CN114132028A - Preparation method of plastic decorative sheet capable of purifying air for a long time - Google Patents

Preparation method of plastic decorative sheet capable of purifying air for a long time Download PDF

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Publication number
CN114132028A
CN114132028A CN202111622726.5A CN202111622726A CN114132028A CN 114132028 A CN114132028 A CN 114132028A CN 202111622726 A CN202111622726 A CN 202111622726A CN 114132028 A CN114132028 A CN 114132028A
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preparing
decorative sheet
plastic decorative
purifying air
sheet capable
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CN202111622726.5A
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区绍贤
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • B32B38/145Printing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/243Coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00Furniture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/221Oxides; Hydroxides of metals of rare earth metal
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/221Oxides; Hydroxides of metals of rare earth metal
    • C08K2003/2213Oxides; Hydroxides of metals of rare earth metal of cerium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a preparation method of a plastic decorative sheet capable of purifying air for a long time, which belongs to the technical field of plastic decorative sheet preparation and comprises the following steps: (1) preparing a base film, (2) preparing a functional coating, (3) preparing a functional patch, and (4) preparing a finished product. The invention provides a preparation method of a plastic decorative sheet capable of purifying air for a long time, the method has simple integral process and easy popularization and application, and the prepared plastic decorative sheet not only can play a traditional effect of beautifying and decorating, but also can continuously decompose various harmful substances such as formaldehyde, toluene, sulfur dioxide, TVOC and the like so as to achieve the purpose of purifying indoor air; meanwhile, the antibacterial and bacteriostatic agent can also inhibit the growth of various bacteria such as escherichia coli, staphylococcus aureus, candida albicans and the like, and has the effects of resisting and inhibiting bacteria and no mildew for a long time; provides a living environment with fresh and clean air for people.

Description

Preparation method of plastic decorative sheet capable of purifying air for a long time
Technical Field
The invention belongs to the technical field of plastic decorative sheet preparation, and particularly relates to a preparation method of a plastic decorative sheet capable of purifying air for a long time.
Background
The plastic decorative sheet is widely applied to the field of home decoration such as wallpaper, wall panels, wardrobes and the like due to exquisite printing and rich patterns and colors, can play a role in beautifying the home, but cannot remove harmful substances such as formaldehyde, toluene, TVOC and the like continuously emitted by indoor decoration materials, and cannot meet the requirements of people on health.
Disclosure of Invention
The invention aims to provide a preparation method of a plastic decorative sheet capable of purifying air for a long time.
The technical purpose of the invention is realized by the following technical scheme:
a preparation method of plastic decorative sheet capable of purifying air for a long time comprises the following steps:
(1) preparing a base film:
printing patterns on the plastic base material film by using a printer to obtain a base film for later use;
(2) preparing a functional coating:
mixing rare earth, nano filler, polyurethane and water to prepare functional coating for later use;
(3) preparing functional dough sheets:
uniformly coating the functional coating prepared in the step (2) on a plastic dough sheet by using a coating machine, and obtaining a functional dough sheet for later use after finishing;
(4) and (3) preparing a finished product:
and (3) compounding and embossing the base film prepared in the step (1) and the functional patch prepared in the step (3) by using a compounding machine, and obtaining a finished product after finishing.
Further, the printing machine in the step (1) adopts a five-color gravure printing machine.
Further, the corresponding weight ratio of the rare earth, the nano filler, the polyurethane and the water in the step (2) is 2-4: 20-25: 10-15: 280 to 300.
Further, the rare earth in the step (2) is any one of lanthanum oxide, cerium oxide and yttrium nitrate.
Further, the nano filler in the step (2) is a mixture of nano titanium dioxide and nano silicon dioxide, and the weight ratio of the nano titanium dioxide to the nano silicon dioxide is 2-3: 1.
further, the speed of the control host machine of the coating machine in the step (3) is not less than 20m/min when the coating machine works; and the baking temperature is controlled to be 80 ℃.
Compared with the prior art, the invention has the following advantages:
the invention provides a preparation method of a plastic decorative sheet capable of purifying air for a long time, the method has simple integral process and easy popularization and application, and the prepared plastic decorative sheet not only can play a traditional effect of beautifying and decorating, but also can continuously decompose various harmful substances such as formaldehyde, toluene, sulfur dioxide, TVOC and the like so as to achieve the purpose of purifying indoor air; meanwhile, the antibacterial and bacteriostatic agent can also inhibit the growth of various bacteria such as escherichia coli, staphylococcus aureus, candida albicans and the like, and has the effects of resisting and inhibiting bacteria and no mildew for a long time; provides a living environment with fresh and clean air for people. Has high market competitiveness and production value.
Detailed Description
Example 1
A preparation method of plastic decorative sheet capable of purifying air for a long time comprises the following steps:
(1) preparing a base film:
printing patterns on the plastic base material film by using a printer to obtain a base film for later use;
(2) preparing a functional coating:
mixing rare earth, nano filler, polyurethane and water to prepare functional coating for later use;
(3) preparing functional dough sheets:
uniformly coating the functional coating prepared in the step (2) on a plastic dough sheet by using a coating machine, and obtaining a functional dough sheet for later use after finishing;
(4) and (3) preparing a finished product:
and (3) compounding and embossing the base film prepared in the step (1) and the functional patch prepared in the step (3) by using a compounding machine, and obtaining a finished product after finishing.
The printing machine in the step (1) adopts a five-color gravure printing machine.
The corresponding weight ratio of the rare earth, the nano filler, the polyurethane and the water in the step (2) is 2: 20: 10: 280.
the rare earth is lanthanum oxide.
The nano filler is a mixture of nano titanium dioxide and nano silicon dioxide, and the weight ratio of the nano titanium dioxide to the nano silicon dioxide is 2: 1.
when the coating machine in the step (3) works, controlling the speed of the host machine to be not less than 20 m/min; and the baking temperature is controlled to be 80 ℃.
Example 2
A preparation method of plastic decorative sheet capable of purifying air for a long time comprises the following steps:
(1) preparing a base film:
printing patterns on the plastic base material film by using a printer to obtain a base film for later use;
(2) preparing a functional coating:
mixing rare earth, nano filler, polyurethane and water to prepare functional coating for later use;
(3) preparing functional dough sheets:
uniformly coating the functional coating prepared in the step (2) on a plastic dough sheet by using a coating machine, and obtaining a functional dough sheet for later use after finishing;
(4) and (3) preparing a finished product:
and (3) compounding and embossing the base film prepared in the step (1) and the functional patch prepared in the step (3) by using a compounding machine, and obtaining a finished product after finishing.
The printing machine in the step (1) adopts a five-color gravure printing machine.
The corresponding weight ratio of the rare earth, the nano filler, the polyurethane and the water in the step (2) is 3: 23: 12: 290.
the rare earth is cerium oxide.
The nano filler is a mixture of nano titanium dioxide and nano silicon dioxide, and the weight ratio of the nano titanium dioxide to the nano silicon dioxide is 2.5: 1.
when the coating machine in the step (3) works, controlling the speed of the host machine to be not less than 20 m/min; and the baking temperature is controlled to be 80 ℃.
Example 3
A preparation method of plastic decorative sheet capable of purifying air for a long time comprises the following steps:
(1) preparing a base film:
printing patterns on the plastic base material film by using a printer to obtain a base film for later use;
(2) preparing a functional coating:
mixing rare earth, nano filler, polyurethane and water to prepare functional coating for later use;
(3) preparing functional dough sheets:
uniformly coating the functional coating prepared in the step (2) on a plastic dough sheet by using a coating machine, and obtaining a functional dough sheet for later use after finishing;
(4) and (3) preparing a finished product:
and (3) compounding and embossing the base film prepared in the step (1) and the functional patch prepared in the step (3) by using a compounding machine, and obtaining a finished product after finishing.
The printing machine in the step (1) adopts a five-color gravure printing machine.
The corresponding weight ratio of the rare earth, the nano filler, the polyurethane and the water in the step (2) is 4: 25: 15: 300.
the rare earth is yttrium nitrate.
The nano filler is a mixture of nano titanium dioxide and nano silicon dioxide, and the weight ratio of the nano titanium dioxide to the nano silicon dioxide is 3: 1.
when the coating machine in the step (3) works, controlling the speed of the host machine to be not less than 20 m/min; and the baking temperature is controlled to be 80 ℃.
The plastic decorative sheet provided by the invention is tested for antibacterial performance by adopting the GB/T31402-2015 standard, and the antibacterial rate of the plastic decorative sheet to escherichia coli is not lower than 99.9%, the antibacterial rate to staphylococcus aureus is not lower than 99.8%, and the antibacterial rate to candida albicans is not lower than 95.1%.
The plastic decorative sheet is subjected to toluene purification performance detection according to the standard of JC/T1074-2008, and the durability of the purification effect under the experimental condition is not lower than 63.0 percent; detecting the formaldehyde purification performance, and finding that the durability of the purification effect under the experimental condition is not lower than 86.3%; and detecting the purification performance of the sulfur dioxide, and finding that the durability of the purification effect under the experimental condition is not lower than 91.4%.
Therefore, the plastic decorative sheet prepared by the method has good use and popularization values.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that modifications can be made by those skilled in the art without departing from the principle of the present invention, and these modifications should also be construed as the protection scope of the present invention.

Claims (6)

1. The preparation method of the plastic decorative sheet capable of purifying air for a long time is characterized by comprising the following steps:
(1) preparing a base film:
printing patterns on the plastic base material film by using a printer to obtain a base film for later use;
(2) preparing a functional coating:
mixing rare earth, nano filler, polyurethane and water to prepare functional coating for later use;
(3) preparing functional dough sheets:
uniformly coating the functional coating prepared in the step (2) on a plastic dough sheet by using a coating machine, and obtaining a functional dough sheet for later use after finishing;
(4) and (3) preparing a finished product:
and (3) compounding and embossing the base film prepared in the step (1) and the functional patch prepared in the step (3) by using a compounding machine, and obtaining a finished product after finishing.
2. The method for preparing plastic decorative sheet capable of permanently purifying air according to claim 1, wherein the printing machine in the step (1) is a five-color gravure printing machine.
3. The method for preparing plastic decorative sheet capable of purifying air permanently according to claim 1, wherein the weight ratio of the rare earth, the nano filler, the polyurethane and the water in the step (2) is 2-4: 20-25: 10-15: 280 to 300.
4. The method for preparing plastic decorative sheet capable of purifying air permanently as claimed in claim 1, wherein the rare earth in step (2) is any one of lanthanum oxide, cerium oxide and yttrium nitrate.
5. The method for preparing plastic decorative sheet capable of purifying air permanently as claimed in claim 1, wherein the nano filler in step (2) is a mixture of nano titanium dioxide and nano silica, and the weight ratio of the nano titanium dioxide to the nano silica is 2-3: 1.
6. the method for preparing plastic decorative sheet capable of permanently purifying air according to claim 1, wherein the speed of the main control machine in the operation of the coating machine in the step (3) is not less than 20 m/min; and the baking temperature is controlled to be 80 ℃.
CN202111622726.5A 2021-04-06 2021-12-28 Preparation method of plastic decorative sheet capable of purifying air for a long time Pending CN114132028A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202110369231X 2021-04-06
CN202110369231.XA CN112959765A (en) 2021-04-06 2021-04-06 Preparation process of plastic decorative sheet capable of purifying air for a long time

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CN114132028A true CN114132028A (en) 2022-03-04

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CN202111622726.5A Pending CN114132028A (en) 2021-04-06 2021-12-28 Preparation method of plastic decorative sheet capable of purifying air for a long time

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104530601A (en) * 2014-12-30 2015-04-22 东莞市悠悠美居家居制造有限公司 High-strength registered embossing composite plastic sheet and preparation method thereof
WO2017016455A1 (en) * 2015-07-27 2017-02-02 宝山钢铁股份有限公司 Environmentally friendly surface treating agent for galvanized steel sheet, galvanized steel sheet, and manufacturing method for galvanized steel sheet
CN106760281A (en) * 2016-11-14 2017-05-31 山东中冠新材料科技有限公司 A kind of anion wall paper and its preparation method
CN107903790A (en) * 2017-11-24 2018-04-13 东莞市明天纳米科技有限公司 Aqueous woodware paint with purification air and sterilizing function and preparation method thereof
CN108676497A (en) * 2018-05-16 2018-10-19 河北晨阳工贸集团有限公司 Environmental protection coating material and preparation method thereof
WO2019196181A1 (en) * 2018-04-08 2019-10-17 江苏中翼汽车新材料科技有限公司 Aluminum oxide short fiber-reinforced magnesium oxide-based foam ceramic filter and preparation method therefor
CN111155731A (en) * 2019-12-25 2020-05-15 安徽赛驰通讯科技有限公司 Non-woven wallpaper capable of purifying indoor air and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104530601A (en) * 2014-12-30 2015-04-22 东莞市悠悠美居家居制造有限公司 High-strength registered embossing composite plastic sheet and preparation method thereof
WO2017016455A1 (en) * 2015-07-27 2017-02-02 宝山钢铁股份有限公司 Environmentally friendly surface treating agent for galvanized steel sheet, galvanized steel sheet, and manufacturing method for galvanized steel sheet
CN106760281A (en) * 2016-11-14 2017-05-31 山东中冠新材料科技有限公司 A kind of anion wall paper and its preparation method
CN107903790A (en) * 2017-11-24 2018-04-13 东莞市明天纳米科技有限公司 Aqueous woodware paint with purification air and sterilizing function and preparation method thereof
WO2019196181A1 (en) * 2018-04-08 2019-10-17 江苏中翼汽车新材料科技有限公司 Aluminum oxide short fiber-reinforced magnesium oxide-based foam ceramic filter and preparation method therefor
CN108676497A (en) * 2018-05-16 2018-10-19 河北晨阳工贸集团有限公司 Environmental protection coating material and preparation method thereof
CN111155731A (en) * 2019-12-25 2020-05-15 安徽赛驰通讯科技有限公司 Non-woven wallpaper capable of purifying indoor air and preparation method thereof

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