CN114165010A - 3D flat printing decorative plate based on electron beam curing technology and application - Google Patents

3D flat printing decorative plate based on electron beam curing technology and application Download PDF

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CN114165010A
CN114165010A CN202111373761.8A CN202111373761A CN114165010A CN 114165010 A CN114165010 A CN 114165010A CN 202111373761 A CN202111373761 A CN 202111373761A CN 114165010 A CN114165010 A CN 114165010A
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layer
electron beam
coating
wear
curing
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CN114165010B (en
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李琳
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Nuosen Changzhou Construction Industry Co ltd
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Nuosen Changzhou Construction Industry Co ltd
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0866Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041Digital printing on surfaces other than ordinary paper
    • B41M5/0047Digital printing on surfaces other than ordinary paper by ink-jet printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0081After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0461Ornamental plaques, e.g. decorative panels, decorative veneers used as wall coverings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/042Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/043Improving the adhesiveness of the coatings per se, e.g. forming primers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/046Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0871Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds

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  • Health & Medical Sciences (AREA)
  • Architecture (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
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Abstract

A3D flat printing decorative plate based on an electron beam curing technology comprises a substrate, a primer layer, a pattern layer, a wear-resistant layer, a texture layer and a scratch-resistant layer from bottom to top in sequence; the primer layer, the pattern layer, the wear layer and the texture layer are made of UV paint. The scratch-resistant layer is formed by uniformly coating a transparent coating cured by electron beam radiation on the surface of the texture layer, and the average dosage of the transparent coating is as follows: 10-14 g/square meter; and then curing by electron beam radiation, wherein the energy of the electron beam is adjusted to 30-40 kgy. The scratch-resistant layer has sufficient protection on the coating below the scratch-resistant layer, the problem of insufficient aging resistance of UV curing ink is solved, and meanwhile, the UV ink with a small content of photoinitiator can be selected to manufacture the pattern layer.

Description

3D flat printing decorative plate based on electron beam curing technology and application
Technical Field
The technical scheme is the application of a material technology in the technical field of decorative plates, and particularly relates to a 3D flat printing decorative plate based on an electron beam curing technology.
Background
In the prior art, the manufacture of decorative boards such as density boards, stone-plastic boards, glass-magnesium boards and the like can be implemented by adopting a flat printing process. The principle of the technology is that firstly, the ground color (white is used mostly) is processed on the substrate, then UV printing ink is sprayed on the ground color layer by a flat printer to form a pattern, and UV is adopted for curing. The process has the advantages that the processing process is simple, the manufactured plate does not need ways of pasting a color film and the like, and glue and hot pressing/cold pressing processes are not used; the printing pattern is flexible, and the pattern is edited in computer software and printed by a flat-panel printer. But there are disadvantages mainly from the UV curing process. While UV curing has replaced the more defective thermal curing in the art, however:
1. the UV curing needs to adopt a photoinitiator with high price, and the cost of printing ink and the like is high; the photoinitiator and the photolysis product are migrated and volatilized, and peculiar smell is generated; insufficient aging resistance of ink and the like; it cannot be used in food and medicine fields.
2. In particular, in the case of colored coatings such as inks and paints, UV curing is difficult to transmit due to the absorption of light by pigments, and a common method for solving this problem is to increase the amount of photoinitiator.
In conclusion, the difficult problems encountered with conventional UV curing are the off-flavors caused by the photoinitiators and the insufficient resistance of the inks to ageing.
Disclosure of Invention
In order to solve the problems of the prior art in which UV ink is adopted in the manufacturing process of the decorative plate, the invention provides a novel decorative plate, which is characterized in that a pattern layer is prepared by printing a pattern on a substrate by adopting a flat printer, then a wear-resistant coating is coated on the surface of the pattern layer to prepare a wear-resistant layer, a texture layer is prepared by spraying varnish on the surface of the wear-resistant layer by adopting the flat printer, and finally a scratch-resistant layer is prepared by coating finish on the surface of the texture layer.
The invention relates to a 3D flat printing decorative plate based on an electron beam curing technology and application thereof, wherein the decorative plate comprises a substrate, a primer layer, a pattern layer, a wear-resistant layer, a texture layer and a scratch-resistant layer from bottom to top in sequence;
the primer layer is made of a UV primer; the pattern layer is made of spray painting color UV ink; the wear-resistant layer is made of UV wear-resistant paint; the texture layer is made of spray-painted transparent UV ink; the scratch-resistant layer is made of transparent coating cured by electron beam radiation;
the manufacturing steps of the decorative plate comprise:
1) uniformly coating the UV primer on the surface of the substrate, and performing radiation curing by using ultraviolet rays with corresponding energy according to the unit dosage of the UV primer;
2) printing the color of a design drawing on the surface of the primer layer by using an ink-jet flat printer and curing to prepare a pattern layer;
3) coating the UV wear-resistant coating on the surface of the pattern layer, and performing radiation curing by using ultraviolet rays with corresponding energy according to the unit dosage of the UV wear-resistant coating;
4) printing design pattern textures on the surface of the wear-resistant layer by using an ink-jet flat printer, and curing to obtain a texture layer;
5) uniformly coating the transparent coating cured by electron beam radiation on the surface of the texture layer, wherein the average dosage of the transparent coating is as follows: 10-14 g/square meter; then, curing by electron beam radiation, wherein the energy of the electron beam is adjusted to 30-40 kgy;
and curing to obtain the decorative board product.
Further: the primer layer is prepared from 20-24 g/square meter of UV primer, and is irradiated and cured by a mercury lamp light source ultraviolet lamp, and the light energy is adjusted to 190-280 mJ; the wear-resistant layer is made of UV wear-resistant paint according to the dosage of 64-96 g/square meter, and is irradiated and cured by a mercury lamp light source ultraviolet lamp, and the light energy is adjusted to 240-280 mJ.
Further: in the steps 1), 3) and 5), the coating mode is roll coating or curtain coating.
Further: the base plate is a density board (furniture veneer), a stone plastic board (floor) and a glass magnesium board (wallboard), and at the moment, the decorative board is used for the floor, the wallboard or the furniture veneer.
Further: the substrate is a PP film, a PET film or a PVC film with the thickness of 0.1-1.0 mm, and the substrate is used as a plate decoration protective film. When the protective film is used as a protective film, the bottom surface of a PP film, a PET film or a PVC film is coated with glue and pasted on site, or a non-dry glue layer is pre-coated during production.
Further: in the steps 1) to 4), the production environment temperature needs to be controlled to be 15-25 ℃.
The layered structure of the decorative plate is the same as that of the decorative plate in the prior art, and the differences mainly comprise the coating used by each functional layer and the unit dosage. The function and performance of the decorative plate are better and the decorative plate is more convenient to produce by combining the processing technology.
In the technical scheme, the penetration depth of the electron beam is large; the electron beam causes chemical bonding (e.g., grafting) between the coating materials of the scratch-resistant layer and between the coating materials of the adjacent layers, thereby improving the adhesion of the scratch-resistant layer. The solidified scratch-resistant layer can completely seal the UV solidified coating, so that peculiar smell brought by the photoinitiator can not be emitted into the air. The scratch-resistant layer has sufficient protection on the coating below the scratch-resistant layer, the problem of insufficient aging resistance of UV curing ink is solved, and meanwhile, the UV ink with a small content of photoinitiator can be selected to manufacture the pattern layer.
Drawings
Fig. 1 is a schematic view of the layered structure of the present decorative sheet.
Detailed Description
A3D flat printing decorative plate based on an electron beam curing technology comprises a substrate, a primer layer, a pattern layer, a wear-resistant layer, a texture layer and a scratch-resistant layer from bottom to top in sequence, and is shown in figure 1;
the primer layer is made of a UV primer; the pattern layer is made of spray painting color UV ink; the wear-resistant layer is made of UV wear-resistant paint; the texture layer is made of spray-painted transparent UV ink; the scratch-resistant layer is made of transparent coating cured by electron beam radiation;
the manufacturing steps of the decorative plate comprise:
1) uniformly coating the UV primer on the surface of the substrate, and performing radiation curing by using ultraviolet rays with corresponding energy according to the unit dosage of the UV primer;
2) printing the color of a design drawing on the surface of the primer layer by using an ink-jet flat printer and curing to prepare a pattern layer;
3) coating the UV wear-resistant coating on the surface of the pattern layer, and performing radiation curing by using ultraviolet rays with corresponding energy according to the unit dosage of the UV wear-resistant coating;
4) printing design pattern textures on the surface of the wear-resistant layer by using an ink-jet flat printer, and curing to obtain a texture layer;
5) uniformly coating the transparent coating cured by electron beam radiation on the surface of the texture layer, wherein the average dosage of the transparent coating is as follows: 10-14 g/square meter; then, curing by electron beam radiation, wherein the energy of the electron beam is adjusted to 30-40 kgy;
and curing to obtain the decorative board product.
In steps 1-4, the production environment temperature needs to be controlled to be 15-25 ℃. UV coatings vary greatly in viscosity due to temperature, so the ambient temperature is tightly controlled and care is taken not to expose the coating to direct sunlight during production.
The invention will now be described with reference to specific embodiments:
in each example, the UV paint and the UV ink are products of Kunlun paint (Shanghai) limited, and the white UV primer used for the primer layer is a UV primer of 161-; HP/CY01 type blue ink, HP/YE01 type yellow ink, and UH012-RD type red ink are used as the pattern layer; the wear-resistant layer is prepared from a UV primer of 161-; the texture layer uses M-1P025-NS transparent top coat.
The clear coating cured by electron beam radiation used was product Remmers industrial lacke GmbH, model number NS-EB 038.
Example 1, for floor panels
The floor is structurally composed of a substrate, a primer layer, a pattern layer, a wear-resistant layer (3 same layers are arranged from bottom to top), a texture layer and a scratch-resistant layer from bottom to top in sequence; the substrate is a stone-plastic plate.
The manufacturing steps comprise:
1) firstly, uniformly roll-coating a white UV primer on the surface of a substrate by using a roll coater, wherein the dosage of the white UV primer is as follows: 20 grams per square meter; then, irradiating and curing by using a mercury lamp light source ultraviolet lamp, and adjusting the light energy to 200 mJ;
2) printing the color of a design drawing on the surface of the primer layer by using an ink-jet flat printer and curing to prepare a pattern layer;
3.1) using a roller coater to roll the UV wear-resistant coating on the surface of the pattern layer, then using a mercury lamp light source ultraviolet lamp to perform irradiation curing, and adjusting the lamp light energy to 90mJ to finally prepare a wear-resistant layer;
3.2) repeating the step 3.1) twice to prepare another 2 wear-resistant layers; the total dosage of the UV wear-resistant coating used for preparing the three wear-resistant layers in the steps 3.1) and 3.2) is 96 g/square meter;
4) printing design pattern textures on the surface of the wear-resistant layer by using an ink-jet flat printer, and curing to obtain a texture layer;
5) firstly, uniformly roll-coating the transparent coating cured by electron beam radiation by using a roll coater, wherein the average dosage of the transparent coating is as follows: 14 grams per square meter; curing was then carried out with electron beam radiation, the electron beam energy being adjusted to 40 kgy.
The abrasion resistance standard of the product adopts the standard of ASTM D3884 and H18, and the abrasion resistance grade exceeds the standard AC 6.
Example 2 for furniture Panels
The furniture decorative panel is structurally composed of a substrate, a primer layer, a pattern layer, a wear-resistant layer, a texture layer and a scratch-resistant layer from bottom to top in sequence; the substrate is a density board.
The manufacturing steps comprise:
1) firstly, uniformly spraying white UV (ultraviolet) primer on the surface of a substrate by using a spraying machine, wherein the dosage of the white UV primer is as follows: 24 grams per square meter; then, irradiating and curing by using a mercury lamp light source ultraviolet lamp, and adjusting the light energy to 280 mJ; because the requirement of the furniture decorative panel on the aesthetic degree of the pattern is higher, and the surface of the density board is provided with a plurality of tiny air holes, the air holes can be better filled and the thickened primer layer covers the color of the substrate by adopting the curtain coating process. And the curtain coating process has partial coating loss, so the process dosage is larger.
2) Printing the color of a design drawing on the surface of the primer layer by using an ink-jet flat printer and curing to prepare a pattern layer;
3) using a roller coater to roll the UV wear-resistant coating on the surface of the pattern layer, wherein the dosage of the UV wear-resistant coating is as follows: 64 grams per square meter; then, irradiating and curing by using a mercury lamp light source ultraviolet lamp, and adjusting the light energy to 240 mJ;
4) printing design pattern textures on the surface of the wear-resistant layer by using an ink-jet flat printer, and curing to obtain a texture layer;
5) firstly, uniformly roll-coating the transparent coating cured by electron beam radiation by using a roll coater, wherein the average dosage of the transparent coating is as follows: 12 grams per square meter; curing was then carried out with electron beam radiation, the electron beam energy being adjusted to 36 kgy.
The abrasion resistance standard of the product adopts the standard of ASTM D3884 and H18, and the abrasion resistance grade exceeds the standard AC 6.
In the embodiment, the wear-resistant layer is used for the furniture veneer, and the wear-resistant requirement is not high, so that the thickness of the wear-resistant layer is lower than that of the floor. However, since the veneer is used indoors, the thickness is large because the photoinitiator volatilized in the UV paint is sufficiently sealed.
Example 3 for wall Panel
The wallboard is structurally characterized in that a substrate, a primer layer, a pattern layer, a wear-resistant layer, a texture layer and a scratch-resistant layer are sequentially arranged from bottom to top; the substrate is a glass magnesium board.
The manufacturing steps comprise:
1) firstly, uniformly spraying white UV (ultraviolet) primer on the surface of a substrate by using a spraying machine, wherein the dosage of the white UV primer is as follows: 20 grams per square meter; then, irradiating and curing by using a mercury lamp light source ultraviolet lamp, and adjusting the light energy to 190 mJ;
because the surface of the glass magnesium board has a plurality of tiny air holes, the air holes can be better filled by adopting the curtain coating process.
2) Printing the color of a design drawing on the surface of the primer layer by using an ink-jet flat printer and curing to prepare a pattern layer;
3) and (3) coating the UV wear-resistant coating on the surface of the pattern layer by using a coating machine, wherein the dosage of the UV wear-resistant coating is as follows: 70 g/square meter; then, irradiating and curing by using a mercury lamp light source ultraviolet lamp, and adjusting the light energy to 250 mJ; further flattening the surface of the plate by adopting a curtain coating process;
4) printing design pattern textures on the surface of the wear-resistant layer by using an ink-jet flat printer, and curing to obtain a texture layer;
5) firstly, uniformly spraying the transparent coating cured by electron beam radiation by using a spraying machine, wherein the average dosage of the transparent coating is as follows: 10 grams per square meter; curing was then carried out with electron beam radiation, the electron beam energy being adjusted to 30 kgy.
The abrasion resistance standard of the product adopts the standard of ASTM D3884 and H18, and the abrasion resistance grade exceeds the standard AC 6.
In the embodiment, as the coating is used for the wallboard, the wear-resisting requirement, the pattern aesthetic requirement and the like are relatively low, and the production efficiency can be better improved by adopting the curtain coating process.
Example 4 protective film for sheet decoration
The structure of the plate decoration protective film is that a substrate, a primer layer, a pattern layer, a wear-resistant layer, a texture layer and a scratch-resistant layer are sequentially arranged from bottom to top; the substrate was a PET film with a thickness of 0.2 mm. In the production process, the process for manufacturing each functional layer on the PP film, the PET film or the PVC film is basically the same, different substrates are adopted due to different use scenes of the product, for example, the PVC film (1mm thick) can be made transparent, and in the application scene, the pattern effect of the protective film product can be combined with the color of the attached surface, and in the special case, the primer layer needs to use a transparent UV primer.
This example is described as a 0.2mm PET film.
The manufacturing steps comprise:
1) firstly, uniformly spraying white UV (ultraviolet) primer on the surface of a substrate by using a spraying machine, wherein the dosage of the white UV primer is as follows: 24 grams per square meter; then, irradiating and curing by using a mercury lamp light source ultraviolet lamp, and adjusting the light energy to 280 mJ; if the substrate is a transparent film, the primer herein is replaced with a similar transparent primer. Because the PET film is light, the film can be adhered by the rubber roller under the roller coating process, and therefore, the curtain coating process is adopted.
2) Printing the color of a design drawing on the surface of the primer layer by using an ink-jet flat printer and curing to prepare a pattern layer;
3) spraying the UV wear-resistant coating on the surface of the pattern layer by using a spray coating machine, and then irradiating and curing by using a mercury lamp light source and an ultraviolet lamp; the total dosage of the UV wear-resistant coating is 64 g/square meter, the lamplight energy is adjusted to 240mJ, and finally a wear-resistant layer is prepared; since the PET film has abrasion resistance, the thickness requirement of the abrasion resistant layer is not high.
4) Printing design pattern textures on the surface of the wear-resistant layer by using an ink-jet flat printer, and curing to obtain a texture layer;
5) firstly, uniformly spraying the transparent coating cured by electron beam radiation by using a spraying machine, wherein the average dosage of the transparent coating is as follows: 10 grams per square meter; curing was then carried out with electron beam radiation, the electron beam energy being adjusted to 30 kgy.
The abrasion resistance standard of the product adopts the standard of ASTM D3884 and H18, and the abrasion resistance grade exceeds the standard AC 6.
In the above examples, the abrasion resistance was good, and the process rationality of the electron beam radiation-cured clear coating and the amount and curing energy was verified. The electron beam radiation curing coating and the physical and chemical properties thereof can overcome the problems of peculiar smell of a photoinitiator, insufficient aging resistance of ink and the like caused by the traditional UV curing without objection.

Claims (8)

1. A3D flat printing decorative plate based on an electron beam curing technology comprises a substrate, a primer layer, a pattern layer, a wear-resistant layer, a texture layer and a scratch-resistant layer from bottom to top in sequence; the primer layer is made of a UV primer; the pattern layer is made of spray painting color UV ink; the wear-resistant layer is made of UV wear-resistant paint; the texture layer is made of spray-painted transparent UV ink and is characterized in that the scratch-resistant layer is made of electron beam radiation cured transparent paint;
the manufacturing steps of the decorative plate comprise:
1) uniformly coating the UV primer on the surface of the substrate, and performing radiation curing by using ultraviolet rays with corresponding energy according to the unit dosage of the UV primer;
2) printing the color of a design drawing on the surface of the primer layer by using an ink-jet flat printer and curing to prepare a pattern layer;
3) coating the UV wear-resistant coating on the surface of the pattern layer, and performing radiation curing by using ultraviolet rays with corresponding energy according to the unit dosage of the UV wear-resistant coating;
4) printing design pattern textures on the surface of the wear-resistant layer by using an ink-jet flat printer, and curing to obtain a texture layer;
5) uniformly coating the transparent coating cured by electron beam radiation on the surface of the texture layer, wherein the average dosage of the transparent coating is as follows: 10-14 g/square meter; then, curing by electron beam radiation, wherein the energy of the electron beam is adjusted to 30-40 kgy;
and curing to obtain the decorative board product.
2. The 3D flatbed printing decorative plate based on the electron beam curing technology as claimed in claim 1, wherein the primer layer is made of UV primer according to the dosage of 20-24 g/square meter, and is irradiated and cured by a mercury lamp light source ultraviolet lamp, and the lamp light energy is adjusted to 190-280 mJ; the wear-resistant layer is made of UV wear-resistant paint according to the dosage of 64-96 g/square meter, and is irradiated and cured by a mercury lamp light source ultraviolet lamp, and the light energy is adjusted to 240-280 mJ.
3. 3D flatbed printed decorative board based on electron beam curing technology according to claim 1, characterized in that in the steps 1), 3) and 5), the coating mode is roll coating or curtain coating.
4. The 3D flatbed printed decorative sheet based on electron beam curing technology of claim 1, wherein the substrate is a density board, a stone-plastic board or a glass-magnesium board.
5. The 3D flat printing decoration plate based on the electron beam curing technology of claim 1, wherein the substrate is a PP film, a PET film or a PVC film with the thickness of 0.1-1.0 mm.
6. The 3D flatbed printing decorative plate based on the electron beam curing technology in claim 1, wherein in the steps 1) to 4), the production environment temperature is controlled to be 15-25 ℃.
7. 3D flatbed printed decorative board based on electron beam curing technique of claim 4, characterized by the use is floor, wallboard or furniture veneer.
8. The 3D flatbed printing decorative plate based on the electron beam curing technology as claimed in claim 5, wherein the purpose is a plate decorative protective film.
CN202111373761.8A 2021-11-19 2021-11-19 3D flat-plate printing decorative plate based on electron beam curing technology and application thereof Active CN114165010B (en)

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CN202111373761.8A CN114165010B (en) 2021-11-19 2021-11-19 3D flat-plate printing decorative plate based on electron beam curing technology and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111373761.8A CN114165010B (en) 2021-11-19 2021-11-19 3D flat-plate printing decorative plate based on electron beam curing technology and application thereof

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CN114165010A true CN114165010A (en) 2022-03-11
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CN1358810A (en) * 2000-11-15 2002-07-17 阿姆斯特郎世界工业公司 Colored radiation solidifed wearing-resistant layer
CN103958213A (en) * 2012-08-24 2014-07-30 阿卡曾塔板材型材有限公司 Method for printing on a wall or floor panel
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CN110802008A (en) * 2019-09-27 2020-02-18 诺森(常州)建筑产业有限公司 Board for realizing high-gloss and matte texture patterns on same base layer
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Publication number Priority date Publication date Assignee Title
CN114775949A (en) * 2022-04-25 2022-07-22 浙江晶通新材料集团有限公司 Anti-aging decorative plate, floor and manufacturing method of plate
CN114775949B (en) * 2022-04-25 2024-02-13 浙江晶通新材料集团有限公司 Anti-aging decorative board, floor and board manufacturing method

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