CN114079111B - Large vertical energy storage battery and energy storage container - Google Patents
Large vertical energy storage battery and energy storage container Download PDFInfo
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- CN114079111B CN114079111B CN202010802191.9A CN202010802191A CN114079111B CN 114079111 B CN114079111 B CN 114079111B CN 202010802191 A CN202010802191 A CN 202010802191A CN 114079111 B CN114079111 B CN 114079111B
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- 238000004146 energy storage Methods 0.000 title claims abstract description 90
- 238000002347 injection Methods 0.000 claims abstract description 113
- 239000007924 injection Substances 0.000 claims abstract description 113
- 238000007789 sealing Methods 0.000 claims abstract description 56
- 239000003792 electrolyte Substances 0.000 claims abstract description 29
- 210000004027 cell Anatomy 0.000 claims description 156
- 239000012530 fluid Substances 0.000 claims description 35
- 210000000352 storage cell Anatomy 0.000 claims description 12
- 230000008093 supporting effect Effects 0.000 claims description 7
- 239000011148 porous material Substances 0.000 claims description 5
- 238000005452 bending Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 13
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- 238000005260 corrosion Methods 0.000 abstract description 9
- 238000007599 discharging Methods 0.000 abstract description 5
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
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- 238000004891 communication Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 9
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- 238000010438 heat treatment Methods 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000000565 sealant Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
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- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
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- 239000000463 material Substances 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
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- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- JRBRVDCKNXZZGH-UHFFFAOYSA-N alumane;copper Chemical compound [AlH3].[Cu] JRBRVDCKNXZZGH-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
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- 238000006056 electrooxidation reaction Methods 0.000 description 1
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- 230000017525 heat dissipation Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
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- 239000002905 metal composite material Substances 0.000 description 1
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- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
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- 239000010935 stainless steel Substances 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention provides a large vertical energy storage battery which is provided with a battery cell unit bracket and a plurality of battery cell units. Each cell unit can be inserted into the insertion port of the cell unit bracket so as to support the weight of the cell unit by using the cell unit bracket. Through the sealing parts at the four corners of the cell unit bracket are in sealing connection with the inner wall of the battery shell, a side injection cavity and a side discharge cavity for injecting liquid and discharging liquid and a front side cavity and a rear side cavity for accommodating the lugs and the bus plate are formed in the large vertical energy storage battery, so that corrosion caused by the fact that the bus plate is immersed in electrolyte during large current bus or electrolyte decomposition caused by a large current thermal effect can be prevented, and electric connection failure caused by interface oxidation corrosion can be avoided especially for a mechanically connected bus structure. The large vertical energy storage battery can provide high energy density, is safe to operate, is easy to integrate, maintain and regenerate, and has long service life.
Description
Technical Field
The invention relates to the field of batteries, in particular to a large vertical energy storage battery.
Background
The lithium ion battery is a novel high-energy battery using lithium intercalation compounds as anode and cathode materials, and has a series of advantages of high specific energy, high voltage, small self-discharge, good cycle performance, long service life and the like compared with lead-acid batteries and nickel-hydrogen batteries, and is more and more focused by people and widely applied to the fields of electric vehicles, energy storage and the like. In the energy storage field, a battery module is generally formed by connecting single batteries in series and parallel, a battery cluster is formed by connecting the battery modules in series and parallel, and a battery system is formed by connecting the battery clusters in series and parallel. If the single battery is small in capacity, multiple battery capacity grades are needed to be provided in parallel, and a plurality of battery pack frames and a plurality of groups of lugs are provided, so that the whole mechanical parts are complicated in connection and assembly, the weight is increased, the calculation amount of a battery management system is complex, and the battery management is difficult, therefore, the battery cells with large capacity are needed for energy storage.
The single battery cell with large capacity can be realized by two ways, namely, the area of a single pole piece is increased, the problems of poor liquid injection uniformity, low electrolyte permeation speed and the like exist at the moment, the requirements of the increased electrode area on an electrode, a diaphragm and the like are higher, and the safety problem is easy to occur; the other is to increase the number of pole piece units, and at the moment, the problems of poor liquid injection uniformity, low electrolyte permeation speed and the like are also caused, and the problems of high current drainage and the like are also caused. Therefore, in order to realize a high-capacity battery cell, a new battery structure form is required and the safety problem of the high-capacity battery cell is solved.
Disclosure of Invention
Aiming at the problems, the invention provides a large vertical energy storage battery, wherein a battery core unit bracket and a plurality of battery core units are arranged in the large vertical energy storage battery. Each cell unit comprises a plurality of horizontally laminated positive electrode plates and negative electrode plates, and each cell unit can be inserted into an insertion port of a cell unit bracket so as to support the weight of the cell unit by using the cell unit bracket, so that the cell unit positioned on the lower side cannot cause performance degradation due to excessive pressure from the cell unit above. Through the sealing parts at the four corners of the cell unit bracket are in sealing connection with the inner wall of the battery shell, a side injection cavity, a side discharge cavity, a front side cavity and a rear side cavity, wherein the side injection cavity and the side discharge cavity are used for injecting liquid and discharging liquid, the front side cavity and the rear side cavity are used for accommodating the electrode lugs and the bus plate, and the front side cavity and the rear side cavity are respectively sealed relative to the side cavity, so that liquid in the side cavity can be prevented from entering the front side cavity and the rear side cavity, corrosion of the bus plate is prevented from being caused by soaking the bus plate in electrolyte when large current is converged, or electrolyte decomposition caused by a large current thermal effect is prevented, and electric connection failure caused by interface oxidation corrosion can be avoided especially for a mechanically connected bus structure. In addition, due to the arrangement of the side discharging cavity, the side cavity is more beneficial to vacuumizing so as to promote the discharging of the fluid in the battery cell and the side cavity. The large vertical energy storage battery can provide high energy density, is safe to operate, is easy to integrate, maintain and regenerate, and has long service life.
The technical scheme provided by the invention is as follows:
according to the present invention there is provided a large vertical energy storage battery comprising: the battery cell comprises a plurality of battery cell units, each battery cell unit is provided with a plurality of positive plates and negative plates which are alternately stacked, in each battery cell unit, positive lugs of the plurality of positive plates are connected in parallel to form a positive lug group, and negative lugs of the plurality of negative plates are connected in parallel to form a negative lug group; the battery cell unit support comprises a plurality of plug-in parts which are arranged along the vertical direction, the bottom surface of each plug-in part is provided with an edge supporting frame for supporting the battery cell unit, one side surface of each plug-in part is provided with an injection opening for fluid injection, the other side surface of each plug-in part is provided with a discharge opening for fluid discharge, and four corners of the battery cell unit support are provided with sealing parts which extend along the vertical direction; a shell for accommodating the cell unit bracket inserted with a plurality of cell units, wherein the sealing part of the cell unit bracket is in sealing connection with the inner wall of the shell, so that a front cavity, a rear cavity, a side injection cavity and a side discharge cavity are respectively formed at the front side, the rear side and the two sides of the cell unit bracket, the side injection cavity and the side discharge cavity are respectively in fluid sealing with the front side cavity and the side injection cavity and the side discharge cavity are respectively in fluid sealing with the rear side cavity; an injection port through which fluid injected into the side injection cavity enters; a discharge port through which fluid in the side discharge chamber is discharged; the positive pole post and negative pole post, positive pole post and all positive pole ear group electricity are connected, and the negative pole post is connected with all negative pole ear group electricity.
The energy storage battery is a vertical large battery, the height-width ratio of the large vertical energy storage battery is 2:1-10:1, the height of the large vertical energy storage battery is 200-3000 mm, and the width of the large vertical energy storage battery is 100-1000 mm. The large vertical energy storage battery is provided with an electric core, an electric core unit bracket, a shell, an injection port, a discharge port, a positive pole column and a negative pole column. The battery cell unit support is of a vertical multi-layer structure, each layer is provided with an inserting part, and four corners of the battery cell unit support are provided with sealing parts extending along the vertical direction. The cell unit bracket can be integrally formed; or, a plurality of plug-in parts of the battery cell unit bracket can be connected and fixed along the vertical direction. When the battery cell unit bracket is assembled by a plurality of plug-in parts, the plug-in parts can be connected and fixed in a plug-in, bonding, welding, clamping and other modes. The battery cell is composed of a plurality of battery cell units, each battery cell unit comprises a plurality of cross-laminated positive plates and negative plates, the positive plates and the negative plates are horizontally placed, positive lugs of the positive plates are connected in parallel to form a positive lug group, and negative lugs of the negative plates are connected in parallel to form a negative lug group. The positive tab set and the negative tab set may be located on the same side of the cell unit, or the positive tab set and the negative tab set may be located on opposite sides of the cell unit. The number of the battery cell units corresponds to the number of the plug-in connection parts of the battery cell unit bracket. After each cell unit is placed in each plug-in portion of the cell unit holder, the plurality of positive tab groups are electrically connected by, for example, a positive electrode bus plate and the plurality of negative tab groups are electrically connected by, for example, a negative electrode bus plate, and then the cell unit holder is placed in the housing so that the sealing portion of the cell unit holder is hermetically connected with the inner wall of the housing to form a front side cavity, a rear side cavity, a side injection cavity and a side discharge cavity on the front side, the rear side and both sides of the cell unit holder, respectively, the positive electrode bus plate is electrically connected with the positive electrode post and the negative electrode bus plate is electrically connected with the negative electrode post, the injection port approximately corresponds to the position of the side injection cavity, and the discharge port approximately corresponds to the position of the side discharge cavity. The injection port, the discharge port, the positive electrode post, and the negative electrode post may be located at the same time on the top surface of the housing, at the same time on the bottom surface of the housing, or at the top surface and the bottom surface of the housing, respectively. When one or more of the injection port, the discharge port, the positive post and the negative post are located on the bottom surface of the housing, a battery holder may be provided under the large vertical energy storage battery so that the battery may be maintained from below the battery.
The sealing parts of the cell holders may be in the form of ribs, which may be sealingly connected to the inner wall of the housing, for example by means of adhesive bonding. In addition, a clamping structure or a plugging structure and the like can be arranged on the inner wall of the shell, and the sealing part of the battery cell unit bracket is provided with a corresponding clamping structure or plugging structure, so that the sealing part of the battery cell unit bracket is in sealing connection with the inner wall of the shell. Through the sealing connection between the sealing part of the electric core unit support and the inner wall of the shell and through the structure settings such as the baffle, the end face sealing plate or the drawer part of the electric core unit support, the fluid seal is arranged between the front side cavity and other cavities, namely the rear side cavity, the side injection cavity and the side discharge cavity, the fluid seal is arranged between the rear side cavity and other cavities, namely the front side cavity, the side injection cavity and the side discharge cavity, and the side injection cavity is only in fluid communication with the inside of the plug-in part and the side discharge cavity. In this way, the fluid such as electrolyte is injected into the cavity, the plug part (the cell unit) and discharged from the cavity only through the side surfaces, and the fluid cannot enter the front cavity and the rear cavity, so that components such as easy corrosion and easy heating can be arranged in the front cavity and the rear cavity without electrolyte. In addition, in the process of liquid exchange, the liquid or vacuum can be pumped out of the side discharging cavity in a targeted manner, so that the liquid can be discharged more conveniently.
The plug-in portion of the cell unit holder may be a frame structure, one side of the frame structure forming an injection opening through the frame strip and the other side of the frame structure forming a discharge opening through the frame strip, the injection opening being in fluid communication with the side injection cavity and the discharge opening being in fluid communication with the side discharge cavity, the frame strip of the bottom surface of the frame structure forming an edge support frame for supporting the cell unit. The shelf can be arranged on the edge supporting frame, the weight of the battery cell unit can be better borne by the shelf, the shelf can be arranged in parallel with the battery cell unit, and preferably, the shelf is made of porous materials, so that electrolyte injected from above smoothly flows downwards, and the whole infiltration of the whole battery cell is facilitated. The frame strips and the shelves can be made of light materials with structural strength such as polyethylene, polypropylene, polytetrafluoroethylene, ceramics, aluminum, alloy aluminum and the like. The frame strip can also adopt aluminum-plastic composite material, and the conductive aluminum part can be connected with the battery cell tab and/or the bus part at the same time, so that the bus effect can be achieved at the same time. In addition, a channel can be arranged in the frame strip, the channel is in fluid communication with the outside, and the cooling fluid or the heating fluid is injected into the channel to play a role in heat dissipation or heating on the battery cell. The side, front and back of the plug-in part can be provided with baffle plates, the baffle plates can be directly and integrally formed with the plug-in part, or the baffle plates can be fixedly connected with the frame strips of the plug-in part. In the case of a baffle plate provided on the side of the plug-in portion, an injection opening may be provided on one side baffle plate and a discharge opening may be provided on the other side baffle plate, the injection opening being in fluid communication with the side injection cavity and the discharge opening being in fluid communication with the side discharge cavity. Under the condition that the baffle is arranged in front of or behind the plug-in part, a groove for extending out of the lug group can be arranged on the baffle. In the case where no baffle is provided in front of or behind the plug-in portion, a separate end face seal plate may be provided, on which a groove is provided. After the battery cell unit is placed in the plug-in part, the positive electrode tab group or the negative electrode tab group of the battery cell unit can extend out of the groove, gaps between the positive electrode tab group or the negative electrode tab group of the battery cell unit and the groove can be sealed through sealant, sealing strips and the like, and then the end face sealing plate is in sealing connection with the front surface and/or the rear surface of the battery cell unit bracket. The end face seal plate may be a cover plate covering the entire front or rear face of the cell holder, or the end face seal plate may be a cover plate covering only one or several plug-in portions. The end face sealing plate can be connected to the cell unit bracket in a plugging, bonding, welding, clamping and other modes, and a sealing strip or a sealing ring and the like can be arranged between the end face sealing plate and the cell unit bracket.
The battery cell unit can be directly inserted into the plug-in part from the top or the front side (other side surfaces can also be adopted) of the plug-in part, and is supported by an edge supporting frame or a shelf on the bottom surface of the plug-in part. In addition, the cell holder may be further provided with a drawer portion comprising a front wall, a rear wall, two side walls and a bottom, substantially box-shaped without a top cover, the front wall and/or the rear wall of the drawer portion may be provided with a slot, one side wall of the drawer portion may be provided with a side wall injection opening and the other side wall may be provided with a side wall discharge opening, the side wall injection opening being in fluid communication with the side injection cavity and the side wall discharge opening being in fluid communication with the side discharge cavity, the bottom of the drawer portion preferably being made of a porous material. The battery cell unit can be placed in the drawer part first, the positive electrode lug group or the negative electrode lug group of the battery cell unit can extend out of the slot, and gaps between the positive electrode lug group or the negative electrode lug group of the battery cell unit and the slot can be sealed through sealant, sealing strips and the like. Under the condition of the drawer part, the independent end face sealing plate can be avoided, the fixing and sealing structure of the end face sealing plate is omitted, and the integral structure of the battery cell unit bracket is greatly simplified; in addition, the drawer part is arranged to facilitate the taking out and putting in of the battery cell unit, so that the maintenance and replacement of the battery cell unit are facilitated, and the safety maintenance process of the large vertical energy storage battery is greatly simplified.
The large vertical energy storage battery can be further provided with a bus plate, the bus plate comprises an anode bus plate and a cathode bus plate, all the anode lug groups are electrically connected with the anode post through the anode bus plate, and all the cathode lug groups are electrically connected with the cathode post through the cathode bus plate. The bus plate comprises a pole electric connection part, a plurality of pole lug group electric connection parts and a bus part. The plurality of tab group electric connection portions are parallel to each other and are spaced apart from each other, and two converging portions are adjacent to the end portions of the two sides of the plurality of tab group electric connection portions respectively, and the post electric connection portion of the positive electrode bus plate is arranged on one side of the positive electrode bus plate, which is close to the positive electrode post, and the post electric connection portion of the negative electrode bus plate is arranged on one side of the negative electrode bus plate, which is close to the negative electrode post. That is, the bus plate may be approximately ladder-shaped, with the middle cross beam being the tab group electrical connection portion, and the vertical beams on both sides being the bus portions. The tab group electrical connection parts correspond to the tab groups and are electrically connected by mechanical means such as screw connection or clamping or by welding, and then are electrically connected to the battery poles via the bus bar parts and the pole electrical connection parts. The electrode post electric connection part and the electrode post of the battery can be connected in a conductive way through screw connection, welding and the like. The material of the bus plate can be conductive metal or conductive metal composite material resistant to electrochemical corrosion, such as an aluminum plate, a copper plate, a stainless steel plate, a copper-nickel composite plate, an aluminum-nickel composite plate, a copper-aluminum composite plate and the like. In the invention, the bus plate, particularly the part of the bus plate connected with the tab group, is arranged in the front side cavity and the rear side cavity without electrolyte, so that corrosion caused by the soaking of the bus plate in the electrolyte can be avoided, and electric connection failure caused by interface oxidation corrosion of the mechanical connection part of the bus plate and the tab group can also be avoided.
Several specific embodiments of the manner in which the tab set electrical connection portion is electrically connected to the tab set are described below. The electric connection part of the tab group can be provided with two fins in the direction facing the battery cell unit, the two fins can clamp the positive tab group or the negative tab group, or the two fins can be welded on the positive tab group or the negative tab group; or, the tab group electric connection part is provided with two fins in the direction facing away from the battery cell unit, the tab group electric connection part is provided with a narrow hole, the positive tab group or the negative tab group can penetrate out of the narrow hole, the two fins can clamp the positive tab group or the negative tab group, or the two fins can be welded on the positive tab group or the negative tab group; or, the tab group electric connection part is provided with a single fin in the direction opposite to the cell unit, the tab group electric connection part is provided with a narrow hole, the positive tab group or the negative tab group can pass out of the narrow hole, the single fin can press and bend the positive tab group or the negative tab group, and the single fin can be welded on the positive tab group or the negative tab group. The electric connection mode of the tab group electric connection part and the tab group can simplify the connection process and the disassembly process of the tab group electric connection part and the tab group.
Since the large-sized vertical energy storage battery is provided with a large number of battery cells, when the large number of vertically stacked battery cells are converged by the converging plate, a larger current is converged closer to the pole portion. In the present invention, it is preferable that the width of the bus portion of the positive electrode bus plate is gradually widened in the direction toward the positive electrode post, and the width of the bus portion of the negative electrode bus plate is gradually widened in the direction toward the negative electrode post. The positive and negative electrode bus plates may be substantially trapezoidal in shape. Therefore, the bus part of the bus plate has larger width at the part close to the pole, so that the part of the bus plate close to the pole has larger conductive area, thereby not only meeting the bus requirement, but also maximally reducing the quality of the bus part and improving the energy density of the battery.
The large vertical energy storage battery can be further provided with an insulating drainage plate, and the insulating drainage plate can be provided with a positive pole opening, a negative pole opening, an injection port opening (or an injection port drainage groove) and a discharge port opening (or a discharge port drainage groove). The insulating drainage plate is made of insulating materials, and the positive electrode column opening, the negative electrode column opening, the injection port opening and the discharge port opening are mutually spaced, so that the positive electrode column, the negative electrode column, the injection port and the discharge port are mutually insulated and isolated. When the injection port drainage groove is provided, the injection port drainage groove corresponds to the position of the injection port, and the opening of the injection port drainage groove faces the side injection cavity, so that the fluid injected from the injection port can be introduced into the side injection cavity via the injection port drainage groove. In addition, when the large-scale vertical energy storage battery is also provided with the injection pipe, the injection port is connected with one end of the injection pipe, and the injection pipe can extend into the side injection cavity. When the large vertical energy storage battery is provided with the discharge pipe, the discharge port is connected with one end of the discharge pipe, and the discharge pipe can extend into the side discharge cavity. Under the condition that the large vertical energy storage battery is provided with the injection pipe and the discharge pipe, the injection port drainage groove and the discharge port drainage groove can also play a role in limiting the injection pipe and the discharge pipe.
The invention also provides an energy storage container, wherein a plurality of large-scale vertical energy storage batteries are arranged in the shell of the energy storage container. Under the condition that a heating system is arranged in the energy storage container, the interior of the energy storage container can be heated in cold areas, winter and low power states, so that the energy storage container is suitable for being used as a high-temperature battery energy storage container in a mode of combining the heating system with self heat release of a large vertical energy storage battery.
The invention has the advantages that:
1) The invention provides a half-open amplifying type vertical energy storage battery with an inner and outer structure fusion design, which can improve the capacity of the battery to kiloampere-hour level on the premise of ensuring the safety of the battery, reduce the cost of an energy storage system, has a vertical structure, is convenient for the operation of hoisting combination and the like of a large-capacity monomer in the process of integrating an energy storage container, and has safe operation, easy system integration, maintenance and regeneration and longer service life;
2) Through the sealing between the cell unit bracket and the inner wall of the shell, cavities are respectively formed on the side surfaces of the cells, so that the isolation of a battery confluence region and an electrolyte region is realized, and the damage and the connection failure of the confluence part are prevented;
3) The supporting effect of the battery cell unit bracket on the battery cell unit can prevent performance difference and degradation of the upper and lower parts of the battery cell caused by uneven stress;
4) The large vertical battery adopts a semi-open structure, the injection port and the discharge port are respectively connected with the sealed side cavity, so that replacement and discharge of fluids such as gas, liquid and the like in the battery cell are conveniently accelerated through vacuumizing, the battery cell body structure and an external safety system are fused, risk judgment and quick treatment are timely carried out when the safety risk of the energy storage battery occurs, and the safety of the battery is ensured.
Drawings
Fig. 1 is an exploded schematic view of a large vertical energy storage cell according to the present invention;
fig. 2 is an assembled schematic view of a large vertical energy storage cell according to the present invention;
FIG. 3 is a schematic view of a cavity of a large vertical energy storage cell according to the present invention;
fig. 4 is a schematic view of a cell holder and a cell of a large-sized vertical energy storage battery according to a first embodiment of the present invention;
fig. 5 is a schematic view of a cell holder and a cell of a large-sized vertical energy storage battery according to a second embodiment of the present invention;
fig. 6 is a schematic view of a cell holder and a cell of a large-sized vertical energy storage battery according to a third embodiment of the present invention;
fig. 7 (a) and 7 (b) are schematic views and partial enlarged views of a bus plate of a large-sized vertical energy storage battery according to an embodiment of the present invention;
fig. 8 (a) and 8 (b) are schematic views and partial enlarged views of a bus plate of a large-sized vertical energy storage battery according to a second embodiment of the present invention;
fig. 9 is a schematic view of a bus plate of a large vertical energy storage battery according to a third embodiment of the present invention;
fig. 10 is a schematic view of an insulating drainage plate of a large vertical energy storage battery according to the present invention.
List of reference numerals
1-shell
2-cell unit bracket
201-plug-in connection
202-seal part
203-baffle
204-injection opening
205-discharge opening
206-shelf
207-protrusion
208-groove
3-cell unit
301-positive tab set
4 a-positive electrode bus plate
4 b-negative electrode bus plate
401-pole electric connection part
402-tab set electrical connection
403-confluence part
404-fin
405-narrow hole
5-end face seal plate
501-groove
6-insulating drainage plate
601-positive post opening
602-negative electrode opening
603-injection port drainage groove
604-drainage groove at discharge port
7-positive pole
8-negative pole
9-injection port
10-discharge port
11-injection tube
12-discharge pipe
1401-front side cavity
1402-rear side cavity
1403-side injection cavity
1404-side discharge chamber
15-drawer part
1501-front wall
1502-rear wall
1503 side wall
1504-bottom
1505-slot
1506-sidewall implantation opening
Detailed Description
The invention will be further illustrated by way of example with reference to the accompanying drawings.
Fig. 1 is an exploded schematic view of a large vertical energy storage cell according to the present invention; fig. 2 is an assembled schematic view of a large vertical energy storage cell according to the present invention, the housing not being shown for clarity; fig. 3 is a schematic view of the cavity of a large vertical energy storage cell according to the present invention, with the insulating drainage plates not shown for clarity. A large-sized vertical energy storage battery according to the present invention will now be described with reference to fig. 1 to 3. In the embodiment shown in fig. 1 to 3, the large vertical energy storage battery includes a housing 1, a cell holder 2, a cell 3, a positive electrode bus plate 4a, a negative electrode bus plate 4b, an end face sealing plate 5, an insulating drain plate 6, a positive electrode post 7, a negative electrode post 8, an injection port 9, a discharge port 10, an injection pipe 11, and a discharge pipe 12. The plurality of battery cells 3 are respectively inserted into the plug-in parts 201 of the battery cell holders, the positive electrode tab groups 301 of the plurality of battery cells 3 face the front side of the large-sized vertical energy storage battery and the negative electrode tab groups face the rear side of the large-sized vertical energy storage battery. The positive electrode tab set 301 protrudes from the groove 501 of the front end face seal plate 5, the gap between the positive electrode tab set 301 and the groove 501 is sealed by sealant, the negative electrode tab set protrudes from the groove of the rear end face seal plate, and the gap between the negative electrode tab set and the groove is sealed by sealant. The front end face sealing plate 5 is fixed with the front surface of the cell unit bracket 2 in a sealing way, and the rear end face sealing plate 5 is fixed with the rear surface of the cell unit bracket 2 in a sealing way. The positive electrode bus plate 4a is electrically connected to all the positive electrode tab groups 301, and the negative electrode bus plate 4b is electrically connected to all the negative electrode tab groups. The cell holder 2 accommodating the cell 3 is placed in the casing 1, the sealing portion 202 of the cell holder 2 is connected with the inner wall of the casing 1 in a sealing manner, a front cavity 1401 is formed at the front side of the cell holder 2, a rear cavity 1402 is formed at the rear side of the cell holder 2, and a side injection cavity 1403 and a side discharge cavity 1404 are formed at both sides of the cell holder 2, respectively. The front side cavity 1401 is fluid tight to the other cavities, the rear side cavity 1402 is fluid tight to the other cavities, the side injection cavity 1403 is in fluid communication with the interior of the hub 201 via the injection opening 204, and the interior of the hub 201 is in fluid communication with the side discharge cavity 1404 via the discharge opening 205. The positive electrode bus plate 4a is electrically connected to the positive electrode post 7 by a screw, and the negative electrode bus plate 4b is electrically connected to the negative electrode post 8 by a screw. Injection port 9 is in fluid communication with injection tube 11, injection tube 11 is inserted into side injection cavity 1403, discharge port 10 is in fluid communication with discharge tube 12, and discharge tube 12 is inserted into side discharge cavity 1404. The positive electrode post 7, the negative electrode post 8, the injection port 9 and the discharge port 10 protrude from the positive electrode post opening, the negative electrode post opening, the injection port opening and the discharge port opening, respectively, which are spaced apart from each other, on the insulating drain plate 6. It should be noted herein that the terms front, back, left, right, and the like in the present invention are merely for the sake of clarity of presentation, and do not serve as any limitation.
The assembled large vertical energy storage battery may be disposed within a container, for example. The large vertical energy storage battery can be used for injecting liquid at a use place. Electrolyte enters the side injection cavity 1403 through the injection port 9 and the injection pipe 11, and the electrolyte entering the side injection cavity 1403 does not flow into the front side cavity 1401 and the rear side cavity 1402, but enters the plug-in part 201 through the injection opening 204 of the cell holder, so that the cell 3 accommodated in the plug-in part 201 is infiltrated, the electrolyte entering the upper plug-in part also flows downwards, and part of the electrolyte entering the plug-in part 201 also enters the side discharge cavity 1404 through the discharge opening 205 of the cell holder until the electrolyte is fully filled in the side injection cavity 1403, the inside of the plug-in part and the side discharge cavity 1404 and each cell is completely infiltrated. The electrolyte stored in the side injection cavity 1403 and the side discharge cavity 1404 can make the battery in a rich state so as to timely supplement the electrolyte consumed in the electrochemical reaction process to the battery cell, thereby improving the service performance of the battery. During the liquid exchange process, the electrolyte in the side discharge cavity 1404 is pumped out through the discharge pipe 12 by the pumping device from the discharge port 10, and the electrolyte in the plug-in portion 201, the cell, and the side injection cavity 1403 enters the side discharge cavity 1404 under the action of the pumping force until the discharge pipe 12 pumps out all the electrolyte in the side discharge cavity 1404, the plug-in portion 201, the cell, and the side injection cavity 1403. Then, cleaning agent can be injected into the large vertical energy storage battery and discharged, and finally new electrolyte is injected. Since the bus plates (or there are also welded portions) placed in the front and rear cavities 1401 and 1402 do not contact the electrolyte, corrosion of the bus plates due to immersion in the electrolyte can be prevented, and failure of electrical connection of the bus plates and tab groups due to oxidation corrosion of the interface can be avoided.
Fig. 4 is a schematic view of a cell holder and a cell of a large-sized vertical energy storage battery according to a first embodiment of the present invention. In this first embodiment, the cell holders are integrally formed, the sealing parts 202 are provided at four corners of the cell holders in the vertical direction, and sealing strips are provided on the surfaces of the sealing parts 202 facing the inner wall of the case. The left and right sides of each plug-in portion 201 are provided with a baffle 203, an injection opening 204 is provided on the baffle 203 adjacent to the side injection chamber, and a discharge opening 205 is provided on the baffle 203 adjacent to the side discharge chamber. The bottom of each socket 201 is provided with a shelf 206, the shelf 206 being made of a porous material. Two end face sealing plates 5 are respectively arranged for each plug-in connection part 201, the tab groups of the battery cell 3 can extend out of the grooves 501 of the end face sealing plates, and the end face sealing plates 5 can be in sealing connection with the front surface and the rear surface of the battery cell support.
Fig. 5 is a schematic view of a cell holder and a cell of a large-sized vertical energy storage battery according to a second embodiment of the present invention. In the second embodiment, the cell holder is a split assembly structure of a plurality of plug parts 201. The four corners of each plug-in part 201 are provided with sealing parts 202, and the sealing parts 202 of all the plug-in parts 201 jointly form an integral sealing part of the cell unit bracket. Each plugging portion 201 may be provided with a protrusion 207 and a groove 208, and the protrusion 207 of the upper plugging portion is inserted into the groove 208 of the lower plugging portion, so that the assembly of the whole cell unit bracket can be completed. The cell unit bracket with the split structure can be provided with plug-in parts 201 with different layers according to the requirement. The left and right sides of each plug-in portion 201 are provided with a baffle 203, an injection opening 204 is provided on the baffle 203 adjacent to the side injection chamber, and a discharge opening 205 is provided on the baffle 203 adjacent to the side discharge chamber. Two end face sealing plates 5 are respectively arranged for each plug-in connection part 201, the tab groups of the battery cell 3 can extend out of the grooves 501 of the end face sealing plates, and the end face sealing plates 5 can be in sealing connection with the front surface and the rear surface of the battery cell support.
Fig. 6 is a schematic view of a cell holder and a cell of a large-sized vertical energy storage battery according to a third embodiment of the present invention. The third embodiment is mainly different from the first embodiment shown in fig. 4 in that the large-sized vertical energy storage battery further includes a drawer portion 15, and the drawer portion 15 can be inserted into the insertion portion 201 of the cell holder. The drawer 15 includes a front wall 1501, a rear wall 1502, two side walls 1503 and a bottom 1504, the front wall 1501 and the rear wall 1502 of the drawer are provided with slots 1505, the positive tab set 301 of the cell unit 3 extends forward from the slots 1505 of the front wall, the negative tab set of the cell unit 3 extends backward from the slots of the rear wall, and the gaps between the positive tab set and the negative tab set and the slots are sealed. A side wall injection opening 1506 of the drawer portion may be provided at a position of the drawer portion side wall 1503 corresponding to the injection opening 204 of the socket portion of the cell holder, and a side wall discharge opening of the drawer portion may be provided at a position of the other side wall of the drawer portion corresponding to the discharge opening 205 of the socket portion of the cell holder. Electrolyte enters the drawer 15 through the side injection cavity, the injection opening 204 of the plug-in part and the side injection opening 1506 of the drawer, and electrolyte in the drawer 15 enters the side discharge cavity through the side discharge opening 205 of the plug-in part and the side discharge opening of the drawer. The bottom 1504 of the drawer portion may be a porous structure, which may not only serve to support the cell unit 3, but also allow electrolyte in the upper drawer portion 15 to flow into the lower drawer portion 15, where the cell unit support may not be provided with a shelf.
Fig. 7 (a) and 7 (b) are schematic views and partial enlarged views of a bus plate of a large-sized vertical energy storage battery according to an embodiment of the present invention. The bus plate includes a post electrical connection portion 401, a plurality of tab set electrical connection portions 402, and a bus portion 403. The plurality of tab set electrical connections 402 are parallel to and spaced apart from one another, and two adjacent tab set electrical connections 402 are spaced apart by approximately the same distance as two adjacent tab sets. Two bus bars 403 are adjacent to the ends of both sides of the plurality of tab group electrical connection portions 402, respectively, so that the entire bus plate has a ladder-like structure. The pole electric connection part 401 is arranged on one side of the bus plate, which is close to the pole, and the pole electric connection part 401 is bent at a certain angle with the plane where the pole ear group electric connection part 402 and the bus part 403 are located. The post electrical connection portion 401 may be provided with a through hole, and the post electrical connection portion 401 and the post may be electrically connected by passing a screw through the through hole. Each tab group electrical connection 402 corresponds to and is electrically connected to each tab group, and is then electrically connected to a battery tab via the bus bar 403 and the tab electrical connection 401.
In the embodiment shown in fig. 7 (a) and 7 (b), the tab group electrical connection part may be provided with two fins 404 in a direction facing the battery cell, the two fins 404 may clamp the positive tab group or the negative tab group, or the two fins 404 may be welded to the positive tab group or the negative tab group. For example, when the tab group electrical connection portion is electrically connected to the tab group, the two fins 404 of the tab group electrical connection portion 402 are bent and clamped toward the tab group, so that the electrical connection between the tab group electrical connection portion and the tab group is completed in a simple mechanical connection manner.
Fig. 8 (a) and 8 (b) are schematic views and partial enlarged views of a bus plate of a large-sized vertical energy storage battery according to a second embodiment of the present invention. In the embodiment shown in fig. 8 (a) and 8 (b), the tab group electrical connection part 402 is provided with two fins 404 in a direction facing away from the battery cell and the tab group electrical connection part 402 is provided with a slit 405, the positive tab group or the negative tab group can be pierced from the slit 405, the two fins 404 can clamp the positive tab group or the negative tab group, or the two fins 404 can be welded to the positive tab group or the negative tab group. When the tab group electrical connection part 402 is provided with the slot 405, the tab group may be guided from the slot 405 to the outside of the bus plate, so that mechanical connection or welding of the tab group electrical connection part 402 and the tab group may be conveniently performed at the outside of the bus plate. For example, the two fins 404 are pre-bent away from the cell, and the distance between the edges of the two fins 404 is approximately equal to the width of the slot 405. The tab group is led out from the narrow hole 405 and passes through the edge positions of the two fins 404, and the fins 404 and the tab group are welded by a welding method, so that the electrical connection of the tab group electrical connection part 402 and the tab group is completed.
Fig. 9 is a schematic view of a bus plate of a large vertical energy storage battery according to a third embodiment of the present invention. In this embodiment, the width of the bus plate is gradually increased from bottom to top, wherein the width of each tab group electrical connection portion 402 is uniform, and the widths of the two bus portions 403 are gradually widened from bottom to top. That is, the closer to the post electrical connection portion 401, the wider the width of the bus portion 403, so that the portion of the bus portion 403 close to the post electrical connection portion 401 can have a larger conductive area for a larger bus current from bottom to top.
Fig. 10 is a schematic view of an insulating drainage plate of a large vertical energy storage battery according to the present invention. The insulating drainage plate is made of polyvinyl chloride. The insulating drainage plate may be provided with a positive electrode column opening 601, a negative electrode column opening 602, an injection port drainage groove 603 and a discharge port drainage groove 604, and positions of the positive electrode column opening 601, the negative electrode column opening 602, the injection port drainage groove 603 and the discharge port drainage groove 604 correspond to positions of the positive electrode column, the negative electrode column, the injection port and the discharge port respectively. The positive electrode post opening 601, the negative electrode post opening 602, the injection port introduction groove 603, and the discharge port introduction groove 604 are spaced apart from each other, thereby insulating and isolating the positive electrode post, the negative electrode post, the injection port, and the discharge port from each other. The injection port drainage groove 603 opens toward the side injection cavity so that fluid injected from the injection port can be introduced into the side injection cavity through the injection port drainage groove 603.
The embodiments of the present invention are not intended to limit the present invention. Any person skilled in the art can make many possible variations and modifications to the technical solution of the present invention or modifications to equivalent embodiments using the methods and technical contents disclosed above, without departing from the scope of the technical solution of the present invention. Therefore, any simple modification, equivalent variation and modification of the above embodiments according to the technical substance of the present invention still fall within the scope of the technical solution of the present invention.
Claims (13)
1. A large vertical energy storage battery, the large vertical energy storage battery comprising: the battery cell comprises a plurality of battery cell units, each battery cell unit is provided with a plurality of positive plates and negative plates which are stacked in a crossing way, in each battery cell unit, positive lugs of the plurality of positive plates are connected in parallel to form a positive lug group, and negative lugs of the plurality of negative plates are connected in parallel to form a negative lug group; the battery cell unit support comprises a plurality of plug-in parts which are arranged along the vertical direction, the bottom surface of each plug-in part is provided with an edge support frame for supporting the battery cell unit, one side surface of each plug-in part is provided with an injection opening for fluid injection, the other side surface of each plug-in part is provided with a discharge opening for fluid discharge, and four corners of the battery cell unit support are provided with sealing parts which extend along the vertical direction; the shell is used for accommodating the cell unit bracket inserted with the plurality of cell units, the sealing part of the cell unit bracket is in sealing connection with the inner wall of the shell, so that a front side cavity, a rear side cavity, a side injection cavity and a side discharge cavity are respectively formed at the front side, the rear side and the two sides of the cell unit bracket, the side injection cavity and the side discharge cavity are respectively in fluid sealing with the front side cavity, and the side injection cavity and the side discharge cavity are respectively in fluid sealing with the rear side cavity; an injection port through which electrolyte injected into the side injection cavity; a discharge port through which fluid within the side discharge chamber is discharged; the positive electrode post is electrically connected with all positive electrode lug groups, and the negative electrode post is electrically connected with all negative electrode lug groups; the bus plate comprises a positive electrode bus plate and a negative electrode bus plate, all positive electrode lug groups are connected with the positive electrode post through the positive electrode bus plate, all negative electrode lug groups are connected with the negative electrode post through the negative electrode bus plate, the bus plate comprises a post electric connection part, a plurality of tab lug group electric connection parts and bus parts, the plurality of tab lug group electric connection parts are parallel to each other and are mutually spaced, two bus parts are adjacent to the end parts of the two sides of the plurality of tab lug group electric connection parts respectively, the post electric connection parts of the positive electrode bus plate are arranged on one side of the positive electrode bus plate, and the post electric connection parts of the negative electrode bus plate are arranged on one side of the negative electrode bus plate, which is close to the negative electrode post.
2. The large vertical energy storage battery of claim 1, wherein the aspect ratio of the large vertical energy storage battery is 2:1-10:1, the height of the large vertical energy storage battery is 200-3000 mm, and the width of the large vertical energy storage battery is 100-1000 mm.
3. The large vertical energy storage battery of claim 1, wherein the cell unit support is integrally formed; or, the plurality of plug-in parts of the battery cell unit bracket are fixedly connected along the vertical direction.
4. A large vertical energy storage cell as claimed in any one of claims 1 to 3 wherein the cell support is further provided with an end face seal plate on which a groove is provided from which the positive or negative tab set of the cell can protrude and the gap between the positive or negative tab set of the cell and the groove is sealed, the end face seal plate being sealingly connectable to the front and/or rear face of the cell support.
5. The large-sized vertical energy storage battery according to claim 4, wherein a shelf is provided on an edge support frame of each of the socket parts of the cell support, the shelf being disposed in parallel with the cell, the shelf being made of a porous material.
6. A large vertical energy storage battery according to any one of claims 1 to 3, wherein the cell holder is further provided with a drawer portion comprising a front wall, a rear wall, two side walls and a bottom, the drawer portion being capable of accommodating the cell, the front and/or rear walls of the drawer portion being provided with slots from which positive or negative tab groups of the cell can protrude and the gap between the positive or negative tab groups of the cell and the slots being sealed, one side wall of the drawer portion being provided with a side wall injection opening and the other side wall being provided with a side wall discharge opening.
7. The large vertical energy storage battery of claim 6, wherein the bottom of the drawer portion is made of a porous material.
8. The large-sized vertical energy storage battery according to claim 1, wherein the tab group electrical connection part is provided with two fins in a direction facing the cell unit, the two fins being capable of clamping the positive tab group or the negative tab group, or the two fins being capable of being welded to the positive tab group or the negative tab group; or, the tab group electric connection part is provided with two fins in the direction facing away from the battery cell unit, the tab group electric connection part is provided with a narrow hole, the positive tab group or the negative tab group can penetrate out of the narrow hole, the two fins can clamp the positive tab group or the negative tab group, or the two fins can be welded on the positive tab group or the negative tab group; or, the tab group electric connection part is provided with a single fin in a direction opposite to the cell unit, the tab group electric connection part is provided with a narrow hole, the positive tab group or the negative tab group can be penetrated out from the narrow hole, the single fin can be used for bending and folding the positive tab group or the negative tab group, and the single fin can be welded to the positive tab group or the negative tab group.
9. The large vertical energy storage battery according to claim 1, wherein the width of the bus portion of the positive electrode bus plate is gradually widened in a direction toward the positive electrode post, and the width of the bus portion of the negative electrode bus plate is gradually widened in a direction toward the negative electrode post.
10. A large vertical energy storage battery according to any one of claims 1 to 3, wherein the large vertical energy storage battery is further provided with an insulating drainage plate, the insulating drainage plate is provided with a positive pole opening, a negative pole opening, an injection port drainage groove and a discharge port opening, the insulating drainage plate insulates the positive pole, the negative pole, the injection port and the discharge port from each other, and the injection port drainage groove guides fluid injected by the injection port into the side injection cavity.
11. A large vertical energy storage cell as claimed in any one of claims 1 to 3 wherein the large vertical energy storage cell is further provided with an injection tube, the injection port being connected to one end of the injection tube, the injection tube extending into the side injection cavity.
12. A large vertical energy storage cell as claimed in any one of claims 1 to 3 wherein the large vertical energy storage cell is further provided with a drain pipe, the drain port being connected to one end of the drain pipe, the drain pipe extending into the side drain cavity.
13. An energy storage container, characterized in that a plurality of large vertical energy storage cells as claimed in any one of claims 1 to 12 are arranged in the energy storage container.
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