CN114280705B - Preparation method of interference-resistant and stain-resistant laminating film, laminating film and screen - Google Patents

Preparation method of interference-resistant and stain-resistant laminating film, laminating film and screen Download PDF

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CN114280705B
CN114280705B CN202111673702.2A CN202111673702A CN114280705B CN 114280705 B CN114280705 B CN 114280705B CN 202111673702 A CN202111673702 A CN 202111673702A CN 114280705 B CN114280705 B CN 114280705B
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resistant
stain
micro
film
interference
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CN114280705A (en
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周鹏
曹建
沈渊
徐宇
王清
孙亮
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Kaixinsen Shanghai Functional Film Industry Co ltd
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Kaixinsen Shanghai Functional Film Industry Co ltd
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Abstract

The application discloses a preparation method of an interference-resistant and stain-resistant laminating film, a laminating film and a screen, wherein the laminating film comprises the following components: a micro-transmissive array film and a prismatic layer, the method comprising: bonding the prism layer under the micro-transparent array film; the peak pitch of the prisms of the prism layer is set to be 25-50 microns, and the peak tangent plane angle of the prisms is configured to be a triangle structure with an angle of 88-90 degrees; setting a prism layer attached to the micro-transparent array film as a shaking structure, wherein the shaking amplitude is larger than 6 microns; laminating the prism layer and the lower part of the micro-permeable array film by adopting PET laminating adhesive paint; the front surface of the micro-permeable array film is coated with a fouling resistant coating. Through the design of the prism microstructure and the new formula of the laminating adhesive, the peeling force of the finished product can be improved, layering in the using process and oversized laminating immersed parts are prevented, and the brightness of the finished product is ensured; and the anti-fouling formula is adopted, so that the smoothness of the front surface of the micro-permeable array film is greatly improved, and the micro-permeable array film is not easy to be polluted by latex gloves in the process of carrying.

Description

Preparation method of interference-resistant and stain-resistant laminating film, laminating film and screen
Technical Field
The application relates to the technical field of MOP laminating film preparation, in particular to a preparation method of an interference-resistant and stain-resistant laminating film, a laminating film and a screen.
Background
With the popularization of TFT-LCD liquid crystal display technology, the requirements for backlight modules and related optical films are increasing, and the requirements for cost are also increasing. The previously adopted 4-piece membrane framework is gradually replaced by three or even two membranes, and the requirements for stiffness and product thinning are increased along with the increasing of the size, and the requirements for membrane assembly of an assembly line are simplified.
Wherein, the MOP attaching film, microlens ON Prism, namely the composite film of the micro-permeable array film and the prism are attached together; the MOP has high performance balance degree and favorable price, so that the MOP is increasingly used in the market, two serious problems are faced by the common MOP, but along with popularization of high-definition televisions, 4K and 8K televisions are more and more popular, the MOP is poorer in shielding and is easier to interfere, and a lower prism structure of the MOP interferes with pixels of a television screen to form thick long strips or annular interference fringes. In addition, the MOP microcoloniens has a special structure (a uniform-height hemispherical structure) and has an unsmooth surface, so that white marks can be transferred after the MOP microcoloniens contacts latex gloves in the carrying process.
Therefore, the prior art needs to reduce interference and pollution on the premise of not affecting the performance of the MOP finished product.
Disclosure of Invention
The embodiment of the application provides a preparation method of an interference-resistant and stain-resistant laminating film, a laminating film and a screen, which are used for solving the problems that the conventional MOP laminating film is poor in interference and surface stain resistance.
A method for preparing an interference-resistant and stain-resistant laminating film, the material laminating film comprises: a micro-transmissive array film and a prismatic layer, the method comprising: bonding the prism layer under the micro-transparent array film;
the peak pitch of the prisms of the prism layer is set to be 25-50 microns, and the peak tangent plane angle of the prisms is configured to be a triangle structure with an angle of 88-90 degrees;
setting a prism layer attached to the micro-transparent array film as a shaking structure, wherein the shaking amplitude is larger than 6 microns;
laminating the prism layer and the lower part of the micro-permeable array film by adopting PET laminating adhesive paint;
the front surface of the micro-permeable array film is coated with a fouling resistant coating.
Preferably, the prism peak pitch of the prism layer is set to 25-50 micrometers specifically: the prism peak pitch is set to 45-50 microns.
Preferably, the method further comprises: the dithering period of the dithering structure is that the heights of the transversely extending peaks of the prisms are consistent, and the widths are configured to be 200-600 um;
the width of the extending wave trough is consistent and is configured to be 0.5-0.75 times of the width of the transverse extending wave crest.
Preferably, the method further comprises: the PET laminating adhesive coating is prepared by the following steps:
mixing acrylic acid active monomers and a photoinitiator, and stirring and dissolving uniformly;
adding acrylic resin and auxiliary agent, stirring and dissolving uniformly;
the composition ratio is as follows: 10-60 parts of acrylic acid active monomer, 30-60 parts of acrylic resin, 1-10 parts of photoinitiator and 0.1-5 parts of auxiliary agent.
Preferably, the stirring and dissolving are uniformly realized by stirring at a speed of 500-2000rpm for 30-120min.
Preferably, the method further comprises: and a step of filtering and purifying, wherein the uniformly mixed solution is filtered through a 0.5-micrometer filter bag.
Preferably, the stain-resistant coating is realized as:
mixing acrylic acid active monomers and a photoinitiator, and stirring and dissolving uniformly;
then adding acrylic resin and auxiliary agent, stirring and dissolving uniformly to obtain the target composition;
40-90 parts of acrylic acid active monomer, 5-30 parts of acrylic resin, 1-10 parts of photoinitiator and 0.1-5 parts of auxiliary agent of the stain-resistant coating.
Preferably, the method further comprises:
the stirring speed and time are 500-2000rpm, and stirring is carried out for 30-120min.
The anti-interference and anti-fouling laminating film is manufactured by adopting the preparation method of the anti-interference and anti-fouling laminating film.
A TFT-LCD liquid crystal display panel adopts the anti-interference and anti-fouling adhesive film.
According to the preparation method of the interference-resistant and stain-resistant laminating film, the laminating film and the screen, which are provided by the embodiment of the application, the problem that the dry phenomenon of the MOP laminating film is related to no stain resistance is displayed, and through the design of the prism microstructure, the peak structure of the prism is improved, and the shaking structure is arranged to reduce interference phenomenon; the new formula of the laminating adhesive is utilized, so that the peeling force of the finished product can be improved, layering in the using process and oversized laminating immersed parts are prevented, and the brightness of the finished product is ensured; and the application also adopts an anti-fouling formula, so that the smoothness of the front surface of the micro-permeable array film is greatly improved, and the micro-permeable array film is not easy to be polluted by latex gloves in the process of carrying.
Additional features and advantages of the application will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the application. The objectives and other advantages of the application will be realized and attained by the structure particularly pointed out in the written description and claims thereof as well as the appended drawings.
Drawings
The accompanying drawings, which are included to provide a further understanding of the application and are incorporated in and constitute a part of this specification, illustrate embodiments of the application and together with the description serve to explain the application and do not constitute a limitation on the application. In the drawings:
FIGS. 1 a-1 c are schematic diagrams illustrating prism layer structures of prior art MOP films according to embodiments of the present application;
FIG. 1d is a schematic view showing brightness performance of a prism layer of a prior art MOP laminated film according to an embodiment of the present application;
FIG. 2a is a schematic flow chart of a method for preparing an anti-interference and anti-fouling adhesive film according to an embodiment of the application;
FIGS. 2b-2c are schematic diagrams of prism layer structures of a method for preparing an anti-interference and anti-fouling adhesive film according to an embodiment of the present application;
FIG. 3 is a schematic diagram of a process for preparing a PET laminating adhesive coating according to an embodiment of the present application;
fig. 4 is a schematic diagram of a preparation flow of a stain-resistant coating material according to an embodiment of the present application.
Detailed Description
In order to promote information, the embodiment of the application provides a preparation method of an interference-resistant and stain-resistant laminating film, a laminating film and a screen. In order to better understand the technical solution provided by the embodiments of the present application, the important concepts of the solution are basically briefly described below:
referring to fig. 1a, in the prism structure of the conventional MOP laminated film structure layer, a large prism peak Pitch equal-height structure (Pitch is between 60 and 70um, and there are one or more pitches with different sizes), the total Pitch value falls in the interval, and the peak of the prism layer and the back of the diffusion layer are adhered together by using adhesive, referring to fig. 1b, the actual situation is that the adhesive has a thickness, a part of the peak of the prism layer is immersed into the adhesive layer, the more the immersed part is, the lower the brightness of the finished product is caused, in other words, the smaller the density of the prism structure peak is, the smaller the area to which the adhesive is adhered is, and the higher the brightness of the finished product is caused, referring to fig. 1c, in the same unit area.
Because the pitch of the prism structure is between 60um and 80um, and exceeds the conventional distance between 60um and 70um, the prism can easily form interference fringes with pixel units of a high-definition screen, and the larger the pitch is, the higher the interference risk is.
In addition, the MOP micro structure has special (equal-height hemispherical structure) surface not smooth, and white printing dirt transfer printing is caused after the MOP micro structure contacts with the latex glove in the conveying process.
The embodiment of the application provides a preparation method of an interference-resistant and stain-resistant laminating film, a laminating film and a screen, which are used for solving the problems that the conventional MOP laminating film is poor in interference and surface stain resistance.
The method for preparing the anti-interference and anti-fouling laminating film according to the embodiment of the application is further described below with reference to the accompanying drawings, as shown in fig. 2a, and the method comprises the following steps: the conformable film includes: a micro-transmissive array film and a prismatic layer, wherein:
s21, bonding the prism layer below the micro-permeable array film;
MOP laminated film, microlens ON Prism, i.e. composite film of micro-transparent array film and prism laminated together
The MOP laminating film structure is respectively a structural layer (prism layer) and a Microlens layer from bottom to top, and the structural surface of the structural layer (prism layer) and the back surface of the Microlens layer are adhered by compound adhesive
The front surface of Microlens is a hemispherical structure arranged in a certain order.
S22, setting the peak pitch of the prisms of the prism layer to be 25-50 microns, and configuring the peak tangent plane angle of the prisms to be a triangle structure with an angle of 88-90 degrees;
referring to fig. 2b, the prism peak pitch of the prism layer is set to 25-50 micrometers specifically: the prism peak pitch is set to 45-50 microns.
The prism layer has triangular structure with apex angle of 88-90 deg. and peak pitch (pitch) of 25-50 microns (45-50 um is preferable). The peaks of the prisms are processed into special structures with staggered height. The vibration rules of two adjacent prism structures are consistent, so that high points and low points in the cross sections of all the prisms are ensured to be on the same horizontal line.
The prism peak pitch of the prism layer becomes smaller, resulting in a reduction in brightness of the finished product, namely: the small structure can lead light to not collect towards the middle area, and the contact surface between the prism peak and the laminating adhesive in unit area is increased, thus the brightness of the product is reduced,
s23, setting a prism layer attached to the micro-transparent array film to be a shaking structure, wherein the shaking amplitude is larger than 6 microns;
the jitter amplitude refers to: jitter peak and jitter valley height fall.
In fig. 2b to fig. 2c, the dithering period of the dithering structure is that the heights of the transversely extending peaks of the prisms are consistent, and the widths are configured to be 200-600 um;
the width of the extending wave trough is consistent and is configured to be 0.5-0.75 times of the width of the transversely extending wave crest
The specific numerical values can be determined according to actual production requirements, and experimental data refer to the following table data:
structure of the In the unit surface joint of the finished product, the prism peak and the bonding adhesive joint area are/mm < 2 >
Equal-height 70pitch 0.143mm 2
Equal-height 60pitch 0.167mm 2
Equal height 50pitch 0.2mm 2
Dithering 50pitch 0.1mm 2 Dithering structure
Equal-height 40pitch 0.25mm 2
Dithering 40pitch 0.125mm 2 Dithering structure
The problem of interference is solved by reducing the peak pitch of the prisms, the contact area of the prism peaks in unit area and the adhesive can be reduced by using dithering, and the brightness of the product is ensured.
S24, laminating the prism layer and the lower part of the micro-permeable array film by adopting PET laminating adhesive paint;
due to the shaking design, the prism peak and the bonding adhesive area are reduced in a unit area, the bonding force between the upper layer and the lower layer is poor due to the small contact area, and then the bonding force is improved on the basis of the same contact surface through the bonding adhesive.
And S25, coating the front surface of the micro-permeable array film with a stain-resistant coating.
The anti-fouling formula is adopted, so that the smoothness of the front surface of the micro-permeable array film is greatly improved, and the micro-permeable array film is not easy to be polluted by latex gloves in the process of carrying
Referring to fig. 3, the preparation process of the pet laminating adhesive coating comprises the following steps:
s31, mixing acrylic acid active monomers and photoinitiators, and stirring and dissolving uniformly;
specifically, the acrylic acid active monomer comprises one or more of o-phenylphenoxyethyl acrylate, (ethoxy) phenol acrylate, 2-phenoxyethyl acrylate, isobornyl acrylate, acryloylmorpholine, tetrahydrofurfuryl acrylate, N-dimethylacrylamide, 1, 6-hexanediol diacrylate, tripropylene glycol diacrylate, (ethoxy) bisphenol A diacrylate, 4 (ethoxy) bisphenol A diacrylate, 10 (ethoxy) bisphenol A diacrylate, 20 (ethoxy) bisphenol A diacrylate, 30 (ethoxy) bisphenol A diacrylate, trimethylolpropane triacrylate, pentaerythritol tetraacrylate and dipentaerythritol hexapentaacrylate;
the photoinitiator comprises one or more of PI184, PI 907, PI TPO, PI BP, PI819 and PI 1173;
s32, adding acrylic resin and an auxiliary agent, and uniformly stirring and dissolving;
the acrylic resin comprises one or more of polyurethane acrylic resin, epoxy acrylic resin, polyester acrylic resin and polycarbonate acrylic resin;
the auxiliary agent is an organosilicon auxiliary agent or a modified organosilicon auxiliary agent, and comprises one or more of BYK 306, BYK 373, BYK 315, BYK 325, BYK 331, BYK333, BYK3500, BYK3505, BYK3510, BYK3530, BYK3535, BYK3570, BYK3575, ZG 400, TEGO100, TEGO410, TEGO450 and TEGO 432;
the composition ratio is as follows: 10-60 parts of acrylic acid active monomer, 30-60 parts of acrylic resin, 1-10 parts of photoinitiator and 0.1-5 parts of auxiliary agent.
And S33, filtering the uniformly mixed solution through a 0.5-micrometer filter bag.
Alternatively the method is such that the stirring and dissolving is carried out uniformly for 30-120min at a speed of 500-2000 rpm.
The adhesive glue using the formula improves the bonding force on the basis of the same contact surface through the adhesive glue, namely: the same contact area peel force can be improved by 50%, experimental data refer to the following table:
for brightness, even with a small PTICH of 40-50, the peel force can reach values of 60-70 pitch large structures after the new laminating adhesive is used. The new structure can make the luminance of MOP reach the high structure such as big pitch, and experimental data refer to the following table:
referring to fig. 4, the preparation of the stain-resistant coating is realized as follows:
s41, mixing acrylic acid active monomers and photoinitiators, and stirring and dissolving uniformly;
s42, adding acrylic resin and an auxiliary agent, and uniformly stirring and dissolving to obtain a target composition;
40-90 parts of acrylic acid active monomer, 5-30 parts of acrylic resin, 1-10 parts of photoinitiator and 0.1-5 parts of auxiliary agent of the stain-resistant coating.
The stirring speed and time are sufficient to achieve uniform mixing, and preferably at 500-2000rpm for 30-120min.
Preferred acrylic acid active monomers are one or more of o-phenylphenoxyethyl acrylate, 2-phenoxyethyl acrylate, isobornyl acrylate, 1, 6-hexanediol diacrylate, tripropylene glycol diacrylate, (ethoxy) bisphenol A diacrylate, 4 (ethoxy) bisphenol A diacrylate, 10 (ethoxy) bisphenol A diacrylate, 20 (ethoxy) bisphenol A diacrylate, 30 (ethoxy) bisphenol A diacrylate and trimethylolpropane triacrylate;
preferably, the acrylic resin is one or more of polyurethane acrylic resin and polyester acrylic resin;
the photoinitiator is preferably one or more of PI184, PITPO, PI819 and PI 1173;
the auxiliary agent is an organosilicon auxiliary agent or a modified organosilicon auxiliary agent, and the preferable organosilicon auxiliary agent or modified organosilicon auxiliary agent is one or more of BYK333, BYK3500, BYK3505, BYK3510, BYK3530, TEGO100, TEGO410, TEGO450 and TEGO 432;
the preparation method of the composition further comprises a step of filtering and purifying, wherein the filtering specifically means that the uniformly mixed solution is filtered through a 0.5-micrometer filter bag and a 0.1-micrometer filter core.
The anti-fouling capability of the anti-fouling paint prepared by the anti-fouling formula is greatly improved, and the following table is referred to:
before improvement After improvement
Anti-fouling gram weight 100g~200g 1000g~1200g
The application also discloses an interference-resistant and pollution-resistant laminating film, which is prepared by adopting the preparation method of the interference-resistant and pollution-resistant laminating film in the embodiment.
In the application, a TFT-LCD liquid crystal display panel is also disclosed, which comprises the anti-interference and anti-pollution attaching film in the embodiment.
To sum up:
according to the preparation method of the interference-resistant and stain-resistant laminating film, the laminating film and the screen, which are provided by the embodiment of the application, the problem that the dry phenomenon of the MOP laminating film is related to no stain resistance is displayed, and through the design of the prism microstructure, the peak structure of the prism is improved, and the shaking structure is arranged to reduce interference phenomenon; the new formula of the laminating adhesive is utilized, so that the peeling force of the finished product can be improved, layering in the using process and oversized laminating immersed parts are prevented, and the brightness of the finished product is ensured; and the application also adopts an anti-fouling formula, so that the smoothness of the front surface of the micro-permeable array film is greatly improved, and the micro-permeable array film is not easy to be polluted by latex gloves in the process of carrying.
While preferred embodiments of the present application have been described, additional variations and modifications in those embodiments may occur to those skilled in the art once they learn of the basic inventive concepts. It is therefore intended that the following claims be interpreted as including the preferred embodiments and all such alterations and modifications as fall within the scope of the application.
It will be apparent to those skilled in the art that various modifications and variations can be made to the present application without departing from the spirit or scope of the application. Thus, it is intended that the present application also include such modifications and alterations insofar as they come within the scope of the appended claims or the equivalents thereof.

Claims (7)

1. An interference-resistant and stain-resistant laminated film, characterized in that the interference-resistant and stain-resistant laminated film comprises: a micro-transparent array film and a prism layer, the prism layer being adhered under the micro-transparent array film;
the prism peak pitch of the prism layer is set to be 25-50 microns, and the prism peak tangent plane angle is configured to be a triangle structure with an angle of 88-90 degrees;
setting a prism layer attached to the micro-transparent array film as a dithering structure, wherein the dithering period of the dithering structure is that the heights of transversely extending peaks of the prisms are consistent, and the dithering amplitude is larger than 6 microns;
laminating the prism layer and the lower part of the micro-permeable array film by adopting PET laminating adhesive paint; the PET laminating adhesive coating comprises the following components in percentage by weight: 10-60 parts of acrylic acid active monomer, 30-60 parts of acrylic resin, 1-10 parts of photoinitiator and 0.1-5 parts of auxiliary agent;
the front surface of the micro-permeable array film is coated with a stain-resistant coating, wherein the stain-resistant coating comprises 40-90 parts of acrylic acid active monomer, 5-30 parts of acrylic resin, 1-10 parts of photoinitiator and 0.1-5 parts of auxiliary agent.
2. The interference-resistant and stain-resistant laminating film according to claim 1, wherein the prism peak pitch of the prism layer is set to 45-50 microns.
3. The interference resistant and stain resistant conformable film of claim 2 further comprising: the dithering period of the dithering structure is that the heights of the transversely extending peaks of the prisms are consistent, and the widths of the transversely extending peaks are configured to be 200-600 um;
the width of the extending wave trough is consistent and is configured to be 0.5-0.75 times of the width of the transverse extending wave crest.
4. A method for producing an interference-resistant and stain-resistant laminated film according to any one of claim 1 to 3,
the preparation process of the PET laminating adhesive coating comprises the following steps: mixing acrylic acid active monomers and a photoinitiator, and stirring and dissolving uniformly; adding acrylic resin and auxiliary agent, stirring and dissolving uniformly;
the preparation method of the stain-resistant coating comprises the following steps: mixing acrylic acid active monomers and a photoinitiator, and stirring and dissolving uniformly; adding acrylic resin and auxiliary agent, stirring and dissolving uniformly to obtain the target composition.
5. The method for producing an interference-resistant and stain-resistant laminated film according to claim 4, wherein the stirring and dissolving are carried out uniformly for 30 to 120 minutes at a speed of 500 to 2000 rpm.
6. The method for producing an interference-resistant and stain-resistant conformable film according to claim 4, further comprising: the paint preparation also includes the step of filtration and purification, and the uniformly mixed solution is filtered through a 0.5 micron filter bag.
7. A TFT-LCD liquid crystal display panel comprising the interference-resistant and stain-resistant adhesive film of any of claims 1-3.
CN202111673702.2A 2021-12-31 2021-12-31 Preparation method of interference-resistant and stain-resistant laminating film, laminating film and screen Active CN114280705B (en)

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KR20130129605A (en) * 2012-05-21 2013-11-29 한국과학기술원 High fill-factor lens array for using fluoro-polymer thin film coating and manufacturing method thereof
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