CN114231168A - High-performance water-based black flashing silver non-stick pan coating and preparation method thereof - Google Patents

High-performance water-based black flashing silver non-stick pan coating and preparation method thereof Download PDF

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CN114231168A
CN114231168A CN202111570771.0A CN202111570771A CN114231168A CN 114231168 A CN114231168 A CN 114231168A CN 202111570771 A CN202111570771 A CN 202111570771A CN 114231168 A CN114231168 A CN 114231168A
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water
stick pan
pan coating
ether
black
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Inventor
钱锋
惠正权
唐特伟
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Jiangsu Sanmu Chemical Co Ltd
Jiangsu Sanmu Group Corp
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Jiangsu Sanmu Chemical Co Ltd
Jiangsu Sanmu Group Corp
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J36/00Parts, details or accessories of cooking-vessels
    • A47J36/02Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
    • A47J36/025Vessels with non-stick features, e.g. coatings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Food Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

The invention discloses a high-performance water-based black flash silver non-stick pan coating and a preparation method thereof. The coating has the advantages of low VOC content, environmental protection, safety, excellent hardness, adhesive force, heat resistance, scratch resistance and other various excellent performances.

Description

High-performance water-based black flashing silver non-stick pan coating and preparation method thereof
Technical Field
The invention relates to a high-performance water-based black flashing silver non-stick pan coating and a preparation method thereof, belonging to the field of environment-friendly special coatings.
Background
The non-stick pan coating is widely used for small kitchen appliances such as electric cookers, toasters, electric irons, baking trays, pans, air fryers, electric ovens and the like. The original oily non-stick pan paint has high VOC content and is not environment-friendly. Therefore, it is necessary to develop and screen a high-performance water-based black flashing silver non-stick pan coating which has low VOC content, excellent heat resistance, scratch resistance and other performances and can meet the requirements of most customers on the basis of the prior art.
Disclosure of Invention
The purpose of the invention is as follows: the invention aims to solve the defects of the prior art and provide the high-performance water-based black flashing silver non-stick pan coating with scientific and reasonable component proportion, low VOC content, environmental protection, safety, heat resistance, scratch resistance and other excellent performances and the preparation method thereof.
The technical scheme is as follows: in order to realize the purpose, the invention adopts the technical scheme that:
a high-performance water-based black flashing silver non-stick pan coating is prepared from the following raw materials: the coating comprises water-based polyester modified silicon resin, high-pigment carbon black, water-based aluminum silver paste, talcum powder, dibutyl ether, ethylene glycol butyl ether and/or propylene glycol methyl ether, purified water, a water-based dispersant, a water-based leveling agent and water-based amino resin.
As a preferred scheme, the high-performance black flash silver non-stick pan coating is prepared from the following raw materials in percentage by mass: 50-70% of water-based polyester modified silicon resin, 3-7% of high-pigment carbon black, 1.5-3% of water-based aluminum silver paste, 3-10% of talcum powder, 3-6% of dibutyl ether, 3-6% of ethylene glycol butyl ether and/or propylene glycol methyl ether, 8-15% of purified water, 0.3-0.8% of water-based dispersant, 0.3-0.8% of water-based flatting agent and 5-10% of water-based amino resin.
As a preferred scheme, the high-performance black flash silver non-stick pan coating is prepared from the following raw materials in percentage by mass: 60% of water-based polyester modified silicon resin, 4% of high-pigment carbon black, 2% of water-based aluminum silver paste, 7% of talcum powder, 3% of dibutyl ether, 3% of butyl cellosolve, 13% of purified water, 0.5% of water-based dispersant, 0.5% of water-based flatting agent and 7% of water-based amino resin.
As a preferred scheme, the high-performance black flash silver non-stick pan coating is prepared from the following raw materials in percentage by mass: 62% of water-based polyester modified silicon resin, 3.5% of high-pigment carbon black, 2.5% of water-based aluminum silver paste, 6% of talcum powder, 3% of dibutyl ether, 3% of propylene glycol methyl ether, 11% of purified water, 0.5% of water-based dispersant, 0.5% of water-based leveling agent and 8% of water-based amino resin.
As a preferred scheme, the high-performance black flash silver non-stick pan coating is prepared from the following raw materials in percentage by mass:
58% of water-based polyester modified silicon resin, 4% of high-pigment carbon black, 2.5% of water-based aluminum silver paste, 7% of talcum powder, 4% of dibutyl ether, 1.5% of ethylene glycol butyl ether, 3% of propylene glycol methyl ether, 11% of purified water, 0.5% of water-based dispersant, 0.5% of water-based leveling agent and 8% of water-based amino resin.
Preferably, the preparation method of the high-performance black flash silver non-stick pan coating comprises the following steps:
sequentially adding the water-based polyester modified silicon resin, the high-color carbon black, the water-based aluminum silver paste, the talcum powder, the dibutyl ether, the ethylene glycol butyl ether and/or the propylene glycol methyl ether, the water-based amino resin, the purified water, the water-based dispersant and the water-based leveling agent into a stainless steel sand mill, starting stirring, simultaneously ensuring that the temperature in the sand mill is not more than 60 ℃, sampling and measuring the fineness of the paint after sand milling until the fineness is ground to be less than 20 micrometers.
Preferably, the preparation method of the high-performance black flash silver non-stick pan coating comprises the following steps:
sequentially adding water-based polyester modified silicon resin, high-color carbon black, water-based aluminum silver paste, talcum powder, dibutyl ether, ethylene glycol butyl ether and/or propylene glycol methyl ether, water-based amino resin, purified water, a water-based dispersing agent and a water-based leveling agent into a stainless steel sand mill, starting stirring, maintaining the revolution number at 200-500 rpm, simultaneously ensuring that the temperature in the sand mill is not more than 60 ℃, sampling and measuring the fineness of the paint after maintaining the sand mill for 6-8 hours until the fineness is ground to be less than 20 micrometers.
Has the advantages that: compared with the prior art, the invention has the following advantages:
the paint is prepared by screening raw materials through a large number of experiments, the mixture ratio of the components is scientific and reasonable, wherein the mass percent of the resin accounts for 50-70%, and the gloss and the fullness of a paint film can be ensured only if the resin content is ensured to be more than or equal to 50% in the total amount of the paint; the water-based amino resin helps a paint film to be cured into a film, improves the curing speed and helps the paint to be crosslinked and cured. 3-7% of high-pigment carbon black, and experiments show that the high-pigment carbon black is low in tinting strength, insufficient in tinting strength and high in dispersibility; the water-based aluminum paste is 1.5-3%, and experiments show that the water-based aluminum paste has more colors and less silver flashing effect. Dibutyl ether, BCS and PM are cosolvents, have hydrophilicity, help to form films, help to disperse and level pigments and fillers, have little effect, and increase VOC.
Detailed Description
Embodiments of the present invention will be described in detail with reference to examples, in which specific conditions are not specified, according to conventional conditions or conditions recommended by manufacturers. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products commercially available.
Example 1
1. A high-performance water-based black flashing silver non-stick pan coating is prepared from the following raw materials in percentage by mass:
composition of raw materials Mass percent%
Water-based polyester modified silicon resin 1162w 60
High pigment carbon black (Digao U black) 4
Aqueous aluminum silverPulp (zw9018) 2
Talcum powder (commercially available) 7
Dibutyl ether 3
Ethylene glycol butyl ether 3
Aqueous amino resin 5717w 7
Purified water 13
Aqueous dispersant SJ1900 0.6
Aqueous leveling agent BYK307 0.4
2. The film forming method of the paint film comprises the following steps: the paint is evenly sprayed on the surface of a 5 x 10cm tin plate by a German Wonde PILOT MINI manual spray gun, the tin plate is dried in the air for half an hour, then is baked for forming a film at 280 ℃ for ten minutes, and the thickness of a varnish dry film is controlled to be about 25 micrometers. The following various performance tests were then performed. Paint film performance test (after 280-degree ten-minute baking):
detecting items The result of the detection Reference standard
Adhesion (circle drawing method) Level 1 GB1720-79
Paint film thickness (Nixon QNIX4500) 28 micron GB/T13452.2-2008
Hardness (Chinese pencil) 4H GB/T6739-1986
Gloss (OUPU, 60 degree) 98 GB/T1743-1989
Flexibility (QTX) 1mm GB/T1731-1993
Impact resistance (QCJ) 50g.cm GB/T1732-1988
Heat resistance (280 degree half hour) Slight yellowing No national standard, visual observation
Resisting boiling in 3% acetic acid solution for 1 hr Intact Without national standard
Boiling resistant for 3 hours Intact Without national standard
VOC content Less than 30 percent
Example 2
1. A high-performance water-based black flashing silver non-stick pan coating is prepared from the following raw materials in percentage by mass:
composition of raw materials Mass percent%
Waterborne polyester modified silicone resin 1172w 62
High pigment carbon black (Digao U black) 3.5
Water-based aluminum paste (zw9018) 2.5
Talcum powder (commercially available) 6
Dibutyl ether 3
Propylene glycol methyl ether 3
Aqueous amino resin 5717w 8
Purified water 11
Aqueous dispersant SJ1900 0.6
Aqueous leveling agent BYK307 0.4
2. The film forming method of the paint film comprises the following steps: the paint is evenly sprayed on the surface of a 5 x 10cm tin plate by a German Wonde PILOT MINI manual spray gun, the tin plate is dried in the air for half an hour, then is baked for forming a film at 280 ℃ for ten minutes, and the thickness of a varnish dry film is controlled to be about 25 micrometers. The following various performance tests were then performed. Paint film performance test (after 280-degree ten-minute baking):
Figure BDA0003423635590000031
Figure BDA0003423635590000041
example 3
1. A high-performance water-based black flashing silver non-stick pan coating is prepared from the following raw materials in percentage by mass:
composition of raw materials Mass percent%
Waterborne polyester modified silicone resin 1172w 58
High pigment carbon black (Digao U black) 4
Water-based aluminum paste (zw9018) 2.5
Talcum powder (commercially available) 7
Dibutyl ether 4
Ethylene glycol butyl ether 1.5
Propylene glycol methyl ether 3
Aqueous amino resin 5717w 8
Purified water 11
Aqueous fractionPowder SJ1900 0.6
Aqueous leveling agent BYK307 0.4
2. The film forming method of the paint film comprises the following steps: the paint is evenly sprayed on the surface of a 5 x 10cm tin plate by a German Wonde PILOT MINI manual spray gun, the tin plate is dried in the air for half an hour, then is baked for forming a film at 280 ℃ for ten minutes, and the thickness of a varnish dry film is controlled to be about 25 micrometers. The following various performance tests were then performed. Paint film performance test (after 280-degree ten-minute baking):
Figure BDA0003423635590000042
the foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.

Claims (7)

1. The high-performance water-based black flashing silver non-stick pan coating is characterized by being prepared from the following raw materials: the coating comprises water-based polyester modified silicon resin, high-pigment carbon black, water-based aluminum silver paste, talcum powder, dibutyl ether, ethylene glycol butyl ether and/or propylene glycol methyl ether, purified water, a water-based dispersant, a water-based leveling agent and water-based amino resin.
2. The high-performance black flash silver non-stick pan coating material according to claim 1, which is prepared from the following raw materials in percentage by mass: 50-70% of water-based polyester modified silicon resin, 3-7% of high-pigment carbon black, 1.5-3% of water-based aluminum silver paste, 3-10% of talcum powder, 3-6% of dibutyl ether, 3-6% of ethylene glycol butyl ether and/or propylene glycol methyl ether, 8-15% of purified water, 0.3-0.8% of water-based dispersant, 0.3-0.8% of water-based flatting agent and 5-10% of water-based amino resin.
3. The high-performance black flash silver non-stick pan coating material according to claim 2, which is prepared from the following raw materials in percentage by mass: 60% of water-based polyester modified silicon resin, 4% of high-pigment carbon black, 2% of water-based aluminum silver paste, 7% of talcum powder, 3% of dibutyl ether, 3% of butyl cellosolve, 13% of purified water, 0.5% of water-based dispersant, 0.5% of water-based flatting agent and 7% of water-based amino resin.
4. The high-performance black flash silver non-stick pan coating material according to claim 2, which is prepared from the following raw materials in percentage by mass: 62% of water-based polyester modified silicon resin, 3.5% of high-pigment carbon black, 2.5% of water-based aluminum silver paste, 6% of talcum powder, 3% of dibutyl ether, 3% of propylene glycol methyl ether, 11% of purified water, 0.5% of water-based dispersant, 0.5% of water-based leveling agent and 8% of water-based amino resin.
5. The high-performance black flash silver non-stick pan coating material according to claim 2, which is prepared from the following raw materials in percentage by mass:
58% of water-based polyester modified silicon resin, 4% of high-pigment carbon black, 2.5% of water-based aluminum silver paste, 7% of talcum powder, 4% of dibutyl ether, 1.5% of ethylene glycol butyl ether, 3% of propylene glycol methyl ether, 11% of purified water, 0.5% of water-based dispersant, 0.5% of water-based leveling agent and 8% of water-based amino resin.
6. The preparation method of the high-performance black flash silver non-stick pan coating material as claimed in any one of claims 1 to 5, which is characterized by comprising the following steps:
sequentially adding the water-based polyester modified silicon resin, the high-color carbon black, the water-based aluminum silver paste, the talcum powder, the dibutyl ether, the ethylene glycol butyl ether and/or the propylene glycol methyl ether, the water-based amino resin, the purified water, the water-based dispersant and the water-based leveling agent into a stainless steel sand mill, starting stirring, simultaneously ensuring that the temperature in the sand mill is not more than 60 ℃, sampling and measuring the fineness of the paint after sand milling until the fineness is ground to be less than 20 micrometers.
7. The preparation method of the high-performance black flash silver non-stick pan coating according to claim 6, characterized by comprising the following steps:
sequentially adding water-based polyester modified silicon resin, high-color carbon black, water-based aluminum silver paste, talcum powder, dibutyl ether, ethylene glycol butyl ether and/or propylene glycol methyl ether, water-based amino resin, purified water, a water-based dispersing agent and a water-based leveling agent into a stainless steel sand mill, starting stirring, maintaining the revolution number at 200-500 rpm, simultaneously ensuring that the temperature in the sand mill is not more than 60 ℃, sampling and measuring the fineness of the paint after maintaining the sand mill for 6-8 hours until the fineness is ground to be less than 20 micrometers.
CN202111570771.0A 2021-12-21 2021-12-21 High-performance water-based black flashing silver non-stick pan coating and preparation method thereof Pending CN114231168A (en)

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Application publication date: 20220325