CN114437643A - Novel light photovoltaic module packaging plate - Google Patents
Novel light photovoltaic module packaging plate Download PDFInfo
- Publication number
- CN114437643A CN114437643A CN202111663362.5A CN202111663362A CN114437643A CN 114437643 A CN114437643 A CN 114437643A CN 202111663362 A CN202111663362 A CN 202111663362A CN 114437643 A CN114437643 A CN 114437643A
- Authority
- CN
- China
- Prior art keywords
- parts
- layer
- photovoltaic module
- module packaging
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 18
- 239000010410 layer Substances 0.000 claims abstract description 41
- 239000000463 material Substances 0.000 claims abstract description 39
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 25
- 239000004611 light stabiliser Substances 0.000 claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 20
- 239000002250 absorbent Substances 0.000 claims abstract description 19
- 230000002745 absorbent Effects 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000012790 adhesive layer Substances 0.000 claims abstract description 12
- 230000007062 hydrolysis Effects 0.000 claims abstract description 12
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 12
- 239000002344 surface layer Substances 0.000 claims abstract description 12
- 239000011159 matrix material Substances 0.000 claims abstract description 11
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 11
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 9
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 6
- 239000004698 Polyethylene Substances 0.000 claims abstract description 5
- 239000003365 glass fiber Substances 0.000 claims abstract description 5
- 229920000573 polyethylene Polymers 0.000 claims abstract description 5
- 229920000098 polyolefin Polymers 0.000 claims abstract description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 3
- 239000004677 Nylon Substances 0.000 claims abstract description 3
- 239000004743 Polypropylene Substances 0.000 claims abstract description 3
- 239000004917 carbon fiber Substances 0.000 claims abstract description 3
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 229920001778 nylon Polymers 0.000 claims abstract description 3
- 229920003023 plastic Polymers 0.000 claims abstract description 3
- 239000004033 plastic Substances 0.000 claims abstract description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 3
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 3
- 239000004417 polycarbonate Substances 0.000 claims abstract description 3
- 229920001155 polypropylene Polymers 0.000 claims abstract description 3
- 229920000642 polymer Polymers 0.000 claims description 14
- 238000000465 moulding Methods 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 11
- 229910052731 fluorine Inorganic materials 0.000 claims description 11
- 239000011737 fluorine Substances 0.000 claims description 11
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 9
- 239000002313 adhesive film Substances 0.000 claims description 8
- 238000003490 calendering Methods 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 238000010345 tape casting Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 150000001718 carbodiimides Chemical class 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 239000000806 elastomer Substances 0.000 claims description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 claims description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 2
- BDNKZNFMNDZQMI-UHFFFAOYSA-N 1,3-diisopropylcarbodiimide Chemical compound CC(C)N=C=NC(C)C BDNKZNFMNDZQMI-UHFFFAOYSA-N 0.000 claims description 2
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 claims description 2
- 229920001780 ECTFE Polymers 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 2
- 239000004831 Hot glue Substances 0.000 claims description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 2
- 150000008360 acrylonitriles Chemical class 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- BGRWYRAHAFMIBJ-UHFFFAOYSA-N diisopropylcarbodiimide Natural products CC(C)NC(=O)NC(C)C BGRWYRAHAFMIBJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 claims description 2
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims description 2
- 229920001112 grafted polyolefin Polymers 0.000 claims description 2
- 239000012760 heat stabilizer Substances 0.000 claims description 2
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 claims description 2
- 229920001910 maleic anhydride grafted polyolefin Polymers 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims description 2
- XLDBGFGREOMWSL-UHFFFAOYSA-N n,n'-bis[2,6-di(propan-2-yl)phenyl]methanediimine Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N=C=NC1=C(C(C)C)C=CC=C1C(C)C XLDBGFGREOMWSL-UHFFFAOYSA-N 0.000 claims description 2
- 229920002338 polyhydroxyethylmethacrylate Polymers 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims 1
- 239000012964 benzotriazole Substances 0.000 claims 1
- 239000008393 encapsulating agent Substances 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims 1
- 229960001860 salicylate Drugs 0.000 claims 1
- 239000003292 glue Substances 0.000 abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- 238000010248 power generation Methods 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 235000008429 bread Nutrition 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 238000013087 polymer photovoltaic Methods 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000013084 building-integrated photovoltaic technology Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/322—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of solar panels
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2427/00—Presence of halogenated polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2427/00—Presence of halogenated polymer
- C09J2427/006—Presence of halogenated polymer in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Computer Hardware Design (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a novel light photovoltaic module packaging plate which sequentially comprises an air surface layer, an adhesive layer, a base material layer and a glue film binding layer from outside to inside, wherein the base material layer comprises the following components in parts by weight: 50-99 parts of matrix resin, 0.1-50 parts of reinforcing filler, 0.1-3 parts of hydrolysis resistance agent, 0.1-3 parts of ultraviolet absorbent, 0.1-3 parts of light stabilizer and 0.1-35 parts of other auxiliary agents, wherein the matrix resin is selected from any one or a mixture of polyethylene terephthalate, polymethyl methacrylate, polycarbonate, polybutylene terephthalate, cyclic polyolefin, cycloolefin polymer, polypropylene, nylon and polyethylene; the reinforcing filler is selected from any one or a mixture of more of metal fibers, carbon fibers, plastic fibers and glass fibers. The invention has the advantages of light weight, high weather resistance, high strength, good impact resistance and high reliability.
Description
Technical Field
The invention belongs to the technical field of photovoltaic power generation assembly sealing, and particularly relates to a high-molecular polymer photovoltaic panel packaging light assembly.
Background
Since the double-carbon target is provided, distributed photovoltaic power generation is developed rapidly, compared with centralized power generation, a distributed scene is more complex, the traditional module packaging scheme mostly adopts glass or a combination of glass and a high polymer material, the weight of the traditional module packaging scheme is usually 20-30 Kg, and the weight of auxiliary components such as a bracket is more than 30Kg, so that the use of distributed photovoltaics (especially BAPV and BIPV) is very limited, for example, some old color steel roofs have certain potential safety hazards and are inconvenient to install if the installation weight is too large.
At present, in order to solve the existing technical problems, the conventional technology generally replaces the upper and lower outer layer structures of the photovoltaic module with the photovoltaic back sheet made of high polymer materials. And present polymer photovoltaic backplate material adopts PET or polyolefin as the substrate (mostly 4 or 5 layer structures) more, but brings the backplate intensity inadequately thereupon, and weatherability subalternation problem, therefore can only compensate the not enough of backplate intensity through increasing the number of piles, increases to 9 layers or more by original 4~5 layer structures. Due to the increase of the number of structural layers, the production process of the back plate is complicated, the weight of the back plate is increased, the production cost of the back plate is improved, and the matching performance of equipment is poor.
Disclosure of Invention
Aiming at the problems and defects in the prior art, the invention provides a novel light photovoltaic module packaging plate which has the advantages of light weight, high weather resistance, high strength, good impact resistance and high reliability.
In order to solve the technical problems, the invention adopts the following technical scheme: the utility model provides a novel light photovoltaic module encapsulates board, includes air surface course, adhesive linkage, substrate layer and glued membrane anchor coat from outer to interior in proper order, wherein:
the base material layer material is prepared by mixing the following components in parts by weight and then carrying out extrusion molding, solution tape casting molding or calendaring molding:
50-99 parts of matrix resin
0.1-50 parts of reinforcing filler
0.1-3 parts of hydrolysis resistant agent
0.1-3 parts of ultraviolet absorbent
0.1-3 parts of light stabilizer
0.1 to 35 portions of other additives
Wherein the matrix resin is selected from one or more of polyethylene terephthalate, polymethyl methacrylate, polycarbonate, polybutylene terephthalate, cyclic polyolefin, cyclic olefin polymer, polypropylene, nylon and polyethylene; the reinforcing filler is selected from any one or a mixture of more of metal fibers, carbon fibers, plastic fibers and glass fibers.
Preferably, the other auxiliary agent comprises at least one of hydrolysis resistance agent, tackifier, acid absorbent, heat stabilizer, antioxidant, filler and colorant. The hydrolysis resisting agent is any one or a mixture of more of polycarbodiimide, epoxy polymer, carbodiimide, bis (2, 6-diisopropylphenyl) carbodiimide, dicyclohexylcarbodiimide and diisopropylcarbodiimide.
Preferably, the ultraviolet absorber is selected from any one or a mixture of at least two of o-hydroxybenzophenones, benzotriazoles, salicylates, triazines and substituted acrylonitriles.
Preferably, the light stabilizer is selected from any one of light-shielding agents, quenchers, radical scavengers, hydroperoxide decomposers, or a mixture of at least two thereof.
Preferably, the air surface layer material is prepared by mixing fluorine-containing resin and other auxiliary agents and then performing extrusion molding, solution casting molding or calendaring molding, wherein the fluorine-containing resin is one or a mixture of two of vinylidene fluoride, ethylene-tetrafluoroethylene copolymer, polychlorotrifluoroethylene, tetrafluoroethylene-hexafluoropropylene copolymer, vinyl fluoride, polytetrafluoroethylene or ethylene-chlorotrifluoroethylene copolymer.
Preferably, the air surface layer material also contains an ultraviolet absorber and a light stabilizer.
Preferably, the adhesive layer is prepared by mixing an adhesive material with the ultraviolet absorber, the light stabilizer and the other auxiliary agents and then performing extrusion molding, solution casting molding or calendaring molding.
Preferably, the bonding material is any one of polyurethane, polymethyl methacrylate, polyhydroxyethyl methacrylate, ethylene-vinyl alcohol copolymer, ethylene-methacrylic acid copolymer, ethyl methacrylate copolymer, glycidyl methacrylate grafted polyolefin elastomer, glycidyl methacrylate grafted polyethylene, maleic anhydride grafted polyolefin elastomer, maleic anhydride grafted polyethylene or a mixture of at least two of them.
Preferably, the thickness of the air surface layer is 15-80 μm, and preferably 20-30 μm; the thickness of the substrate layer is 10-1000 microns, preferably 50-400 microns; the thickness of the bonding layer is 6-20 mu m.
Preferably, the adhesive film bonding layer is selected from a coating, a hot melt adhesive or other bonding materials, and plays a role in assisting bonding.
Preferably, the air surface layer and the base material layer are respectively subjected to extrusion molding, solution tape casting or calendaring molding to prepare the film layer, the prepared air surface layer and the prepared base material layer are combined together through an adhesive layer, and the adhesive film combining layer is formed on the other surface of the base material layer in a coating or film spraying mode.
Has the advantages that: compared with the prior art, the invention has the following advantages:
1. the weight is light: the invention adopts the polymer front plate and the polymer rear plate for packaging, and the weight is reduced by more than 70 percent compared with the glass packaging;
2. high weather resistance: the air surface is prepared by selecting fluorine-containing resin which contains carbon-fluorine bonds, and due to the local ionic bond characteristic of the fluorine-containing resin, the fluorine-containing resin is a strongest single bond and relatively short bonds, and has excellent weather resistance in organic chemistry; meanwhile, the ultraviolet absorbent is stably matched with light, so that ultraviolet rays (the blocking rate is more than 98%) can be effectively prevented, internal materials are protected, and the ultraviolet resistance of the material can even reach 1500kWh/m2The above;
3. high strength and good impact resistance: the strength and the impact resistance of the base material are improved through the matching of the matrix resin, the reinforcing filler, the hydrolysis resistance agent, the ultraviolet absorbent, the light stabilizer and other additives;
4. the reliability is high: through the design of each layer of material and the combination of the multiple layers of material through adhesives, the polymer front plate and the polymer rear plate provided by the invention can not generate the defects of cracking, layering, yellowing and the like in the use process.
Drawings
FIG. 1 is a schematic structural view of a novel lightweight photovoltaic module according to the present invention;
fig. 2 is a schematic structural diagram of the novel lightweight photovoltaic module packaging plate according to the present invention.
In the figure, a polymer front plate 1, a glue film 2, a battery piece 3, a glue film 4, a polymer rear plate 5, an air surface layer A, an adhesive layer B, a base material layer C and a glue film bonding layer D.
Detailed Description
The invention is further elucidated with reference to the drawings and the embodiments. It is to be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention, which is to be given the full breadth of the appended claims and any and all equivalent modifications thereof which may occur to those skilled in the art upon reading the present specification.
Example 1: polymer front panel
The polymer front plate comprises an air surface (25 mu m, transparent light blue), an adhesive layer (8 mu m), a base material layer (600 mu m) and a glue film bonding surface (5 mu m) from outside to inside in sequence, wherein:
the air bread comprises the following components in parts by weight:
85 parts of fluorine-containing resin
Ultraviolet absorber 0.6 part
Light stabilizer 0.3 part
14.1 parts of other auxiliary agents;
wherein the fluorine-containing resin is polyvinylidene fluoride, the ultraviolet absorbent is UV234, the light stabilizer is UV770, the other auxiliary agents are PMMA (polymethyl methacrylate) 14 parts, acid absorbent 0.05 part and acid absorbent 0.05 part;
wherein the bonding layer comprises the following components in parts by weight:
99.5 parts of binding material
0.2 portion of ultraviolet absorbent
Light stabilizer 0.1 part
Other auxiliary agents; 0.2 part
Wherein the bonding material is polyurethane, the ultraviolet absorbent is UV234, the light stabilizer is UV770, and the other auxiliary agents are 1010;
wherein, by weight, the substrate layer comprises the following components:
93 parts of matrix resin
Reinforcing filler 5 parts
0.5 portion of hydrolysis resistant agent
Ultraviolet absorber 0.6 part
Light stabilizer 0.3 part
Other auxiliary agents; 0.6 part
Wherein the matrix resin is polyethylene terephthalate, the reinforcing filler is glass fiber, the hydrolysis resistance agent is carbodiimide, the ultraviolet absorbent is UV234, the light stabilizer is UV770, and the other auxiliary agents are 1010;
wherein the adhesive film bonding surface is a transparent FEVE coating;
the preparation method comprises the steps of coating the adhesive film bonding surface on the base material layer in a coating mode, then coating the adhesive layer on the base material layer, and then compounding the adhesive layer with the air surface to obtain the polymer rear plate.
Example 2: polymer back plate
As a polymer rear plate, from outside to inside, an air surface (25 μm, opaque white), an adhesive layer (8 μm), a base material layer (600 μm), and a glue film bonding surface (5 μm) were provided in this order, wherein:
the air bread comprises the following components in parts by weight:
75 parts of fluorine-containing resin
Ultraviolet absorber 0.6 part
Light stabilizer 0.3 part
24.1 parts of other auxiliary agents;
wherein the fluorine-containing resin is polyvinylidene fluoride, the ultraviolet absorbent is UV234, the light stabilizer is UV770, the other auxiliary agents are PMMA (polymethyl methacrylate) 14 parts, titanium dioxide 10 parts, acid absorbent 0.05 part and 1010.05 part;
wherein the bonding layer comprises the following components in parts by weight:
99.5 parts of binding material
0.2 portion of ultraviolet absorbent
Light stabilizer 0.1 part
Other auxiliary agents; 0.2 part
Wherein the bonding material is polyurethane, the ultraviolet absorbent is UV234, the light stabilizer is UV770, and the other auxiliary agents are 1010;
wherein, by weight, the substrate layer comprises the following components:
83 parts of matrix resin
Reinforcing filler 5 parts
0.5 portion of hydrolysis resistant agent
0.6 part of ultraviolet absorber
Light stabilizer 0.3 part
Other auxiliary agents; 10.6 parts
Wherein the matrix resin is polyethylene terephthalate, the reinforcing filler is glass fiber, the hydrolysis resistance agent is carbodiimide, the ultraviolet absorbent is UV234, the light stabilizer is UV770, and the other auxiliary agents are 10 parts of titanium dioxide and 0.6 part of 1010;
wherein the adhesive film bonding surface is a white FEVE coating;
the preparation method comprises the steps of coating the adhesive film bonding surface on the base material layer in a coating mode, then coating the adhesive layer on the base material layer, and then compounding the adhesive layer with the air surface to obtain the polymer rear plate.
Claims (10)
1. The utility model provides a novel light photovoltaic module packaging board which characterized in that: include air surface course, adhesive linkage, substrate layer and glued membrane anchor coat from outside to interior in proper order, wherein:
the base material layer material is prepared by mixing the following components in parts by weight and then carrying out extrusion molding, solution tape casting molding or calendaring molding:
50-99 parts of matrix resin
0.1-50 parts of reinforcing filler
0.1-3 parts of hydrolysis resistant agent
0.1-3 parts of ultraviolet absorbent
0.1-3 parts of light stabilizer
0.1 to 35 portions of other auxiliary agents
Wherein the matrix resin is selected from one or more of polyethylene terephthalate, polymethyl methacrylate, polycarbonate, polybutylene terephthalate, cyclic polyolefin, cycloolefin polymer, polypropylene, nylon and polyethylene; the reinforcing filler is selected from any one or a mixture of more of metal fibers, carbon fibers, plastic fibers and glass fibers.
2. The novel lightweight photovoltaic module package panel of claim 1, wherein: the other auxiliary agents comprise at least one of hydrolysis resistance agent, tackifier, acid absorbent, heat stabilizer, antioxidant, filler and colorant;
the hydrolysis resisting agent is any one or a mixture of more of polycarbodiimide, epoxy polymer, carbodiimide, bis (2, 6-diisopropylphenyl) carbodiimide, dicyclohexylcarbodiimide and diisopropylcarbodiimide.
3. The novel lightweight photovoltaic module packaging sheet of claim 1, wherein: the ultraviolet absorbent is selected from any one or a mixture of at least two of o-hydroxybenzophenone, benzotriazole, salicylate, triazine and substituted acrylonitrile.
4. The novel lightweight photovoltaic module packaging sheet of claim 1, wherein: the light stabilizer is selected from any one or a mixture of at least two of light shielding agents, quenchers, radical trapping agents and hydroperoxide decomposers.
5. The novel lightweight photovoltaic module packaging sheet of claim 1, wherein: the air surface layer material is prepared by mixing fluorine-containing resin and other auxiliary agents and then performing extrusion molding, solution tape casting or calendaring molding, wherein the fluorine-containing resin is any one or a mixture of two of vinylidene fluoride, ethylene-tetrafluoroethylene copolymer, polychlorotrifluoroethylene, tetrafluoroethylene-hexafluoropropylene copolymer, vinyl fluoride, polytetrafluoroethylene or ethylene-chlorotrifluoroethylene copolymer.
6. The novel lightweight photovoltaic module packaging sheet of claim 5, wherein: the air surface layer material also contains an ultraviolet absorber and a light stabilizer.
7. The novel lightweight photovoltaic module packaging sheet of claim 5, wherein: the adhesive layer is prepared by mixing an adhesive material with the ultraviolet absorber, the light stabilizer and the other auxiliary agents and then carrying out extrusion molding, solution tape casting or calendaring molding.
8. The novel lightweight photovoltaic module encapsulant sheet in accordance with claim 7, wherein: the bonding material is any one or a mixture of at least two of polyurethane, polymethyl methacrylate, polyhydroxyethyl methacrylate, ethylene-vinyl alcohol copolymer, ethylene-methacrylic acid copolymer, ethyl methacrylate copolymer, glycidyl methacrylate grafted polyolefin elastomer, glycidyl methacrylate grafted polyethylene, maleic anhydride grafted polyolefin elastomer and maleic anhydride grafted polyethylene.
9. The novel lightweight photovoltaic module packaging sheet of claim 1, wherein: the thickness of the air surface layer is 15-80 μm, and preferably 20-30 μm; the thickness of the substrate layer is 10-1000 microns, preferably 50-400 microns; the thickness of the bonding layer is 6-20 mu m; the adhesive film bonding layer is selected from a coating, a hot melt adhesive or other bonding materials, and plays a role in assisting bonding.
10. The novel light photovoltaic module packaging plate as claimed in any one of claims 1 to 9, wherein: the air surface layer and the base material layer are respectively subjected to extrusion molding, solution tape casting molding or calendaring molding to prepare the film layers, the prepared air surface layer and the prepared base material layer are combined together through the adhesive layer, and the adhesive film combining layer is formed on the other surface of the base material layer in a coating or film spraying mode.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111663362.5A CN114437643A (en) | 2021-12-31 | 2021-12-31 | Novel light photovoltaic module packaging plate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111663362.5A CN114437643A (en) | 2021-12-31 | 2021-12-31 | Novel light photovoltaic module packaging plate |
Publications (1)
Publication Number | Publication Date |
---|---|
CN114437643A true CN114437643A (en) | 2022-05-06 |
Family
ID=81366055
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111663362.5A Pending CN114437643A (en) | 2021-12-31 | 2021-12-31 | Novel light photovoltaic module packaging plate |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114437643A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN118085373A (en) * | 2024-04-26 | 2024-05-28 | 上海品诚晶曜光伏科技有限公司 | Thermoplastic flame-retardant hyperboloid PC packaging assembly and preparation method and application thereof |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104201224A (en) * | 2014-08-20 | 2014-12-10 | 杭州福斯特光伏材料股份有限公司 | Transparent back plate for solar cell module |
CN206401338U (en) * | 2016-12-19 | 2017-08-11 | 中天光伏材料有限公司 | A kind of photovoltaic cell encapsulation integration glued membrane backboard |
CN108034377A (en) * | 2017-11-16 | 2018-05-15 | 明冠新材料股份有限公司 | A kind of glued membrane backboard integrated material and its preparation process |
CN108400186A (en) * | 2018-04-26 | 2018-08-14 | 江阴四方游泳康复产业股份有限公司 | A kind of SMC monoblock types photovoltaic module, manufacturing method and application |
CN108682707A (en) * | 2018-06-13 | 2018-10-19 | 常州回天新材料有限公司 | A kind of solar photovoltaic battery component transparent back panel for generating electricity on two sides |
CN109337260A (en) * | 2018-11-13 | 2019-02-15 | 常州回天新材料有限公司 | A kind of transparent polyvinylidene fluoride film and its manufacturing method |
CN110181913A (en) * | 2019-05-15 | 2019-08-30 | 安徽金兑新材料科技有限公司 | A kind of low warpage solar cell backboard substrate and preparation method thereof |
CN111690335A (en) * | 2020-04-29 | 2020-09-22 | 乐凯胶片股份有限公司 | Transparent back plate for packaging solar cell |
-
2021
- 2021-12-31 CN CN202111663362.5A patent/CN114437643A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104201224A (en) * | 2014-08-20 | 2014-12-10 | 杭州福斯特光伏材料股份有限公司 | Transparent back plate for solar cell module |
CN206401338U (en) * | 2016-12-19 | 2017-08-11 | 中天光伏材料有限公司 | A kind of photovoltaic cell encapsulation integration glued membrane backboard |
CN108034377A (en) * | 2017-11-16 | 2018-05-15 | 明冠新材料股份有限公司 | A kind of glued membrane backboard integrated material and its preparation process |
CN108400186A (en) * | 2018-04-26 | 2018-08-14 | 江阴四方游泳康复产业股份有限公司 | A kind of SMC monoblock types photovoltaic module, manufacturing method and application |
CN108682707A (en) * | 2018-06-13 | 2018-10-19 | 常州回天新材料有限公司 | A kind of solar photovoltaic battery component transparent back panel for generating electricity on two sides |
CN109337260A (en) * | 2018-11-13 | 2019-02-15 | 常州回天新材料有限公司 | A kind of transparent polyvinylidene fluoride film and its manufacturing method |
CN110181913A (en) * | 2019-05-15 | 2019-08-30 | 安徽金兑新材料科技有限公司 | A kind of low warpage solar cell backboard substrate and preparation method thereof |
CN111690335A (en) * | 2020-04-29 | 2020-09-22 | 乐凯胶片股份有限公司 | Transparent back plate for packaging solar cell |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN118085373A (en) * | 2024-04-26 | 2024-05-28 | 上海品诚晶曜光伏科技有限公司 | Thermoplastic flame-retardant hyperboloid PC packaging assembly and preparation method and application thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101780925B1 (en) | Photovoltaic modules having a polyvinylidene fluoride backsheet | |
CN108682707B (en) | Transparent back plate of solar photovoltaic cell module for double-sided power generation | |
CN108565307B (en) | Packaging material for photovoltaic module | |
CN108198884B (en) | Damp-heat resistant solar cell back plate and manufacturing method thereof | |
WO2010038875A1 (en) | Solar cell back surface protective film, and solar cell module provided with same | |
CN108242473B (en) | Color photovoltaic module and preparation method thereof | |
CN103052505A (en) | Multilayer films containing a fluorinated copolymer resin layer and an encapsulant layer | |
CN101615635B (en) | Heat resistance-treated back board of solar cell | |
US20140109956A1 (en) | High Performance Backsheet for Photovoltaic Applications and Method for Manufacturing the Same | |
WO2017140002A1 (en) | Resin-based composite thin-film material and preparation method therefor, and solar cell module | |
CN111303790A (en) | Glue film and back plate integrated packaging material and processing technology thereof | |
CN106244032A (en) | A kind of EVA adhesive film used for solar batteries and preparation method thereof | |
CN114437643A (en) | Novel light photovoltaic module packaging plate | |
JP2001326374A (en) | Solar battery module | |
CN104124300A (en) | Solar cell backplane and solar cell module | |
CN103730531B (en) | A kind of humidity-resisting solar cell backplate without adhesive and manufacture method thereof | |
CN103722840A (en) | Humidity-resisting solar cell backplate without adhesive and manufacturing method thereof | |
US10665742B2 (en) | Co-extruded backsheet for solar cell modules | |
EP3164891B1 (en) | Mono-backsheet for solar cell modules | |
CN218827176U (en) | Back plate and photovoltaic module | |
CN218939702U (en) | Back sheet for photovoltaic module and photovoltaic module | |
CN116144284B (en) | Raw material package, integrated adhesive film backboard, preparation method of integrated adhesive film backboard and photovoltaic module | |
CN110323296A (en) | A kind of photovoltaic shoe plate | |
JP6660037B2 (en) | Solar cell module | |
CN115663048A (en) | Back plate for photovoltaic module and application thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220506 |