CN114409376A - Preparation method of high-saturation amorphous photonic crystal structure colored glaze - Google Patents
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Abstract
The invention discloses a preparation method of a colored glaze with a high-saturation amorphous photonic crystal structure, which comprises the steps of mixing clay with high iron content, feldspar, quartz and kaolin; or taking black tailings or slag, feldspar, quartz and kaolin for mixing; ball-milling the mixed blank, and drying, grinding, granulating, ageing, tabletting and the like to obtain a black blank; mixing feldspar, quartz, calcite, talc, kaolin, tricalcium phosphate and boron frit, sodium carboxymethylcellulose and sodium tripolyphosphate to obtain a mixed glaze; uniformly applying the mixed glaze material on the prepared blank after ball milling to obtain a glazed blank; and drying the glazing blank, and then putting the dried glazing blank into an electric furnace to be fired in an oxidizing atmosphere. The invention provides a new method for the application of the amorphous photonic crystal structure colored glaze in the traditional ceramic decoration, and can open up a new way for the efficient utilization of low-quality raw materials in ceramic blanks.
Description
Technical Field
The invention relates to the technical field of ceramic material manufacturing, in particular to a preparation method of a colored glaze with a high-saturation amorphous photonic crystal structure.
Background
According to different sources of the structural colors, the structural colored glaze can be divided into the amorphous photonic crystal structural colored glaze and the structural colored glaze formed by Rayleigh scattering and Mie scattering. As the amorphous photonic crystal structure has the characteristics of isotropic photonic band gap, non-iridescence effect, light localization and the like, the ceramic glaze is soft and bright and has a color rendering effect which is not changed along with the angle, and the ceramic glaze has a wider application space in the field of ceramic decoration (material report, 2017,31(1): 43-55). However, in the amorphous photonic crystal structure colored glaze, the color saturation of the structural color formed by Bragg scattering is reduced due to the influence of incoherent scattering (Advanced Materials,2018,30(28):1706654), and the color visibility is not strong, so that the wide application of the amorphous photonic crystal structure colored glaze in the traditional ceramic industry is limited.
In the field of new materials, researchers select nanoscale carbon black, magnetite, black TiO2Polypyrrole and the like absorb incoherent scattered light, and colored pigments and films of amorphous photonic crystal structures with high color rendering have been successfully prepared (Chemical Communications,2018,54(39):4905-&Interfaces,2016,8(25): 16289-. In addition, Takeoka et al can also make amorphous photonic crystal structure color thin films and colorants show potential structural color effects by using black background instead of black light absorber (ACS Applied Nano Materials,2020,3(7): 7047-7056). Colored glaze for amorphous photonic crystal structureIn other words, if a high-temperature resistant black pigment is introduced into the formula of the porcelain glaze, not only the granularity of the pigment, the dispersibility, the thermal stability and the distribution rule of the pigment crystal grains in the phase-separated glaze after firing are considered, but also the influence of the pigment on the structural color of the amorphous photonic crystal is considered, and the experimental process is too complicated. Based on this, by using the method of absorbing stray light by the black background, a black light absorption layer can be formed at the bottom of the glaze layer, and the purpose of improving the color saturation of the colored glaze of the amorphous photonic crystal structure is achieved.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide a preparation method of a high-saturation amorphous photonic crystal structure colored glaze, which takes clay or black tailings and slag with high iron content as raw materials of a ceramic blank body, and forms a black light absorption layer at the bottom of the amorphous photonic crystal structure colored glaze by diffusion of transition metal ions in the blank body in the glaze firing process. The black light absorption layer can absorb incoherent scattered light in the glaze layer, so that the aim of improving the color glaze saturation of the amorphous photonic crystal structure is fulfilled. The invention can provide a new method for the application of the amorphous photonic crystal structure colored glaze in the traditional ceramic decoration, and can open up a new way for the efficient utilization of low-quality raw materials in ceramic blanks.
In order to achieve the purpose, the invention adopts the technical scheme that:
a preparation method of high-saturation amorphous photonic crystal structure colored glaze comprises the following steps;
the method comprises the following steps: mixing 10-85% of clay (such as black crucible soil, purple golden soil, etc.), 2-20% of feldspar, 8-20% of quartz and 5-50% of kaolin according to mass ratio;
or mixing 5-50% black tailings, slag (such as iron tailings, manganese tailings, slag and the like), 5-20% feldspar, 5-15% quartz and 40-60% kaolin according to the mass ratio;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank;
step three: 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talcum and 4% of kaolin are taken according to the mass ratio, and tricalcium phosphate (Ca) with the total mass of 2% is added3(PO4)2) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and after the sample is cooled, preparing the amorphous photonic crystal structure colored glaze with high saturation.
In the second step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the material to the balls to the water is 1:2: 0.6.
And in the second step, pressing the aged blank powder under the pressure of 25MPa by using a tablet press, taking out, biscuiting to 900 ℃, and preserving heat for 120 min.
In the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials, the balls and the water is 1:2: 0.8.
The firing temperature in the fifth step is 1200-1350 ℃, and the temperature is kept for 10-50 min.
At high temperature, the transition metal elements in the blank exist in an ion state, and due to the action of concentration gradient, the ions gradually diffuse to the bottom layer of the structural colored glaze and form a black light absorption layer. And after the sample is cooled, preparing the amorphous photonic crystal structure colored glaze with high saturation.
The invention has the beneficial effects that:
according to the invention, the clay or black metal tailings and slag with high iron content are used for preparing the ceramic body, and the diffusion of transition metal ions is utilized to form the black light absorption layer at the bottom of the glaze layer, so that the color saturation of the colored glaze with the amorphous photonic crystal structure is effectively improved, and the application range of the structural color in the traditional ceramic decoration is widened. In addition, the application of the low-quality raw materials greatly reduces the production cost of the product and has good environmental and social benefits. Therefore, the invention not only improves the innovation of ceramic enterprises in the preparation of the amorphous photonic crystal structure colored glaze, but also provides an effective solution for the energy-saving and environment-friendly production of ceramic industries.
Drawings
FIG. 1 is an optical micrograph of a cross section of a sample in a black crucible porcelain body.
FIG. 2 is a reflection spectrum of the surface of the colored glaze with amorphous photonic crystal structure in black crucible clay enamel.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1:
the method comprises the following steps: mixing 85% of black crucible soil, 2% of feldspar, 8% of quartz and 5% of kaolin according to the mass ratio;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank.
Step three: 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talcum and 4% of kaolin are taken according to the mass ratio, and tricalcium phosphate (Ca) with the total mass of 2% is added3(PO4)2) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and after the sample is cooled, preparing the amorphous photonic crystal structure colored glaze with high saturation.
In the second step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the material to the balls to the water is 1:2: 0.6.
And in the second step, pressing the aged blank powder under the pressure of 25MPa by using a tablet press, taking out, biscuiting to 900 ℃, and preserving heat for 120 min.
In the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials, the balls and the water is 1:2: 0.8.
And the firing temperature in the fifth step is 1350 ℃, and the temperature is kept for 10 min.
As shown in figure 1, the transition metal element in the matrix diffuses to the bottom of the glaze layer and forms a black light absorption layer with a certain thickness.
As shown in fig. 2, the formation of the black light absorbing layer effectively improves the color saturation of the amorphous photonic crystal structure colored glaze.
Example 2:
the method comprises the following steps: taking 50% of iron tailings, 5% of feldspar, 5% of quartz and 40% of kaolin according to the mass ratio;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank.
Step three: 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talcum and 4% of kaolin are taken according to the mass ratio, and tricalcium phosphate (Ca) with the total mass of 2% is added3(PO4)2) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and after the sample is cooled, preparing the amorphous photonic crystal structure colored glaze with high saturation.
In the second step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the material to the balls to the water is 1:2: 0.6.
And in the second step, pressing the aged blank powder under the pressure of 25MPa by using a tablet press, taking out, biscuiting to 900 ℃, and preserving heat for 120 min.
In the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials, the balls and the water is 1:2: 0.8.
And the firing temperature in the fifth step is 1200 ℃, and the temperature is kept for 50 min.
Example 3:
the method comprises the following steps: taking 5% of manganese slag, 20% of feldspar, 15% of quartz and 60% of kaolin according to the mass ratio;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank.
Step three: 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talcum and 4% of kaolin are taken according to the mass ratio, and tricalcium phosphate (Ca) with the total mass of 2% is added3(PO4)2) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and cooling the sample to prepare the amorphous photon structure colored glaze with high saturation.
In the second step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the material to the balls to the water is 1:2: 0.6.
And in the second step, pressing the aged blank powder under the pressure of 25MPa by using a tablet press, taking out, biscuiting to 900 ℃, and preserving heat for 120 min.
In the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials, the balls and the water is 1:2: 0.8.
And the firing temperature in the fifth step is 1300 ℃, and the temperature is kept for 30 min.
Claims (5)
1. A preparation method of high-saturation amorphous photonic crystal structure colored glaze is characterized by comprising the following steps;
the method comprises the following steps: taking 10-85% of clay with high iron content, 2-20% of feldspar, 8-20% of quartz and 5-50% of kaolin according to the mass ratio for mixing;
or mixing 5-50% black tailings, slag (such as iron tailings, manganese tailings, slag and the like), 5-20% feldspar, 5-15% quartz and 40-60% kaolin according to the mass ratio;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank;
step three: 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talcum and 4% of kaolin are taken according to the mass ratio, and tricalcium phosphate (Ca) with the total mass of 2% is added3(PO4)2) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and after the sample is cooled, preparing the amorphous photonic crystal structure colored glaze with high saturation.
2. The method for preparing the colored glaze with the high saturation amorphous photonic crystal structure according to claim 1, wherein in the second step, the rotating speed of a ball mill is 300r/min, the ball milling time is 40min, and the ratio of material to ball to water is 1:2: 0.6.
3. The method for preparing high-saturation colored glaze with amorphous photonic crystal structure according to claim 1, wherein in the second step, a tablet press is used for pressing the aged blank powder under the pressure of 25MPa, the blank powder is bisque-fired to 900 ℃ after being taken out, and the temperature is kept for 120 min.
4. The method for preparing the colored glaze with the high-saturation amorphous photonic crystal structure according to claim 1, wherein the rotating speed of a ball mill in the fourth step is 300r/min, the ball milling time is 40min, and the ratio of material to ball to water is 1:2: 0.8.
5. The method for preparing the colored glaze with the high saturation amorphous photonic crystal structure as claimed in claim 1, wherein the firing temperature in the fifth step is 1200-1350 ℃, and the temperature is maintained for 10-50 min.
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| CN116444252A (en) * | 2023-04-04 | 2023-07-18 | 天欣科技股份有限公司 | Manufacturing method of whole-body black gold-flash ceramic tile manufactured by slag |
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