CN114392199A - Hair conditioner without silicone oil and cations and having scalp care function and preparation method thereof - Google Patents
Hair conditioner without silicone oil and cations and having scalp care function and preparation method thereof Download PDFInfo
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- CN114392199A CN114392199A CN202210107492.9A CN202210107492A CN114392199A CN 114392199 A CN114392199 A CN 114392199A CN 202210107492 A CN202210107492 A CN 202210107492A CN 114392199 A CN114392199 A CN 114392199A
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- 229920002545 silicone oil Polymers 0.000 title claims abstract description 17
- 210000004761 scalp Anatomy 0.000 title claims abstract description 11
- 150000001768 cations Chemical class 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 239000004519 grease Substances 0.000 claims abstract description 20
- 239000012875 nonionic emulsifier Substances 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 6
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- 239000004973 liquid crystal related substance Substances 0.000 claims description 26
- 239000000839 emulsion Substances 0.000 claims description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 23
- 239000003921 oil Substances 0.000 claims description 23
- 235000019198 oils Nutrition 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 150000002191 fatty alcohols Chemical class 0.000 claims description 15
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 10
- 239000008158 vegetable oil Substances 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 229930182478 glucoside Natural products 0.000 claims description 9
- 150000008131 glucosides Chemical class 0.000 claims description 9
- 235000013399 edible fruits Nutrition 0.000 claims description 7
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- 244000144725 Amygdalus communis Species 0.000 claims description 3
- 235000011437 Amygdalus communis Nutrition 0.000 claims description 3
- 235000018330 Macadamia integrifolia Nutrition 0.000 claims description 3
- 240000000912 Macadamia tetraphylla Species 0.000 claims description 3
- 235000003800 Macadamia tetraphylla Nutrition 0.000 claims description 3
- 240000007817 Olea europaea Species 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- 239000008168 almond oil Substances 0.000 claims description 3
- 239000008163 avocado oil Substances 0.000 claims description 3
- 235000021302 avocado oil Nutrition 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- 239000010466 nut oil Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 239000007764 o/w emulsion Substances 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims 2
- 229920005862 polyol Polymers 0.000 claims 2
- 150000003077 polyols Chemical class 0.000 claims 2
- 230000003750 conditioning effect Effects 0.000 abstract description 5
- 229920006317 cationic polymer Polymers 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000003093 cationic surfactant Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000009960 carding Methods 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 208000003251 Pruritus Diseases 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007803 itching Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/066—Multiple emulsions, e.g. water-in-oil-in-water
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Birds (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention belongs to the field of daily chemicals, in particular relates to a hair conditioner which does not contain silicone oil and cations and has a scalp care function, and also relates to a preparation method of the hair conditioner. Besides essence and preservative, the invention also comprises (1) grease which is liquid at room temperature and accounts for 2-10% of the weight of the hair conditioner, (2) nonionic emulsifier which accounts for 2-8% of the weight of the hair conditioner, and (3) polyalcohol which accounts for 1-10% of the weight of the hair conditioner. The hair conditioner has better dry and wet hair conditioning effects than common hair conditioners, does not need to add cationic polymers and silicone oil, and has the advantages of simple raw material source, low cost and mild property.
Description
Technical Field
The invention belongs to the field of daily chemicals, in particular to a hair conditioner without silicone oil and cationic polymer, and also relates to a preparation method of the hair conditioner.
Background
Cosmetic emulsification techniques generally refer to liquid to semisolid emulsion technology systems of rheological significance such as, oil-in-water O/W emulsions, water-in-oil emulsions W/O, water-in-water emulsions W/W, oil-in-oil emulsions O/O; other special structure emulsion such as multi-layer emulsion W/O/W, O/W/O, liquid crystal emulsion O/LC/W, etc. And the basic control of the particle size can be realized technically.
Cosmetic products, whether they are skin and hair care systems, are largely different from the above systems. Most of emulsification technologies related to hair conditioners, hair membranes, hair lotions and the like in hair care products belong to oil-in-water O/W emulsion systems, and the oil-in-water O/W emulsion systems comprise O/W emulsion systems with liquid crystal structures (LC structures for short) and O/W emulsion systems without the liquid crystal structures.
The technical formulas of the hair care products on the market such as common hair conditioners belong to O/W emulsion systems mostly, the technical formulas comprise cationic surfactants such as quaternary ammonium salts 1631, 1831 and 2231, the cationic surfactants of the quaternary ammonium salts are used as an emulsifier and a hair conditioner in the hair conditioner formula respectively, and the hair conditioner formula also comprises dimethyl silicone oil and amino silicone oil conditioners. The hair conditioner containing the quaternary ammonium salt cationic surfactant can observe a liquid crystal structure under a polarized light microscope generally, but the liquid crystal arrangement is not dense enough, so that the hair conditioner is not effective for reducing hair friction. In addition, conditioners containing quaternary cationic surfactants are generally not mild enough, and quaternary cationic surfactants (e.g., 1631, 1831, 2231) are limited cosmetic materials and are generally not recommended for massaging or contacting the scalp when using conditioner products.
Disclosure of Invention
An object of the present invention is to provide a hair conditioner which is less abrasive to the hair and more lubricious when used, whether after rinsing or drying wet hair, and which is mild in the system, does not contain any cationic surfactant and silicone oil conditioner, and can be used as both a hair conditioner and a leave-on hair conditioner.
The invention also relates to a preparation method of the hair conditioner.
A hair conditioner with scalp care function without silicone oil and cation is characterized in that; except essence and preservative, the preservative comprises the following components in percentage by weight:
(1) the grease is liquid grease at room temperature and contains 2-10 wt%, wherein the grease is a mixture of nonpolar grease and polar grease according to the weight ratio of 1: 2 to 2: 1, wherein the nonpolar oil is mineral oil, the polar oil is vegetable oil, and the vegetable oil is natural vegetable oil with the oleic acid (C18:1) content of more than or equal to 50 percent and is selected from any one of macadamia nut oil, Bridgy fruit oil, sweet almond oil, olive fruit oil and avocado oil;
(2) contains 2-8 wt% of nonionic emulsifier, wherein the nonionic emulsifier is composed of fatty alcohol, stearic acid monoglyceride and cetylstearyl glucoside, and the content of monoester in stearic acid monoglyceride is 35-99%; the weight ratio of fatty alcohol, stearic acid monoglyceride and cetearyl glucoside in the nonionic emulsifier is 2: 1: 1, and the fatty alcohol is a C12 alcohol, a C14 alcohol, a C16 alcohol, and a C18 alcohol in a weight ratio of 1: 1: 1: 1 of the components in the ratio of (1),
(3) contains 1-10% of polyhydric alcohol by weight, wherein the polyhydric alcohol is any one of glycerol, propylene glycol and 1, 3-propylene glycol, and the glycerol is preferred in the invention;
(4) the balance of deionized water.
The invention relates to a hair conditioner without silicone oil and cation and with a scalp care function, which comprises the following production processes:
a) preparing liquid crystal oil-in-liquid (O/LC), heating a nonionic emulsifier to 75 ℃, adding water with the temperature of 75 ℃ while stirring (the adding amount of the water is equivalent to the weight of 1/10-1/2 nonionic emulsifier), continuously stirring, adding liquid grease while stirring to form uniform liquid crystal emulsion (liquid crystal oil-in-liquid emulsion (O/LC), wherein the particle size range of the liquid crystal structure is that PS is more than or equal to 5um and less than or equal to 25um, the temperature is kept at 40-45 ℃,
b) adding the oil-in-liquid emulsion O/LC of the a) into the rest deionized water, stirring at a low speed, and slowly cooling to 38 ℃ to form the oil-in-liquid-in-water O/LC/W emulsion.
The invention has the advantages of
The hair conditioner disclosed by the invention is of an O/LC/W structure of an oil-in-water liquid crystal emulsion, has better dry and wet hair conditioning effects than the common hair conditioner on the premise of not containing a quaternary ammonium salt type cationic conditioner and silicone oil used in the formula of the common hair conditioner, does not need to add a cationic polymer and silicone oil, and is simple in raw material source, low in cost and mild.
Drawings
FIG. 1 is an image of hair conditioner emulsion liquid crystal structure observed by microscope 4X objective.
Detailed Description
The present invention will be described in more detail with reference to examples.
The characteristics and the cautions of the components selected by the invention are described and explained in detail.
The non-ionic emulsifier is selected from an amphiphilic structure with an HLB value ranging from 2 to 13 and can also contribute to forming a seed crystal, namely a fatty alcohol liquid crystal structure with particles of a certain size, the non-ionic emulsifier selected in the invention is composed of fatty alcohol (HLB 1-3), stearic acid monoglyceride (HLB 3-5) and cetylstearyl glucoside (HLB 10-13), and the three non-ionic emulsifiers form a gradient in the range of HLB 2-13, namely HLB fatty alcohol < HLB stearic acid monoglyceride < HLB cetylstearyl glucoside. Wherein the fatty alcohol is C12 alcohol, C14 alcohol, C16 alcohol and C18 alcohol in a weight ratio of 1: 1: 1: 1, the content of monoester in the stearic acid monoglyceride is 30-90%; the weight ratio of fatty alcohol, stearic acid monoglyceride and cetearyl glucoside in the nonionic emulsifier is 2: 1: 1. the percentage or weight ratio of the emulsifier is favorable for the formation of large-particle fatty alcohol liquid crystal which plays a role in conditioning dry combing and wet combing of hair in the hair conditioner, thereby playing a key role in replacing silicone oil and cations and playing a conditioning role.
The grease is liquid at room temperature, and is prepared from nonpolar grease and polar grease in a weight ratio of 1: 2 to 2: 1, the non-polar grease is mineral oil, the polar grease is vegetable oil, the vegetable oil is selected from natural vegetable oil with the oleic acid (C18:1) content of more than or equal to 50%, and the natural vegetable oil is selected from any one of macadamia nut oil, Bridgkin fruit oil, sweet almond oil, olive fruit oil and avocado oil. The grease is selected to be liquid at room temperature and consists of nonpolar grease and polar grease, and is beneficial to formation of liquid crystal.
The polyhydric alcohol is any one of glycerol, propylene glycol and 1, 3-propylene glycol, and the glycerol is preferred in the invention. Glycerol contributes to the formation of liquid crystals and to the stabilization of the system.
Examples I to V
TABLE 1
Wherein:
the non-ionic emulsifier is composed of fatty alcohol, stearic acid monoglyceride and cetylstearyl glucoside, wherein the content of monoester in stearic acid monoglyceride is 60%; the weight ratio of fatty alcohol, stearic acid monoglyceride and cetearyl glucoside in the nonionic emulsifier is 2: 1: 1, and the fatty alcohol is a C12 alcohol, a C14 alcohol, a C16 alcohol, and a C18 alcohol in a weight ratio of 1: 1: 1: 1 in a certain proportion.
The grease is a mixture of nonpolar grease and polar grease in a weight ratio of 1: 1, wherein the nonpolar oil is mineral oil, and the polar oil is Bridgkin fruit oil;
the polyhydric alcohol is glycerol.
The preparation process comprises the following steps:
a) first preparation of the liquid Crystal oil (O/LC): heating a nonionic emulsifier to 75 ℃, adding water with the temperature of 75 ℃ while stirring (the adding amount of the water is equal to the weight of 1/10-1/2 nonionic emulsifier), continuously stirring, adding liquid grease with stirring and forming uniform liquid crystal emulsion (liquid crystal oil-in-liquid emulsion O/LC), wherein the particle size range of the liquid crystal structure is more than or equal to 5um and less than or equal to 25um PS (shown in figure 1), and the temperature is kept at 40-45 ℃;
b) preparation of liquid-in-water oil-in-liquid O/LC/W: adding the oil-in-liquid-crystal emulsion O/LC in the step a) into the rest deionized water, stirring at a low speed, and slowly cooling to 38 ℃ to form the oil-in-liquid-crystal-in-water O/LC/W emulsion.
Efficacy verification
Hair combing test
The test instrument used an Instron hair comb to test the wet combing work when the hair was treated with the conditioner sample and the dry combing work after the hair was treated with the conditioner sample, each group of samples was tested 10 times and the average was taken.
Blank: hair treated without conditioner and combing work mJ,
sample preparation: tresses treated with conditioner and combing work mJ,
percent remaining carding work%,
the smaller the remaining percent carding work% ratio, the better the carding performance.
The carding work% remaining test results are as follows (see table 2):
EXAMPLES I-V Hair conditioner vs. COMPARATIVE 1 (commercially available conditioner containing cation)
EXAMPLES I-V Hair conditioner vs. 2 (commercial conditioner containing cation and silicone oil)
TABLE 2
Table 2 combing work test results show: the% remaining work values (H-mJ for wet combing and D-mJ for dry combing) of the conditioners of examples I-V of the invention were all less than the% remaining work values (comparative 1 and comparative 2) for commercial conditioners containing cations and silicone oils, respectively. It is illustrated that examples I-V of the present invention, which do not contain a cationic and silicone oil, have superior dry/wet combing properties than conditioners containing a cationic and silicone oil.
The invention has mild property
The raw materials used by the hair conditioner disclosed by the invention are all in skin-care grade, and do not contain any cationic polymers (cosmetic limiting substances) such as 1631, 1831 and 2231 for hair conditioners, so that the hair conditioner disclosed by the invention can be used for conditioning hair and also can be used for nursing scalp, and is good in mildness.
Use comfort clinical test method:
the samples of preparation examples I-V and comparative examples 1 and 2 were distributed to 10 subjects belonging to dry scalp, and before use, hair was cleansed with shampoo, and then a proper amount of each sample of preparation examples or comparative examples was applied to scalp and hair, and then rinsed with water, and applied every other day for one week continuously, and the rating scale was 10 points, 1 point (scalp itching, no effect) representing the worst, and 10 points (scalp comfortable, no dryness and no itching) representing the best. And finally, taking the average value of the scores of 10 tested persons, wherein the higher the score is, the better the effect is. The evaluation shows that the hair conditioner has obvious superiority compared with the traditional hair conditioner. The evaluation results are shown in Table 3
TABLE 3 evaluation of comfort of use statistics
Claims (3)
1. A hair conditioner which does not contain silicone oil and cations and has a scalp care function is characterized in that; except essence and preservative, the preservative comprises the following components in percentage by weight:
(1) the oil which is liquid at room temperature and accounts for 2-10% of the hair conditioner by weight percentage is non-polar oil and polar oil, and the weight ratio of the oil to the non-polar oil to the polar oil is 1: 2 to 2: 1, wherein the nonpolar oil is mineral oil, the polar oil is vegetable oil, and the vegetable oil is natural vegetable oil with the oleic acid (C18:1) content of more than or equal to 50 percent and is selected from any one of macadamia nut oil, Bridgy fruit oil, sweet almond oil, olive fruit oil and avocado oil;
(2) the hair conditioner comprises a hair conditioner body, a nonionic emulsifier which accounts for 2-8% of the hair conditioner body in weight percentage, wherein the nonionic emulsifier is composed of fatty alcohol, stearic acid monoglyceride and cetearyl glucoside, and the content of monoester in the stearic acid monoglyceride is 30-99%; the weight ratio of fatty alcohol, stearic acid monoglyceride and cetearyl glucoside in the nonionic emulsifier is 2: 1: 1, and the fatty alcohol is a C12 alcohol, a C14 alcohol, a C16 alcohol, and a C18 alcohol in a weight ratio of 1: 1: 1: 1 in proportion;
(3) the hair conditioner comprises 1-10 wt% of a polyol, wherein the polyol is any one of glycerol, propylene glycol and 1, 3-propylene glycol.
(4) The balance of deionized water.
2. The hair conditioner according to claim 1, wherein the polyhydric alcohol is preferably glycerin.
3. The hair conditioner according to claim 1, which is produced by a process comprising:
a) preparing (O/LC) liquid crystal oil-in-liquid, heating a nonionic emulsifier to 75 ℃, adding water with the temperature of 75 ℃ while stirring, wherein the adding amount of the water is equal to the weight of 1/10-1/2 nonionic emulsifier, continuously stirring, adding liquid grease while stirring, and forming uniform liquid crystal emulsion, namely the O/LC liquid crystal oil-in-liquid emulsion, wherein the particle size range of the liquid crystal structure is that PS is more than or equal to 5um and less than or equal to 25um, the temperature is kept at 40-45 ℃,
b) and adding the liquid crystal oil-in-water emulsion O/LC into the rest deionized water, stirring at a low speed, and slowly cooling to 38 ℃ to form the liquid crystal oil-in-water O/LC/W emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210107492.9A CN114392199B (en) | 2022-01-28 | 2022-01-28 | Hair conditioner with scalp care function and containing no silicone oil and cations and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210107492.9A CN114392199B (en) | 2022-01-28 | 2022-01-28 | Hair conditioner with scalp care function and containing no silicone oil and cations and preparation method thereof |
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| CN114392199A true CN114392199A (en) | 2022-04-26 |
| CN114392199B CN114392199B (en) | 2024-03-19 |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004143093A (en) * | 2002-10-24 | 2004-05-20 | Kose Corp | Hair conditioning composition |
| US20040115158A1 (en) * | 2001-04-12 | 2004-06-17 | Ludwig Schieferstein | Cosmetic preparations |
| CN102438581A (en) * | 2009-05-19 | 2012-05-02 | 株式会社资生堂 | Cosmetic preparation |
| CN102470088A (en) * | 2009-06-30 | 2012-05-23 | 考格尼斯知识产权管理有限责任公司 | Ester mixtures and compositions comprising such ester mixtures |
| CN102470087A (en) * | 2009-06-30 | 2012-05-23 | 考格尼斯知识产权管理有限责任公司 | Ester mixtures and compositions comprising such ester mixtures |
| CN107714492A (en) * | 2016-08-12 | 2018-02-23 | 伽蓝（集团）股份有限公司 | A kind of multiplet emulsion containing liquid crystal structure and preparation method thereof |
| CN111603395A (en) * | 2020-05-27 | 2020-09-01 | 山东大学 | Whitening and moisturizing emulsion containing lamellar liquid crystal and preparation method thereof |
-
2022
- 2022-01-28 CN CN202210107492.9A patent/CN114392199B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040115158A1 (en) * | 2001-04-12 | 2004-06-17 | Ludwig Schieferstein | Cosmetic preparations |
| JP2004143093A (en) * | 2002-10-24 | 2004-05-20 | Kose Corp | Hair conditioning composition |
| CN102438581A (en) * | 2009-05-19 | 2012-05-02 | 株式会社资生堂 | Cosmetic preparation |
| CN102470088A (en) * | 2009-06-30 | 2012-05-23 | 考格尼斯知识产权管理有限责任公司 | Ester mixtures and compositions comprising such ester mixtures |
| CN102470087A (en) * | 2009-06-30 | 2012-05-23 | 考格尼斯知识产权管理有限责任公司 | Ester mixtures and compositions comprising such ester mixtures |
| CN107714492A (en) * | 2016-08-12 | 2018-02-23 | 伽蓝（集团）股份有限公司 | A kind of multiplet emulsion containing liquid crystal structure and preparation method thereof |
| CN111603395A (en) * | 2020-05-27 | 2020-09-01 | 山东大学 | Whitening and moisturizing emulsion containing lamellar liquid crystal and preparation method thereof |
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