CN114130560B - Sophorolipid compound for improving soil and spraying device - Google Patents

Sophorolipid compound for improving soil and spraying device Download PDF

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Publication number
CN114130560B
CN114130560B CN202111480371.0A CN202111480371A CN114130560B CN 114130560 B CN114130560 B CN 114130560B CN 202111480371 A CN202111480371 A CN 202111480371A CN 114130560 B CN114130560 B CN 114130560B
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sophorolipid
layer
pneumatic
compound
storage layer
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CN114130560A (en
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马晓静
王彤
邵君前
程旭
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Anhui Cuiying Lanmeng Biotechnology Co.,Ltd.
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Hefei University of Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/08Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B12/00Arrangements for controlling delivery; Arrangements for controlling the spray area
    • B05B12/02Arrangements for controlling delivery; Arrangements for controlling the spray area for controlling time, or sequence, of delivery
    • B05B12/04Arrangements for controlling delivery; Arrangements for controlling the spray area for controlling time, or sequence, of delivery for sequential operation or multiple outlets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil

Abstract

The invention discloses a sophorolipid compound for improving soil and a spraying device, belonging to the field of soil remediation. A sophorolipid compound for improving soil comprises the following components: sophorolipid, NaCl, ethylenediamine tetraacetic acid, diethyl aminoethyl hexanoate, konjac glucomannan and water; the utility model provides a sprinkler for improving soil includes by the storage layer that connects gradually under to, rotates layer and base, and the storage layer has a plurality of skewed teeth with the junction that rotates the layer, and the top of adjacent skewed tooth is equipped with outflow passageway, and outflow passageway intercommunication storage layer. In the technical scheme, the sprayed substance is special and is a sophorolipid compound with certain viscosity. Therefore, in the technical scheme, the sophorolipid compound flowing from the storage layer to the outflow channel is cut through the helical teeth, so that the phenomenon that the clustered viscous compound blocks the channel is avoided, the volume of the compound is reduced, the single-flow sophorolipid compound can be conveniently sprayed out, and the spraying speed and distance of the sophorolipid compound can be conveniently kept.

Description

Sophorolipid compound for improving soil and spraying device
Technical Field
The invention belongs to the field of soil remediation, and particularly relates to a sophorolipid compound for improving soil and a spraying device.
Background
With the rapid development of the petroleum industry, a large amount of petroleum-polluted soil is inevitably generated in the processes of crude oil exploration, transportation, processing and storage, and oil in the soil can permeate into an underground water layer to influence the growth of plants and crops.
The active agents for remedying the toxicity of soil are mainly classified into biological surfactants and non-biological surfactants. The non-biological surfactant is usually sodium dodecyl benzene sulfonate, sodium dodecyl sulfate and the like, has certain toxicity to plant growth and is not beneficial to further treatment of recovered soil, and compared with the biological surfactant, the biological surfactant has the characteristics of low toxicity, biodegradability and the like. Sophorolipid is a typical biological surfactant, is produced by microbial fermentation, has easily available raw materials, not only has the general property of the conventional surfactant, but also has the characteristics of no toxicity and 100 percent biodegradability.
The sophorolipid produced by taking glucose and fatty acid as raw materials is used for the biological repair research of the soil polluted by the lubricating oil, and the sophorolipid has good emulsification effect on various hydrocarbons such as toluene, n-heptane and the like and the lubricating oil; when the solubilizing performance of various surfactant solutions on kerosene is researched through kerosene extraction experiments, the sophorolipid has the best effect on extracting hydrocarbon compounds in polluted soil. However, in practical application, since the sophorolipid and the compound thereof with a certain viscosity are sprayed, the problem of viscosity of sophorolipid and the compound thereof in the spraying process needs to be solved, and the defects that the sophorolipid and the compound thereof are not enough in kinetic energy of a pressure device are overcome.
Disclosure of Invention
In order to solve the problems, the invention aims to solve the defects of viscosity of the sophorolipid compound in the spraying process and insufficient kinetic energy provided by a pressure device to the sophorolipid compound in the spraying process.
In order to achieve the purpose, the technical scheme of the invention is as follows: the utility model provides a sophorolipid complex sprinkler for improving soil includes by the storage layer that connects gradually from top to bottom, layer and base rotate, the junction on storage layer and rotation layer has a plurality of skewed teeth, the one end fixed connection of skewed tooth rotates the layer, the other end of skewed tooth extends to the storage layer, the coincidence department of skewed tooth and storage layer has rotatory notch, and the top of adjacent skewed tooth is equipped with the outflow passageway, outflow passageway intercommunication storage layer, the below of adjacent skewed tooth is equipped with flow channel, flow channel is located and rotates the in situ, flow channel is equipped with feed inlet and discharge gate along the flow direction of sophorolipid complex, the feed inlet is close to the storage layer, the discharge gate is located the rotation layer surface, and every discharge gate is apart from the height difference of base, arbitrary discharge gate all is equipped with pneumatic spout.
After the scheme is adopted, the following beneficial effects are realized: 1. compared with the prior art of water flow spraying after pipeline connection, the spraying substance in the technical scheme is the sophorolipid compound due to the fact that the spraying substance is special, and for the spraying of the sophorolipid compound, the problem of viscosity of the sophorolipid compound in the spraying process needs to be solved, therefore, in the technical scheme, the viscosity is relieved by cutting the sophorolipid compound flowing from a storage layer to an outflow channel through the skewed teeth in a rotation mode of a rotating layer, so that the phenomenon that the clustered viscous sophorolipid compound blocks the channel is avoided, meanwhile, the volume of the sophorolipid compound is reduced, the single-flow sophorolipid compound is conveniently sprayed out, and the spraying speed and distance of the sophorolipid compound are conveniently kept.
2. For the prior art that adopts the sophorolipid complex to cut apart, utilize the rotation layer to carry out the rotation among this technical scheme to drive and rotate the skewed tooth rotation of layer body coupling, form quick air current in rotatory notch when the skewed tooth is rotatory, because the formation of quick air current, thereby make and form the negative pressure space in the rotatory notch, with the sophorolipid complex suction of storage layer, thereby solve the viscidity of sophorolipid complex, flow the sophorolipid complex, be convenient for combine the effect of gravity to transport the sophorolipid complex.
3. Compared with the prior art adopting the sophorolipid compound to be sucked out, the sophorolipid compound cannot flow like water flow or other Newtonian fluids due to the characteristics of the sophorolipid compound in the technical scheme, so that if the sophorolipid compound is continuously sprayed, soil sophorolipid compound close to a spraying device is excessive, soil sophorolipid compound far away from the spraying device is less, and the aim of soil improvement cannot be fulfilled.
4. Compared with the prior art of conglobation spraying, the technical scheme has no continuous spraying pressure, so that the sophorolipid compound is required to fall on different falling points to realize the coverage of a spraying range, at the moment, the conglobation sophorolipid compound performs parabolic motion due to different heights of the discharge ports, the linear distance of the sophorolipid compound is changed by utilizing the different heights of the discharge ports to realize different falling points, and the rotating part rotates to perform range coverage on the sophorolipid compound so as to solve the problem that the coverage can not be continuously sprayed linearly.
Furthermore, the rotating layer comprises a flowing layer, a pneumatic layer and a rotating layer from inside to outside, the flowing layer is communicated with the flowing channel, the pneumatic layer is connected with the pneumatic nozzle, the spraying direction of the pneumatic nozzle faces the discharge hole, the lower side of the rotating layer is connected with a rotation motor, and the rotation motor is placed on the surface of the base.
Further, a pneumatic distribution pump and a single chip microcomputer are arranged in the base, the pneumatic distribution pump, the single chip microcomputer and a pneumatic nozzle are connected to form a pneumatic system, and the single chip microcomputer and a rotation motor are connected to form a rotating speed system;
the pneumatic system and the rotating speed system both comprise converters for converting communication signals into electric signals, the singlechip in the pneumatic system is used for controlling the air pressure distributed to different pneumatic nozzles by the pneumatic distribution pump and the opening and closing time of the pneumatic nozzles, and the singlechip in the rotating speed system is used for controlling the rotating speed of the rotating motor.
Has the advantages that: compared with the prior art of changing different height sprays, thereby utilize among this technical scheme to utilize pneumatic system to adjust pneumatic spout spun initial kinetic energy, change thick form sophorolipid complex spun initial velocity in this technical scheme to carry out the fine setting of spraying the drop point, adjust the rotational speed of rotation motor in addition in order to improve the splash effect of sophorolipid complex spun, control the scope that splashes.
Further, the pneumatic system has the atmospheric pressure inductor of a plurality of response pneumatic spouts, and the rotational speed inductor that the rotational speed system has a plurality of response rotation motor rotational speeds, the singlechip is connected with the signal transmitter who is used for sending atmospheric pressure inductor data and rotational speed inductor data, and the singlechip still is connected with the signal receiver of received signal instruction, and signal receiver is connected with bluetooth module.
Has the advantages that: the remote control of the signal and the remote control of the spraying signal data are convenient.
Further, the width of the helical teeth gradually increases from the outflow channel to the flow channel, and the helical teeth form an acute angle towards the direction of the outflow channel.
Has the advantages that: in the technical scheme, the acute angle of the helical teeth is utilized to facilitate cutting, and the helical teeth are gradually widened to realize that the sophorolipid compound flows along the helical teeth and the sophorolipid compound is collected to the flow channel at a fixed point.
Further, a storage groove is formed in the vertical center of the storage layer and communicated with the outflow channel.
Has the beneficial effects that: realizing the shunting of the sophorolipid compound.
Further, the sophorolipid compound for improving soil comprises the following components: sophorolipid, NaCl, ethylenediamine tetraacetic acid, diethyl aminoethyl hexanoate, konjac glucomannan and water.
Further, the proportion of the sophorolipid, NaCl, ethylene diamine tetraacetic acid, diethyl aminoethyl hexanoate, konjac glucomannan and water is 4:1:2:2:2: 6.
Has the beneficial effects that: firstly, the toxicity of petroleum polluted soil repaired by the sophorolipid compound is effectively controlled; secondly, the sophorolipid compound is processed into a soil repairing agent, so that the soil slow release in the area can be repaired conveniently; thirdly, the sophorolipid compound has low flow rate, and the possibility that the pollution toxicity in the soil expands the influence range along with the flow is reduced; finally, the chelation of the nutrients by the EDTA enhances the absorption capacity of plants and promotes the metabolism of soil plants.
Drawings
FIG. 1 is a schematic diagram of a first embodiment of the present invention;
FIG. 2 is a view showing a connection relationship between a storage layer and a rotation layer in FIG. 1;
FIG. 3 is a half-sectional view of the storage layer and the rotation layer of FIG. 1;
FIG. 4 shows the germination rates of Lolium perenne 7d under different soils in example two.
Detailed Description
The following is further detailed by way of specific embodiments:
reference numerals in the drawings of the specification include: the device comprises a storage layer 1, a rotating layer 2, a base 3, helical teeth 4, a rotating notch 5, an outflow channel 6, a flow channel 7, a discharge hole 8, a pneumatic nozzle 9 and a self-rotating motor 10.
Example one
The embodiment is basically as shown in the attached figure 1: the utility model provides a sophorolipid compound sprinkler for improving soil includes storage layer 1, rotation layer 2 and base 3 by connecting gradually from top to bottom, and the junction of storage layer 1 and rotation layer 2 has a plurality of skewed teeth 4, and the one end fixed connection of skewed tooth 4 rotates layer 2, and the other end of skewed tooth 4 extends to storage layer 1.
Referring to fig. 2 and fig. 3, a rotary notch 5 is formed in a position where the helical teeth 4 coincide with the storage layer 1, an outflow channel 6 is arranged above the adjacent helical teeth 4, the outflow channel 6 is communicated with the storage layer 1, a flow channel 7 is arranged below the adjacent helical teeth 4, the flow channel 7 is located in the rotating layer 2, a feed inlet and a discharge outlet 8 are arranged on the flow channel 7 along the flow direction of the sophorolipid complex, the feed inlet is close to the storage layer 1, the discharge outlets 8 are located on the surface of the rotating layer 2, the height of each discharge outlet 8 from the base 3 is different, a pneumatic nozzle 9 is arranged at any discharge outlet 8, the width of the helical teeth 4 is gradually widened along the flow channel 6 to the flow channel 7, an acute angle is formed in the direction of the helical teeth 4 towards the outflow channel 6, a storage groove is formed in the vertical center of the storage layer 1, and the storage groove is communicated with the outflow channel 6.
Rotate layer 2 from interior to exterior and include flow layer, pneumatic layer and rotation layer 2, flow layer intercommunication in flow channel 7, pneumatic layer connects in pneumatic spout 9, and the blowout direction of pneumatic spout 9 is towards discharge gate 8, and the below of rotating layer 2 is connected with rotation motor 10, and rotation motor 10 places in base 3 surface, and wherein rotate layer 2 and storage layer 1 and separately rotate, mainly utilizes the clearance fit of skewed tooth 4 and rotatory notch 5.
A pneumatic distribution pump and a single chip microcomputer are arranged in the base 3, the pneumatic distribution pump, the single chip microcomputer and a pneumatic nozzle 9 are connected to form a pneumatic system, and the single chip microcomputer and a rotation motor 10 are connected to form a rotating speed system;
the pneumatic system and the rotating speed system both comprise converters for converting communication signals into electric signals, a singlechip in the pneumatic system is used for controlling the air pressure distributed to different pneumatic nozzles 9 by the pneumatic distribution pump and the opening and closing time of the pneumatic nozzles 9, and the singlechip in the rotating speed system is used for controlling the rotating speed of the rotating motor 10.
The pneumatic system is provided with a plurality of air pressure sensors for sensing the pneumatic nozzles 9, the rotating speed system is provided with a plurality of rotating speed sensors for sensing the rotating speed of the rotating motor 10, the single chip microcomputer is connected with a signal transmitter for transmitting data of the air pressure sensors and data of the rotating speed sensors, the single chip microcomputer is further connected with a signal receiver for receiving signal instructions, and the signal receiver is connected with a Bluetooth module.
The specific implementation process is as follows:
in the process of spraying the sophorolipid compound, the sprayed substance is the sophorolipid compound in the technical scheme, and for the spraying of the sophorolipid compound, the problem of the viscosity of the glycolipid compound in the spraying process needs to be solved, and the problem that the kinetic energy provided by a pressure device for the sophorolipid compound substance in the spraying process is insufficient is solved, so that the viscosity is relieved in the technical scheme that the sophorolipid compound flowing from the storage layer 1 to the outflow channel 6 is cut by the aid of the self-rotation mode of the rotating layer 2 through the inclined teeth 4, the acute angle of the inclined teeth 4 is used for facilitating the cutting, and the inclined teeth 4 are gradually widened, so that the sophorolipid compound flows along the inclined teeth 4, and the sophorolipid compound is collected to the flow channel 7 at fixed points. Thereby avoiding the blocking of the channel by the agglomerated viscous sophorolipid compound, and simultaneously reducing the volume of the sophorolipid compound, so as to facilitate the ejection of the single-flow sophorolipid compound and maintain the ejection speed and distance of the sophorolipid compound.
Rotate layer 2 and carry out the rotation to the skewed tooth 4 that drives and rotate layer 2 body coupling rotates, forms quick air current in rotatory notch 5 when skewed tooth 4 is rotatory, because the formation of quick air current, thereby form the negative pressure space in making rotatory notch 5, with the suction of the sophorolipid complex of storage layer 1, thereby solve the consistency of sophorolipid complex, flow the sophorolipid complex, be convenient for combine the effect of gravity to transport the sophorolipid complex. Therefore, the device cuts the sophorolipid compound, and utilizes the pneumatic nozzle 9 to spray the sophorolipid compound small groups out to fall to a designated place so as to improve the soil.
Compared with the prior art of conglobation ejection, the technical scheme is free of continuous ejection pressure, so that the sophorolipid compound is required to fall on different falling points to realize the coverage of the spraying range, at the moment, the conglobation sophorolipid compound performs parabolic motion due to different heights of the discharge ports 8, the linear distance of the sophorolipid compound is changed by utilizing the different heights of the discharge ports 8, the different falling points are realized, and in addition, the rotating part rotates to perform the coverage of the sophorolipid compound in a range manner, so that the problem that the coverage can not be continuously sprayed in a linear manner is solved.
Example two
The difference between the technical scheme and the above embodiment is that the sophorolipid compound for improving soil disclosed in the embodiment comprises the following components: sophorolipid, NaCl, ethylenediamine tetraacetic acid, diethyl aminoethyl hexanoate, konjac glucomannan and water, wherein the proportion of the sophorolipid, the NaCl, the ethylenediamine tetraacetic acid, the diethyl aminoethyl hexanoate, the konjac glucomannan and the water is 4:1:2:2:2: 6.
(1) Screening out a better oil-containing soil cleaning process: through a single-factor experiment, the scheme for cleaning the oil-containing soil is determined under the formula: the liquid-solid ratio is 2: 1, the temperature is 35 ℃, the stirring speed is 600r/min, the cleaning time is 20min, and the highest soil crude oil removal rate can reach 92.31 percent under the condition.
(2) The scale amplification experiment and the repeated use experiment show that the removal rate of the crude oil can be kept above 90% by amplifying the oil-containing soil to 300 times.
(3) The oil sample density and ash content of the recovered oil sample treated by the sophorolipid compound are slightly increased compared with those of the original oil sample, the content of saturated components is increased, the contents of aromatic components, colloid and asphaltene are reduced, the viscosity is reduced, and the recovered crude oil has a certain utilization value.
(4) Compared with the original unpolluted soil, the soil after the sophorolipid compound restoration has slightly increased organic matter content, pH reduced from 8.53 to 7.46, full salt content reduced from 1.51 to 0.24%, and soil grade reduced from severe saline-alkali soil to mild saline-alkali soil.
Referring to fig. 4, the residual toxicity of the restored soil is checked through a seed germination and growth experiment, and the restored soil is found to promote the germination and growth of ryegrass and alfalfa, and the results show that: the toxicity of the soil after the sophorolipid compound is repaired is effectively controlled.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
The foregoing is merely an example of the present invention, and common general knowledge in the field of known specific structures and characteristics is not described herein in any greater extent than that known in the art at the filing date or prior to the priority date of the application, so that those skilled in the art can now appreciate that all of the above-described techniques in this field and have the ability to apply routine experimentation before this date can be combined with one or more of the present teachings to complete and implement the present invention, and that certain typical known structures or known methods do not pose any impediments to the implementation of the present invention by those skilled in the art. It should be noted that, for those skilled in the art, without departing from the structure of the present invention, several changes and modifications can be made, which should also be regarded as the protection scope of the present invention, and these will not affect the effect of the implementation of the present invention and the practicability of the patent. The scope of the claims of the present application shall be determined by the contents of the claims, and the description of the embodiments and the like in the specification shall be used to explain the contents of the claims.

Claims (5)

1. The utility model provides a sophorolipid compound sprinkler for improving soil which characterized in that: include by the storage layer that connects gradually from top to bottom, rotate layer and base, the junction on storage layer and rotation layer has a plurality of skewed teeth, the one end fixed connection of skewed tooth is in rotating the layer, the other end of skewed tooth extends to the storage layer, the coincidence department of skewed tooth and storage layer has rotatory notch, and the top of adjacent skewed tooth is equipped with the outflow passageway, outflow passageway intercommunication storage layer, the below of adjacent skewed tooth is equipped with flow channel, flow channel is located and rotates the in situ, flow channel is equipped with feed inlet and discharge gate on the flow direction of sophorolipid complex, the feed inlet is close to the storage layer, the discharge gate is located the rotation layer surface, and every discharge gate is apart from the highly different of base, arbitrary discharge gate all is equipped with pneumatic spout, the width of skewed tooth is widened gradually along outflow passageway to flow channel, and the skewed tooth forms the acute angle towards the direction of outflow passageway.
2. A sophorolipid formulation spray device for soil amendment according to claim 1, wherein: the rotating layer comprises a flowing layer, a pneumatic layer and a rotating layer from inside to outside, the flowing layer is communicated with the flowing channel, the pneumatic layer is connected with the pneumatic nozzle, the spraying direction of the pneumatic nozzle faces the discharge port, the lower part of the rotating layer is connected with a rotation motor, and the rotation motor is placed on the surface of the base.
3. The sophorolipid formulation spray device for soil improvement as claimed in claim 2, wherein: a pneumatic distribution pump and a single chip microcomputer are arranged in the base, the pneumatic distribution pump, the single chip microcomputer and a pneumatic nozzle are connected into a pneumatic system, and the single chip microcomputer and an autorotation motor are connected into a rotating speed system;
the pneumatic system and the rotating speed system both comprise converters for converting communication signals into electric signals, the singlechip in the pneumatic system is used for controlling the air pressure distributed to different pneumatic nozzles by the pneumatic distribution pump and the opening and closing time of the pneumatic nozzles, and the singlechip in the rotating speed system is used for controlling the rotating speed of the rotating motor.
4. A sophorolipid formulation spray device for soil amendment according to claim 3, wherein: the pneumatic system has the atmospheric pressure inductor of a plurality of response pneumatic spouts, and rotational speed system has the rotational speed inductor of a plurality of response rotation motor rotational speeds, the singlechip is connected with the signal transmitter who is used for sending atmospheric pressure inductor data and rotational speed inductor data, and the singlechip still is connected with the signal receiver of received signal instruction, and signal receiver is connected with bluetooth module.
5. A sophorolipid formulation spray device for soil amendment according to claim 4, wherein: the vertical center of the storage layer is provided with a storage groove which is communicated with the outflow channel.
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CN116116891B (en) * 2023-04-10 2023-06-30 河北大美环境修复科技股份有限公司 Soil remediation device with even function of dosing

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