CN114292576A - TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof - Google Patents
TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof Download PDFInfo
- Publication number
- CN114292576A CN114292576A CN202111621980.3A CN202111621980A CN114292576A CN 114292576 A CN114292576 A CN 114292576A CN 202111621980 A CN202111621980 A CN 202111621980A CN 114292576 A CN114292576 A CN 114292576A
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- CN
- China
- Prior art keywords
- parts
- tpo
- multicolor
- layer
- automotive interior
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920002397 thermoplastic olefin Polymers 0.000 title claims abstract description 108
- 239000000463 material Substances 0.000 title claims abstract description 91
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 239000010410 layer Substances 0.000 claims abstract description 73
- 239000004743 Polypropylene Substances 0.000 claims abstract description 37
- 239000002344 surface layer Substances 0.000 claims abstract description 36
- 239000002002 slurry Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 27
- 229920002635 polyurethane Polymers 0.000 claims abstract description 26
- 239000004814 polyurethane Substances 0.000 claims abstract description 26
- 238000001035 drying Methods 0.000 claims abstract description 23
- 239000006260 foam Substances 0.000 claims abstract description 20
- -1 polypropylene Polymers 0.000 claims abstract description 19
- 229920001155 polypropylene Polymers 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 239000002335 surface treatment layer Substances 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 70
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 53
- 239000000843 powder Substances 0.000 claims description 53
- 235000012239 silicon dioxide Nutrition 0.000 claims description 42
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 38
- 239000010453 quartz Substances 0.000 claims description 32
- 238000003756 stirring Methods 0.000 claims description 28
- 239000004408 titanium dioxide Substances 0.000 claims description 26
- 239000002245 particle Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- 239000000377 silicon dioxide Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 13
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 10
- 239000004611 light stabiliser Substances 0.000 claims description 10
- 239000000049 pigment Substances 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 9
- LUCXVPAZUDVVBT-UHFFFAOYSA-N methyl-[3-(2-methylphenoxy)-3-phenylpropyl]azanium;chloride Chemical compound Cl.C=1C=CC=CC=1C(CCNC)OC1=CC=CC=C1C LUCXVPAZUDVVBT-UHFFFAOYSA-N 0.000 claims description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000003063 flame retardant Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 230000008961 swelling Effects 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- 238000005187 foaming Methods 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 4
- 239000011265 semifinished product Substances 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical compound O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000012796 inorganic flame retardant Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 23
- 239000011049 pearl Substances 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- 239000003086 colorant Substances 0.000 description 11
- 239000008187 granular material Substances 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 229940018564 m-phenylenediamine Drugs 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000001132 ultrasonic dispersion Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical group [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical group C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- YCIHPQHVWDULOY-FMZCEJRJSA-N (4s,4as,5as,6s,12ar)-4-(dimethylamino)-1,6,10,11,12a-pentahydroxy-6-methyl-3,12-dioxo-4,4a,5,5a-tetrahydrotetracene-2-carboxamide;hydrochloride Chemical compound Cl.C1=CC=C2[C@](O)(C)[C@H]3C[C@H]4[C@H](N(C)C)C(=O)C(C(N)=O)=C(O)[C@@]4(O)C(=O)C3=C(O)C2=C1O YCIHPQHVWDULOY-FMZCEJRJSA-N 0.000 description 1
- MTEZSDOQASFMDI-UHFFFAOYSA-N 1-trimethoxysilylpropan-1-ol Chemical compound CCC(O)[Si](OC)(OC)OC MTEZSDOQASFMDI-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000001034 iron oxide pigment Substances 0.000 description 1
- KCWDJXPPZHMEIK-UHFFFAOYSA-N isocyanic acid;toluene Chemical group N=C=O.N=C=O.CC1=CC=CC=C1 KCWDJXPPZHMEIK-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000011050 natural pearl Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
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CN202111621980.3A CN114292576B (en) | 2021-12-28 | 2021-12-28 | TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof |
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CN202111621980.3A CN114292576B (en) | 2021-12-28 | 2021-12-28 | TPO (thermoplastic polyolefin) multicolor automotive interior material and preparation method thereof |
Publications (2)
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CN114292576A true CN114292576A (en) | 2022-04-08 |
CN114292576B CN114292576B (en) | 2022-08-12 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115286831A (en) * | 2022-08-24 | 2022-11-04 | 苏州瑞高新材料有限公司 | Mildew-proof antibacterial TPO (thermoplastic polyolefin) automotive interior leather and preparation method thereof |
Citations (11)
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US20030066708A1 (en) * | 2001-10-05 | 2003-04-10 | Allison T. J. | Sound attenuating material for use within vehicles and methods of making same |
CN1430551A (en) * | 2000-04-14 | 2003-07-16 | 纳幕尔杜邦公司 | Multilayer co-extruded ionomeric decorative surfacing |
CN107177322A (en) * | 2017-06-30 | 2017-09-19 | 苏州瑞高新材料有限公司 | A kind of automotive trim TPO epidermises preparation method and TPO epidermises |
CN107177242A (en) * | 2017-05-24 | 2017-09-19 | 贝内克-长顺汽车内饰材料(张家港)有限公司 | TPO automotive interior material of resistance to alcohol and preparation method thereof |
CN107351495A (en) * | 2017-05-24 | 2017-11-17 | 贝内克-长顺汽车内饰材料(张家港)有限公司 | A kind of polychrome TPO automotive interior materials and preparation method thereof |
CN107814969A (en) * | 2017-12-06 | 2018-03-20 | 东莞市瑞年塑胶科技有限公司 | A kind of translucent minute surface colorful film and preparation method thereof |
CN108587351A (en) * | 2018-03-30 | 2018-09-28 | 上海长润化工有限公司 | A kind of automotive trim water transfer aqueous priming paint coating and preparation method thereof |
CN109159513A (en) * | 2018-07-18 | 2019-01-08 | 苏州瑞高新材料有限公司 | A kind of soft TPO material and preparation method thereof for automobile interior decoration |
CN112455016A (en) * | 2020-11-26 | 2021-03-09 | 上海诗冠印刷有限公司 | Preparation method of golden electrostatic sticker |
CN113059877A (en) * | 2019-12-31 | 2021-07-02 | 苏州瑞高新材料有限公司 | Novel wood-like decoration leather for automobile interior and preparation method thereof |
WO2021136230A1 (en) * | 2019-12-31 | 2021-07-08 | 苏州瑞高新材料有限公司 | Novel, safe and environmentally-friendly lightweight automotive interior material and preparation method therefor |
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2021
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CN1430551A (en) * | 2000-04-14 | 2003-07-16 | 纳幕尔杜邦公司 | Multilayer co-extruded ionomeric decorative surfacing |
US20030066708A1 (en) * | 2001-10-05 | 2003-04-10 | Allison T. J. | Sound attenuating material for use within vehicles and methods of making same |
CN107177242A (en) * | 2017-05-24 | 2017-09-19 | 贝内克-长顺汽车内饰材料(张家港)有限公司 | TPO automotive interior material of resistance to alcohol and preparation method thereof |
CN107351495A (en) * | 2017-05-24 | 2017-11-17 | 贝内克-长顺汽车内饰材料(张家港)有限公司 | A kind of polychrome TPO automotive interior materials and preparation method thereof |
CN107177322A (en) * | 2017-06-30 | 2017-09-19 | 苏州瑞高新材料有限公司 | A kind of automotive trim TPO epidermises preparation method and TPO epidermises |
CN107814969A (en) * | 2017-12-06 | 2018-03-20 | 东莞市瑞年塑胶科技有限公司 | A kind of translucent minute surface colorful film and preparation method thereof |
CN108587351A (en) * | 2018-03-30 | 2018-09-28 | 上海长润化工有限公司 | A kind of automotive trim water transfer aqueous priming paint coating and preparation method thereof |
CN109159513A (en) * | 2018-07-18 | 2019-01-08 | 苏州瑞高新材料有限公司 | A kind of soft TPO material and preparation method thereof for automobile interior decoration |
CN113059877A (en) * | 2019-12-31 | 2021-07-02 | 苏州瑞高新材料有限公司 | Novel wood-like decoration leather for automobile interior and preparation method thereof |
WO2021136230A1 (en) * | 2019-12-31 | 2021-07-08 | 苏州瑞高新材料有限公司 | Novel, safe and environmentally-friendly lightweight automotive interior material and preparation method therefor |
CN113119552A (en) * | 2019-12-31 | 2021-07-16 | 苏州瑞高新材料有限公司 | Novel safe, environment-friendly and lightweight automotive interior material and preparation method thereof |
CN112455016A (en) * | 2020-11-26 | 2021-03-09 | 上海诗冠印刷有限公司 | Preparation method of golden electrostatic sticker |
Non-Patent Citations (1)
Title |
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周杉鸿等: "热塑性弹性体材料在汽车轻量化研究中的应用", 《江苏科技信息》, no. 15, 30 May 2018 (2018-05-30), pages 40 - 42 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115286831A (en) * | 2022-08-24 | 2022-11-04 | 苏州瑞高新材料有限公司 | Mildew-proof antibacterial TPO (thermoplastic polyolefin) automotive interior leather and preparation method thereof |
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CN114292576B (en) | 2022-08-12 |
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CP01 | Change in the name or title of a patent holder |
Address after: 215000 No. 5, Youyi Road, Huangjing Town Industrial Park, Taicang City, Suzhou City, Jiangsu Province Patentee after: Suzhou Rui High Tech Materials Co.,Ltd. Address before: 215000 No. 5, Youyi Road, Huangjing Town Industrial Park, Taicang City, Suzhou City, Jiangsu Province Patentee before: SUZHOU GREENTECH Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder | ||
CB03 | Change of inventor or designer information |
Inventor after: Gao Jingang Inventor after: Guo Jia Inventor after: Zhu Menglin Inventor after: Ren Zhongwei Inventor after: Li Chao Inventor before: Guo Jia Inventor before: Zhu Menglin Inventor before: Ren Zhongwei Inventor before: Li Chao Inventor before: Gao Jingang |
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CB03 | Change of inventor or designer information |