CN114106629A - Invisible colorful film ink capable of being printed on PVB (polyvinyl butyral) and EVA (ethylene vinyl acetate) films - Google Patents

Invisible colorful film ink capable of being printed on PVB (polyvinyl butyral) and EVA (ethylene vinyl acetate) films Download PDF

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Publication number
CN114106629A
CN114106629A CN202111651844.9A CN202111651844A CN114106629A CN 114106629 A CN114106629 A CN 114106629A CN 202111651844 A CN202111651844 A CN 202111651844A CN 114106629 A CN114106629 A CN 114106629A
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parts
pvb
invisible
printed
film ink
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CN202111651844.9A
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CN114106629B (en
Inventor
孙加元
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Jiangsu Youwei Science And Technology Co ltd
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Jiangsu Youwei Science And Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/36Inkjet printing inks based on non-aqueous solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/38Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses invisible multicolor film ink capable of being printed on PVB (polyvinyl butyral) and EVA (ethylene vinyl acetate) films, which comprises the following components in parts by weight: 40-50 parts of diethylene glycol methyl ethyl ether, 5-15 parts of butyrolactone, 5-15 parts of NMP5, 5-15 parts of ethyl acetate, 1-3 parts of vinyl chloride-vinyl acetate, 0.3-2 parts of surfactant and 0.1-0.5 part of nano titanium dioxide. The invention has the advantages that: the production process is simple, the production cost is low, and the process is stable; the laser engraving machine does not need plate making, can be customized individually, has the production efficiency far higher than that of laser engraving, and has high pattern precision and good invisible effect.

Description

Invisible colorful film ink capable of being printed on PVB (polyvinyl butyral) and EVA (ethylene vinyl acetate) films
Technical Field
The invention relates to the technical field of automobile decorative glass, in particular to invisible multicolor film ink capable of being printed on PVB (polyvinyl butyral) and EVA (ethylene vinyl acetate) films.
Background
Nowadays, with the development of economy and the progress of society, the application of glass is wider and wider, the area of architectural glass and automobile glass is larger and larger, the number of people with automobiles is larger and larger, the age group of people gradually tends to be younger, young people also pursue the fashion sense of automobiles while pursuing automobile performance, and accordingly, automobile starry sky roof films come into play.
The star film can present various customized patterns, can well dry and support atmosphere, and is widely applied to various vehicle glass such as automobiles and the like. The ultraviolet excitation starry sky film sold in the market at present generally adopts the processes of silk screen printing, UV transfer printing or laser engraving and filling, the silk screen printing needs plate opening, the printing precision is low, and the screen lines can be generated. The UV transfer printing is high in plate opening cost, high in price sharing cost for small-batch orders and only suitable for large-batch production orders. The laser engraving and filling production efficiency is low, and the equipment investment is high.
Disclosure of Invention
In order to solve the problems, the invention provides the invisible multicolor film ink capable of being printed on PVB and EVA films, which has the advantages of simple production process, low production cost and stable process; the laser engraving machine does not need plate making, can be customized individually, has the production efficiency far higher than that of laser engraving, and has high pattern precision and good invisible effect.
In order to solve the technical problems, the technical scheme provided by the invention is as follows: an invisible multicolor film ink capable of being printed on PVB and EVA films comprises the following components in parts by weight: 40-50 parts of diethylene glycol methyl ethyl ether, 5-15 parts of butyrolactone, 5-15 parts of NMP5, 5-15 parts of ethyl acetate, 1-3 parts of vinyl chloride-vinyl acetate, 0.3-2 parts of surfactant and 0.1-0.5 part of nano titanium dioxide.
Preferably, the specific weight components are as follows: 40 parts of diethylene glycol methyl ethyl ether, 5 parts of butyrolactone, 5 parts of NMP, 5 parts of ethyl acetate, 1 part of vinyl chloride-vinyl acetate copolymer, 0.3 part of surfactant and 0.1 part of nano titanium dioxide.
Preferably, the specific weight components are as follows: 50 parts of diethylene glycol methyl ethyl ether, 15 parts of butyrolactone, NMP10 parts, 15 parts of ethyl acetate, 3 parts of vinyl chloride-vinyl acetate copolymer, 2 parts of surfactant and 0.5 part of nano titanium dioxide.
Preferably, the specific weight components are as follows: 45 parts of diethylene glycol methyl ethyl ether, 10 parts of butyrolactone, 7 parts of NMP, 10 parts of ethyl acetate, 2 parts of vinyl chloride-vinyl acetate copolymer, 1.2 parts of surfactant and 0.3 part of nano titanium dioxide.
The invention also comprises a processing technology of the invisible colorful film ink capable of being printed on PVB and EVA films, which comprises the following processing steps:
the method comprises the following steps: selecting required amount of diethylene glycol methyl ethyl ether, butyrolactone, NMP, ethyl acetate, vinyl chloride-vinyl acetate copolymer, surfactant and nano titanium dioxide;
step two: pouring the raw materials in the step one into a stirring container for stirring until the raw materials are uniformly stirred;
step three: and D, filtering the uniformly stirred mixed liquid in the step two through a filter membrane to obtain filtered liquid, namely the required ink.
Preferably, in the second step, the stirring speed is 500rpm, and the stirring time is 60 min.
Preferably, in the third step, the pore size of the filter membrane is 0.22 μm.
Compared with the prior art, the invention has the advantages that: when the invention is used, the production process is simple, the production cost is low, and the process is stable. The ink is printed on the surface of a PVB adhesive film, an alcohol solvent in the ink can swell the surface of the PVB adhesive film, and nano ultraviolet developing powder in the ink permeates into the surface layer of the PVB film and is fused with the PVB film into a whole. Because the printing output is realized through a computer, plate making is not needed, personalized customization can be realized, and the production efficiency is far higher than that of laser engraving. And the pattern precision is high, and the stealthy effect is good.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1
An invisible multicolor film ink capable of being printed on PVB and EVA films comprises the following specific components in parts by weight: 40 parts of diethylene glycol methyl ethyl ether, 5 parts of butyrolactone, 5 parts of NMP, 5 parts of ethyl acetate, 1 part of vinyl chloride-vinyl acetate copolymer, 0.3 part of surfactant and 0.1 part of nano titanium dioxide.
Example 2
An invisible multicolor film ink capable of being printed on PVB and EVA films comprises the following specific components in parts by weight: 50 parts of diethylene glycol methyl ethyl ether, 15 parts of butyrolactone, NMP10 parts, 15 parts of ethyl acetate, 3 parts of vinyl chloride-vinyl acetate copolymer, 2 parts of surfactant and 0.5 part of nano titanium dioxide.
Example 3
An invisible multicolor film ink capable of being printed on PVB and EVA films comprises the following specific components in parts by weight: 45 parts of diethylene glycol methyl ethyl ether, 10 parts of butyrolactone, 7 parts of NMP, 10 parts of ethyl acetate, 2 parts of vinyl chloride-vinyl acetate copolymer, 1.2 parts of surfactant and 0.3 part of nano titanium dioxide.
The best results of example 3 are evident from the observation of the printing effect of inks obtained in example 1, example 2 and example 3 printed on the same PVB or EVA film.
The invention also comprises a processing technology of the invisible colorful film ink capable of being printed on PVB and EVA films, which comprises the following processing steps:
the method comprises the following steps: selecting required amount of diethylene glycol methyl ethyl ether, butyrolactone, NMP, ethyl acetate, vinyl chloride-vinyl acetate copolymer, surfactant and nano titanium dioxide;
step two: pouring the raw materials in the step one into a stirring container for stirring, wherein the stirring speed is 500rpm, and the stirring time is 60min until the raw materials are uniformly stirred;
step three: and D, filtering the uniformly stirred mixed solution in the step two through a filter membrane with the aperture of 0.22 mu m to obtain filtered liquid, namely the required ink.
The present invention and its embodiments have been described above, but the description is not limited thereto, and the embodiments shown in the examples are only some embodiments of the present invention, and the practical manner is not limited thereto. In summary, those skilled in the art should appreciate that embodiments and examples similar to those of the present invention can be devised without departing from the spirit and scope of the invention.

Claims (7)

1. An invisible multicolor film ink capable of being printed on PVB and EVA films is characterized by comprising the following components in parts by weight: 40-50 parts of diethylene glycol methyl ethyl ether, 5-15 parts of butyrolactone, 5-15 parts of NMP5, 5-15 parts of ethyl acetate, 1-3 parts of vinyl chloride-vinyl acetate, 0.3-2 parts of surfactant and 0.1-0.5 part of nano titanium dioxide.
2. The invisible magic color film ink printable on PVB and EVA films according to claim 1, wherein: comprises the following specific components in parts by weight: 40 parts of diethylene glycol methyl ethyl ether, 5 parts of butyrolactone, 5 parts of NMP, 5 parts of ethyl acetate, 1 part of vinyl chloride-vinyl acetate copolymer, 0.3 part of surfactant and 0.1 part of nano titanium dioxide.
3. The invisible magic color film ink printable on PVB and EVA films according to claim 1, wherein: comprises the following specific components in parts by weight: 50 parts of diethylene glycol methyl ethyl ether, 15 parts of butyrolactone, NMP10 parts, 15 parts of ethyl acetate, 3 parts of vinyl chloride-vinyl acetate copolymer, 2 parts of surfactant and 0.5 part of nano titanium dioxide.
4. The invisible magic color film ink printable on PVB and EVA films according to claim 1, wherein: comprises the following specific components in parts by weight: 45 parts of diethylene glycol methyl ethyl ether, 10 parts of butyrolactone, 7 parts of NMP, 10 parts of ethyl acetate, 2 parts of vinyl chloride-vinyl acetate copolymer, 1.2 parts of surfactant and 0.3 part of nano titanium dioxide.
5. A processing technology of invisible colorful film ink capable of being printed on PVB and EVA films is characterized in that: the method comprises the following processing steps:
the method comprises the following steps: selecting required amount of diethylene glycol methyl ethyl ether, butyrolactone, NMP, ethyl acetate, vinyl chloride-vinyl acetate copolymer, surfactant and nano titanium dioxide;
step two: pouring the raw materials in the step one into a stirring container for stirring until the raw materials are uniformly stirred;
step three: and D, filtering the uniformly stirred mixed liquid in the step two through a filter membrane to obtain filtered liquid, namely the required ink.
6. The process of claim 5, wherein the invisible iridescent film ink capable of being printed on PVB and EVA films comprises: in the second step, the stirring speed is 500rpm, and the stirring time is 60 min.
7. The process of claim 5, wherein the invisible iridescent film ink capable of being printed on PVB and EVA films comprises: in the third step, the aperture of the filter membrane is 0.22 μm.
CN202111651844.9A 2021-12-30 2021-12-30 Invisible multicolor film ink capable of being printed on PVB (polyvinyl butyral) film and EVA (ethylene vinyl acetate) film Active CN114106629B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102702847A (en) * 2012-06-04 2012-10-03 福州三龙喷码科技有限公司 White ink for large-character inkjet printing machine
CN111070822A (en) * 2018-10-18 2020-04-28 比亚迪股份有限公司 Laminated glass, preparation method thereof, electronic equipment shell and electronic equipment
CN111607286A (en) * 2020-05-28 2020-09-01 珠海天威新材料股份有限公司 Environment-friendly pyrograph ink, PET film heat transfer printing method and application thereof
CN113337157A (en) * 2021-06-29 2021-09-03 高宝新材料(珠海)有限公司 Reflective film weak solvent inkjet ink and preparation method and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102702847A (en) * 2012-06-04 2012-10-03 福州三龙喷码科技有限公司 White ink for large-character inkjet printing machine
CN111070822A (en) * 2018-10-18 2020-04-28 比亚迪股份有限公司 Laminated glass, preparation method thereof, electronic equipment shell and electronic equipment
CN111607286A (en) * 2020-05-28 2020-09-01 珠海天威新材料股份有限公司 Environment-friendly pyrograph ink, PET film heat transfer printing method and application thereof
CN113337157A (en) * 2021-06-29 2021-09-03 高宝新材料(珠海)有限公司 Reflective film weak solvent inkjet ink and preparation method and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张玉龙: "《纳米复合材料手册》", 中国石化出版 *

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