CN106478148B - It is a kind of can be in the multifunctional stone protective agent that wet plate state uses - Google Patents
It is a kind of can be in the multifunctional stone protective agent that wet plate state uses Download PDFInfo
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- CN106478148B CN106478148B CN201610964252.5A CN201610964252A CN106478148B CN 106478148 B CN106478148 B CN 106478148B CN 201610964252 A CN201610964252 A CN 201610964252A CN 106478148 B CN106478148 B CN 106478148B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5072—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with oxides or hydroxides not covered by C04B41/5025
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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Abstract
The present invention it is a kind of can include in the multifunctional stone protective agent that wet plate state uses following weight ingredient：18 30 parts of 3 aminopropyl trimethoxysilanes of N 2 (aminoethyl), 1 10 parts of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters, 6 13 parts of the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, bis- 2 16 parts of (trimethylsilyl) trifluoroacetamides of O, 5 10 parts of 2 amino, 4 trifluoromethyl pyrimidine, 5 carboxylic acid, ethyl ester, 1,5,6,7 tetrahydro cyclopentyls simultaneously 1 10 parts of 4 ketone of [d] pyrimidine, 1,2 10 30 parts of propylene glycol, 25 parts of iso-butyl p-hy-droxybenzoate, 15 25 parts of ethylene glycol, 3 hydroxyls 4（3 hydroxyl, 3 phenylacrylic acid）3 12 parts of phenylester, 10 50 parts of ethyl alcohol and TiO20 15 parts of colloidal sol.The present invention has the following advantages：（1）It can wet plate construction；（2）Have both antibacterial, sterilization and the function of decomposing toxic and harmful gas in air；（3）It is cheap；（4）Construction is simple is suitable for the stone protector demand of various material.
Description
Technical field
The present invention relates to stone protector technical field, more particularly to it is a kind of can be in the multifunctional stone that wet plate state uses
Protective agent.
Background technology
Stone material becomes indispensable in buildings decoration industry because of its noble, elegant, firm, beautiful decorative characteristic
A part.With the rapid growth of entire real-estate market, stone decoration presents huge development space in decoration marked.
However, many lithotomes because of origin cause of formation difference, contain in stone material, there are many invisible gap and pores, can make stone material
There is certain water imbibition.Meanwhile the water that can be cooled in the cutting process of stone material is soaked.This infiltration and adsorb in environment easily
Absorb the corrosive gas in moisture content, pollutant and air, will make stone material that water spots occur in the short time, spit yellow, stone acupuncture needle alkali and
Various stone material lesions, influence decorative effect and service life.To alleviate this case, " stone protectant " product comes into being.
With the development of science and technology stone protectant experienced one from single to complexity, from general to special, from foundation protection to environmental protection
The evolution of multifunctional protection.From earliest stone protector paraffin environmentally friendly class immersion-type stone protectant newest till now,
People are constantly pursuing the development and innovation of protective agent product functionally.However, the behind people in product but often ignore
The demand of work progress and targetedly product improvement.Stone material waterproofing agent with outstanding water proof anti-soil function in market at present
Have the characteristics that on construction requirement common, i.e., product is before waterproof construction, it is necessary to just can be into after stone material cleaning is dried
Row protective treatment.These protective agents had both included aqueous Protection Product, also included oiliness Protection Product.However, due to the original of weather
Cause, in southern gathering area of stone material factory rainy water season, northern area winter temperature is low, itself band has the gap the stone with pore
Such as fully drying will lead to postponing for entire duration to material, affect the increase of the process and cost of entire project under construction.If no
Ensure the drying property of stone material, then can seriously affect the protection effect of stone material, or even protective treatment can not be carried out to stone material.
Therefore, in the prior art there are problem, it is urgent to provide it is a kind of can under wet plate state construction usage stone
Material guard technology is particularly important.
Invention content
It is an object of the invention to avoid shortcoming in the prior art and provide a kind of to use in wet plate state
Multifunctional stone protective agent.
The purpose of the present invention is achieved through the following technical solutions：
A kind of can include the ingredient of following weight in the multifunctional stone protective agent that wet plate state uses：
18-30 parts of N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes,
1-10 parts of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters,
6-13 parts of the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
2-16 parts of N, O- bis- (trimethylsilyl) trifluoroacetamides,
5-10 parts of 2- amino -4- trifluoromethyl pyrimidines -5- carboxylic acid, ethyl esters,
1,5,6,7- tetrahydro cyclopentyl simultaneously 1-10 parts of [d] pyrimidin-4-one,
10-30 parts of 1,2-PD,
2-5 parts of iso-butyl p-hy-droxybenzoate,
15-25 parts of ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）3-12 parts of phenylester,
10-50 parts of ethyl alcohol,
TiO20-15 parts of colloidal sol.
Preferably, can in the multifunctional stone protective agent that wet plate state uses by following weight at being grouped as：
20 parts of N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes,
6 parts of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters,
6 parts of the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- 5 parts of (trimethylsilyl) trifluoroacetamides of N, O-,
7 parts of 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters,
1,5,6,7- tetrahydro cyclopentyl simultaneously 8 parts of [d] pyrimidin-4-one,
14 parts of 1,2-PD,
4 parts of iso-butyl p-hy-droxybenzoate,
12 parts of ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）6 parts of phenylester,
11 parts of ethyl alcohol,
TiO21 part of colloidal sol.
It is another preferred, it can be in the multifunctional stone protective agent that wet plate state uses by the ingredient of following weight：
18 parts of N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes,
1 part of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters,
6 parts of the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- 2 parts of (trimethylsilyl) trifluoroacetamides of N, O-,
5 parts of 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters,
1,5,6,7- tetrahydro cyclopentyl simultaneously 1 part of [d] pyrimidin-4-one,
10 parts of 1,2-PD,
2 parts of iso-butyl p-hy-droxybenzoate,
15 parts of ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）3 parts of phenylester,
10 parts of ethyl alcohol.
It is another preferred, can in the multifunctional stone protective agent that wet plate state uses by following weight at grouping
At：
30 parts of N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes,
10 parts of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters,
13 parts of the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- 16 parts of (trimethylsilyl) trifluoroacetamides of N, O-,
10 parts of 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters,
1,5,6,7- tetrahydro cyclopentyl simultaneously 10 parts of [d] pyrimidin-4-one,
30 parts of 1,2-PD,
5 parts of iso-butyl p-hy-droxybenzoate,
25 parts of ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）12 parts of phenylester,
50 parts of ethyl alcohol,
TiO215 parts of colloidal sol.
Another object of the present invention is to avoid shortcoming in the prior art and providing one kind can make in wet plate state
The preparation method of multifunctional stone protective agent.
Another object of the present invention is achieved through the following technical solutions：
A kind of can include following steps in the preparation method for the multifunctional stone protective agent that wet plate state uses：By upper
State can in the weight feeding for the multifunctional stone protective agent that wet plate state uses,
By 1,2- propylene glycol, 1,5,6,7- tetrahydro cyclopentyls simultaneously [d] pyrimidin-4-one, iso-butyl p-hy-droxybenzoate, ethylene glycol, 3- hydroxyls
Base -4-（3- hydroxyl -3- phenylacrylic acids）It is sufficiently stirred 4-6 hours after phenylester and ethyl alcohol mixing,
N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy) is added
Titanate esters, the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, the bis- (trimethyl silicanes of O-
Alkyl) trifluoroacetamide and 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters, are stirred 1 ~ 3 hour, then dropwise at room temperature
Add TiO2Colloidal sol, static 25 ~ 35 minutes.
Preferably, can include following steps in the preparation method for the multifunctional stone protective agent that wet plate state uses,
By 1,2- propylene glycol, 1,5,6,7- tetrahydro cyclopentyls simultaneously [d] pyrimidin-4-one, iso-butyl p-hy-droxybenzoate, ethylene glycol, 3- hydroxyls
Base -4-（3- hydroxyl -3- phenylacrylic acids）It is sufficiently stirred 5 hours after phenylester and ethyl alcohol mixing,
N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy) is added
Titanate esters, the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, the bis- (trimethyl silicanes of O-
Alkyl) trifluoroacetamide and 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters, stir 2 hours at room temperature, then dropwise plus
TiO2Colloidal sol, static 30 minutes.
Beneficial effects of the present invention：
The a kind of of the present invention can include following weight in the multifunctional stone protective agent that wet plate state uses
Ingredient：18-30 parts of N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy)
6-13 parts, N of the chelate solution of 1-10 parts of titanate esters, Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
2-16 parts of O- bis- (trimethylsilyl) trifluoroacetamides, 5-10 parts of 2- amino -4- trifluoromethyl pyrimidines -5- carboxylic acid, ethyl esters, 1,
5,6,7- tetrahydro cyclopentyls simultaneously 1-10 parts of [d] pyrimidin-4-one, 10-30 parts of 1,2-PD, 2-5 parts of iso-butyl p-hy-droxybenzoate, ethylene glycol
15-25 parts, 3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）3-12 parts of phenylester, 10-50 parts of ethyl alcohol and TiO2Colloidal sol 0-15
Part.The effect that the present invention gives full play to each component forms the stone material for being applicable to moisture state, with the common stone material waterproofing agent in market
It compares, has the following advantages：
（1）It can wet plate construction.Due to capillarity, moisture, common stone protector are easily absorbed in the pore of stone material gap
Agent is only to form one layer of protective layer for being similar to protective film in stone surface, and it is original ventilative not only to influence stone material in this way
Property, and construct under hygrometric state, the moisture in stone material can not just be evaporated.Over time, various stone material problems
Just occur in succession.Hydrone can be started by the stone material waterproofing agent constructed under the wet plate state of the present invention from bottom, directly be penetrated into
Inside stone material, product is in stone material pore and is attached on mineral molecule, is acted on by crosslinking agent, but do not change stone surface shape
State occupies the original spatial position of hydrone, therefore does not influence original stone material gas permeability not only, but also wet plate processes same energy
Protection effect is played, waterproof, the soil resistance of high-efficient and lasting are generated.
（2）Have both antibacterial, sterilization and the function of decomposing toxic and harmful gas in air
The multifunctional stone protective agent used under the wettable board status of the present invention is innovatively added to the good TiO of compatibility2
（Titanium dioxide）Colloidal sol photocatalyst solution, this photocatalyst solution nano-particle are respectively less than 10nm, and solvent is alcoholic solvent clear solution,
Other solvents have good compatibility with protective agent, do not influence its original waterproof, antifouling property, while can give full play to
Its photocatalysis performance.The toxic and harmful gas in ultraviolet light degradation outdoor air is absorbed and utilized in outdoor environment, indoors ring
The sterilization of effective spectrum of fluorescent lamp, antibacterial, toxic and harmful gas in decomposition chamber are utilized in border.
（3）It is cheap
The preparation method of the multifunctional stone protective agent used under the wettable board status of the present invention is simple, without high pressure and finely
The production operations such as temperature control, are simply mixed stirring.
（4）Construction is simple is suitable for the stone protector demand of various material
The multifunctional stone protective agent occupation mode used under the wettable board status of the present invention is simple, spraying, brushing, roller coating,
The mode of dip-coating, and a variety of stone surfaces such as can be widely used in granite, marble, sandstone, volcanic rock, after processing
Stone appearance color is unchanged, is particularly suitable for the light stone protector such as hemp.
Specific implementation mode
The invention will be further described with the following Examples.
Embodiment 1
The a kind of of the present embodiment can include consisting of in the multifunctional stone protective agent that wet plate state uses：
N-2- (aminoethyl) -3- aminopropyl trimethoxysilane 29kg,
Tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters 5kg,
The chelate solution 5kg of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- (trimethylsilyl) the trifluoroacetamide 7.5kg of N, O-,
2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl ester 10.5kg,
1,5,6,7- tetrahydro cyclopentyl simultaneously [d] pyrimidin-4-one 12kg,
1,2-PD 21kg,
Iso-butyl p-hy-droxybenzoate 6kg,
Ethylene glycol 27kg,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）Phenylester 9kg,
Ethyl alcohol 16.5kg,
TiO2Colloidal sol 1.5kg.
The a kind of of the present embodiment can be in the preparation method for the multifunctional stone protective agent that wet plate state uses：According to above-mentioned
Composition and ratio feeding, by 1,2-PD, 1,5,6,7- tetrahydro cyclopentyls simultaneously [d] pyrimidin-4-one, iso-butyl p-hy-droxybenzoate, ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）It is sufficiently stirred 5 hours after phenylester and ethyl alcohol mixing,
N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy) is added
Titanate esters, the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, the bis- (trimethyl silicanes of O-
Alkyl) trifluoroacetamide and 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters, stir 2 hours at room temperature, then dropwise plus
TiO2Colloidal sol, static 30 minutes.
Embodiment 2
The main technical schemes of the present embodiment are substantially the same manner as Example 1, and the feature not laid down a definition in the present embodiment is adopted
With the explanation in embodiment 1, no longer repeated herein.
N-2- (aminoethyl) -3- aminopropyl trimethoxysilane 20kg,
Tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters 6kg,
The chelate solution 6kg of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- (trimethylsilyl) the trifluoroacetamide 5kg of N, O-,
2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl ester 7kg,
1,5,6,7- tetrahydro cyclopentyl simultaneously [d] pyrimidin-4-one 8kg,
1,2-PD 14kg,
Iso-butyl p-hy-droxybenzoate 4kg,
Ethylene glycol 12kg,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）Phenylester 6kg,
Ethyl alcohol 11kg,
TiO2Colloidal sol 1kg.
The present invention can the component materials for the multifunctional stone protective agent that wet plate state uses can be from purchasing on the market
Buy acquisition.
The a kind of of the present embodiment can be in the preparation method for the multifunctional stone protective agent that wet plate state uses：According to above-mentioned
Composition and ratio feeding, by 1,2-PD, 1,5,6,7- tetrahydro cyclopentyls simultaneously [d] pyrimidin-4-one, iso-butyl p-hy-droxybenzoate, ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）It is sufficiently stirred 4 hours after phenylester and ethyl alcohol mixing,
N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy) is added
Titanate esters, the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, the bis- (trimethyl silicanes of O-
Alkyl) trifluoroacetamide and 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters, stir 2 hours at room temperature, then dropwise plus
TiO2Colloidal sol, static 25 minutes.
Embodiment 3
The main technical schemes of the present embodiment are substantially the same manner as Example 1, and the feature not laid down a definition in the present embodiment is adopted
With the explanation in embodiment 1, no longer repeated herein.
N-2- (aminoethyl) -3- aminopropyl trimethoxysilane 18kg,
Tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters 1kg,
The chelate solution 6kg of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- (trimethylsilyl) the trifluoroacetamide 2kg of N, O-,
2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl ester 5kg,
1,5,6,7- tetrahydro cyclopentyl simultaneously [d] pyrimidin-4-one 1kg,
1,2-PD 10kg,
Iso-butyl p-hy-droxybenzoate 2kg,
Ethylene glycol 15kg,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）Phenylester 3kg,
Ethyl alcohol 10kg.
The a kind of of the present embodiment can be in the preparation method for the multifunctional stone protective agent that wet plate state uses：According to above-mentioned
Composition and ratio feeding, by 1,2-PD, 1,5,6,7- tetrahydro cyclopentyls simultaneously [d] pyrimidin-4-one, iso-butyl p-hy-droxybenzoate, ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）It is sufficiently stirred 5 hours after phenylester and ethyl alcohol mixing,
N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy) is added
Titanate esters, the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, the bis- (trimethyl silicanes of O-
Alkyl) trifluoroacetamide and 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters, are stirred 2.5 hours at room temperature.
Embodiment 4
The main technical schemes of the present embodiment are substantially the same manner as Example 1, and the feature not laid down a definition in the present embodiment is adopted
With the explanation in embodiment 1, no longer repeated herein.
N-2- (aminoethyl) -3- aminopropyl trimethoxysilane 30kg,
Tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters 10kg,
The chelate solution 13kg of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- (trimethylsilyl) the trifluoroacetamide 16kg of N, O-,
2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl ester 10kg,
1,5,6,7- tetrahydro cyclopentyl simultaneously [d] pyrimidin-4-one 10kg,
1,2-PD 30kg,
Iso-butyl p-hy-droxybenzoate 5kg,
Ethylene glycol 25kg,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）Phenylester 12kg,
Ethyl alcohol 50kg,
TiO2Colloidal sol 15kg.
The a kind of of the present embodiment can be in the preparation method for the multifunctional stone protective agent that wet plate state uses：According to above-mentioned
Composition and ratio feeding, by 1,2-PD, 1,5,6,7- tetrahydro cyclopentyls simultaneously [d] pyrimidin-4-one, iso-butyl p-hy-droxybenzoate, ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）It is sufficiently stirred 6 hours after phenylester and ethyl alcohol mixing,
N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy) is added
Titanate esters, the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, the bis- (trimethyl silicanes of O-
Alkyl) trifluoroacetamide and 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters, stir 3 hours at room temperature, then dropwise plus
TiO2Colloidal sol, static 35 minutes.
Performance test：
1 stone material water resistance contrast table of table
2 stone material antifouling property contrast table of table
Common protective agent can only make the effect of protective agent reach best under stone material dry state, and the stone protectant of this product
Either in the case of dry state or hygrometric state, protection effect is the same, and can be penetrated into and be formed lasting protection inside stone material
Layer.
Pollutants in air gas and microbial bacterial removal rate are tested.
Test condition：One cubic metre of artificial environment climate box（Equipped with fluorescent lamp, fan）
Test stone material：Marble slabs after the protection of this patent Protection Product
The removal rate of formaldehyde in air, ammonia, benzene, TVOC are tested according to GB50325-2001.
To the removal rate of the microbial bacterial in air, tested according to GB/T18204.1-2000.
Table 3 tests table to pollutants in air gas and microbial bacterial removal rate
Finally it should be noted that above example is only used to illustrate the technical scheme of the present invention explanation rather than is wanted to right
Ask the limitation of protection domain.Those skilled in the art should be appreciated that with reference to preferred embodiment and can be to the present invention's
Technical solution is modified or replaced equivalently, but belongs to the substantially identical and protection domain of technical solution of the present invention.
Claims (5)
1. a kind of can be in the multifunctional stone protective agent that wet plate state uses, which is characterized in that include following weight
Ingredient：
18-30 parts of N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes,
1-10 parts of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters,
6-13 parts of the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
2-16 parts of N, O- bis- (trimethylsilyl) trifluoroacetamides,
5-10 parts of 2- amino -4- trifluoromethyl pyrimidines -5- carboxylic acid, ethyl esters,
1,5,6,7- tetrahydro cyclopentyl simultaneously 1-10 parts of [d] pyrimidin-4-one,
10-30 parts of 1,2-PD,
2-5 parts of iso-butyl p-hy-droxybenzoate,
15-25 parts of ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）3-12 parts of phenylester,
10-50 parts of ethyl alcohol,
TiO20-15 parts of colloidal sol.
2. it is according to claim 1 it is a kind of can be in the multifunctional stone protective agent that wet plate state uses, which is characterized in that by
The ingredient of following weight：
18 parts of N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes,
1 part of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters,
6 parts of the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- 2 parts of (trimethylsilyl) trifluoroacetamides of N, O-,
5 parts of 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters,
1,5,6,7- tetrahydro cyclopentyl simultaneously 1 part of [d] pyrimidin-4-one,
10 parts of 1,2-PD,
2 parts of iso-butyl p-hy-droxybenzoate,
15 parts of ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）3 parts of phenylester,
10 parts of ethyl alcohol.
3. it is according to claim 1 it is a kind of can be in the multifunctional stone protective agent that wet plate state uses, which is characterized in that by
Following weight at being grouped as：
30 parts of N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes,
10 parts of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters,
13 parts of the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine,
Bis- 16 parts of (trimethylsilyl) trifluoroacetamides of N, O-,
10 parts of 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters,
1,5,6,7- tetrahydro cyclopentyl simultaneously 10 parts of [d] pyrimidin-4-one,
30 parts of 1,2-PD,
5 parts of iso-butyl p-hy-droxybenzoate,
25 parts of ethylene glycol,
3- hydroxyls -4-（3- hydroxyl -3- phenylacrylic acids）12 parts of phenylester,
50 parts of ethyl alcohol,
TiO215 parts of colloidal sol.
4. a kind of can be in the preparation method for the multifunctional stone protective agent that wet plate state uses, which is characterized in that be used to prepare as
Described in claim 1 ~ 3 any one can include following steps in the multifunctional stone protective agent that wet plate state uses：
According to described in claim 1 ~ 3 any one can be in the parts by weight for the multifunctional stone protective agent that wet plate state uses
Feeding is matched,
By 1,2- propylene glycol, 1,5,6,7- tetrahydro cyclopentyls simultaneously [d] pyrimidin-4-one, iso-butyl p-hy-droxybenzoate, ethylene glycol, 3- hydroxyls -4-
（3- hydroxyl -3- phenylacrylic acids）It is sufficiently stirred 4-6 hours after phenylester and ethyl alcohol mixing,
N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy) metatitanic acid is added
Ester, the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, the bis- (trimethyl silanes of O-
Base) trifluoroacetamide and 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters, stir 1 ~ 3 hour at room temperature, then dropwise plus
TiO2Colloidal sol, static 25 ~ 35 minutes.
5. it is according to claim 4 it is a kind of can in the preparation method for the multifunctional stone protective agent that wet plate state uses,
It is characterized in that, includes following steps：
By 1,2- propylene glycol, 1,5,6,7- tetrahydro cyclopentyls simultaneously [d] pyrimidin-4-one, iso-butyl p-hy-droxybenzoate, ethylene glycol, 3- hydroxyls -4-
（3- hydroxyl -3- phenylacrylic acids）It is sufficiently stirred 5 hours after phenylester and ethyl alcohol mixing,
N-2- (aminoethyl) -3- aminopropyl trimethoxysilanes, tetra isopropyl two (dioctyl phosphito acyloxy) metatitanic acid is added
Ester, the chelate solution of Di(dioctylpyrophosphato) ethylene titanate and triethanolamine, N, the bis- (trimethyl silanes of O-
Base) trifluoroacetamide and 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl esters, stir 2 hours at room temperature, then dropwise plus
TiO2Colloidal sol, static 30 minutes.
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| CN113980577B (en) * | 2021-10-26 | 2022-07-29 | 厦门锶特材料科技有限公司 | Prehydrolysis organic silicon precursor composition for stone protection and preparation method thereof |
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| DE10124499A1 (en) * | 2001-05-19 | 2002-11-21 | Remmers Bauchemie Gmbh | Industrially-produced surface coating agent, useful on stone material, brickwork and other surfaces, e.g. wood, metal, plastics and mineral surfaces, contains crushed stone fraction |
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| US20020006481A1 (en) * | 2000-01-03 | 2002-01-17 | Morris Barrington A. | Color coated landscape stones, surface coating, preparations therefor, and methods of producing same |
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| DE10124499A1 (en) * | 2001-05-19 | 2002-11-21 | Remmers Bauchemie Gmbh | Industrially-produced surface coating agent, useful on stone material, brickwork and other surfaces, e.g. wood, metal, plastics and mineral surfaces, contains crushed stone fraction |
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