CN114163948A - High-temperature-resistant waterproof inorganic glue and preparation method and application thereof - Google Patents

High-temperature-resistant waterproof inorganic glue and preparation method and application thereof Download PDF

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Publication number
CN114163948A
CN114163948A CN202111456800.0A CN202111456800A CN114163948A CN 114163948 A CN114163948 A CN 114163948A CN 202111456800 A CN202111456800 A CN 202111456800A CN 114163948 A CN114163948 A CN 114163948A
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parts
temperature
inorganic glue
resistant waterproof
mixture
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朱德丰
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Guangdong Qiwo Environmental Technology Co ltd
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Guangdong Qiwo Environmental Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention discloses high-temperature-resistant waterproof inorganic glue and a preparation method and application thereof, wherein the high-temperature-resistant waterproof inorganic glue is prepared from the following raw materials in parts by weight: 20-35 parts of white latex, 15-25 parts of sodium stearate, 13-17 parts of acrylic emulsion, 12-18 parts of melamine resin, 15-20 parts of talcum powder, 8-12 parts of ethylene glycol, 4-8 parts of flame retardant, 5-9 parts of water repellent agent, 2-3 parts of defoaming agent, 2-5 parts of flatting agent and 4-7 parts of cosolvent, and the beneficial effects of the invention are that: through adding multiple auxiliary agents in the raw materials, and the cooperation sodium stearate for the inorganic glue of preparation has good high temperature resistance, is difficult for melting in high temperature environment, simultaneously through adding water repellent in the component, makes the inorganic glue of preparation have good water resistance, thereby can avoid taking place the phenomenon of infiltration, is favorable to actual use.

Description

High-temperature-resistant waterproof inorganic glue and preparation method and application thereof
Technical Field
The invention relates to the technical field of inorganic glue, in particular to high-temperature-resistant waterproof inorganic glue and a preparation method and application thereof.
Background
In the existing life, inorganic glue is a chemical component without magnesium, phosphorus, aluminum, iron and the like in an additive, has good chemical activity, is waterproof and moistureproof, and reduces the reduction amount of fixed carbon, and so-called organic glue is glue containing organic components.
However, most of the inorganic glue prepared and produced in the prior art has single component, can only meet the requirement of simple bonding function, lacks certain high temperature resistance, is very easy to melt in a high temperature environment, and is not beneficial to use in the high temperature environment, and most of the inorganic glue prepared and produced in the prior art has no waterproof performance, is easy to have water seepage phenomenon when being used for sealing or bonding, and is not beneficial to practical use.
Disclosure of Invention
The invention aims to provide high-temperature-resistant waterproof inorganic glue and a preparation method and application thereof, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme that the high-temperature-resistant waterproof inorganic glue is prepared from the following raw materials in parts by weight: 20-35 parts of white latex, 15-25 parts of sodium stearate, 13-17 parts of acrylic emulsion, 12-18 parts of melamine resin, 15-20 parts of talcum powder, 8-12 parts of ethylene glycol, 4-8 parts of flame retardant, 5-9 parts of water repellent agent, 2-3 parts of defoaming agent, 2-5 parts of flatting agent and 4-7 parts of cosolvent.
Preferably, the flame retardant is one of potassium tungstate and sodium tungstate.
Preferably, the water repellent agent is one of fatty acid aluminum salt or polyamide polyurea.
Preferably, the defoaming agent is one of silicone or polyether.
Preferably, the leveling agent is one of poly terephthalic acid or polydimethylsiloxane.
Preferably, the cosolvent is one of urea and zinc oxide.
The preparation method of the high-temperature-resistant waterproof inorganic glue comprises the following steps:
s1, weighing white latex, sodium stearate, acrylic emulsion, melamine resin, talcum powder and ethylene glycol according to the formula parts, mixing, pouring into a stirrer, setting the stirring speed at 2000-3000r/min, and the stirring time at 15-28min, and obtaining a mixture I after stirring;
s2, weighing the flame retardant according to the formula parts, adding the flame retardant into the mixture I, setting the stirring speed at 1500-;
s3, weighing the water repellent agent according to the formula parts, adding the water repellent agent into the mixture II, setting the stirring speed at 1200-1800r/min, setting the stirring time at 6-9min, and obtaining a mixture III after the stirring is finished;
s4, weighing the defoaming agent, the leveling agent and the cosolvent according to the formula parts, sequentially adding the defoaming agent, the leveling agent and the cosolvent into the mixture III, setting the stirring speed at 2500-;
and S5, adding deionized water into the obtained mixture IV, and adjusting the viscosity to be used so as to obtain the high-temperature-resistant waterproof inorganic glue.
The application mode of the high-temperature-resistant waterproof inorganic glue is that the mixture IV with the viscosity adjusted by adding the deionized water is smeared on an article and stands for more than 30min at the temperature of 10-25 ℃.
Compared with the prior art, the invention has the beneficial effects that:
through adding multiple auxiliary agents in the raw materials, and the cooperation sodium stearate for the inorganic glue of preparation has good high temperature resistance, is difficult for melting in high temperature environment, simultaneously through adding water repellent in the component, makes the inorganic glue of preparation have good water resistance, thereby can avoid taking place the phenomenon of infiltration, is favorable to actual use.
Detailed Description
The invention provides a technical scheme that: the high-temperature-resistant waterproof inorganic glue is prepared from the following raw materials in parts by weight: 20-35 parts of white latex, 15-25 parts of sodium stearate, 13-17 parts of acrylic emulsion, 12-18 parts of melamine resin, 15-20 parts of talcum powder, 8-12 parts of ethylene glycol, 4-8 parts of flame retardant, 5-9 parts of water repellent agent, 2-3 parts of defoaming agent, 2-5 parts of flatting agent and 4-7 parts of cosolvent.
Wherein, the flame retardant is one of potassium tungstate and sodium tungstate.
Wherein the water repellent agent is one of fatty acid aluminum salt or polyamide polyurea.
Wherein, the defoaming agent is one of organic silicon or polyether.
Wherein, the leveling agent is one of polyterephthalic acid or polydimethylsiloxane.
Wherein, the cosolvent is one of urea or zinc oxide.
The preparation method of the high-temperature-resistant waterproof inorganic glue comprises the following steps:
s1, weighing white latex, sodium stearate, acrylic emulsion, melamine resin, talcum powder and ethylene glycol according to the formula parts, mixing, pouring into a stirrer, setting the stirring speed at 2000-3000r/min, and the stirring time at 15-28min, and obtaining a mixture I after stirring;
s2, weighing the flame retardant according to the formula parts, adding the flame retardant into the mixture I, setting the stirring speed at 1500-;
s3, weighing the water repellent agent according to the formula parts, adding the water repellent agent into the mixture II, setting the stirring speed at 1200-1800r/min, setting the stirring time at 6-9min, and obtaining a mixture III after the stirring is finished;
s4, weighing the defoaming agent, the leveling agent and the cosolvent according to the formula parts, sequentially adding the defoaming agent, the leveling agent and the cosolvent into the mixture III, setting the stirring speed at 2500-;
and S5, adding deionized water into the obtained mixture IV, and adjusting the viscosity to be used so as to obtain the high-temperature-resistant waterproof inorganic glue.
The application mode of the high-temperature-resistant waterproof inorganic glue is that the mixture IV with the viscosity adjusted by adding the deionized water is smeared on an article and stands for more than 30min at the temperature of 10-25 ℃.
Example 1, the high-temperature resistant waterproof inorganic glue is prepared from the following raw materials in parts by weight: 20 parts of white latex, 15 parts of sodium stearate, 13 parts of acrylic emulsion, 12 parts of melamine resin, 15 parts of talcum powder, 8 parts of ethylene glycol, 4 parts of potassium tungstate, 5 parts of fatty acid aluminum salt, 2 parts of organic silicon, 2 parts of poly terephthalic acid and 4 parts of urea.
Figure 783483DEST_PATH_IMAGE001
A preparation method of high-temperature-resistant waterproof inorganic glue comprises the following steps:
s1, weighing white latex, sodium stearate, acrylic emulsion, melamine resin, talcum powder and ethylene glycol according to the formula parts, mixing, pouring into a stirrer, setting the stirring speed at 2000r/min, and stirring for 15min to obtain a first mixture after stirring;
s2, weighing potassium tungstate according to the formula parts, adding the potassium tungstate into the first mixture, setting the stirring speed to be 1500r/min, setting the stirring time to be 5min, and obtaining a second mixture after stirring;
s3, weighing fatty acid aluminum salt according to the formula parts, adding the fatty acid aluminum salt into the mixture II, setting the stirring speed to 1200r/min, setting the stirring time to 6min, and obtaining a mixture III after stirring;
s4, weighing organic silicon, poly (terephthalic acid) and urea according to the formula parts, sequentially adding the organic silicon, the poly (terephthalic acid) and the urea into the third mixture, setting the stirring speed to be 2500r/min, and the stirring time to be 20min, and obtaining a fourth mixture after the stirring is finished;
and S5, adding deionized water into the obtained mixture IV, and adjusting the viscosity to be used so as to obtain the high-temperature-resistant waterproof inorganic glue.
The application mode of the high-temperature-resistant waterproof inorganic glue is that the mixture IV with the viscosity adjusted by adding the deionized water is smeared on an article and stands for more than 30min at the temperature of 10 ℃.
Embodiment 2, a high temperature resistant waterproof inorganic glue, which is prepared from the following raw materials in parts by weight: 35 parts of white latex, 25 parts of sodium stearate, 17 parts of acrylic emulsion, 18 parts of melamine resin, 20 parts of talcum powder, 12 parts of ethylene glycol, 8 parts of sodium tungstate, 9 parts of polyamide polyurea, 3 parts of polyether, 5 parts of polydimethylsiloxane and 7 parts of zinc oxide.
Figure 253779DEST_PATH_IMAGE002
A preparation method of high-temperature-resistant waterproof inorganic glue comprises the following steps:
s1, weighing white latex, sodium stearate, acrylic emulsion, melamine resin, talcum powder and ethylene glycol according to the formula parts, mixing, pouring into a stirrer, setting the stirring speed to be 3000r/min, and stirring for 28min to obtain a mixture I;
s2, weighing sodium tungstate according to the formula parts, adding the sodium tungstate into the first mixture, setting the stirring speed to be 2000r/min, setting the stirring time to be 8min, and obtaining a second mixture after stirring;
s3, weighing polyamide polyurea according to the formula parts, adding the polyamide polyurea into the mixture II, setting the stirring speed to be 1800r/min, setting the stirring time to be 9min, and obtaining a mixture III after stirring;
s4, weighing polyether, polydimethylsiloxane and zinc oxide according to the formula parts, sequentially adding the polyether, polydimethylsiloxane and zinc oxide into the third mixture, setting the stirring speed to be 4000r/min and the stirring time to be 35min, and obtaining a fourth mixture after stirring is finished;
and S5, adding deionized water into the obtained mixture IV, and adjusting the viscosity to be used so as to obtain the high-temperature-resistant waterproof inorganic glue.
The application mode of the high-temperature-resistant waterproof inorganic glue is that the mixture IV with the viscosity adjusted by adding the deionized water is smeared on an article and stands for more than 30min at the temperature of 25 ℃.
In the present invention, unless otherwise expressly specified or limited, the terms "mounted," "disposed," "connected," "secured," "screwed" and the like are to be construed broadly, e.g., as meaning fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; the terms may be directly connected or indirectly connected through an intermediate, and may be communication between two elements or interaction relationship between two elements, unless otherwise specifically limited, and the specific meaning of the terms in the present invention will be understood by those skilled in the art according to specific situations.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (8)

1. The high-temperature-resistant waterproof inorganic glue is characterized by being prepared from the following raw materials in parts by weight: 20-35 parts of white latex, 15-25 parts of sodium stearate, 13-17 parts of acrylic emulsion, 12-18 parts of melamine resin, 15-20 parts of talcum powder, 8-12 parts of ethylene glycol, 4-8 parts of flame retardant, 5-9 parts of water repellent agent, 2-3 parts of defoaming agent, 2-5 parts of flatting agent and 4-7 parts of cosolvent.
2. The high-temperature-resistant waterproof inorganic glue according to claim 1, characterized in that: the flame retardant is one of potassium tungstate and sodium tungstate.
3. The high-temperature-resistant waterproof inorganic glue according to claim 1, characterized in that: the water repellent agent is one of fatty acid aluminum salt or polyamide polyurea.
4. The high-temperature-resistant waterproof inorganic glue according to claim 1, characterized in that: the defoaming agent is one of organic silicon or polyether.
5. The high-temperature-resistant waterproof inorganic glue according to claim 1, characterized in that: the leveling agent is one of poly terephthalic acid or polydimethylsiloxane.
6. The high-temperature-resistant waterproof inorganic glue according to claim 1, characterized in that: the cosolvent is one of urea or zinc oxide.
7. The preparation method of the high-temperature-resistant waterproof inorganic glue according to claim 1, characterized in that: the method comprises the following steps:
s1, weighing white latex, sodium stearate, acrylic emulsion, melamine resin, talcum powder and ethylene glycol according to the formula parts, mixing, pouring into a stirrer, setting the stirring speed at 2000-3000r/min, and the stirring time at 15-28min, and obtaining a mixture I after stirring;
s2, weighing the flame retardant according to the formula parts, adding the flame retardant into the mixture I, setting the stirring speed at 1500-;
s3, weighing the water repellent agent according to the formula parts, adding the water repellent agent into the mixture II, setting the stirring speed at 1200-1800r/min, setting the stirring time at 6-9min, and obtaining a mixture III after the stirring is finished;
s4, weighing the defoaming agent, the leveling agent and the cosolvent according to the formula parts, sequentially adding the defoaming agent, the leveling agent and the cosolvent into the mixture III, setting the stirring speed at 2500-;
and S5, adding deionized water into the obtained mixture IV, and adjusting the viscosity to be used so as to obtain the high-temperature-resistant waterproof inorganic glue.
8. The use of the high temperature resistant waterproof inorganic glue according to claim 1, characterized in that: and smearing the mixture IV with the viscosity adjusted by the deionized water on an article, and standing for more than 30min at the temperature of 10-25 ℃.
CN202111456800.0A 2021-12-01 2021-12-01 High-temperature-resistant waterproof inorganic glue and preparation method and application thereof Pending CN114163948A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005281626A (en) * 2004-03-30 2005-10-13 Nitto Polymer Kogyo Kk Inorganic-organic composite type aqueous adhesive composition
CN106995669A (en) * 2017-05-23 2017-08-01 阮传华 Industrial glue of a kind of water proof type and preparation method thereof
CN111019583A (en) * 2019-12-03 2020-04-17 江苏科趣新材料科技有限公司 Polyurethane glue and preparation method thereof
CN112126296A (en) * 2020-09-19 2020-12-25 河北迎尧建筑工程有限公司 Sound insulation emulsion paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005281626A (en) * 2004-03-30 2005-10-13 Nitto Polymer Kogyo Kk Inorganic-organic composite type aqueous adhesive composition
CN106995669A (en) * 2017-05-23 2017-08-01 阮传华 Industrial glue of a kind of water proof type and preparation method thereof
CN111019583A (en) * 2019-12-03 2020-04-17 江苏科趣新材料科技有限公司 Polyurethane glue and preparation method thereof
CN112126296A (en) * 2020-09-19 2020-12-25 河北迎尧建筑工程有限公司 Sound insulation emulsion paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中国室内装饰协会主编: "《室内装饰材料实用教程》", 30 September 2006, 上海科学技术出版社 *

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