CN114316715A - High-molecular fast-drying type tank-making water-based paint and preparation method thereof - Google Patents

High-molecular fast-drying type tank-making water-based paint and preparation method thereof Download PDF

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CN114316715A
CN114316715A CN202111475614.1A CN202111475614A CN114316715A CN 114316715 A CN114316715 A CN 114316715A CN 202111475614 A CN202111475614 A CN 202111475614A CN 114316715 A CN114316715 A CN 114316715A
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parts
mixed solution
based paint
water
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石素娜
蔡竹彬
曹雪梅
叶发斌
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Shenzhen Shensaier Co Ltd
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Abstract

The invention discloses a high-molecular quick-drying type can-making water-based paint and a preparation method thereof, relates to the technical field of industrial water-based paints, and particularly relates to a high-molecular quick-drying type can-making water-based paint and a preparation method thereof, wherein the high-molecular quick-drying type can-making water-based paint comprises the following raw materials in parts by weight: 20-40 parts of acrylate emulsion, 20-30 parts of wax emulsion, 15-30 parts of deionized water, 1-5 parts of ethylene glycol monobutyl ether, 1-5 parts of cellulose, 0.5-3 parts of aqueous acrylic acid drier, 10-25 parts of pigment, 0.2-1 part of thickener, 0.2-1 part of dispersant, 0.5-2 parts of defoaming agent and 0.2-0.5 part of preservative. According to the high-molecular fast-drying type can-making water-based paint prepared by the invention, the wax emulsion is introduced into the acrylate emulsion, so that the surface performance of the paint can be effectively improved, and meanwhile, the ethylene glycol monobutyl ether and the drier are introduced, so that the later-stage film forming of the paint is facilitated and the drying speed of the paint is accelerated.

Description

High-molecular fast-drying type tank-making water-based paint and preparation method thereof
Technical Field
The invention relates to the technical field of industrial water-based paint production, in particular to a high-molecular quick-drying type can-making water-based paint and a preparation method thereof.
Background
The water paint is a paint using water as solvent or dispersion medium, and is a relatively new paint in the paint market, including three kinds of water-soluble paint, water-dilutable paint and water-dispersible paint (latex paint). The water-based paint takes water-soluble resin as a film forming material, takes polyvinyl alcohol and various modified substances thereof as representatives, and also comprises water-soluble alkyd resin, water-soluble epoxy resin, inorganic high-molecular water-based resin and the like; the water paint in the prior art generally has the defects of long drying time and poor curing effect, and is easily damaged by people in a short time after being coated, so that a high-molecular fast-drying type can-making water paint and a preparation method thereof are provided.
Disclosure of Invention
The invention aims to provide a high-molecular quick-drying type can-making water-based paint and a preparation method thereof aiming at the defects of the prior art so as to solve the problems in the background art.
In order to achieve the purpose, the invention provides the following technical scheme: a high-molecular fast-drying type water-based paint for making cans comprises the following basic raw materials: 20-40 parts of acrylate emulsion, 20-30 parts of wax emulsion, 15-30 parts of deionized water, 1-5 parts of ethylene glycol monobutyl ether, 1-5 parts of cellulose, 0.5-3 parts of aqueous acrylic acid drier, 10-25 parts of pigment, 0.2-1 part of thickener, 0.2-1 part of dispersant, 0.5-2 parts of defoaming agent and 0.2-0.5 part of preservative.
As a preferable technical scheme of the invention, the high-molecular fast-drying type water-based paint for manufacturing the tank comprises the following basic raw materials: 20-30 parts of acrylate emulsion, 20-25 parts of wax emulsion, 15-25 parts of deionized water, 1-4 parts of ethylene glycol monobutyl ether, 1-4 parts of cellulose, 0.5-2.5 parts of aqueous acrylic acid drier, 15-25 parts of pigment, 0.2-0.8 part of thickening agent, 0.2-0.8 part of dispersing agent, 0.5-1.5 parts of defoaming agent and 0.2-0.4 part of preservative.
As a preferable technical scheme of the invention, the high-molecular fast-drying type water-based paint for manufacturing the tank comprises the following basic raw materials: 25 parts of acrylate emulsion, 20 parts of wax emulsion, 20 parts of deionized water, 2 parts of ethylene glycol monobutyl ether, 2 parts of cellulose, 1 part of aqueous acrylic acid drier, 20 parts of pigment, 0.5 part of thickening agent, 0.5 part of dispersing agent, 1 part of defoaming agent and 0.2 part of preservative.
As a preferred technical scheme of the invention, the pigment is composed of pigment and filler, the pigment is one or more of titanium dioxide, pigment carbon black, scarlet powder, phthalocyanine green and superfine talcum powder, the filler is one of nano glass flakes, stainless steel flakes or mica flakes, the thickener is polyurethane thickener, and the dispersant is one of anionic wetting dispersant or cationic wetting dispersant.
According to the preferable technical scheme, the defoaming agent is one of polyether defoaming agent, organic silicon defoaming agent, polyether modified silicon vial defoaming agent or polysiloxane defoaming agent, and the preservative is isothiazolinone preservative.
As a preferred technical scheme of the invention, the wax emulsion is prepared by the following method: stirring paraffin and beeswax to be uniform, adding stearate, heating to 75 ℃ until the wax is completely melted, adding a certain amount of hot water again, stirring, filtering and cooling for 30 minutes.
As a preferable technical scheme of the invention, the mass ratio of the paraffin, the beeswax and the stearic acid ester is 1-2: 2-3: 0.5.
the invention also provides a preparation method of the high-molecular fast-drying type tank-making water-based paint, which comprises the following steps:
s1, weighing 20-40 parts of acrylate emulsion, 20-30 parts of wax emulsion and 15-30 parts of deionized water by weight, adding the three into a stirrer, and stirring at 1500 revolutions until the three are completely mixed to obtain a mixed solution a;
s2, adding 10-25 parts of pigment and 1-5 parts of cellulose into the mixed solution a, slowly stirring until the pigment is completely dispersed, and then adding 0.2-1 part of thickening agent and 0.2-1 part of dispersing agent into the mixed solution a again to ensure that the mixed solution a is not stirred until the mixed solution a is adjusted to a proper viscosity, so as to obtain mixed solution b;
s3, adding 0.2-0.5 part of preservative into the mixed solution b, adding 0.5-2 parts of defoaming agent after the preservative is fused, and standing for 30 minutes until no obvious bubbles are generated in the mixed solution b, thus obtaining mixed solution c;
and S4, adding 1-5 parts of ethylene glycol monobutyl ether into the mixed solution c, mixing and stirring until the ethylene glycol monobutyl ether is completely mixed, adding 0.5-3 parts of aqueous acrylic acid drier into the mixed solution c, stirring at a constant speed, and standing for 30 minutes to obtain the high-molecular quick-drying type can-making aqueous coating.
Compared with the prior art, the invention provides the high-molecular fast-drying type can-making water-based paint and the preparation method thereof, and the high-molecular fast-drying type can-making water-based paint has the following beneficial effects:
1. according to the high-polymer quick-drying type can-making water-based paint and the preparation method thereof, the acrylate emulsion is used as the base material, the wax emulsion is added into the acrylate emulsion, the surface performance of the paint can be effectively improved, the smoothness, the scratch resistance and the waterproof performance of the paint are greatly improved, meanwhile, the addition of the ethylene glycol monobutyl ether can dissolve or disperse film-forming substances in the paint into a uniform liquid state, the construction film forming is facilitated, the addition of the drier can improve the drying speed of the water-dispersed paint, enhance the drying speed of the paint after spraying and reduce the artificial damage of the paint after spraying.
Drawings
FIG. 1 is a schematic diagram showing the relationship between the water resistance and the amount of the drier used in the water-based paint of the present invention;
FIG. 2 is a graph showing the hardness and drying time of a coating film of the water-based paint of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it should be apparent that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1 and fig. 2, the specific analysis in accordance with the embodiment is as follows:
the first embodiment is as follows:
the invention provides a high-molecular fast-drying type can-making water-based paint which comprises the following raw materials in parts by weight: 20 parts of acrylate emulsion, 20 parts of wax emulsion, 15 parts of deionized water, 1 part of ethylene glycol monobutyl ether, 1 part of cellulose, 0.5 part of aqueous acrylic acid drier, 20 parts of pigment, 0.5 part of thickening agent, 0.5 part of dispersing agent, 1 part of defoaming agent and 0.2 part of preservative.
Wherein, the wax emulsion is prepared by the following method: stirring the paraffin and the beeswax to be uniform, then adding the stearate, heating to 75 ℃ until the wax is completely melted, adding a certain amount of hot water again, stirring, filtering and cooling for 30 minutes, wherein the mass ratio of the paraffin to the beeswax to the stearate is 1: 2: 0.5.
the invention also provides a preparation method of the high-molecular fast-drying type tank-making water-based paint, which comprises the following steps:
s1, weighing 20 parts of acrylic ester emulsion, 20 parts of wax emulsion and 15 parts of deionized water in parts by weight, adding the acrylic ester emulsion, the wax emulsion and the deionized water into a stirrer, and stirring at 1500 revolutions until the acrylic ester emulsion, the wax emulsion and the deionized water are completely mixed to obtain a mixed solution a;
s2, adding 20 parts of pigment and 1 part of cellulose into the mixed solution a, slowly stirring until the pigment is completely dispersed, and then adding 0.5 part of thickening agent and 0.5 part of dispersing agent into the mixed solution a again to ensure that the mixed solution a is not stirred until the mixed solution a is adjusted to a proper viscosity to obtain a mixed solution b;
s3, adding 0.2 part of preservative into the mixed solution b, adding 1 part of defoaming agent after the preservative is fused, and standing for 30 minutes until no obvious bubbles are generated in the mixed solution b, so as to obtain mixed solution c;
and S4, adding 1 part of ethylene glycol monobutyl ether into the mixed solution c, mixing and stirring until the ethylene glycol monobutyl ether is completely mixed, adding 0.5 part of aqueous acrylic acid drier into the mixed solution c at the moment, stirring at a constant speed, and standing for 30 minutes to obtain the high-molecular quick-drying can-making aqueous coating.
Example two:
the invention provides a high-molecular fast-drying type can-making water-based paint which comprises the following raw materials in parts by weight: 20 parts of acrylate emulsion, 20 parts of wax emulsion, 15 parts of deionized water, 2 parts of ethylene glycol monobutyl ether, 2 parts of cellulose, 1.5 parts of aqueous acrylic acid drier, 20 parts of pigment, 0.5 part of thickening agent, 0.5 part of dispersing agent, 1 part of defoaming agent and 0.2 part of preservative.
Wherein, the wax emulsion is prepared by the following method: stirring the paraffin and the beeswax to be uniform, then adding the stearate, heating to 75 ℃ until the wax is completely melted, adding a certain amount of hot water again, stirring, filtering and cooling for 30 minutes, wherein the mass ratio of the paraffin to the beeswax to the stearate is 1: 3: 0.5.
the invention also provides a preparation method of the high-molecular fast-drying type tank-making water-based paint, which comprises the following steps:
s1, weighing 20 parts of acrylic ester emulsion, 20 parts of wax emulsion and 15 parts of deionized water in parts by weight, adding the acrylic ester emulsion, the wax emulsion and the deionized water into a stirrer, and stirring at 1500 revolutions until the acrylic ester emulsion, the wax emulsion and the deionized water are completely mixed to obtain a mixed solution a;
s2, adding 20 parts of pigment and 2 parts of cellulose into the mixed solution a, slowly stirring until the pigment is completely dispersed, and then adding 0.5 part of thickening agent and 0.5 part of dispersing agent into the mixed solution a again to ensure that the mixed solution a is not stirred until the mixed solution a is adjusted to a proper viscosity to obtain a mixed solution b;
s3, adding 0.2 part of preservative into the mixed solution b, adding 1 part of defoaming agent after the preservative is fused, and standing for 30 minutes until no obvious bubbles are generated in the mixed solution b, so as to obtain mixed solution c;
and S4, adding 2 parts of ethylene glycol monobutyl ether into the mixed solution c, mixing and stirring until the ethylene glycol monobutyl ether is completely mixed, adding 1.5 parts of aqueous acrylic acid drier into the mixed solution c at the moment, stirring at a constant speed, and standing for 30 minutes to obtain the high-molecular quick-drying can-making aqueous coating.
Example three:
the invention provides a high-molecular fast-drying type can-making water-based paint which comprises the following raw materials in parts by weight: 25 parts of acrylate emulsion, 20 parts of wax emulsion, 20 parts of deionized water, 2 parts of ethylene glycol monobutyl ether, 2 parts of cellulose, 1.5 parts of aqueous acrylic acid drier, 20 parts of pigment, 0.5 part of thickening agent, 0.5 part of dispersing agent, 1 part of defoaming agent and 0.2 part of preservative.
Wherein, the wax emulsion is prepared by the following method: stirring the paraffin and the beeswax to be uniform, then adding the stearate, heating to 75 ℃ until the wax is completely melted, adding a certain amount of hot water again, stirring, filtering and cooling for 30 minutes, wherein the mass ratio of the paraffin to the beeswax to the stearate is 1: 1: 0.5.
the invention also provides a preparation method of the high-molecular fast-drying type tank-making water-based paint, which comprises the following steps:
s1, weighing 25 parts of acrylate emulsion, 20 parts of wax emulsion and 20 parts of deionized water in parts by weight, adding the three into a stirrer, and stirring at 1500 revolutions until the three are completely mixed to obtain a mixed solution a;
s2, adding 20 parts of pigment and 2 parts of cellulose into the mixed solution a, slowly stirring until the pigment is completely dispersed, and then adding 0.5 part of thickening agent and 0.5 part of dispersing agent into the mixed solution a again to ensure that the mixed solution a is not stirred until the mixed solution a is adjusted to a proper viscosity to obtain a mixed solution b;
s3, adding 0.2 part of preservative into the mixed solution b, adding 1 part of defoaming agent after the preservative is fused, and standing for 30 minutes until no obvious bubbles are generated in the mixed solution b, so as to obtain mixed solution c;
and S4, adding 2 parts of ethylene glycol monobutyl ether into the mixed solution c, mixing and stirring until the ethylene glycol monobutyl ether is completely mixed, adding 1.5 parts of aqueous acrylic acid drier into the mixed solution c at the moment, stirring at a constant speed, and standing for 30 minutes to obtain the high-molecular quick-drying can-making aqueous coating.
Example four:
the invention provides a high-molecular fast-drying type can-making water-based paint which comprises the following raw materials in parts by weight: 25 parts of acrylate emulsion, 20 parts of wax emulsion, 20 parts of deionized water, 3 parts of ethylene glycol monobutyl ether, 3 parts of cellulose, 1.5 parts of aqueous acrylic acid drier, 20 parts of pigment, 0.5 part of thickening agent, 0.5 part of dispersing agent, 1 part of defoaming agent and 0.2 part of preservative.
Wherein, the wax emulsion is prepared by the following method: stirring the paraffin and the beeswax to be uniform, then adding the stearate, heating to 75 ℃ until the wax is completely melted, adding a certain amount of hot water again, stirring, filtering and cooling for 30 minutes, wherein the mass ratio of the paraffin to the beeswax to the stearate is 1: 1: 0.5.
the invention also provides a preparation method of the high-molecular fast-drying type tank-making water-based paint, which comprises the following steps:
s1, weighing 25 parts of acrylate emulsion, 20 parts of wax emulsion and 20 parts of deionized water in parts by weight, adding the three into a stirrer, and stirring at 1500 revolutions until the three are completely mixed to obtain a mixed solution a;
s2, adding 20 parts of pigment and 3 parts of cellulose into the mixed solution a, slowly stirring until the pigment is completely dispersed, and then adding 0.5 part of thickening agent and 0.5 part of dispersing agent into the mixed solution a again to ensure that the mixed solution a is not stirred until the mixed solution a is adjusted to a proper viscosity to obtain a mixed solution b;
s3, adding 0.2 part of preservative into the mixed solution b, adding 1 part of defoaming agent after the preservative is fused, and standing for 30 minutes until no obvious bubbles are generated in the mixed solution b, so as to obtain mixed solution c;
and S4, adding 3 parts of ethylene glycol monobutyl ether into the mixed solution c, mixing and stirring until the ethylene glycol monobutyl ether is completely mixed, adding 1.5 parts of aqueous acrylic acid drier into the mixed solution c at the moment, stirring at a constant speed, and standing for 30 minutes to obtain the high-molecular quick-drying can-making aqueous coating.
A part of the high-molecular fast-drying type can-making water-based paint prepared in the first to fourth embodiments of the present invention was taken out and tested as follows:
attached table 1
Figure BDA0003393108800000091
As can be seen from the attached Table 1, the high molecular fast drying type water-based paint for can making prepared in the first to fourth embodiments of the present invention has excellent adhesion, scratch resistance and water resistance compared with the existing water-based paint, and simultaneously, the drying time of the paint is greatly shortened, and the artificial damage after the paint is sprayed is reduced.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments described above, or equivalents may be substituted for elements thereof. Any modification, equivalent replacement, or improvement made without departing from the spirit and principle of the present invention shall fall within the protection scope of the present invention.

Claims (8)

1. The utility model provides a polymer quick drying type system jar water based paint which characterized in that: comprises the following basic raw materials: 20-40 parts of acrylate emulsion, 20-30 parts of wax emulsion, 15-30 parts of deionized water, 1-5 parts of ethylene glycol monobutyl ether, 1-5 parts of cellulose, 0.5-3 parts of aqueous acrylic acid drier, 10-25 parts of pigment, 0.2-1 part of thickener, 0.2-1 part of dispersant, 0.5-2 parts of defoaming agent and 0.2-0.5 part of preservative.
2. The high-molecular fast-drying type water-based paint for can making according to claim 1, characterized in that: 20-30 parts of acrylate emulsion, 20-25 parts of wax emulsion, 15-25 parts of deionized water, 1-4 parts of ethylene glycol monobutyl ether, 1-4 parts of cellulose, 0.5-2.5 parts of aqueous acrylic acid drier, 15-25 parts of pigment, 0.2-0.8 part of thickening agent, 0.2-0.8 part of dispersing agent, 0.5-1.5 parts of defoaming agent and 0.2-0.4 part of preservative.
3. The high-molecular fast-drying type water-based paint for can making according to claim 1, characterized in that: 25 parts of acrylate emulsion, 20 parts of wax emulsion, 20 parts of deionized water, 2 parts of ethylene glycol monobutyl ether, 2 parts of cellulose, 1 part of aqueous acrylic acid drier, 20 parts of pigment, 0.5 part of thickening agent, 0.5 part of dispersing agent, 1 part of defoaming agent and 0.2 part of preservative.
4. The high-molecular fast-drying type water-based paint for can making according to claim 1, characterized in that: the pigment is composed of pigment and filler, the pigment is one or more of titanium dioxide, pigment carbon black, scarlet powder, phthalocyanine green and superfine talcum powder, the filler is one of nano glass flakes, stainless steel flakes or mica flakes, the thickener is polyurethane thickener, and the dispersant is one of anionic wetting dispersant or cationic wetting dispersant.
5. The high-molecular fast-drying type water-based paint for can making according to claim 1, characterized in that: the defoaming agent is one of polyether defoaming agent, organic silicon defoaming agent, polyether modified silicon vial defoaming agent or polysiloxane defoaming agent, and the preservative is isothiazolinone preservative.
6. The polymeric fast drying can-making water-based paint as claimed in claim 1, wherein the wax emulsion is prepared by the following method: stirring paraffin and beeswax to be uniform, adding stearate, heating to 75 ℃ until the wax is completely melted, adding a certain amount of hot water again, stirring, filtering and cooling for 30 minutes.
7. The high-molecular fast-drying can-making water-based paint according to claim 6, characterized in that: the mass ratio of the paraffin, the beeswax and the stearic acid ester is 1-2: 2-3: 0.5.
8. the preparation method of the high-molecular fast-drying type water-based paint for can making according to any one of claims 1 to 6, characterized by comprising the following specific steps:
s1, weighing 20-40 parts of acrylate emulsion, 20-30 parts of wax emulsion and 15-30 parts of deionized water in parts by weight, adding the three into a stirrer, and stirring at 1500 revolutions until the three are completely mixed to obtain a mixed solution a;
s2, adding 10-25 parts of pigment and 1-5 parts of cellulose into the mixed solution a, slowly stirring until the pigment is completely dispersed, and then adding 0.2-1 part of thickening agent and 0.2-1 part of dispersing agent into the mixed solution a again to ensure that the mixed solution a is not stirred until the mixed solution a is adjusted to a proper viscosity, so as to obtain mixed solution b;
s3, adding 0.2-0.5 part of preservative into the mixed solution b, adding 0.5-2 parts of defoaming agent after the preservative is fused, and standing for 30 minutes until no obvious bubbles are generated in the mixed solution b, thus obtaining mixed solution c;
and S4, adding 1-5 parts of ethylene glycol monobutyl ether into the mixed solution c, mixing and stirring until the ethylene glycol monobutyl ether is completely mixed, adding 0.5-3 parts of aqueous acrylic acid drier into the mixed solution c, stirring at a constant speed, and standing for 30 minutes to obtain the high-molecular quick-drying can-making aqueous coating.
CN202111475614.1A 2021-12-06 2021-12-06 High-molecular fast-drying type tank-making water-based paint and preparation method thereof Pending CN114316715A (en)

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Publication number Priority date Publication date Assignee Title
CN103627276A (en) * 2013-12-02 2014-03-12 藏新国 Water-based cold cut road marking coating and preparation method thereof
CN103666280A (en) * 2013-11-07 2014-03-26 齐河力厚化工有限公司 Polishing wax emulsion for leather finishing and preparation method thereof
CN104631207A (en) * 2015-01-08 2015-05-20 湖南华望科技股份有限公司 Waterproof coating for water-based paperboards and preparation method thereof
CN107011773A (en) * 2017-02-14 2017-08-04 滁州金桥德克新材料有限公司 A kind of high ferro vehicle body is with aqueous quick-drying corrosion resistant coating
CN109880417A (en) * 2019-01-28 2019-06-14 河北惠驰装饰材料有限公司 Watersoluble metal self-drying paint and preparation method thereof
CN110684205A (en) * 2018-07-06 2020-01-14 上海诺科生物科技有限公司 Low-viscosity high-solid-content wax emulsion, preparation method thereof and emulsifier
CN111234603A (en) * 2020-03-27 2020-06-05 石家庄市博思特油墨有限公司 Water-based ink for printing PVC decorative material and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103666280A (en) * 2013-11-07 2014-03-26 齐河力厚化工有限公司 Polishing wax emulsion for leather finishing and preparation method thereof
CN103627276A (en) * 2013-12-02 2014-03-12 藏新国 Water-based cold cut road marking coating and preparation method thereof
CN104631207A (en) * 2015-01-08 2015-05-20 湖南华望科技股份有限公司 Waterproof coating for water-based paperboards and preparation method thereof
CN107011773A (en) * 2017-02-14 2017-08-04 滁州金桥德克新材料有限公司 A kind of high ferro vehicle body is with aqueous quick-drying corrosion resistant coating
CN110684205A (en) * 2018-07-06 2020-01-14 上海诺科生物科技有限公司 Low-viscosity high-solid-content wax emulsion, preparation method thereof and emulsifier
CN109880417A (en) * 2019-01-28 2019-06-14 河北惠驰装饰材料有限公司 Watersoluble metal self-drying paint and preparation method thereof
CN111234603A (en) * 2020-03-27 2020-06-05 石家庄市博思特油墨有限公司 Water-based ink for printing PVC decorative material and preparation method thereof

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Application publication date: 20220412