CN114369899A - Light warm sweat-discharging fabric and preparation method thereof - Google Patents

Light warm sweat-discharging fabric and preparation method thereof Download PDF

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Publication number
CN114369899A
CN114369899A CN202210030592.6A CN202210030592A CN114369899A CN 114369899 A CN114369899 A CN 114369899A CN 202210030592 A CN202210030592 A CN 202210030592A CN 114369899 A CN114369899 A CN 114369899A
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fabric
preparation
solution
light warm
grey cloth
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贾右兵
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Shanghai Xiaolanxiang Garment Co ltd
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Shanghai Xiaolanxiang Garment Co ltd
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/18Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/41Amides derived from unsaturated carboxylic acids, e.g. acrylamide
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28Acrylonitrile; Methacrylonitrile
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38Polyurethanes
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/10Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Abstract

The invention discloses a light warm perspiring fabric and a preparation method thereof, wherein double-resistant acrylic fibers, Modal and heat-insulating acrylic fibers are mixed to prepare siro compact spun yarns, the siro compact spun yarns are interwoven with polyester low stretch yarns at intervals, spandex is added to prepare plain weave fabrics with dense roots, and the light warm perspiring fabrics are prepared through blank setting → dyeing → scutching → sizing drying → shearing → finished product sizing → cloth inspection. According to the invention, the hand feeling of the fabric is improved through the shaping process, the coil position is adjusted through heat shaping, the fabric tissue specification is stabilized, pretreatment is carried out in dyeing, the dye uptake is improved, the far infrared thermal performance of the fabric is endowed, and the specification is 140g/m2The heat preservation rate of the light warm perspiration fabric is 23.4 percent, which is higher than that of the pure cotton fabric with the same gram weight.

Description

Light warm sweat-discharging fabric and preparation method thereof
Technical Field
The invention belongs to the technical field of textiles, and particularly relates to a light warm sweat-releasing fabric and a preparation method thereof.
Background
The human body system is fragile, the normal temperature range is narrow, and the thermal comfort is important to the health and the safety of the human body. It is generally considered that the normal temperature range of a human body at rest is only 36 to 38 ℃. Both low and high temperatures can have adverse health effects, resulting in respiratory infections and heart related diseases. The clothing is used as an interface for exchanging energy between the human body and the surrounding air, and plays a key role in thermal comfort of the human body. Therefore, the development of thermal management fabrics is of great interest in the field of personal thermal comfort research.
In the prior art, by improving the heat transfer between the human body and its local environment, effective temperature regulation of the human body can be achieved, thereby enhancing thermal comfort. The infrared transparent nanometer porous polyethylene textile can radiate heat radiation in a middle infrared wavelength range to the maximum extent, so that radiation cooling is realized. The low emissivity textile can reduce the transmittance of mid-infrared wavelength radiation, thereby producing a warming effect. The composite material prepared by the materials such as the woven aramid fiber, the metal nanowire, the reduced graphene oxide, the polydimethylsiloxane and the like has a good warming effect. However, most of the currently investigated thermal management textiles are based on thermal conduction, which is bulky, heavy, air impermeable, not self-regulating, and does little to improve thermal comfort. In addition, the manufacturing processes for these advanced thermal textiles are often complex and expensive, making mass production difficult.
CN 105239398A discloses a sweat-discharging pajama fabric, which is woven by the following raw materials in parts by weight: 20-40 parts of Coolmax fiber, 60-80 parts of regenerated cellulose fiber and 1-5 parts of spandex. Aiming at the characteristics of moisture-absorbing and sweat-releasing fiber Coolmax, regenerated cellulose fiber and spandex, in the fabric after-finishing process, comparison tests are carried out on the fabric hand feeling, color and moisture-absorbing effect, the moisture-absorbing and sweat-releasing auxiliary agent varieties are screened and compared, and an optimal after-finishing process and an optimal moisture-absorbing effect functional auxiliary agent formula which are suitable for fabric products with different raw material ratios, different qualities and different colors are groped; the sweat-releasing pajama fabric disclosed by the invention is smooth and soft in hand feeling, good in drapability, good in moisture-absorbing and sweat-releasing effect, pure in gloss and excellent in quality, and the internal physical index test of the sweat-releasing pajama fabric meets the standard, so that the sweat-releasing pajama fabric can completely meet the requirements of comfort, ventilation and coolness of a wearer, and is the best choice of the moisture-absorbing and sweat-releasing fabric. The process is convenient to operate and suitable for mass production processes. However, the moisture-absorbing and sweat-releasing finishing agent prepared by the method has the defects of easy falling and water washing resistance, and the fabric has low content of functional substances and unobvious effect.
CN 109288143A relates to a trinity uterus warming trousers of drawing abdomen of seamless no trace, including the uterus warming trousers body, the uterus warming trousers body is the uterus warming trousers body of seamless cylinder, the internal surface of uterus warming trousers body corresponds human belly and is equipped with the functional layer, the functional layer include the precoat and set up in a plurality of uterus warming functional area and a plurality of temperature sensing discoloration district on the far infrared surface fabric, the surface printing of uterus warming functional area has trinity coating, trinity coating includes nanometer anion powder, chitin, nanometer far infrared powder. The uterus warming trousers are seamlessly woven into a seamless cylinder shape by adopting the cylinder, so that all parts of the whole uterus warming trousers are seamlessly connected without generating a seam bone, and the uterus warming trousers are comfortable to wear, high in skin affinity and good in air permeability; the effects of resisting bacteria, warming uterus, improving metabolism, promoting toxin expelling and the like of the uterus warming trousers can be improved by arranging the uterus warming functional area, and the temperature rise condition of the uterus warming trousers can be known in real time through the color change condition by arranging the temperature sensing color changing area. However, the method adopts a printing mode to coat the far infrared powder, has the defects of poor water washing resistance and easy falling of functional materials, and has weak far infrared performance, unobvious color change of the coating, and difficult realization of related functions.
The preparation method of the light-warm sweat-discharging fabric provided by the invention has an obvious effect on improving the personal heat-humidity comfort, the manufacturing method can be used for mass production to meet the requirements of heat-humidity comfort textiles, and a novel light-warm sweat-discharging fabric is creatively invented.
Disclosure of Invention
In view of the defects of the prior art, the technical problem to be solved by the invention is to provide the light-warm sweat-discharging fabric and the preparation method thereof, the light-warm sweat-discharging fabric is simple in preparation method, the heat generated by a human body can be completely reflected back through underwear in the wearing process and then radiated to the body again, and the fabric is light and thin and has excellent sweat discharging performance. The preparation steps are as follows:
a preparation method of a light warm sweat-discharging fabric comprises the following steps:
step 1, spinning: mixing the double-resistance acrylic fibers, the Modal fibers and the heat-insulation acrylic fibers uniformly to prepare a siro compact spinning yarn;
step 2, weaving: weaving by adopting a weft circular knitting machine, feeding and interweaving siro compact spun yarns and polyester low stretch yarns at intervals, and adding spandex to weave a dense-root plain fabric:
and step 3, post-processing: the post-processing procedure is carried out by adopting the following processing flow in sequence, namely blank fixing → dyeing → scutching → shaping and drying → shearing → finished product shaping → cloth inspection, and the light and warm sweat-releasing fabric is prepared.
Preferably, the mass percentages of the double-resistant acrylic fibers, the modal fibers, the heat-insulating acrylic fibers in the step 1 are 30-50%, 30-45% and 15-30%.
Preferably, the linear density of the single double-resistant acrylic fiber in the step 1 is less than 1.0dtex, and the fiber length is 35-40 mm.
Preferably, the density of the semi-dull functional polyester low-elasticity yarns in the step 2 is 60-80D, and the number of holes is 80-120F; the mass ratio of the semi-dull functional polyester low stretch yarn to the siro compact spun yarn is 1: (2-4).
Preferably, the linear density of the spandex in the step 2 is 20-40D, and the mass ratio of the siro compact spun yarn to the spandex is 1: (0.1-0.4).
Preferably, in the step 2, the specification of the plain weave fabric with dense roots is 165-175 cm in width, and the gram weight is 135-145 g/m2
Preferably, the blank setting process parameters in the step 3 are as follows: the temperature is 185-195 ℃, the machine speed is 18-22 m/min, and the width of the machine frame is 170-190 cm.
The blank setting process in the treatment step is to heat the fiber to ensure that the molecular chain segments of the fiber are rearranged through thermal motion, thereby eliminating the internal stress, eliminating the crease existing on the fabric, keeping better dimensional stability, facilitating subsequent dyeing and being not easy to shrink at high temperature.
Preferably, the dyeing in step 3 comprises the following processing steps:
s1, soaking the gray fabric in absolute ethyl alcohol, washing with water, and drying to obtain a clean gray fabric; dissolving ferrocene in absolute ethyl alcohol, soaking the cleaned grey cloth in the solution, taking out and drying to obtain ferrocene grey cloth;
s2, adding 11-maleamidoundecanoic acid into toluene to prepare a solution, and soaking the ferrocene gray fabric prepared by the S1 into the solution; then dripping 3-acetylpyrrole into the solution, standing for reaction, taking out the grey cloth, standing and drying to obtain pretreated grey cloth;
s3, adding anhydrous sodium sulphate into water, adjusting the pH value by adopting acetic acid, then adding disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, adding the pretreated gray fabric prepared in the S2 into the dye solution for dyeing, raising the temperature of the solution, and adding an aqueous solution of sodium carbonate for reaction; then cooling at normal temperature, and taking out the grey cloth.
The inventor carries out a large number of experiments, ferrocene and 11-maleamidoundecanoic acid are added, can be connected with grey cloth through hydrogen bonds and continuously coated on the grey cloth, the surface of the grey cloth is covered with a long-chain group of 11-maleamidoundecanoic acid, 3-acetylpyrrole is introduced through vapor deposition, pyrrole polymerization reaction is carried out, and the grey cloth with photo-thermal performance is obtained. The modified grey cloth has good dyeing and photo-thermal properties. In simulated sunlight, it can be bonded to the surface of a material by in-situ chemical oxidative polymerization, vapor deposition polymerization, and electrochemical polymerization. Among them, chemical vapor deposition polymerization is a simple and effective method for depositing a polymer on a substrate. 11-maleamidoundecanoic acid is an ideal surface modifier, and due to the long alkyl chain, the surface energy of the material can be obviously reduced, the addition of 11-maleamidoundecanoic acid reduces the surface energy, while the polymerization of 3-acetylpyrrole increases the surface roughness of the fiber, and the active groups on the rough surface are increased. The fiber with the rough surface is easy to fully contact with the dye, and the dye-uptake rate is higher. The modified grey cloth has obvious photothermal conversion characteristic, and the main absorption peak of the grey cloth is subjected to absorption conversion in a near infrared region due to the conjugated structure of polypyrrole. In addition, the 3-acetyl pyrrole has lower fluorescence emission capability, so that the modified grey cloth can effectively convert most of absorbed light energy into heat energy, and the fabric is endowed with a warm-keeping effect.
The modified grey cloth is further dyed, and the active groups of the modified grey cloth are increased, so that the modified grey cloth is beneficial to being combined with dye molecules in the dyeing process, the dye uptake is improved, and the color fastness is enhanced.
Preferably, the setting and drying process parameters in the step 3 are as follows: the temperature is 128-132 ℃, the machine speed is 19-21 m/min, and the width of the machine frame is 170-175 cm.
Preferably, the shearing process parameters in the step 3 are as follows: the speed is 20 to 30m/min, and the tension is 20 to 30N.
Preferably, the method for shaping the product in step 3 comprises: the setting temperature is controlled to be 110-130 ℃, the machine speed is 10-20 m/min, and the width of the setting blank is 150-200 cm.
Further preferably, the dyeing in step 3 comprises the following steps in parts by weight:
s1, weighing 1-3 parts of grey cloth after blank fixing, soaking the grey cloth in 15-30 parts of absolute ethyl alcohol for 3-10 minutes, washing the grey cloth with water for 1-3 times, and drying the grey cloth in an oven at 40-70 ℃ for 3-8 hours to obtain clean grey cloth; dissolving 0.5-1 part of ferrocene in 8-12 parts of absolute ethyl alcohol, stirring, completely dissolving, putting the cleaned grey cloth into the solution, soaking for 0.5-2 h, taking out, and drying for 1-3 h at 40-55 ℃ in an oven to obtain ferrocene grey cloth;
s2, weighing 0.5-1 part of 11-maleamidoundecanoic acid, adding the 11-maleamidoundecanoic acid into 15-25 parts of toluene to prepare a solution, and soaking the ferrocene gray fabric prepared by the S1 in the solution for 20-40 min; then, 0.1-0.3 part of 3-acetylpyrrole is dripped into the solution, the solution is kept stand for 10-30 min, the solution is taken out and kept stand for 1-3 h at normal temperature, and the solution is dried for 3-5 h at 50-70 ℃ to obtain pretreated gray fabric;
s3, weighing 0.1-0.5 part of anhydrous sodium sulphate, adding 15-20 parts of 50-60 ℃ water, adjusting the pH to 6.0-6.5 by adopting acetic acid, then adding 0.1-0.5 disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, adding the pretreated gray fabric prepared by S2 into the dye solution, dyeing for 15-30 min, raising the temperature of the solution to 60-70 ℃, adding 1-2 parts of 0.3-0.8 g/L sodium carbonate aqueous solution, and reacting for 40-60 min; then cooling at normal temperature, and taking out the grey cloth.
The invention has the beneficial effects that:
(1) the invention improves the hand feeling of the fabric through the shaping process, and stabilizes the fabric tissue specification by adjusting the coil position through heat shaping.
(2) The specification of the light warm sweat-removing fabric prepared by the invention is 140g/m2The heat preservation rate of the fabric is 23.4 percent, which is higher than that of a pure cotton fabric with the same gram weight.
(3) Ferrocene and 11-maleamidoundecanoic acid are connected with grey cloth through hydrogen bonds and continuously coated on the grey cloth, and then 3-acetylpyrrole is introduced through vapor deposition to generate pyrrole polymerization reaction, so that the dyed grey cloth obtained after treatment has increased dye uptake and color fastness, and has photo-thermal performance and enhanced heat retention.
Detailed Description
Ferrocene: shandong Changhui chemical Co., Ltd, goods number: a635, content 99.9%, CAS number: 102-54-5.
11-maleimidoundecanoic acid, Shanghai Ji to Biochemical technology, Ltd., molecular weight: 281.347, CAS number: 57079-01-3.
3-acetylpyrrole: wuhananabai pharmaceutical chemicals ltd, molecular weight: 109.13, CAS number: 1072-82-8.
The other raw materials which are not mentioned are common raw materials, and the grade is industrial grade or above.
The double-resistant acrylic fibers refer to anti-pilling and antistatic acrylic fibers; the double-resistance acrylic fibers in the embodiment of the invention are Dongyang spun silk double-resistance acrylic fibers, the linear density of a single fiber is less than 1.0dtex, and the fiber length is 35-40 mm.
The thermal insulation acrylic fiber is prepared from special fibers of Jiangjiade, Zhejiang, and has the linear density of 1.0-1.5 dtex, the fiber length of 70-80 mm, and the elongation at break of 10-26%.
Example 1
A preparation method of a light warm sweat-discharging fabric comprises the following steps:
step 1, spinning: uniformly mixing 40kg of double-resistant acrylic fibers, 38kg of modal fibers and 22kg of heat-insulating acrylic fibers, and preparing a siro compact spinning yarn by adopting siro compact spinning, wherein the density of the siro compact spinning yarn is 36 tex;
step 2, weaving: weaving by using a circular weft knitting machine, feeding 60kg of siro compact spun yarn and 20kg of semi-dull functional polyester low stretch yarn of 75D/100F into the loom alternately, adding 18kg of 30D spandex to weave a dense root plain fabric, wherein the fabric width is 170cm, and the gram weight is 140g/m2
And step 3, post-processing: the post-processing procedure is carried out by the following processing procedures in sequence, namely, blank setting → dyeing → scutching → sizing and drying → shearing → finished product sizing → cloth inspection, and blank setting process parameters: the temperature is 190 ℃, the machine speed is 20m/min, and the width of the frame is 180 cm; the parameters of the sizing and drying process are as follows: the temperature is 130 ℃, the machine speed is 20m/min, and the width of the machine frame is 173 cm; shearing technological parameters: the speed is 25m/min, and the tension is 25N; the finished product setting parameters are as follows: setting temperature is controlled at 120 ℃, the machine speed is 15m/min, and the breadth of the setting blank is 170 cm; the fabric with the functions of warming and perspiration is prepared.
The dyeing process in the step 3 comprises the following steps:
s1, weighing 2kg of blank-shaped gray fabric, soaking the blank-shaped gray fabric in 20kg of absolute ethyl alcohol for 5 minutes, washing the blank-shaped gray fabric with water for 2 times, and drying the blank-shaped gray fabric in an oven at 60 ℃ for 6 hours to obtain a clean gray fabric; dissolving 0.8kg of ferrocene in 10kg of absolute ethyl alcohol, stirring, completely dissolving, putting the cleaned grey cloth into the solution, soaking for 1h, taking out, and drying for 2h at 50 ℃ in an oven to obtain ferrocene grey cloth;
s2, weighing 0.7kg of 11-maleamidoundecanoic acid, adding into 20kg of toluene to prepare a solution, and soaking the ferrocene gray fabric prepared in the S1 into the solution for 30 min; then 0.2kg of 3-acetylpyrrole is dripped into the solution, the solution is kept stand for 20min, the solution is taken out and kept stand for 2h at normal temperature, and then the solution is dried in an oven at 60 ℃ for 4h to obtain pretreated gray fabric;
s3, weighing 0.3kg of anhydrous sodium sulphate, adding the anhydrous sodium sulphate into 18kg of water at 55 ℃, adjusting the pH to 6.2 by adopting acetic acid, then adding 0.2kg of disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, adding the pretreated gray fabric prepared by the S2 into the dye solution, dyeing for 18min, raising the temperature of the solution to 65 ℃, adding 1.5kg of 0.5g/L sodium carbonate aqueous solution, and reacting for 55 min; then cooling at normal temperature, and taking out the grey cloth.
Example 2
The preparation method of the light warm sweat-discharging fabric is basically the same as that of the embodiment 1, and the only difference is that: the dyeing process in step 3 is different.
The dyeing process in step 3 of this example was as follows:
s1, weighing 2kg of blank-shaped gray fabric, soaking the blank-shaped gray fabric in 20kg of absolute ethyl alcohol for 5 minutes, washing the blank-shaped gray fabric with water for 2 times, and drying the blank-shaped gray fabric in an oven at 60 ℃ for 6 hours to obtain a clean gray fabric; soaking the cleaned grey cloth in 10kg of absolute ethyl alcohol for 1h, taking out, and drying in an oven at 50 ℃ for 2h to obtain dried grey cloth;
s2, weighing 0.7kg of 11-maleamidoundecanoic acid, adding into 20kg of toluene to prepare a solution, and soaking the dried gray fabric prepared in the S1 state in the solution for 30 min; then 0.2kg of 3-acetylpyrrole is dripped into the solution, the solution is kept stand for 20min, the solution is taken out and kept stand for 2h at normal temperature, and then the solution is dried in an oven at 60 ℃ for 4h to obtain pretreated gray fabric;
s3, weighing 0.3kg of anhydrous sodium sulphate, adding the anhydrous sodium sulphate into 18kg of water at 55 ℃, adjusting the pH to 6.2 by adopting acetic acid, then adding 0.2kg of disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, adding the pretreated gray fabric prepared by the S2 into the dye solution, dyeing for 18min, raising the temperature of the solution to 65 ℃, adding 1.5kg of 0.5g/L sodium carbonate aqueous solution, and reacting for 55 min; then cooling at normal temperature, and taking out the grey cloth.
Example 3
The preparation method of the light warm sweat-discharging fabric is basically the same as that of the embodiment 1, and the only difference is that: the dyeing process in step 3 is different.
The dyeing process in step 3 of this example was as follows:
s1, weighing 2kg of blank-shaped gray fabric, soaking the blank-shaped gray fabric in 20kg of absolute ethyl alcohol for 5 minutes, washing the blank-shaped gray fabric with water for 2 times, and drying the blank-shaped gray fabric in an oven at 60 ℃ for 6 hours to obtain a clean gray fabric; dissolving 0.8kg of ferrocene in 10kg of absolute ethyl alcohol, stirring, completely dissolving, putting the cleaned grey cloth into the solution, soaking for 1h, taking out, and drying for 2h at 50 ℃ in an oven to obtain ferrocene grey cloth;
s2, soaking the ferrocene gray fabric prepared in the S1 in 20kg of methylbenzene for 30 min; then 0.2kg of 3-acetylpyrrole is dropped into toluene, and the mixture is kept stand for 20min, taken out, kept stand for 2h at normal temperature, and then dried in an oven at 60 ℃ for 4h to obtain pretreated gray fabric;
s3, weighing 0.3kg of anhydrous sodium sulphate, adding the anhydrous sodium sulphate into 18kg of water at 55 ℃, adjusting the pH to 6.2 by adopting acetic acid, then adding 0.2kg of disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, adding the pretreated gray fabric prepared by the S2 into the dye solution, dyeing for 18min, raising the temperature of the solution to 65 ℃, adding 1.5kg of 0.5g/L sodium carbonate aqueous solution, and reacting for 55 min; then cooling at normal temperature, and taking out the grey cloth.
Example 4
The preparation method of the light warm sweat-discharging fabric is basically the same as that of the embodiment 1, and the only difference is that: the dyeing process in step 3 is different.
The dyeing process in step 3 of this example was as follows:
s1, weighing 2kg of blank-shaped gray fabric, soaking the blank-shaped gray fabric in 20kg of absolute ethyl alcohol for 5 minutes, washing the blank-shaped gray fabric with water for 2 times, and drying the blank-shaped gray fabric in an oven at 60 ℃ for 6 hours to obtain a clean gray fabric; dissolving 0.8kg of ferrocene in 10kg of absolute ethyl alcohol, stirring, completely dissolving, putting the cleaned grey cloth into the solution, soaking for 1h, taking out, and drying for 2h at 50 ℃ in an oven to obtain ferrocene grey cloth;
s2, weighing 0.7kg of 11-maleamidoundecanoic acid, adding into 20kg of toluene to prepare a solution, and soaking the ferrocene gray fabric prepared in the S1 into the solution for 30 min; taking out, standing at normal temperature for 2h, and baking in an oven at 60 ℃ for 4h to obtain pretreated gray fabric;
s3, weighing 0.3kg of anhydrous sodium sulphate, adding the anhydrous sodium sulphate into 18kg of water at 55 ℃, adjusting the pH to 6.2 by adopting acetic acid, then adding 0.2kg of disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, adding the pretreated gray fabric prepared by the S2 into the dye solution, dyeing for 18min, raising the temperature of the solution to 65 ℃, adding 1.5kg of 0.5g/L sodium carbonate aqueous solution, and reacting for 55 min; then cooling at normal temperature, and taking out the grey cloth.
Comparative example 1
The preparation method of the light warm sweat-discharging fabric is basically the same as that of the embodiment 1, and the only difference is that: the dyeing process in step 3 is different.
The dyeing process in step 3 of this example was as follows:
s1, weighing 2kg of blank-shaped gray fabric, soaking the blank-shaped gray fabric in 20kg of absolute ethyl alcohol for 5 minutes, washing the blank-shaped gray fabric with water for 2 times, and drying the blank-shaped gray fabric in an oven at 60 ℃ for 6 hours to obtain a clean gray fabric; soaking the cleaned grey cloth in 10kg of absolute ethyl alcohol for 1h, taking out, and drying in an oven at 50 ℃ for 2h to obtain dried grey cloth;
s2, soaking the dried gray fabric prepared in the S1 process in 20kg of methylbenzene for 30 min; taking out, standing at normal temperature for 2h, and baking in an oven at 60 ℃ for 4h to obtain pretreated gray fabric;
s3, weighing 0.3kg of anhydrous sodium sulphate, adding the anhydrous sodium sulphate into 18kg of water at 55 ℃, adjusting the pH to 6.2 by adopting acetic acid, then adding 0.2kg of disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, adding the pretreated gray fabric prepared by the S2 into the dye solution, dyeing for 18min, raising the temperature of the solution to 65 ℃, adding 1.5kg of 0.5g/L sodium carbonate aqueous solution, and reacting for 55 min; then cooling at normal temperature, and taking out the grey cloth.
Comparative example 2
The preparation method of the light warm sweat-discharging fabric is basically the same as that of the embodiment 1, and the only difference is that: the dyeing process in step 3 is different.
The dyeing process in step 3 of this example was as follows:
s1, weighing 0.3kg of anhydrous sodium sulphate, adding the anhydrous sodium sulphate into 18kg of water at 55 ℃, adjusting the pH to 6.2 by adopting acetic acid, then adding 0.2kg of disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, weighing 2kg of grey cloth fixed by a blank, adding the grey cloth into the dye solution, dyeing for 18min, raising the temperature of the solution to 65 ℃, adding 1.5kg of 0.5g/L sodium carbonate aqueous solution, and reacting for 55 min; then cooling at normal temperature, and taking out the grey cloth.
Test example 1
Far infrared performance test
The test sample material is tested according to GB/T30127 plus 2013 detection and evaluation of far infrared performance of textiles, and the tested far infrared emissivity and the far infrared radiation temperature rise value are used as indexes for measuring the far infrared performance of the test sample.
3 emissivity and temperature rise test specimens are cut from each sample, and the samples are taken at the flat test specimens, wherein the diameter of the test specimens is 60 mm.
Humidifying according to the temperature and humidity environment and the program of the standard atmosphere specified in GB/T6529 + 2008 Standard atmosphere for humidifying and testing textiles, no influence on the indoor environment by other heat radiation sources is caused, testing each sample for three times, and taking the average value of the results of the three times, wherein the test results are shown in Table 1.
TABLE 1 far infrared Performance test results
Figure BDA0003466303600000101
Figure BDA0003466303600000111
It can be seen from table 1 that the far infrared effect of example 1 is the best, the effects of examples 2 to 4 are slightly poor, and the effects of comparative examples 1 to 2 are the worst, probably because ferrocene and 11-maleamidoundecanoic acid in example 1 are connected with the grey cloth through hydrogen bonds and continuously coated on the fabric, the surface of the fabric is coated with a long-chain group of 11-maleamidoundecanoic acid, 11-maleamidoundecanoic acid is an ideal surface modifier, the surface energy of the material can be significantly reduced due to the long alkyl chain, the surface energy is reduced due to the addition of 11-maleamidoundecanoic acid, 3-acetylpyrrole can be better introduced through vapor deposition, pyrrole polymerization occurs, and the conjugated structure of polypyrrole indicates that the absorption conversion of the main absorption peak occurs in the near infrared region. In addition, the 3-acetyl pyrrole has lower fluorescence emission capability, so that the modified fabric can effectively convert most of absorbed light energy into heat energy, and the fabric is endowed with a warm-keeping effect.
Test example 2
Moisture absorption quick drying Performance test
The test is referred to the standard GB/T21655.1-2008, evaluation of moisture absorption quick drying of textiles part 1: single combinatorial testing approach "; the washing process adopts an A-type standard washing machine and an A1-type overturning dryer according to GB/T8629-2017 household washing and drying program for textile test, cotton-type washing objects are selected, and a standard detergent 2, 4N washing program is added. The fabric moisture absorption rate, the dripping diffusion time, the wicking height in the weft weaving direction, the evaporation rate and the moisture permeability before and after washing are tested, each sample is tested for three times, and the moisture absorption and quick drying performance of the fabric is comprehensively judged. The results are shown in Table 2.
Table 2 moisture absorption quick drying property test results
Figure BDA0003466303600000112
Figure BDA0003466303600000121
It can be seen from table 2 that the moisture absorption quick drying performance of all the samples is slightly increased after washing, probably because the flexibility of the fiber is increased after washing, the covered water-repellent substances such as grease are reduced, and the moisture absorption quick drying performance of the fabric is enhanced. The best moisture absorption and quick drying performance of the fabric in the embodiment 1 is probably because the modified fabric has more surface active groups and enhanced hydrophilicity.
Test example 3
Soaping color fastness test
The test is carried out according to the test standard of GB/T3921-2008 'soaping color fastness resistance of textile color fastness test'. A sample of a sample to be tested is taken, and the sample is clamped between two single fibers with the diameter of 40mm multiplied by 100mm and pasted with cotton lining. Washing for 30min by rinsing. And after the experiment is finished, taking out the sample, cleaning the sample by using clear water, extruding excessive water on the sample, drying the sample, comparing the original sample by using a gray sample card, and evaluating the discoloration of the sample and the staining of the cotton lining fabric. The test results are shown in Table 3.
TABLE 3 soaping color fastness test results
Figure BDA0003466303600000122
Figure BDA0003466303600000131
As can be seen in Table 3, the soaping fastness of example 1 is the best, that of examples 2-4 and that of comparative example is the worst, probably due to two aspects. In the first aspect, the sizing process in the treatment step is to heat the fiber to cause the molecular chain segments of the fiber to be rearranged through thermal motion, thereby eliminating the internal stress, eliminating the crease existing on the fabric, maintaining better dimensional stability, facilitating subsequent dyeing and being not easy to shrink at high temperature. In a second aspect, ferrocene, 11-maleimidoundecanoic acid and 3-acetylpyrrole are bonded to the surface of the material by in situ chemical oxidation polymerization, vapor deposition polymerization and electrochemical polymerization. The polymerization of the 3-acetyl pyrrole increases the surface roughness of the fiber, the active groups on the rough surface are increased, the fiber with the rough surface is easy to fully contact with the dye, the dye uptake is higher, and the color fastness is better.

Claims (10)

1. A preparation method of a light warm sweat-discharging fabric is characterized by comprising the following preparation steps:
step 1, spinning: mixing the double-resistance acrylic fibers, the Modal fibers and the heat-insulation acrylic fibers uniformly to prepare a siro compact spinning yarn;
step 2, weaving: weaving by adopting a weft circular knitting machine, feeding and interweaving siro compact spun yarns and polyester low stretch yarns at intervals, and adding spandex to weave a dense-root plain fabric:
and step 3, post-processing: the post-processing procedure is carried out by adopting the following processing flow in sequence, namely blank fixing → dyeing → scutching → shaping and drying → shearing → finished product shaping → cloth inspection, and the light and warm sweat-releasing fabric is prepared.
2. The preparation method of the light warm perspiring fabric according to claim 1, characterized in that: in the step 1, the linear density of single fibers of the double-resistant acrylic fibers is less than 1.0dtex, and the fiber length is 35-40 mm.
3. The preparation method of the light warm perspiring fabric according to claim 1, characterized in that: the polyester low stretch yarn in the step 1 is a semi-extinction polyester low stretch yarn, the linear density is 60-80D, and the number of holes is 80-120F; the mass ratio of the semi-dull functional polyester low stretch yarn to the siro compact spun yarn is 1: (2-4).
4. The preparation method of the light warm perspiring fabric according to claim 1, characterized in that: in the step 2, the linear density of spandex is 20-40D, and the mass ratio of siro compact spinning to spandex is 1: (0.1-0.4).
5. The preparation method of the light warm perspiring fabric according to claim 1, characterized in that: in the step 2, the specification of the plain dense-root fabric is 165-175 cm in width and 135-145 g/m in gram weight2
6. The method for preparing a light warm perspiring fabric according to claim 1, wherein the blank setting process parameters in the step 3 are as follows: the temperature is 185-195 ℃, the machine speed is 18-22 m/min, and the width of the machine frame is 170-190 cm.
7. The preparation method of the light warm perspiring fabric according to claim 1, characterized in that: the dyeing process in the step 3 comprises the following steps:
s1, soaking the gray fabric in absolute ethyl alcohol, washing with water, and drying to obtain a clean gray fabric; dissolving ferrocene in absolute ethyl alcohol, soaking the cleaned grey cloth in the solution, taking out and drying to obtain ferrocene grey cloth;
s2, adding 11-maleamidoundecanoic acid into toluene to prepare a solution, and soaking the ferrocene gray fabric prepared by the S1 into the solution; then dripping 3-acetylpyrrole into the solution, standing for reaction, taking out the grey cloth, standing and drying to obtain pretreated grey cloth;
s3, adding anhydrous sodium sulphate into water, adjusting the pH value by adopting acetic acid, then adding disperse light yellow 6GSL dye, uniformly mixing to prepare a dye solution, adding the pretreated gray fabric prepared in the S2 into the dye solution for dyeing, raising the temperature of the solution, and adding an aqueous solution of sodium carbonate for reaction; then cooling at normal temperature, and taking out the grey cloth.
8. The preparation method of the light warm sweat-discharging fabric according to claim 1, wherein the setting and drying process parameters in the step 3 are as follows: the temperature is 128-132 ℃, the machine speed is 19-21 m/min, and the width of the machine frame is 170-175 cm.
9. The method for preparing a light warm perspiring fabric according to claim 1, wherein the shearing process parameters in the step 3 are as follows: the speed is 20 to 30m/min, and the tension is 20 to 30N.
10. The light warm sweat-discharging fabric is characterized in that: the fabric is prepared by the preparation method of the light warm sweat-discharging fabric according to any one of claims 1-9.
CN202210030592.6A 2022-01-12 2022-01-12 Light warm sweat-discharging fabric and preparation method thereof Pending CN114369899A (en)

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