CN114262531A - Inorganic anticorrosive paint prepared from pure nano modified inorganic mineral substance by non-chemical method - Google Patents

Inorganic anticorrosive paint prepared from pure nano modified inorganic mineral substance by non-chemical method Download PDF

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Publication number
CN114262531A
CN114262531A CN202210063404.XA CN202210063404A CN114262531A CN 114262531 A CN114262531 A CN 114262531A CN 202210063404 A CN202210063404 A CN 202210063404A CN 114262531 A CN114262531 A CN 114262531A
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China
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inorganic
parts
anticorrosive paint
chemical method
mineral substance
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CN202210063404.XA
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傅锋辉
邓福南
姚二小
刘守辉
李志浩
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Huazhu Lvjian Beijing Technology Co ltd
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Huazhu Lvjian Beijing Technology Co ltd
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Abstract

The invention belongs to the technical field of anticorrosive coatings, and particularly relates to an inorganic anticorrosive coating prepared by a pure nano modified inorganic mineral substance non-chemical method. The inorganic anticorrosive paint prepared by the pure nano modified inorganic mineral substance non-chemical method has high corrosion resistance and low requirement on chemical raw materials, so that the inorganic anticorrosive paint has low production cost, can be mass-produced and widely used, has good fireproof performance and high temperature resistance, has low requirement on spraying surface treatment, and is convenient to use.

Description

Inorganic anticorrosive paint prepared from pure nano modified inorganic mineral substance by non-chemical method
Technical Field
The invention belongs to the technical field of anticorrosive coatings, and particularly relates to an inorganic anticorrosive coating prepared by a pure nano modified inorganic mineral non-chemical method.
Background
The loss of corrosion to human beings is remarkable, economic loss caused by corrosion is huge every year, huge loss stimulates the development of anticorrosive coatings, heavy anticorrosive coatings refer to coatings capable of long-acting protection in harsh corrosive environments, the protection life is generally more than 10 years, the heavy anticorrosive coatings can be used for 3-5 years in corrosive medium environments such as acid, alkali, salt and solvents at a certain temperature, the anticorrosive coatings can form a layer of thin film on the building surface to isolate the building surface from air, so that the anticorrosive effect is achieved, the anticorrosive thin film formed by curing the anticorrosive coatings has certain weather resistance, water resistance, extensibility, elastoplasticity and crack resistance, and the anticorrosive, anti-seepage and protective effects can be achieved, and the existing anticorrosive coatings have the following problems:
1. the existing anticorrosive paint has poor corrosion resistance, is particularly seriously dependent on chemical raw materials, has high cost, is not beneficial to mass production and is widely used;
2. the existing anticorrosive paint has poor fireproof performance and high temperature resistance and has high requirement on spraying surface treatment.
Aiming at the problems, innovative design is urgently needed on the basis of the original anticorrosive paint.
Disclosure of Invention
The invention aims to provide an inorganic anticorrosive paint prepared by a pure nano modified inorganic mineral substance non-chemical method, and aims to solve the problems that the existing anticorrosive paint in the background art has poor corrosion resistance, especially has serious dependence on chemical raw materials, high cost, is not beneficial to mass production and wide use, has poor fireproof performance and high temperature resistance, and has high requirement on spraying surface treatment.
In order to achieve the purpose, the invention provides the following technical scheme: the utility model provides an inorganic anticorrosive coating that inorganic mineral substance non-chemical method of pure nanometer modification was made, includes inorganic anticorrosive coating layer and seal box, inorganic anticorrosive coating layer includes powder group and liquid group, and the below of inorganic anticorrosive coating layer is provided with the manganese steel sheet, the below of manganese steel sheet is provided with the fly leaf, and the upper surface inside of fly leaf has seted up square groove, the edge of square groove is provided with the extension groove, the lower fixed surface of fly leaf installs first slider, and the below of first slider is provided with first spout, the outside of first spout is provided with the bottom plate, the seal box is located the top of bottom plate, and the inner wall of seal box has seted up the second spout, the internally mounted of second spout has the second slider.
Optionally, the powder group comprises 20-30 parts of quartz powder, 20-30 parts of nano fly ash, 10-20 parts of metakaolin, 5-15 parts of barite, 1-3 parts of nano master batch, 0.5-1.5 parts of toughening agent, 5-15 parts of titanium dioxide and 8-16 parts of iron oxide pigment.
Optionally, the liquid group comprises 25-35 parts of nano inorganic resin, 20-30 parts of nano modifier, 30-40 parts of water, 5-15 parts of water-soluble rare earth, 0.1-0.5 part of defoaming agent and 0-2 parts of thickening agent.
Optionally, the weight mixing ratio range between the powder group and the liquid group is 1: 1.1-1: 1.3.
Optionally, the liquid group is strongly alkaline, and the ph of the liquid group ranges from 13 to 14.
Optionally, the upper surface of the manganese steel plate is attached to the lower surface of the inorganic anticorrosive coating layer, the external dimension of the manganese steel plate is matched with the internal dimension of the square groove, and the vertical central lines of the extending grooves are symmetrical about the manganese steel plate.
Optionally, the movable plate and the bottom plate form a sliding structure through the first sliding block and the first sliding groove, and the movable plate and the first sliding block are welded.
Optionally, the second sliding block is connected with the side plate, and an electric heating wire is fixedly mounted on the surface of the side plate.
Optionally, the number of the side plates is two, and the side plates are connected with the seal box in a sliding mode through the second sliding grooves and the second sliding blocks.
Compared with the prior art, the invention has the beneficial effects that: the inorganic anticorrosive paint prepared by the pure nano modified inorganic mineral substance non-chemical method has high corrosion resistance and low requirement on chemical raw materials, so that the inorganic anticorrosive paint has low production cost, can be mass-produced and widely used, has good fireproof performance and high temperature resistance, has low requirement on spraying surface treatment, and is convenient to use.
1. The inorganic anticorrosive coating uses nano aluminosilicate to modify inorganic mineral substances, forms an inorganic polymer network with nano island chains connected in series as a film forming substance, blocks the pore gaps of the film by using nano materials to isolate air and water from corroding a metal base surface, uses the crystal of the nano materials after the nano materials penetrate into the capillary pores of the base material as a crystal whisker to be used as a main grabbing force, and when the metal surface has rust, the nano materials grab the metal base surface under the rust through the gap of rust molecules to realize spraying with the rust;
2. the product adopts nano materials to modify inorganic minerals to generate a nano cage with the diameter of 20 nanometers, and atoms on the surface of metal are locked in the nano cage, so that the super-strong salt mist resistance and the super-strong acid-base salt resistance are realized, meanwhile, the novel non-chemical coating components are inorganic materials, and the excellent characteristics of zero voc and harmful substances, A1-grade fire resistance, 1200-degree high temperature resistance, aging resistance and the like are naturally realized;
3. the device is provided with curb plate, second spout, second slider, electric heating wire and seal box, makes the inside temperature of seal box rise through electric heating wire, and higher temperature can accelerate inorganic anticorrosive paint's solidification to shorten the time of inorganic anticorrosive paint experiment.
Drawings
FIG. 1 is a schematic structural diagram of the formula of the inorganic anticorrosive paint of the present invention;
FIG. 2 is a schematic view of the seal box of the present invention;
FIG. 3 is a schematic top view of the movable plate of the present invention;
fig. 4 is a schematic front view of the side panel of the present invention.
In the figure: 1. an inorganic anti-corrosion coating layer; 101. a powder group; 102. a liquid group; 2. a manganese steel sheet; 3. a movable plate; 4. a square groove; 5. an extension groove; 6. a first slider; 7. a first chute; 8. a base plate; 9. a sealing box; 10. a second chute; 11. a second slider; 12. a side plate; 13. an electric heating wire.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1-4, the present invention provides a technical solution: the utility model provides an inorganic anticorrosive paint that inorganic mineral substance non-chemical method of pure nanometer modification was made, including inorganic anticorrosive paint layer 1 and seal box 9, inorganic anticorrosive paint layer 1 includes powder group 101 and liquid group 102, and the below of inorganic anticorrosive paint layer 1 is provided with manganese steel sheet 2, manganese steel sheet 2's below is provided with fly leaf 3, and square groove 4 has been seted up to the upper surface inside of fly leaf 3, the edge of square groove 4 is provided with extension groove 5, the lower fixed surface of fly leaf 3 installs first slider 6, and the below of first slider 6 is provided with first spout 7, the outside of first spout 7 is provided with bottom plate 8, seal box 9 is located the top of bottom plate 8, and the inner wall of seal box 9 has seted up second spout 10, the internally mounted of second spout 10 has second slider 11.
Further, the powder group 101 comprises 20-30 parts of quartz powder, 20-30 parts of nano fly ash, 10-20 parts of metakaolin, 5-15 parts of barite, 1-3 parts of nano master batch, 0.5-1.5 parts of toughening agent, 5-15 parts of titanium dioxide and 8-16 parts of iron oxide pigment, the main components of the nano master batch in the product are nano aluminum oxide and silicon oxide, the aluminum oxide and the silicon oxide are mixed according to the proportion of 1: 0.2-1: 5 to prepare the nano master batch, the main component of the toughening agent is hydroxypropyl methyl cellulose with the viscosity of 100-400, the inorganic anticorrosive coating uses nano aluminosilicate modified inorganic mineral matter to form an inorganic polymer network with nano island chains connected in series as a film forming substance, the nano material is used for blocking film hole gaps to realize the corrosion isolation of air and water to a metal base surface, the nano material is used for crystallizing as a whisker to serve as a main grabbing force after penetrating into capillary holes of the base material, when the metal surface has the rust, the nano material grabs the metal base surface under the rust through the rust molecular gap to realize spraying with the rust;
further, the liquid group 102 comprises 25-35 parts of nano inorganic resin, 20-30 parts of nano modifier, 30-40 parts of water, 5-15 parts of water-soluble rare earth, 0.1-0.5 part of defoamer and 0-2 parts of thickener, wherein the nano inorganic resin is prepared by fusing inorganic silicon and organic silicon at high temperature and performing hybrid grafting, the nano modifier is aluminosilicate as a raw material, the aluminosilicate is ground to 100 nm level to form the required nano modifier, the water-soluble rare earth is various lanthanide series rare earth salts, the defoamer is a water-soluble silane defoamer, and the thickener is formed by hybridizing various water-soluble celluloses,
further, the weight mixing ratio range of the powder group 101 to the liquid group 102 is 1: 1.1-1: 1.3, the coating is prepared by mixing the powder group 101 and the liquid group 102, the effect of the coating prepared from the powder group 101 and the liquid group 102 in different parts is different, and multiple test results show that when the mixing ratio range of the powder group 101 to the liquid group 102 is 1: 1.1-1: 1.3, the coating can realize the excellent characteristics of zero voc and harmful substances, A1-grade fire resistance, high temperature resistance of 1200 ℃, aging resistance and the like;
further, the liquid group 102 is strong alkaline, the ph value of the liquid group 102 ranges from 13 to 14, the nano material modifies the inorganic mineral to generate a nano cage of 20 nanometers, and atoms on the metal surface are locked into the nano cage, so that the super-strong salt mist resistance and the super-strong acid, alkali and salt resistance are realized;
further, the upper surface of the manganese steel plate 2 is attached to the lower surface of the inorganic anti-corrosion coating layer 1, the external size of the manganese steel plate 2 is matched with the internal size of the square groove 4, the extending grooves 5 are symmetrical about the vertical central line of the manganese steel plate 2, the manganese steel plate 2 is placed inside the square groove 4, then the powder group 101 and the liquid group 102 are mixed according to a certain proportion to prepare an inorganic anti-corrosion coating, the inorganic anti-corrosion coating is coated on the surface of the manganese steel plate 2, and the extending grooves 5 are used for taking and placing the manganese steel plate 2;
further, the movable plate 3 forms a sliding structure with the bottom plate 8 through the first sliding block 6 and the first sliding groove 7, and the movable plate 3 and the first sliding block 6 are welded, after the inorganic anticorrosive paint is completely coated, the movable plate 3 can be pushed inwards, so that the first sliding block 6 moves inwards along the first sliding groove 7 until the movable plate 3 is pushed into the seal box 9, the temperature in the seal box 9 is higher, and the inorganic anticorrosive paint layer 1 on the surface of the manganese steel plate 2 is more easily solidified at the higher temperature, so that the time required by an experiment is shortened;
further, the second sliding block 11 is connected with the side plate 12, the surface of the side plate 12 is fixedly provided with an electric heating wire 13, and the electrifying temperature of the electric heating wire 13 is increased, so that the internal temperature of the sealing box 9 is increased, and the solidification speed of the inorganic anticorrosive coating layer 1 is increased;
further, curb plate 12 is provided with two altogether, and curb plate 12 passes through second spout 10 and second slider 11 and seal box 9 sliding connection, curb plate 12 is connected with electric heating wire 13 integration, curb plate 12 can drive electric heating wire 13 and remove, after inorganic anticorrosive paint experiment finishes, can pull out electric heating wire 13 from seal box 9 is inside, make seal box 9 internal temperature drop to normal temperature fast, secondly electric heating wire 13 appears after the short circuit phenomenon, can take out the maintenance from seal box 9 is inside.
The working principle is as follows: when the product is used, firstly, a powder group 101 and a liquid group 102 are prepared into an inorganic anticorrosive coating according to different proportions, wherein the first proportion comprises 25 parts of quartz powder, 15 parts of metakaolin, 25 parts of nano fly ash, 10 parts of barite, 2.5 parts of nano potassium aluminosilicate, 0.5 part of 200-viscosity hydroxypropyl methyl cellulose, 15 parts of titanium dioxide rutile, 7 parts of iron oxide red, 30 parts of nano inorganic resin, 15 parts of nano modifier, 40 parts of water, 10 parts of water-soluble rare earth, 0.2 part of defoamer and 5 parts of thickener, the powder group 101 and the liquid group 102 are mixed and stirred according to a proportion of 1:1.2 for 120 seconds, then the manganese steel plate 2 is sprayed on the manganese steel plate 2 for a steel structure, the manganese steel plate 2 is placed in a square groove 4, then a movable plate 3 is pushed inwards, so that a first sliding block 6 moves inwards along the first sliding groove 7 until the movable plate 3 is pushed into a sealing box 9, the electrifying temperature of an electric heating wire 13 rises, the temperature in the seal box 9 rises, the inorganic anticorrosive coating layer 1 on the surface of the manganese steel plate 2 is accelerated to solidify at a higher temperature, and the second mixture comprises 30 parts of quartz powder, 10 parts of metakaolin, 20 parts of nano fly ash, 8 parts of barite, 2.5 parts of nano potassium aluminosilicate, 0.5 part of 400-viscosity hydroxypropyl methyl cellulose, 15 parts of rutile titanium dioxide, 11 parts of iron oxide blue and 3 parts of iron oxide yellow. The component B comprises 60 parts of nano inorganic resin, 25 parts of nano modifier, 10 parts of water-soluble rare earth, 0.3 part of defoaming agent and 5 parts of thickening agent, the powder group 101 and the liquid group 102 are mixed and stirred for 120 seconds according to a ratio of 1:1.15, then the mixture is sprayed on the galvanized steel plate 2, the manganese steel plate 2 is placed in the sealing box 9 to be heated and solidified in the same way, the movable plate 3 is drawn out after solidification, then the manganese steel plate 2 is taken out to be observed, neutral salt mist of the inorganic anticorrosive coating layer 1 prepared by testing two ratios exceeds 1000 hours, water resistance lasts for 480 hours, acid and alkali salt solution resistance lasts for 164 hours, and the two ratios are respectively a 1-grade fire resistance of zero toxic and harmful substances, 1200-degree high temperature resistance, mildew resistance, antibiosis and 1000-time accelerated aging resistance.
Finally, it should be noted that the above-mentioned contents are only used for illustrating the technical solutions of the present invention, and not for limiting the protection scope of the present invention, and that the simple modifications or equivalent substitutions of the technical solutions of the present invention by those of ordinary skill in the art can be made without departing from the spirit and scope of the technical solutions of the present invention.

Claims (9)

1. The utility model provides an inorganic anticorrosive paint that inorganic mineral substance non-chemical method was made is modified to pure nanometer, includes inorganic anticorrosive paint layer (1) and seal box (9), its characterized in that: inorganic anticorrosive paint layer (1) includes powder group (101) and liquid group (102), and the below of inorganic anticorrosive paint layer (1) is provided with manganese steel sheet (2), the below of manganese steel sheet (2) is provided with fly leaf (3), and the upper surface inside of fly leaf (3) has seted up square groove (4), the edge of square groove (4) is provided with extending groove (5), the lower fixed surface of fly leaf (3) installs first slider (6), and the below of first slider (6) is provided with first spout (7), the outside of first spout (7) is provided with bottom plate (8), seal box (9) are located the top of bottom plate (8), and the inner wall of seal box (9) has seted up second spout (10), the internally mounted of second spout (10) has second slider (11).
2. The inorganic anticorrosive paint prepared by the pure nanometer modified inorganic mineral substance non-chemical method according to claim 1, characterized in that: the powder group (101) comprises 20-30 parts of quartz powder, 20-30 parts of nano fly ash, 10-20 parts of metakaolin, 5-15 parts of barite, 1-3 parts of nano master batch, 0.5-1.5 parts of flexibilizer, 5-15 parts of titanium dioxide and 8-16 parts of iron oxide pigment.
3. The inorganic anticorrosive paint prepared by the pure nanometer modified inorganic mineral substance non-chemical method according to claim 1, characterized in that: the liquid group (102) comprises 25-35 parts of nano inorganic resin, 20-30 parts of nano modifier, 30-40 parts of water, 5-15 parts of water-soluble rare earth, 0.1-0.5 part of defoaming agent and 0-2 parts of thickening agent.
4. The inorganic anticorrosive paint prepared by the pure nanometer modified inorganic mineral substance non-chemical method according to claim 1, characterized in that: the weight mixing ratio range of the powder group (101) and the liquid group (102) is 1: 1.1-1: 1.3.
5. The inorganic anticorrosive paint prepared by the pure nanometer modified inorganic mineral substance non-chemical method according to claim 1, characterized in that: the liquid set (102) is strongly alkaline and the ph of the liquid set (102) ranges from 13 to 14.
6. The inorganic anticorrosive paint prepared by the pure nanometer modified inorganic mineral substance non-chemical method according to claim 1, characterized in that: the upper surface of manganese steel sheet (2) and the lower surface of inorganic anticorrosive paint layer (1) laminate mutually, and the external dimension of manganese steel sheet (2) is identical with the inside dimension of square groove (4), and is symmetrical about the vertical central line of manganese steel sheet (2) between extension groove (5) moreover.
7. The inorganic anticorrosive paint prepared by the pure nanometer modified inorganic mineral substance non-chemical method according to claim 1, characterized in that: the movable plate (3) and the bottom plate (8) form a sliding structure through the first sliding block (6) and the first sliding groove (7), and the movable plate (3) and the first sliding block (6) are welded.
8. The inorganic anticorrosive paint prepared by the pure nanometer modified inorganic mineral substance non-chemical method according to claim 1, characterized in that: the second sliding block (11) is connected with the side plate (12), and an electric heating wire (13) is fixedly mounted on the surface of the side plate (12).
9. The inorganic anticorrosive paint prepared by the non-chemical method of pure nanometer modified inorganic mineral substances according to claim 8, characterized in that: the number of the side plates (12) is two, and the side plates (12) are connected with the seal box (9) in a sliding mode through the second sliding grooves (10) and the second sliding blocks (11).
CN202210063404.XA 2022-01-19 2022-01-19 Inorganic anticorrosive paint prepared from pure nano modified inorganic mineral substance by non-chemical method Pending CN114262531A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN208213576U (en) * 2018-04-10 2018-12-11 江苏鼎胜新能源材料股份有限公司 A kind of hot air circulation curing oven and apply machine
CN210730069U (en) * 2019-09-27 2020-06-12 清远佳致新材料研究院有限公司 Coating machine drying oven capable of automatically adjusting air volume
CN214056012U (en) * 2020-11-06 2021-08-27 昆明叠鑫包装材料有限公司 High polymer material preheats oven
CN113698800A (en) * 2021-08-27 2021-11-26 华筑绿建(北京)科技有限公司 Double-component inorganic interior and exterior wall coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN208213576U (en) * 2018-04-10 2018-12-11 江苏鼎胜新能源材料股份有限公司 A kind of hot air circulation curing oven and apply machine
CN210730069U (en) * 2019-09-27 2020-06-12 清远佳致新材料研究院有限公司 Coating machine drying oven capable of automatically adjusting air volume
CN214056012U (en) * 2020-11-06 2021-08-27 昆明叠鑫包装材料有限公司 High polymer material preheats oven
CN113698800A (en) * 2021-08-27 2021-11-26 华筑绿建(北京)科技有限公司 Double-component inorganic interior and exterior wall coating

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Application publication date: 20220401