- methoxy ethoxies) silane.
3. low bullet Antiskid rubber according to claim 1, it is characterised in that described age resistor is 1-3 parts by weight；It is
One or more combinations in 2,6- di-tert-butyl methyl phenols, age resistor CPL, age resistor 1076.
4. low bullet Antiskid rubber according to claim 1, it is characterised in that described activating agent is 3-5 parts by weight；It is
One or more combinations in activating agent polyethylene glycol, activating agent KETTLITZ AKTIOL, activating agent R1987.
5. low bullet Antiskid rubber according to claim 1, it is characterised in that described accelerator is by the two of 1-3 parts by weight
Dibenzothiazyl disulfide, the 2- benzothiazolyl mercaptans of 0.5-1 parts by weight, the curing tetrabenzyl autumn of 0.1-0.5 parts by weight are blue
Nurse forms.
6. low bullet Antiskid rubber according to claim 1, it is characterised in that described sulphur is 2-3 parts by weight, is insoluble
Property sulphur.
A kind of 7. preparation method of low bullet Antiskid rubber as described in claim 1-6 is any, it is characterised in that will remove sulphur,
Then other raw materials outside accelerator add sulphur and accelerator carry out mixing and is well mixed material, so by mixing, mill
Produced by sulfidization molding.
8. the low preparation method for playing Antiskid rubber rubber according to claim 7, it is characterised in that described mixing temperature
No more than 80 DEG C.
9. the low preparation method for playing Antiskid rubber according to claim 8, it is characterised in that during sulfidization molding, mould
It is 155 ± 2 DEG C to have temperature.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710984546.9A CN107629341A (en) | 2017-10-20 | 2017-10-20 | A kind of low bullet Antiskid rubber and preparation method thereof |
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| CN201710984546.9A CN107629341A (en) | 2017-10-20 | 2017-10-20 | A kind of low bullet Antiskid rubber and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329538A (en) * | 2018-02-08 | 2018-07-27 | 浙江中瑞橡胶高分子材料股份有限公司 | A kind of formula and preparation method thereof of new type rubber rubber overshoes sole |
| CN108485086A (en) * | 2018-04-11 | 2018-09-04 | 东莞市福斯特橡塑科技有限公司 | A kind of isobutyl group and the compound rubber sole on-slip agent prescription and preparation method thereof of halobutyl |
| CN109401089A (en) * | 2018-11-20 | 2019-03-01 | 中策橡胶集团有限公司 | A kind of rubber composition and its tire for low smell tire |
| CN111040264A (en) * | 2019-12-24 | 2020-04-21 | 柯祥 | Wear-resistant anti-slip rubber for shoe sole and preparation method thereof |
| CN111560143A (en) * | 2020-05-21 | 2020-08-21 | 杭州巨星科技股份有限公司 | Low-rebound rubber material and rubber hammer made of same |
| CN112300502A (en) * | 2020-10-09 | 2021-02-02 | 莆田星昌鞋业有限公司 | Anti-slip sole, preparation method and anti-slip sports shoes |
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| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN102964645A (en) * | 2012-11-29 | 2013-03-13 | 泰亚鞋业股份有限公司 | Ice surface anti-slip rubber sports shoe soles and manufacturing method thereof |
| CN104893027A (en) * | 2015-06-24 | 2015-09-09 | 厦门迈图新材料有限公司 | Cold-resistant non-slip rubber sports shoe material and manufacturing method thereof |
| CN105778172A (en) * | 2016-04-11 | 2016-07-20 | 泉州集友鞋业有限公司 | High-anti-slippery abrasion-resistant material for shoes and preparation method thereof |
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2017
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN102964645A (en) * | 2012-11-29 | 2013-03-13 | 泰亚鞋业股份有限公司 | Ice surface anti-slip rubber sports shoe soles and manufacturing method thereof |
| CN104893027A (en) * | 2015-06-24 | 2015-09-09 | 厦门迈图新材料有限公司 | Cold-resistant non-slip rubber sports shoe material and manufacturing method thereof |
| CN105778172A (en) * | 2016-04-11 | 2016-07-20 | 泉州集友鞋业有限公司 | High-anti-slippery abrasion-resistant material for shoes and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329538A (en) * | 2018-02-08 | 2018-07-27 | 浙江中瑞橡胶高分子材料股份有限公司 | A kind of formula and preparation method thereof of new type rubber rubber overshoes sole |
| CN108329538B (en) * | 2018-02-08 | 2020-10-16 | 浙江中瑞橡胶高分子材料股份有限公司 | Rubber shoe sole |
| CN108485086A (en) * | 2018-04-11 | 2018-09-04 | 东莞市福斯特橡塑科技有限公司 | A kind of isobutyl group and the compound rubber sole on-slip agent prescription and preparation method thereof of halobutyl |
| CN109401089A (en) * | 2018-11-20 | 2019-03-01 | 中策橡胶集团有限公司 | A kind of rubber composition and its tire for low smell tire |
| CN109401089B (en) * | 2018-11-20 | 2021-02-02 | 中策橡胶集团有限公司 | Rubber composition for low-odor tire and tire thereof |
| CN111040264A (en) * | 2019-12-24 | 2020-04-21 | 柯祥 | Wear-resistant anti-slip rubber for shoe sole and preparation method thereof |
| CN111560143A (en) * | 2020-05-21 | 2020-08-21 | 杭州巨星科技股份有限公司 | Low-rebound rubber material and rubber hammer made of same |
| CN112300502A (en) * | 2020-10-09 | 2021-02-02 | 莆田星昌鞋业有限公司 | Anti-slip sole, preparation method and anti-slip sports shoes |
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