CN114454100A - Preparation method of metal-based diamond abrasive belt - Google Patents

Preparation method of metal-based diamond abrasive belt Download PDF

Info

Publication number
CN114454100A
CN114454100A CN202111596430.0A CN202111596430A CN114454100A CN 114454100 A CN114454100 A CN 114454100A CN 202111596430 A CN202111596430 A CN 202111596430A CN 114454100 A CN114454100 A CN 114454100A
Authority
CN
China
Prior art keywords
metal
diamond
abrasive belt
diamond abrasive
metal matrix
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111596430.0A
Other languages
Chinese (zh)
Inventor
黎宙瑛
罗进
张洪涛
罗超洪
黎骥
易敏
雷杜康
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUBEI YULI ABRASIVE BELTS GROUP CO Ltd
Original Assignee
HUBEI YULI ABRASIVE BELTS GROUP CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUBEI YULI ABRASIVE BELTS GROUP CO Ltd filed Critical HUBEI YULI ABRASIVE BELTS GROUP CO Ltd
Priority to CN202111596430.0A priority Critical patent/CN114454100A/en
Publication of CN114454100A publication Critical patent/CN114454100A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • B24D11/001Manufacture of flexible abrasive materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • B24D11/02Backings, e.g. foils, webs, mesh fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0054Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for by impressing abrasive powder in a matrix
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0072Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using adhesives for bonding abrasive particles or grinding elements to a support, e.g. by gluing
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/134Plasma spraying

Abstract

The invention provides a preparation method of a metal-based diamond abrasive belt, which comprises the following steps: 1) polishing the surface of a metal matrix, washing with alkali to remove oil, washing with distilled water, and drying for later use; 2) pre-plating a metal titanium layer on the surface of the diamond abrasive; 3) uniformly mixing the pretreated diamond abrasive with the low-melting-point metal-based brazing material to obtain a mixture; 4) and (3) loading the mixture into a spray gun of plasma spraying equipment, spraying the mixture on the surface of the metal matrix by adopting a plasma spraying process in an argon environment, cooling and rolling. The abrasive belt adopts the metal brazing material as the binder, the mixture is uniformly sprayed on the metal matrix through an argon plasma spraying process, so that the diamond abrasive is firmly combined on the metal matrix, the problem that the existing abrasive is easy to fall off is effectively avoided, and the diamond abrasive is combined with the metal matrix through a plasma spraying mode, so that the cutting height of the diamond abrasive is improved, and the sharpness and the grinding efficiency of the abrasive belt are improved.

Description

Preparation method of metal-based diamond abrasive belt
Technical Field
The invention belongs to the technical field of industrial grinding, and particularly relates to a preparation method of a metal-based diamond abrasive belt.
Background
The conventional abrasive belt is a belt-like tool made of a flexible material such as paper, cloth, polyester film, etc. and bonded with an abrasive by a binder, and is a main form of a coated abrasive. The conventional abrasive belt for the abrasive belt is common abrasive materials such as aluminum oxide, silicon carbide and the like, the application of the common abrasive belt is very wide, but the abrasive material is easy to fall off and short in service life, the abrasive belt needs to be frequently replaced, the grinding processing efficiency is seriously influenced, and the strength and the grinding sharpness of the conventional abrasive belt are not high.
Disclosure of Invention
The invention aims to provide a preparation method of a metal-based diamond abrasive belt, which can at least solve part of defects in the prior art.
In order to realize the purpose, the invention adopts the following scheme:
a preparation method of a metal-based diamond abrasive belt comprises the following steps:
1) pretreatment of the metal substrate: polishing the surface of the metal matrix, removing oil by alkali washing, cleaning by distilled water, and drying for later use;
2) pretreatment of the diamond grinding material: pre-plating a metal titanium layer on the surface of the diamond grinding material, cleaning the titanium-plated diamond grinding material in acetone, removing surface impurities, and drying for later use;
3) uniformly mixing the diamond abrasive pretreated in the step 2) with the low-melting-point metal-based brazing material to obtain a mixture;
4) loading the mixture obtained in the step 3) into a spray gun of plasma spraying equipment, and spraying the mixture on the surface of the metal matrix treated in the step 1) by adopting a plasma spraying process in an argon environment; and cooling and rolling to obtain the metal-based diamond abrasive belt.
Furthermore, the metal substrate is a copper strip with the thickness of 0.3-0.5 mm.
Further, the alkali washing specific process in the step 1): preparing a sodium hydroxide solution with the concentration of 5 wt%, placing the sodium hydroxide solution into an ultrasonic cleaner tank, keeping the temperature at 55-65 ℃, and then placing the metal substrate into the ultrasonic cleaner tank for cleaning.
Further, the granularity of the diamond abrasive is 45-240 meshes.
Further, the diamond abrasive is a mixture of at least two abrasives with different particle sizes.
Further, the metal-based brazing material in the step 3) is copper-based brazing material, and the mass ratio of the diamond abrasive to the metal-based brazing material is 1 (0.5-1).
Further, the plasma spraying process conditions in the step 4) are as follows: the spraying temperature is 700-900 ℃, the spraying operation speed is 2-5 m/min, the height of the spray head is 800 mm, and the argon flow is 0.3-0.5L/min.
Further, the thickness of the plasma spraying mixture in the step 4) is 30-150 micrometers.
Further, the preparation method of the metal-based diamond abrasive belt further comprises the step 5) of cutting the metal-based diamond abrasive belt into designed length and width, and converting the cut metal-based diamond abrasive belt into an endless belt in a laser welding joint mode.
Compared with the prior art, the invention has the beneficial effects that:
(1) the preparation method of the metal-based diamond abrasive belt provided by the invention adopts the metal brazing material with low melting point as the binder, mixes the diamond grinding material and the metal brazing material, and uniformly sprays the mixture onto the metal matrix through the argon plasma spraying process, so that the diamond grinding material is firmly combined on the metal matrix, the problem that the existing grinding material is easy to fall off is effectively avoided, and the diamond grinding material is combined with the metal matrix through the plasma spraying mode, so that the cutting height of the diamond grinding material can be improved, and the sharpness and the grinding efficiency of the abrasive belt are improved.
(2) The preparation method of the metal-based diamond abrasive belt provided by the invention adopts the copper belt as the base body of the abrasive belt, has good flexibility and small elongation, has higher strength than the traditional base bodies such as cloth, paper, polyester film and the like, improves the overall strength of the abrasive belt and prolongs the service life of the abrasive belt.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The embodiment provides a preparation method of a metal-based diamond abrasive belt, which comprises the following steps:
(1) pretreatment of the metal substrate: and (3) grinding and polishing the surface of the metal matrix, and cleaning with alkali to remove oil, distilled water and drying for later use.
Specifically, the metal substrate in the embodiment adopts a copper belt with the thickness of 0.3-0.5 mm, the copper belt has good electric conductivity, heat conductivity, corrosion resistance and processability, the copper belt has good flexibility, small elongation, smooth surface and convenient bending processing, the strength of the copper belt is higher than that of the substrates such as cloth, paper, polyester film and the like used for the traditional abrasive belt, and the overall strength and the service life of the abrasive belt are improved.
The surface of the red copper belt is polished by using an abrasive belt, burrs and an oxide film on the surface of the red copper belt are removed, and oil stains on the surface of the red copper belt are completely removed by alkali washing. Specifically, the alkali washing process is as follows: preparing a sodium hydroxide solution with the concentration of 5 wt%, placing the sodium hydroxide solution into an ultrasonic cleaner tank, keeping the temperature at 55-65 ℃, and then placing the metal substrate into the ultrasonic cleaner tank for cleaning.
(2) Pretreatment of diamond abrasive: pre-plating a metal titanium layer on the surface of the diamond grinding material, cleaning the titanium-plated diamond grinding material in acetone, removing surface impurities, and drying for later use.
Specifically, the diamond abrasive is granular, one or more of MBD, SMD and DMD is selected, and the granularity is 45-240 meshes; preferably, mixed diamond grinding materials with different granularities are adopted to cut off the surface of the workpiece material in a large quantity, so that the grinding efficiency is higher, the diamond grinding materials with larger granularities are abraded along with grinding processing, the height of the blade of the diamond grinding materials is reduced, the diamond grinding materials can be leveled with the diamond grinding materials with smaller granularities and then gradually transferred to a fine grinding stage of the workpiece material, and the grinding efficiency can be effectively ensured.
Pre-plating metal titanium on the selected diamond grinding material to ensure that the surface of the diamond grinding material is uniformly wrapped with a layer of metal titanium, and the specific process is as follows: placing titanium metal and diamond abrasive in a high-temperature vacuum titanium gold furnace, ionizing titanium metal vapor by glow discharge of inert gas, and accelerating the ions by an electric field to deposit the diamond abrasive with negative charges, thereby forming a metal film with bright color; the thickness of the coating is controlled to be 0.5-5 microns according to the granularity of the diamond abrasive. The surface of the diamond abrasive is plated with titanium, so that the corrosion resistance and the wear resistance of the diamond abrasive are improved.
(3) And (3) uniformly mixing the diamond grinding material pretreated in the step (2) with the low-melting-point metal-based brazing material to obtain a mixture.
Specifically, the metal-based brazing material is copper-based brazing material, and the mass ratio of the diamond abrasive to the metal-based brazing material is 1 (0.5-1). The metal-based brazing material is used as an adhesive, and after the metal-based brazing material is melted through metallurgical bonding, the diamond abrasive can be uniformly dispersed in the metal-based brazing material, and after the metal-based brazing material is cooled and solidified, the diamond abrasive can be firmly bonded on a metal matrix, so that the bonding strength is high, and the problem that the existing abrasive is easy to fall off is effectively solved.
(4) Putting the mixture obtained in the step (3) into a spray gun of plasma spraying equipment, and spraying the mixture on the surface of the metal matrix treated in the step (1) by adopting a plasma spraying process in an argon environment; and cooling and rolling to obtain the metal-based diamond abrasive belt.
Specifically, the metal substrate processed in the step (1) passes through a quartz long box, argon is introduced into the quartz long box, and a plasma spraying device is arranged in the middle of the quartz long box and can automatically move up and down; after the power is switched on, a spray gun of the plasma spraying equipment moves up and down to adjust to a designed spraying distance, the spraying temperature of the plasma spraying equipment is controlled to be 700-900 ℃, the spraying operation speed is 2-5 m/min, the height of the spray head is 800 mm, the argon flow is 0.3-0.5L/min, the metal-based brazing material and the granular diamond in a molten state are sprayed on the surface of the metal matrix, meanwhile, the metal matrix uniformly passes through the quartz long box under the traction action, and the metal matrix is rolled after being cooled.
Through the mixture of above-mentioned plasma spraying technology spraying metal base brazing filler metal and diamond abrasive to control spraying thickness is 30 ~ 150 microns (metal base brazing filler metal thickness), can make diamond abrasive's the height of going out the sword 2/3 for diamond abrasive, the diamond height of going out of comparing in traditional abrasive band is the 1/2 of diamond at most, its height of going out the sword improves greatly, thereby the sharpness and the grinding efficiency in this embodiment metal base diamond abrasive band have been improved, and be favorable to erodeing the abrasive dust, make its surperficial abrasive grain be difficult for blockking up and lose grinding ability.
Furthermore, the manufactured metal-based diamond abrasive belt can be cut to design the length and the width according to the application requirements of different occasions; and for the ring belt, the cut metal-based diamond abrasive belt can be converted into the ring belt by adopting a laser welding joint form. In the embodiment, a laser welding joint form is adopted, the cutting welding area is small, nearby metal-based brazing materials are not affected during welding, and the strength of the welding joint can reach the strength of a base material.
The properties of the metal matrix diamond coated abrasive belt of the present invention will be described by way of specific examples.
(1) Preparing a metal matrix: polishing 0.4mm copper strips, cleaning for 3min in alkali liquor by using an ultrasonic cleaning machine, cleaning by using distilled water, and drying for later use.
(2) Preparing a diamond abrasive: the diamond abrasives of 60 meshes, 80 meshes and 100 meshes of the brands SMD and DMD are selected for vacuum titanizing for standby.
(3) Mixing diamond abrasives: the diamond grinding materials with different grades and particle sizes are mixed according to the mass proportion stated in the table 1.
(4) Preparing a mixture: and mixing the mixed diamond abrasive material and the low-melting-point metal-based brazing solder according to the mass ratio of 1:1 to obtain a mixture.
(5) Spraying: putting the mixture into a spray gun of plasma spraying equipment, and spraying the mixture on the surface of the metal matrix treated in the step (1) by adopting a plasma spraying process in an argon environment; and cooling and rolling to obtain the metal-based diamond abrasive belt. Wherein, the plasma spraying process conditions are as follows: the spraying temperature is 700-900 ℃, the spraying operation speed is 2-5 m/min, the height of the spray head is 800 mm, and the argon flow is 0.3-0.5L/min.
Table 1:
Figure BDA0003431359160000051
Figure BDA0003431359160000061
the metal-based diamond abrasive belt prepared in the embodiments 1 to 6 is converted into an endless belt of 1900mm × 30mm by cutting and laser welding, a hard alloy cutter is ground on a special numerical control grinding machine, the grinding time is 10 minutes, and the removal amount (unit g) of the hard alloy material and the abrasion amount (unit g) of the abrasive belt in the grinding period are examined; meanwhile, an 80-mesh resin bond diamond abrasive belt is purchased as a comparative example 1, an 80-mesh electroplated diamond abrasive belt is purchased as a comparative example 2, a P80 ceramic abrasive Y-shaped cloth-based abrasive belt is purchased as a comparative example 3, and the test results are shown in Table 2.
Table 2:
Figure BDA0003431359160000062
the above examples are merely illustrative of the present invention and should not be construed as limiting the scope of the invention, which is intended to be covered by the claims and any design similar or equivalent to the scope of the invention.

Claims (9)

1. A preparation method of a metal-based diamond abrasive belt is characterized by comprising the following steps:
1) pretreatment of the metal substrate: polishing the surface of the metal matrix, removing oil by alkali washing, cleaning by distilled water, and drying for later use;
2) pretreatment of diamond abrasive: pre-plating a metal titanium layer on the surface of the diamond grinding material, cleaning the titanium-plated diamond grinding material in acetone, removing surface impurities, and drying for later use;
3) uniformly mixing the diamond abrasive pretreated in the step 2) with the low-melting-point metal-based brazing material to obtain a mixture;
4) loading the mixture obtained in the step 3) into a spray gun of plasma spraying equipment, and spraying the mixture on the surface of the metal matrix treated in the step 1) by adopting a plasma spraying process in an argon environment; and cooling and rolling to obtain the metal-based diamond abrasive belt.
2. The method of making a metal matrix diamond coated abrasive belt according to claim 1, wherein: the metal substrate is a copper strip with the thickness of 0.3-0.5 mm.
3. The method of making a metal matrix diamond coated abrasive belt according to claim 1, wherein: the specific alkali washing process in the step 1): preparing a sodium hydroxide solution with the concentration of 5 wt%, placing the sodium hydroxide solution into an ultrasonic cleaner tank, keeping the temperature at 55-65 ℃, and then placing the metal substrate into the ultrasonic cleaner tank for cleaning.
4. The method of making a metal matrix diamond coated abrasive belt according to claim 1, wherein: the granularity of the diamond abrasive is 45-240 meshes.
5. The method of making a metal matrix diamond coated abrasive belt according to claim 4, wherein: the diamond abrasive is a mixture of at least two abrasives with different particle sizes.
6. The method of making a metal matrix diamond coated abrasive belt according to claim 1, wherein: the metal-based brazing material in the step 3) is copper-based brazing material, and the mass ratio of the diamond abrasive to the metal-based brazing material is 1 (0.5-1).
7. The method of making a metal matrix diamond coated abrasive belt according to claim 1, wherein: the plasma spraying process conditions in the step 4) are as follows: the spraying temperature is 700-900 ℃, the spraying operation speed is 2-5 m/min, the height of the spray head is 800 mm, and the argon flow is 0.3-0.5L/min.
8. The method of making a metal matrix diamond coated abrasive belt according to claim 7, wherein: the thickness of the plasma spraying mixture in the step 4) is 30-150 microns.
9. The method of making a metal matrix diamond coated abrasive belt according to claim 1, wherein: and 5) cutting the metal-based diamond abrasive belt to design the length and the width, and converting the cut metal-based diamond abrasive belt into an endless belt in a laser welding joint mode.
CN202111596430.0A 2021-12-24 2021-12-24 Preparation method of metal-based diamond abrasive belt Pending CN114454100A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111596430.0A CN114454100A (en) 2021-12-24 2021-12-24 Preparation method of metal-based diamond abrasive belt

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111596430.0A CN114454100A (en) 2021-12-24 2021-12-24 Preparation method of metal-based diamond abrasive belt

Publications (1)

Publication Number Publication Date
CN114454100A true CN114454100A (en) 2022-05-10

Family

ID=81407489

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111596430.0A Pending CN114454100A (en) 2021-12-24 2021-12-24 Preparation method of metal-based diamond abrasive belt

Country Status (1)

Country Link
CN (1) CN114454100A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020069592A1 (en) * 1999-12-07 2002-06-13 Sherman Andrew J. Abrasive particles with metallurgically bonded metal coatings
CN1644319A (en) * 2004-01-19 2005-07-27 广东工业大学 Manufacture of single-layer diamond grinder
CN202498461U (en) * 2012-02-29 2012-10-24 河南富耐克超硬材料股份有限公司 Abrasive belt used for grinding and machining
US20150290771A1 (en) * 2012-03-27 2015-10-15 Yundong Li Abrasive article and method for making the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020069592A1 (en) * 1999-12-07 2002-06-13 Sherman Andrew J. Abrasive particles with metallurgically bonded metal coatings
CN1644319A (en) * 2004-01-19 2005-07-27 广东工业大学 Manufacture of single-layer diamond grinder
CN202498461U (en) * 2012-02-29 2012-10-24 河南富耐克超硬材料股份有限公司 Abrasive belt used for grinding and machining
US20150290771A1 (en) * 2012-03-27 2015-10-15 Yundong Li Abrasive article and method for making the same

Similar Documents

Publication Publication Date Title
EP1378323B1 (en) Bond for abrasive tool
CN101209505B (en) Method for preparing metal binding agent diamond scroll saw
JP2001252873A (en) Tool for polishing dressing, and method of manufacturing the same
CN102770240A (en) Super-abrasive grain fixed type wire saw, and method of manufacturing super-abrasive grain fixed type wire saw
CN105619272B (en) A kind of production method of laser Furnace Brazing of Diamond Grinding Wheel With Ni
CN109048690A (en) Diamond-impregnated wheel and its manufacturing process
CN112981169B (en) Copper-based composite powder and preparation method thereof, and anti-corrosion wear-resistant composite coating and preparation method thereof
JP3227854U (en) Diamond composite brazed coating layer structure
US6309433B1 (en) Polishing pad conditioner for semiconductor substrate
CN110218994A (en) A kind of manufacturing method of high efficiency cutting silicon wafer diamond wire
CN109016196B (en) Electroplated diamond wire saw
CN114454100A (en) Preparation method of metal-based diamond abrasive belt
CN108972387B (en) Preparation method of induction brazing single-layer diamond grinding wheel
US6187071B1 (en) Bond for abrasive tool
JP6755378B1 (en) Target material polishing method, target material manufacturing method, and recycled ingot manufacturing method
CN108161778A (en) A kind of diamond grinding head and its preparation process
CN100386832C (en) Surface treatment of electric contact
CN102492367A (en) Low-melting-point metal adhesive and diamond wire saw obtained by metal adhesion
JP2007126736A (en) Sputtering target and its production method
CN217371994U (en) Metal-based diamond abrasive belt
CN108655970A (en) A kind of preparation of laser near-net-shape structuring diamond outer circle grinding wheel and its dressing method
CN210011174U (en) Dip welding diamond wire
CN110714183B (en) Method for making brazed diamond tools
CN109203264B (en) Dip-soldering diamond wire and manufacturing method thereof
JP2002192470A (en) Grinding wheel tool

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination