CN114292576B - TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof - Google Patents
TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof Download PDFInfo
- Publication number
- CN114292576B CN114292576B CN202111621980.3A CN202111621980A CN114292576B CN 114292576 B CN114292576 B CN 114292576B CN 202111621980 A CN202111621980 A CN 202111621980A CN 114292576 B CN114292576 B CN 114292576B
- Authority
- CN
- China
- Prior art keywords
- parts
- tpo
- multicolor
- layer
- automotive interior
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920002397 thermoplastic olefin Polymers 0.000 title claims abstract description 107
- 239000000463 material Substances 0.000 title claims abstract description 87
- 238000002360 preparation method Methods 0.000 title abstract description 14
- 239000010410 layer Substances 0.000 claims abstract description 73
- 239000004743 Polypropylene Substances 0.000 claims abstract description 37
- 239000002344 surface layer Substances 0.000 claims abstract description 36
- 239000002002 slurry Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000002994 raw material Substances 0.000 claims abstract description 27
- 229920002635 polyurethane Polymers 0.000 claims abstract description 26
- 239000004814 polyurethane Substances 0.000 claims abstract description 26
- 238000001035 drying Methods 0.000 claims abstract description 25
- 239000006260 foam Substances 0.000 claims abstract description 20
- -1 polypropylene Polymers 0.000 claims abstract description 19
- 229920001155 polypropylene Polymers 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 239000002335 surface treatment layer Substances 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 76
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 59
- 239000000843 powder Substances 0.000 claims description 57
- 235000012239 silicon dioxide Nutrition 0.000 claims description 46
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 41
- 239000010453 quartz Substances 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 34
- 239000004408 titanium dioxide Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 26
- 239000002245 particle Substances 0.000 claims description 21
- 239000000377 silicon dioxide Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 13
- 239000008187 granular material Substances 0.000 claims description 11
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 10
- 239000004611 light stabiliser Substances 0.000 claims description 10
- 239000000049 pigment Substances 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- LUCXVPAZUDVVBT-UHFFFAOYSA-N methyl-[3-(2-methylphenoxy)-3-phenylpropyl]azanium;chloride Chemical compound Cl.C=1C=CC=CC=1C(CCNC)OC1=CC=CC=C1C LUCXVPAZUDVVBT-UHFFFAOYSA-N 0.000 claims description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000003063 flame retardant Substances 0.000 claims description 8
- 230000008961 swelling Effects 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 238000005187 foaming Methods 0.000 claims description 7
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 6
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 229940018564 m-phenylenediamine Drugs 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 4
- 239000011265 semifinished product Substances 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical compound O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 claims description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000012796 inorganic flame retardant Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 23
- 239000011049 pearl Substances 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 13
- 239000003086 colorant Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical group [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical group C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- YCIHPQHVWDULOY-FMZCEJRJSA-N (4s,4as,5as,6s,12ar)-4-(dimethylamino)-1,6,10,11,12a-pentahydroxy-6-methyl-3,12-dioxo-4,4a,5,5a-tetrahydrotetracene-2-carboxamide;hydrochloride Chemical compound Cl.C1=CC=C2[C@](O)(C)[C@H]3C[C@H]4[C@H](N(C)C)C(=O)C(C(N)=O)=C(O)[C@@]4(O)C(=O)C3=C(O)C2=C1O YCIHPQHVWDULOY-FMZCEJRJSA-N 0.000 description 1
- MTEZSDOQASFMDI-UHFFFAOYSA-N 1-trimethoxysilylpropan-1-ol Chemical compound CCC(O)[Si](OC)(OC)OC MTEZSDOQASFMDI-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000001034 iron oxide pigment Substances 0.000 description 1
- KCWDJXPPZHMEIK-UHFFFAOYSA-N isocyanic acid;toluene Chemical group N=C=O.N=C=O.CC1=CC=CC=C1 KCWDJXPPZHMEIK-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000011050 natural pearl Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Abstract
The application relates to the technical field of automotive interior materials, and particularly discloses a TPO (thermoplastic polyolefin) multicolor automotive interior material and a preparation method thereof. The automotive interior material comprises a surface treatment layer, a colorful surface layer, a TPO film layer, a PP Foam layer and a back treatment layer; the preparation method comprises the following steps: preparing water-based polyurethane slurry, a TPO film layer, multicolor slurry and polypropylene slurry, coating the polypropylene slurry on the surface of the TPO film layer, drying to obtain a PP Foam layer, coating the water-based polyurethane slurry on the PP Foam layer, drying to obtain a back treatment layer, coating the multicolor slurry on one surface of the TPO film layer far away from the PP Foam layer, drying to obtain an multicolor surface layer, coating the water-based polyurethane slurry on the multicolor surface layer, and drying to obtain a surface treatment layer, thereby obtaining the TPO multicolor automotive interior material. The TPO multicolor automotive interior material has the advantage that the automotive interior shows the multicolor effect through the synergistic effect of the raw materials.
Description
Technical Field
The application relates to the technical field of automotive interior materials, in particular to a TPO (thermoplastic polyolefin) multicolor automotive interior material and a preparation method thereof.
Background
With the development of science and technology and the progress of society, automobiles appear more and more frequently. The automobile is not only a tool for people to take a walk for commuting, but also the time for people to play activities is gradually increased, the time occupation ratio of people in the automobile is also gradually increased, and therefore, the demand of people for the interior of the automobile is more and more. People not only require comfort level of the interior of the automobile, but also require the design of the appearance and the interior of the automobile.
At present, automotive interior material generally includes surface course, TPO rete, PP Foam layer, and the surface course sets firmly the surface at the TPO rete, and PP Foam layer sets firmly the one side of keeping away from surface course TPO rete at the surface course. When the front surface of the surface layer is illuminated, different colors can be shown, however, as the surface layer is directly exposed in the natural environment, the surface of the surface layer is damaged along with the increase of the using time, and the surface layer is easy to fade.
Disclosure of Invention
In order to improve the color fastness to rubbing of the automotive interior material, the application provides a TPO multicolor automotive interior material and a preparation method thereof.
In a first aspect, the present application provides a TPO multicolor automotive interior material, which adopts the following technical scheme:
the TPO multicolor automotive interior material sequentially comprises a surface treatment layer, a multicolor surface layer, a TPO film layer, a PP Foam layer and a back treatment layer from top to bottom, wherein the surface treatment layer and the back treatment layer are both aqueous polyurethane layers;
the waterborne polyurethane layer comprises the following raw materials in parts by weight: 50-75 parts of aqueous polyurethane dispersoid, 1-5 parts of silicon dioxide, 0.2-3.2 parts of acrylic acid alkali swelling thickener, 0.2-2.5 parts of curing agent and 10-40 parts of water;
the colorful surface layer comprises the following raw materials in parts by weight: 65-95 parts of modified epoxy acrylate, 12-35 parts of pearl powder, 6-15 parts of titanium dioxide, 2-6 parts of dicyclopentenyl acrylate, 1-5 parts of ethylene glycol phenyl ether, 1-5 parts of photoinitiator and 15-35 parts of water, wherein the modified epoxy acrylate is prepared by modifying epoxy acrylate with quartz powder;
the TPO membrane layer comprises the following raw materials in parts by weight: 85-100 parts of modified TPO particles, 0.3-9 parts of auxiliary agent and 0.5-7 parts of pigment.
The PP Foam layer is made of a polypropylene foaming material.
Further, the modified epoxy acrylate is prepared by the following method: adding acetone into quartz powder, performing ultrasonic dispersion for 30-50min under the power of 180 plus 210W, adding epoxy acrylate, performing ultrasonic dispersion for 30-50min under the power of 180 plus 210W, adding m-phenylenediamine, stirring for 15-20min to obtain a mixture, and then curing the mixture at the temperature of 80-90 ℃ for 4-6h to obtain modified epoxy acrylate;
wherein, the addition amount of acetone in 1kg of quartz powder is 3-5L, and the weight ratio of epoxy acrylate, quartz powder and m-phenylenediamine is (11-12): (6-8): (3-4).
By adopting the technical scheme, the TPO multicolor automotive interior material can enable the automotive interior material to have excellent rubbing color fastness, light color fastness and wear resistance through the synergistic effect of the raw materials, so that the automotive interior can present different colors from different angles, and the personalized requirements of people on the automotive interior can be conveniently met, wherein the rubbing color fastness is 4-6 grade, the light color fastness is 4-6 grade, and the wear resistance is free from obvious damage and peeling.
The surface treatment layer and the back treatment layer can protect the internal layer structure, reduce friction damage and improve wear resistance and color fastness. The surface treatment layer and the back treatment layer are both aqueous polyurethane layers, the mechanical strength of the aqueous polyurethane layers is good, the wear resistance of the aqueous polyurethane layers is improved, and the protection effect on the colorful surface layer is further enhanced.
The main component of the quartz powder is silicon dioxide, the silicon dioxide has strong wear resistance, and the wear resistance of the epoxy acrylate can be enhanced by modifying the quartz powder, so that the rubbing color fastness of the colorful surface layer is improved, and the automobile interior material presents different colors from the front. The dicyclopentenyl acrylate is a cross-linking agent and can be cross-linked with the epoxy acrylate to form a net structure of the epoxy acrylate, so that the adhesive force of the multicolor slurry on the TPO film is improved, and the color fastness to friction of the multicolor surface layer is improved.
The pearl powder can not only present the glittering effect of the metallic pigment, but also can generate the soft color of the natural pearl, when the pearl powder is irradiated by sunlight, multi-level reflection can be generated, the reflected light interacts to present colorful colors, and when the pearl powder is applied to the raw materials of the colorful surface layer, the automobile interior material can present more colors. The titanium dioxide is applied to the raw materials of the colorful surface layer, can show more bright colors together with the pearl powder, not only can play a role in covering flaws, but also can improve the performance of the colorful surface layer, and can improve the light fastness, the adhesive force and the aging resistance of the colorful surface layer, thereby improving the light fastness of the colorful surface layer. The ethylene glycol phenyl ether is used as a film forming auxiliary agent, and can facilitate the rapid film forming of the multicolor surface layer.
The TPO film layer is made of modified TPO particles, auxiliaries and pigments, and is beneficial to improving mechanical properties and increasing wear resistance. The PP Foam layer is a polypropylene Foam material, has excellent mechanical property, durability and environmental protection, and can protect the TPO film layer.
Preferably, the method comprises the following steps: the waterborne polyurethane layer comprises the following raw materials in parts by weight: 55-70 parts of aqueous polyurethane dispersoid, 2-3 parts of silicon dioxide, 0.5-2.5 parts of acrylic acid alkali swelling thickener, 0.5-1.5 parts of curing agent and 15-35 parts of water;
the colorful surface layer comprises the following raw materials in parts by weight: 70-85 parts of modified epoxy acrylate, 16-32 parts of pearl powder, 8-12 parts of titanium dioxide, 3-5 parts of dicyclopentenyl acrylate, 2-4 parts of ethylene glycol phenyl ether, 2-4 parts of photoinitiator and 20-30 parts of water; the TPO membrane layer comprises the following raw materials in parts by weight: 92-98 parts of modified TPO particles, 0.9-3.9 parts of auxiliary agent and 1-4 parts of pigment.
By adopting the technical scheme, the color fastness to rubbing of the multicolor surface layer can be conveniently improved by optimizing the mixing amount of the raw materials.
Preferably, the method comprises the following steps: the weight ratio of the pearl powder to the modified epoxy acrylate is 1: (5-8).
The addition amount of the pearl powder is too small, so that the multicolor surface layer can not present more excellent colors; the addition amount of the pearl powder is too much, so that the pearl powder cannot be well mixed with the modified epoxy acrylate, the dispersion is not uniform, and the colorful color cannot be better presented. By adopting the technical scheme, when the weight ratio of the pearl powder to the modified epoxy acrylate is in the range, the colorful surface layer can show different colors from the front.
Preferably, the method comprises the following steps: the quartz powder is pretreated by adopting a silane coupling agent before use.
Further, the quartz powder is pretreated by adopting the following method: putting gamma-glycidoxypropyltrimethoxysilane into an acetic acid solution, stirring for 15-20min to obtain a mixture, then adding quartz powder into the mixture, stirring for 20-30min, standing at 60-80 ℃ for 4-6h, filtering, washing the solid for 3-5 times, and drying the solid at 50-60 ℃ for 40-60min to obtain pretreated quartz powder;
wherein the addition amount of the gamma-glycidoxypropyltrimethoxysilane is 4-6 wt% of the quartz powder, the addition amount of acetic acid solution in each 1kg of the gamma-glycidoxypropyltrimethoxysilane is 6-8L, and the mass fraction of the acetic acid solution is 30-40%.
By adopting the technical scheme, the quartz powder has good hydrophilicity, but has poor compatibility with epoxy acrylate. The silane coupling agent is utilized to pretreat the quartz powder, so that the compatibility of the quartz powder and the epoxy acrylic acid can be improved, and the quartz powder is better dispersed in the epoxy acrylate, thereby better enhancing the wear resistance of the colorful surface layer and improving the color fastness to friction of the colorful surface layer. Specifically, the silane coupling agent can be hydrolyzed in water to generate silanol groups, and the silanol groups can be combined with silicon dioxide in quartz powder to form a homogeneous system, so that the surface energy of the quartz powder is reduced, the quartz powder has good affinity with epoxy acrylate, and the compatibility of the quartz powder and the epoxy acrylate is improved.
Preferably, the method comprises the following steps: the titanium dioxide is pretreated by adopting alumina before use.
Further, the titanium dioxide is pretreated by adopting the following method: putting titanium dioxide into water, stirring for 15-25min to obtain a mixture, adding alumina into the mixture, stirring for 10-20min, adjusting the pH to 8.5 by using a sodium hydroxide solution, curing at 70-90 ℃ for 2-3h, filtering, and drying at 30-50 ℃ for 1-3h to obtain pretreated titanium dioxide;
wherein, the addition amount of water in every 1kg of titanium dioxide is 3-4L, and the addition amount of alumina is 4-6 wt% of the titanium dioxide.
By adopting the technical scheme, the titanium dioxide has poor dispersibility and poor compatibility with epoxy acrylate. The titanium dioxide is pretreated by using the aluminum oxide, and the aluminum ions are added into the multicolor surface layer, so that the metallic luster and the glittering sensation of the multicolor surface layer can be enhanced, and the multicolor surface layer can conveniently show different colors from the front.
Preferably, the method comprises the following steps: the modified TPO particles are prepared by modifying the TPO particles by adopting silica.
Further, modified TPO pellets were prepared using the following method: melting TPO granules and silica at the temperature of 125-140 ℃, adding 3-5kg of sodium hexametaphosphate, stirring for 20-30min, then extruding and granulating to obtain modified TPO granules, wherein the weight ratio of the TPO granules to the silica is 1: (0.5-0.7).
Through adopting above-mentioned technical scheme, the silica cost is lower, and TPO granule cost is higher, utilizes the silica to modify TPO granule, not only can reduce cost, can also improve the wear resistance of TPO granule to improve the colour fastness to rubbing.
Preferably, the method comprises the following steps: the auxiliary agent comprises a light stabilizer, an antioxidant and a flame retardant, and the weight ratio of the light stabilizer to the antioxidant to the flame retardant is 1:1: 1.
Preferably, the method comprises the following steps: the light stabilizer is a hindered amine light stabilizer, the antioxidant is an amine antioxidant, and the flame retardant is an inorganic flame retardant.
By adopting the technical scheme, the light stabilizer, the antioxidant and the flame retardant are applied to the raw materials of the TPO film layer, so that the light resistance, the wear resistance and the flame retardance of the automotive interior material can be enhanced, and the practicability of the automotive interior material is enhanced.
In a second aspect, the present application provides a preparation method of a TPO multicolor automotive interior material, which adopts the following technical scheme: a preparation method of TPO multicolor automotive interior material comprises the following steps:
mixing the aqueous polyurethane dispersion, silicon dioxide and water, stirring for 25-35min, adding an acrylic acid-alkali swelling thickener and a curing agent, and stirring for 10-15min to obtain aqueous polyurethane slurry;
mixing the modified epoxy acrylate, the dicyclopentenyl acrylate, the photoinitiator and water, stirring for 25-40min to obtain a mixture, adding the pearl powder and the titanium dioxide into the mixture, stirring for 5-10min, adding the ethylene glycol phenyl ether, and stirring for 5-10min to obtain a magic color slurry;
melting the polypropylene foaming material at the temperature of 170-220 ℃ to obtain polypropylene slurry;
s1: melting the modified TPO particles at the temperature of 130-140 ℃, adding the auxiliary agent and the pigment for mixing, stirring for 20-35min, extruding, pressing into a film with the thickness of 0.4-0.6mm, and drying at the temperature of 60-80 ℃ for 3-5h to obtain a TPO film layer;
s2: uniformly coating polypropylene slurry on the surface of the TPO film layer, and drying at the temperature of 70-80 ℃ for 25-45min to form a PP Foam layer; uniformly coating the surface of the PP Foam layer, which is far away from the TPO film layer, with water-based polyurethane slurry, drying at the temperature of 60-80 ℃ for 30-50min to form a back treatment layer, uniformly coating the multicolor slurry on the surface of the TPO film layer, which is far away from the PP Foam layer, drying at the temperature of 60-80 ℃ for 30-50min to form a multicolor surface layer, so as to obtain a TPO multicolor base material and obtain a semi-finished product; uniformly coating the surface of the TPO multicolor substrate far away from the TPO film layer with water-based polyurethane slurry, and drying at the temperature of 70-90 ℃ for 20-30min to form a surface treatment layer; obtaining the TPO multicolor automobile interior material.
By adopting the technical scheme, the waterborne polyurethane slurry, the multicolor slurry, the TPO film layer and the polypropylene slurry are firstly prepared and then coated, so that the raw materials of all layers are mixed more uniformly, and the improvement of the color fastness to rubbing is facilitated.
In summary, the present application includes at least one of the following beneficial technical effects:
1. according to the application, the epoxy acrylate is modified by the quartz powder, and then the pearl powder and the titanium dioxide are adopted, so that the rubbing color fastness and the light fastness of the colorful surface layer are enhanced, the automobile interior can show colorful colors from the front, the rubbing color fastness can reach 6 levels, the light fastness reaches 6 levels, and the surface is not obviously damaged or peeled.
2. In the application, the silane coupling agent is preferably adopted to pretreat the quartz powder, so that the dispersibility of the quartz powder can be enhanced, the compatibility of the quartz powder and the modified epoxy acrylate can be enhanced, the wear resistance and the wear-resistant color fastness of the multicolor surface layer are enhanced, the rubbing color fastness can reach 6 levels, the light-resistant color fastness reaches 6 levels, and the surface is not obviously damaged or peeled off.
Detailed Description
The present application is described in further detail below with reference to specific contents.
Raw materials
The epoxy acrylate is selected from Suzhou Sen Fida chemical company; the average particle size of the pearl powder is 10 μm, and is selected from Ningbo Posth materials science and technology Co., Ltd; the average particle size of the titanium dioxide is 10 μm, and is selected from Hangzhou Hengge nanotechnology limited company; the dicyclopentenyl acrylate is selected from chemical material of Sanwang, Guangzhou; the ethylene glycol phenyl ether is selected from Jiangsu Jiafeng chemical company, Inc.; the photoinitiator is 2,4, 6-trimethyl benzoyl ethyl phosphonate and is selected from Henan Tianfu chemical company, Ltd; the m-phenylenediamine is selected from Nanjing Guang Jun chemical industry Co.Ltd; the gamma-glycidyl ether oxypropyl trimethoxy silane is selected from Jeccard chemical Co., Ltd, Hangzhou; the quartz powder has an average particle diameter of 15 μm and is selected from Kogyangshentai mining Co., Ltd; TPO particle is selected from New Material Co., Ltd, of Dongguan city, Xinrui; the aqueous polyurethane dispersion is selected from the new material of unicin, Guangzhou; the acrylic acid alkali swelling thickener is selected from Guandong Nanhui New Material Co; the curing agent is toluene diisocyanic acid vinegar and is selected from Shenzhen Shang sourced Biotech limited company; the light stabilizer is 292 selected from Qingdao Euglean functional materials science and technology limited; the antioxidant is diphenylamine and is selected from Suzhou Kaifa new material science and technology company; the flame retardant is aluminum hydroxide, the pigment is iron oxide 722R water-soluble black inorganic pigment, and is selected from Orminum iron oxide pigment factory in the Luquan area; the polypropylene foaming material is an EPP foaming polypropylene material, has the characteristics of light weight, heat insulation, buffering, insulation, corrosion prevention and the like, and is selected from the technical limited company of new materials for plastic and fertilizer combination.
Preparation example
Preparation example 1
A modified epoxy acrylate is prepared by the following method:
adding 28L of acetone into 7kg of quartz powder, carrying out ultrasonic dispersion for 40min under the power of 195W, adding 11.5kg of epoxy acrylate, carrying out ultrasonic dispersion for 40min under the power of 195W, adding 3.5kg of m-phenylenediamine, stirring for 17min to obtain a mixture, and then curing the mixture at the temperature of 85 ℃ for 5h to obtain the modified epoxy acrylate.
Preparation example 2
A modified TPO particle made by the process of:
10kg of TPO granules and 6kg of silica are put at the temperature of 135 ℃ for melting, 4kg of sodium hexametaphosphate is added, the mixture is stirred for 25min, and then the mixture is extruded and granulated to obtain the modified TPO granules.
Examples
Example 1
The TPO multicolor automobile interior material comprises the raw materials in the proportion shown in Table 1.
Wherein, the modified epoxy acrylate is prepared by the preparation example 1, and the modified TPO particles are prepared by the preparation example 2.
A preparation method of TPO multicolor automobile interior material comprises the following steps:
mixing the aqueous polyurethane dispersion, silicon dioxide and water, stirring for 30min, adding an acrylic acid-alkali swelling thickener and a curing agent, and stirring for 17min to obtain aqueous polyurethane slurry;
mixing the modified epoxy acrylate, the dicyclopentenyl acrylate, the photoinitiator and water, stirring for 32min to obtain a mixture, adding the pearl powder and the titanium dioxide into the mixture, stirring for 7min, adding the ethylene glycol phenyl ether, and stirring for 7min to obtain a magic color slurry; melting the polypropylene foaming material at the temperature of 195 ℃ to obtain polypropylene slurry;
s1: melting the modified TPO particles at 135 ℃, adding the auxiliary agent and the black pigment, mixing, stirring for 28min, extruding, pressing into a 0.5mm film, and drying at 70 ℃ for 4h to obtain a TPO film layer;
s2: uniformly coating polypropylene slurry on the surface of the TPO film layer, and drying at the temperature of 75 ℃ for 35min to form a PP Foam layer with the thickness of 0.3 mm; uniformly coating the surface of the PP Foam layer, which is far away from the TPO film layer, with water-based polyurethane slurry, drying at the temperature of 70 ℃ for 40min to form a back treatment layer with the thickness of 0.10mm, uniformly coating the multicolor slurry on the surface of the TPO film layer, which is far away from the PP Foam layer, drying at the temperature of 70 ℃ for 40min to form a multicolor surface layer with the thickness of 0.12mm, and obtaining a TPO multicolor base material to obtain a semi-finished product; uniformly coating the surface of the TPO multicolor substrate far away from the TPO film layer with water-based polyurethane slurry, and drying at the temperature of 80 ℃ for 25min to form a surface treatment layer with the thickness of 0.10 mm; obtaining the TPO multicolor automobile interior material.
Examples 2 to 5
The TPO multicolor automobile interior material is different from the material ratio of the example 1, and the material ratio is shown in the table 1.
TABLE 1 EXAMPLES 1-5TPO magic color automobile interior materials mixing amount (unit: kg)
Examples 6 to 9
The TPO multicolor automobile interior material is different from the TPO multicolor automobile interior material in the raw material ratio shown in the table 2.
TABLE 2 examples 6-9TPO magic color automobile interior materials mixing amount (unit: kg)
Examples 10 to 13
A TPO multicolor automotive interior material is different from that of example 7 in the raw material ratio shown in Table 3.
TABLE 3 examples 10-13TPO magic color automobile interior materials mixing amount (unit: kg)
Example 14
A TPO multicolor automotive interior material, which is different from example 11 in that quartz powder in the multicolor automotive interior material was pretreated before use by the following method:
putting gamma-glycidoxypropyltrimethoxysilane into an acetic acid solution with the mass fraction of 35%, stirring for 17min to obtain a mixture, then adding quartz powder into the mixture, stirring for 25min, then standing for 5h at the temperature of 70 ℃, then filtering, washing the solid with water for 4 times, and drying the solid at the temperature of 40 ℃ for 50min to obtain pretreated quartz powder; wherein the addition amount of the gamma-glycidoxypropyltrimethoxysilane is 5 wt% of the quartz powder, and the addition amount of acetic acid solution in 1kg of the gamma-glycidoxypropyltrimethoxysilane is 7L.
Example 15
The TPO multicolor automobile interior material is different from the embodiment 14 in that the titanium white in the multicolor automobile interior material is pretreated by the following method before use:
putting titanium dioxide into water, stirring for 20min to obtain a mixture, adding alumina into the mixture, stirring for 15min, adjusting the pH to 8.5 by using a sodium hydroxide solution, curing at the temperature of 80 ℃ for 2.5h, filtering, and drying at the temperature of 40 ℃ for 2h to obtain pretreated titanium dioxide; wherein, the addition amount of water in every 1kg of titanium dioxide is 3.5L, and the addition amount of alumina is 5 wt% of the titanium dioxide.
Comparative example
Comparative example 1
A TPO multicolor automotive interior material is different from the material in example 1 in that the same amount of epoxy acrylate is used to replace the modified epoxy acrylate.
Comparative example 2
The TPO multicolor automobile interior material is different from the embodiment 1 in that titanium dioxide is not added in the raw material of the multicolor surface layer of the multicolor automobile interior material.
Comparative example 3
A TPO multicolor automobile interior material is different from the example 1 in that silica is not added to the raw material of the water-based polyamide ester layer of the multicolor automobile interior material.
Comparative example 4
A TPO fantasy color automotive interior material, which is different from example 1 in that the modified TPO particles are replaced with the same amount of TPO particles in the raw material of the TPO film layer of the fantasy color automotive interior material.
Performance test
The semi-finished products prepared in examples 1 to 15 and comparative examples 1 to 4 were used as test specimens, and the following property tests were carried out:
rubbing fastness: the results of measuring the rubbing fastness of the automobile interior material according to QB/T2537-2001, reciprocating rubbing fastness of leather color fastness test, are shown in Table 4.
Color fastness to light: according to QB/T2727-2005, leather color fastness to light test: xenon arc "was used to measure the light fastness of the automotive interior material, and the measurement results are shown in table 4.
Wear resistance: the abrasion resistance of the automobile interior material was measured according to QB/T2726-2005, "measurement of abrasion resistance in physical and mechanical leather tests", and the results are shown in Table 4.
TABLE 4 test results
Note: the higher the level of the rubbing color fastness and the light fastness is, the higher the color fastness is, and the more stable the color is.
The automotive interior material has the advantages that the automotive interior material has excellent color fastness to rubbing, color fastness to light and wear resistance through the synergistic effect of the raw materials, so that the automotive interior can show different colors from the front, wherein the color fastness to rubbing is 4-6 grade, the color fastness to light is 4-6 grade, and the wear resistance is that the surface is not obviously damaged or peeled.
Combining example 1 and comparative example 1, it can be seen that the color fastness to rubbing in example 1 is grade 4, the color fastness to light is grade 4, the surface has no obvious damage or peeling, and the color fastness to light is better than that in comparative example 1, which indicates that the epoxy acrylate in the automotive interior material is more suitable for modification, and the color fastness to rubbing, the color fastness to light and the wear resistance of the automotive interior material can be enhanced.
Combining the example 1 and the comparative example 2, it can be seen that the rubbing color fastness in the example 1 is grade 4, the light color fastness is grade 4, the surface has no obvious damage and peeling, and the comparison example 2 is superior, which indicates that the addition of titanium dioxide in the automotive interior material is more suitable, and the rubbing color fastness, the light color fastness and the wear resistance of the automotive interior material can be enhanced.
Combining example 1 and comparative example 3, it can be seen that the rubbing color fastness in example 1 is grade 4, the light color fastness is grade 4, the surface has no obvious damage and peeling, and is better than that in comparative example 3, which indicates that the addition of silica to the automotive interior material is more suitable for enhancing the rubbing color fastness, the light color fastness and the wear resistance of the automotive interior material.
Combining example 1 and comparative example 4, it can be seen that the color fastness to rubbing in example 1 is grade 4, the color fastness to light is grade 4, the surface has no obvious damage and peeling, and is better than that in comparative example 3, which indicates that the modification of TPO particles in the automotive interior material is more suitable, and the color fastness to light and the wear resistance of the automotive interior material can be enhanced.
As can be seen by combining examples 1-5, the color fastness to rubbing in example 3 is grade 5, the color fastness to light is grade 5, and the surface is not obviously damaged or peeled, which is better than other examples, and shows that the addition amount of the modified epoxy acrylate in example 3 is more suitable, and the color fastness to rubbing, the color fastness to light and the wear resistance of the automotive interior material can be enhanced.
It can be seen from the combination of examples 6 to 9 that the rubbing color fastness in example 7 is grade 5, the light color fastness is grade 5, the surface has no obvious damage and peeling, and the addition amount of the pearl powder in example 7 is more suitable than that in other examples, so that the rubbing color fastness, the light color fastness and the wear resistance of the automotive interior material can be enhanced.
Combining example 11 with example 14, it can be seen that the rubbing color fastness of example 14 is grade 6, the light color fastness is grade 5, the surface has no obvious damage and peeling, and the result is better than that of example 11, which shows that the quartz powder is more suitable for pretreatment before use, and can enhance the rubbing color fastness, light color fastness and wear resistance of the automotive interior material.
Combining example 14 and example 15, it can be seen that example 15 has a crocking color fastness of 6 grade, a light fastness of 6 grade, and no obvious damage or peeling on the surface, which is superior to example 14, indicating that the titanium dioxide powder is more suitable for pretreatment before use, and can enhance the crocking color fastness, light fastness and wear resistance of the automotive interior material.
The embodiments of the present invention are preferred embodiments of the present application, and the scope of the present application is not limited by the embodiments of the present application, so: equivalent changes in structure, shape and principle of the present application shall be covered by the protection scope of the present application.
Claims (5)
1. A TPO multicolor automotive interior material is characterized in that: the automotive interior material sequentially comprises a surface treatment layer, a colorful surface layer, a TPO (thermoplastic polyolefin) film layer, a PP Foam layer and a back treatment layer from top to bottom, wherein the surface treatment layer and the back treatment layer are both aqueous polyurethane layers;
the waterborne polyurethane layer comprises the following raw materials in parts by weight: 50-75 parts of aqueous polyurethane dispersoid, 1-5 parts of silicon dioxide, 0.2-3.2 parts of acrylic acid alkali swelling thickener, 0.2-2.5 parts of curing agent and 10-40 parts of water;
the colorful surface layer comprises the following raw materials in parts by weight: 65-95 parts of modified epoxy acrylate, 12-35 parts of pearl powder, 6-15 parts of titanium dioxide, 2-6 parts of dicyclopentenyl acrylate, 1-5 parts of ethylene glycol phenyl ether, 1-5 parts of photoinitiator and 15-35 parts of water, wherein the modified epoxy acrylate is prepared by modifying epoxy acrylate with quartz powder;
the modified epoxy acrylate is prepared by the following method: adding acetone into quartz powder, performing ultrasonic dispersion for 30-50min under the power of 180 plus 210W, adding epoxy acrylate, performing ultrasonic dispersion for 30-50min under the power of 180 plus 210W, adding m-phenylenediamine, stirring for 15-20min to obtain a mixture, and then curing the mixture at the temperature of 80-90 ℃ for 4-6h to obtain modified epoxy acrylate;
the TPO membrane layer comprises the following raw materials in parts by weight: 85-100 parts of modified TPO particles, 0.3-9 parts of auxiliary agent and 0.5-7 parts of pigment;
the PP Foam layer is made of a polypropylene foaming material;
the weight ratio of the pearl powder to the modified epoxy acrylate is 1: (2.5-5);
the quartz powder is pretreated by adopting a silane coupling agent before use;
the quartz powder is pretreated by the following method: putting gamma-glycidoxypropyltrimethoxysilane into an acetic acid solution, stirring for 15-20min to obtain a mixture, then adding quartz powder into the mixture, stirring for 20-30min, standing at 60-80 ℃ for 4-6h, filtering, washing the solid for 3-5 times, and drying the solid at 50-60 ℃ for 40-60min to obtain pretreated quartz powder;
the titanium dioxide is pretreated by adopting alumina before use;
the titanium dioxide is pretreated by adopting the following method: putting titanium dioxide into water, stirring for 15-25min to obtain a mixture, adding alumina into the mixture, stirring for 10-20min, adjusting the pH to 8.5 by using a sodium hydroxide solution, curing at 70-90 ℃ for 2-3h, filtering, and drying at 30-50 ℃ for 1-3h to obtain pretreated titanium dioxide;
the modified TPO particles are prepared by modifying TPO particles by adopting silica;
the modified TPO granules were prepared as follows: melting TPO granules and silica at the temperature of 125-140 ℃, adding 3-5kg of sodium hexametaphosphate, stirring for 20-30min, extruding and granulating to obtain the modified TPO granules.
2. The TPO multicolor automotive interior material according to claim 1, wherein:
the waterborne polyurethane layer comprises the following raw materials in parts by weight: 55-70 parts of aqueous polyurethane dispersoid, 2-3 parts of silicon dioxide, 0.5-2.5 parts of acrylic acid alkali swelling thickener, 0.5-1.5 parts of curing agent and 15-35 parts of water;
the colorful surface layer comprises the following raw materials in parts by weight: 70-85 parts of modified epoxy acrylate, 16-32 parts of pearl powder, 8-12 parts of titanium dioxide, 3-5 parts of dicyclopentenyl acrylate, 2-4 parts of ethylene glycol phenyl ether, 2-4 parts of photoinitiator and 20-30 parts of water;
the TPO membrane layer comprises the following raw materials in parts by weight: 92-98 parts of modified TPO particles, 0.9-3.9 parts of auxiliary agent and 1-4 parts of pigment.
3. The TPO multicolor automotive interior material according to claim 1, wherein: the auxiliary agent comprises a light stabilizer, an antioxidant and a flame retardant, and the weight ratio of the light stabilizer to the antioxidant to the flame retardant is 1:1: 1.
4. The TPO multicolor automotive interior material according to claim 3, wherein: the light stabilizer is a hindered amine light stabilizer, the antioxidant is an amine antioxidant, and the flame retardant is an inorganic flame retardant.
5. A method for preparing the TPO multicolor automotive interior material according to any one of claims 1 to 4, comprising the steps of:
mixing the aqueous polyurethane dispersion, silicon dioxide and water, uniformly stirring, adding an acrylic acid-alkali swelling thickener and a curing agent, and uniformly stirring to obtain aqueous polyurethane slurry;
mixing the modified epoxy acrylate, the dicyclopentenyl acrylate, the photoinitiator and water, uniformly stirring to obtain a mixture, adding the pearl powder and the titanium dioxide into the mixture, uniformly stirring, adding the ethylene glycol phenyl ether, and uniformly stirring to obtain a multicolor slurry;
heating and melting the polypropylene foaming material to obtain polypropylene slurry;
s1: melting the modified TPO particles, adding the auxiliary agent and the pigment, uniformly mixing, extruding, pressing into a film, and drying to obtain a TPO film layer;
s2: uniformly coating polypropylene slurry on the surface of the TPO film layer, and drying to form a PP Foam layer; uniformly coating the surface of the PP Foam layer, which is far away from the TPO film layer, with water-based polyurethane slurry, drying to form a back treatment layer, uniformly coating the multicolor slurry on one surface of the TPO film layer, which is far away from the PP Foam layer, drying to form a multicolor surface layer, obtaining a TPO multicolor base material, and obtaining a semi-finished product; and uniformly coating the surface of the TPO multicolor substrate far away from the TPO film layer with water-based polyurethane slurry, drying, and forming a surface treatment layer to obtain the TPO multicolor automotive interior material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111621980.3A CN114292576B (en) | 2021-12-28 | 2021-12-28 | TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111621980.3A CN114292576B (en) | 2021-12-28 | 2021-12-28 | TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114292576A CN114292576A (en) | 2022-04-08 |
| CN114292576B true CN114292576B (en) | 2022-08-12 |
Family
ID=80970234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111621980.3A Active CN114292576B (en) | 2021-12-28 | 2021-12-28 | TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114292576B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115286831A (en) * | 2022-08-24 | 2022-11-04 | 苏州瑞高新材料有限公司 | Mildew-proof antibacterial TPO (thermoplastic polyolefin) automotive interior leather and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107177242A (en) * | 2017-05-24 | 2017-09-19 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | TPO automotive interior material of resistance to alcohol and preparation method thereof |
| CN107814969A (en) * | 2017-12-06 | 2018-03-20 | 东莞市瑞年塑胶科技有限公司 | A kind of translucent minute surface colorful film and preparation method thereof |
| CN108587351A (en) * | 2018-03-30 | 2018-09-28 | 上海长润化工有限公司 | A kind of automotive trim water transfer aqueous priming paint coating and preparation method thereof |
| CN112455016A (en) * | 2020-11-26 | 2021-03-09 | 上海诗冠印刷有限公司 | Preparation method of golden electrostatic sticker |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MXPA02010080A (en) * | 2000-04-14 | 2003-04-25 | Du Pont | Multilayer, co extruded, ionomeric decorative surfacing. |
| US6659223B2 (en) * | 2001-10-05 | 2003-12-09 | Collins & Aikman Products Co. | Sound attenuating material for use within vehicles and methods of making same |
| CN107351495B (en) * | 2017-05-24 | 2019-07-30 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | A kind of polychrome TPO automotive interior material and preparation method thereof |
| CN107177322A (en) * | 2017-06-30 | 2017-09-19 | 苏州瑞高新材料有限公司 | A kind of automotive trim TPO epidermises preparation method and TPO epidermises |
| CN109159513A (en) * | 2018-07-18 | 2019-01-08 | 苏州瑞高新材料有限公司 | A kind of soft TPO material and preparation method thereof for automobile interior decoration |
| CN113059877B (en) * | 2019-12-31 | 2023-02-28 | 苏州瑞高新材料有限公司 | Novel wood-like decorative leather for automobile interior and preparation method thereof |
| CN113119552B (en) * | 2019-12-31 | 2022-10-18 | 苏州瑞高新材料有限公司 | Novel safe, environment-friendly and lightweight automotive interior material and preparation method thereof |
-
2021
- 2021-12-28 CN CN202111621980.3A patent/CN114292576B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107177242A (en) * | 2017-05-24 | 2017-09-19 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | TPO automotive interior material of resistance to alcohol and preparation method thereof |
| CN107814969A (en) * | 2017-12-06 | 2018-03-20 | 东莞市瑞年塑胶科技有限公司 | A kind of translucent minute surface colorful film and preparation method thereof |
| CN108587351A (en) * | 2018-03-30 | 2018-09-28 | 上海长润化工有限公司 | A kind of automotive trim water transfer aqueous priming paint coating and preparation method thereof |
| CN112455016A (en) * | 2020-11-26 | 2021-03-09 | 上海诗冠印刷有限公司 | Preparation method of golden electrostatic sticker |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114292576A (en) | 2022-04-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN114292576B (en) | TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof | |
| CN110922874B (en) | Water-based acrylic polyurethane amino baking pearlescent paint and preparation method thereof | |
| CN102286240A (en) | PE (Polyurethane) gloss white paint | |
| CN107083150B (en) | A kind of UV coating for automobile interiors and its preparation method and application | |
| CN105538936B (en) | A kind of mobile phone glass form printing technology | |
| CN105837074B (en) | A kind of chemistry dye sand technique | |
| CN114410175B (en) | High-wear-resistance coating for automotive upholstery and preparation method thereof | |
| CN105907213A (en) | Marble-imitating colorful piece coating and preparation method of imitated marble | |
| CN108624126B (en) | Bi-component silk-screen glass printing ink and preparation and use methods thereof | |
| CN112521817A (en) | Single-component matte clear finish paint and preparation method thereof | |
| CN109705278B (en) | Water-based acrylic emulsion for automobile electrophoresis finish paint and preparation method thereof | |
| CN111349385A (en) | Polishing-free water-based primer surfacer matched with ceramic finish and preparation method thereof | |
| CN109181461B (en) | Environment-friendly water-based automobile metal flashing paint and preparation method thereof | |
| CN111978902B (en) | Two-component seam beautifying agent and preparation method thereof | |
| CN114539889B (en) | High-gloss weather-resistant high-temperature-resistant detergent powder coating and preparation method and application thereof | |
| CN111892871A (en) | High-toughness anti-crack rock slice paint and preparation method thereof | |
| CN109207053B (en) | Color coating composition and application method thereof | |
| CN103819991B (en) | Protection material suitable for dinosaur fossil and preparation method thereof | |
| CN112852292B (en) | Dyeing resin for sand dyeing | |
| CN113980533B (en) | Water-based acrylic resin coating | |
| CN110003762A (en) | A kind of preparation method of high tenacity intensity cathode electrodip painting coating | |
| CN115260797A (en) | Preparation method of colored aluminum powder pigment | |
| CN114736575A (en) | High-gloss boiling-resistant water-based silver powder baking paint for stainless steel tableware and preparation method thereof | |
| CN114958196A (en) | High-temperature-resistant black wrinkle powder coating and preparation method thereof | |
| CN113831775A (en) | Water-based inorganic mineral composite bright scratch-resistant varnish and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 215000 No. 5, Youyi Road, Huangjing Town Industrial Park, Taicang City, Suzhou City, Jiangsu Province Patentee after: Suzhou Rui High Tech Materials Co.,Ltd. Address before: 215000 No. 5, Youyi Road, Huangjing Town Industrial Park, Taicang City, Suzhou City, Jiangsu Province Patentee before: SUZHOU GREENTECH Co.,Ltd. |
|
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Gao Jingang Inventor after: Guo Jia Inventor after: Zhu Menglin Inventor after: Ren Zhongwei Inventor after: Li Chao Inventor before: Guo Jia Inventor before: Zhu Menglin Inventor before: Ren Zhongwei Inventor before: Li Chao Inventor before: Gao Jingang |