CN114054484A - 一种可渗透反应墙及其修复污染地下水的方法 - Google Patents
一种可渗透反应墙及其修复污染地下水的方法 Download PDFInfo
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- CN114054484A CN114054484A CN202010761065.3A CN202010761065A CN114054484A CN 114054484 A CN114054484 A CN 114054484A CN 202010761065 A CN202010761065 A CN 202010761065A CN 114054484 A CN114054484 A CN 114054484A
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/002—Reclamation of contaminated soil involving in-situ ground water treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/06—Contaminated groundwater or leachate
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Soil Sciences (AREA)
- Catalysts (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Claims (15)
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CN202010761065.3A CN114054484B (zh) | 2020-07-31 | 2020-07-31 | 一种可渗透反应墙及其修复污染地下水的方法 |
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CN202010761065.3A CN114054484B (zh) | 2020-07-31 | 2020-07-31 | 一种可渗透反应墙及其修复污染地下水的方法 |
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CN114054484A true CN114054484A (zh) | 2022-02-18 |
CN114054484B CN114054484B (zh) | 2024-06-07 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113979508A (zh) * | 2021-11-19 | 2022-01-28 | 中国石油化工股份有限公司 | 一种可渗透反应墙的填充材料、制备方法和应用 |
Citations (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5041408A (en) * | 1989-05-09 | 1991-08-20 | Imperial Chemical Industries Plc | Catalyst comprising calcium aluminate cement and at least one oxide of nickel or cobalt |
US20090090677A1 (en) * | 2007-10-09 | 2009-04-09 | National Cheng Kung University | Method of treating organic compounds in groundwater |
CN101698537A (zh) * | 2009-11-05 | 2010-04-28 | 吉林大学 | 泥炭作为添加介质用于石油烃污染地下水的原位修复方法 |
CN101973610A (zh) * | 2010-04-22 | 2011-02-16 | 吉林大学 | 以电气石作为添加介质原位修复石油烃污染地下水的方法 |
CN102583827A (zh) * | 2012-03-01 | 2012-07-18 | 中国环境科学研究院 | 一种双层可渗透反应墙修复体系及制法和应用 |
CN102826632A (zh) * | 2012-07-22 | 2012-12-19 | 大连理工大学 | 一种原位吸附-微电解-催化氧化的污水处理设备及方法 |
CN103170304A (zh) * | 2013-03-11 | 2013-06-26 | 常州大学 | 采用凹凸棒土制备直链烷烃吸附用5a分子筛的方法 |
CN103241792A (zh) * | 2013-05-10 | 2013-08-14 | 中山大学 | 一种可渗透反应墙墙体材料及其制备方法 |
US20150018196A1 (en) * | 2012-10-29 | 2015-01-15 | China Petroleum & Chemical Corporation | 5A Molecular Sieve Adsorbent and Method for Preparation of the Same |
CN104438312A (zh) * | 2014-11-14 | 2015-03-25 | 华中科技大学 | 一种重度复合污染场地的修复方法 |
CN104478071A (zh) * | 2014-11-25 | 2015-04-01 | 东华大学 | 一种稀土-凹凸棒土生物催化污泥的制备方法 |
CN105668689A (zh) * | 2016-04-11 | 2016-06-15 | 华东理工大学 | 一种应用于地下水原位修复的多功能缓释修复剂 |
CN106142318A (zh) * | 2016-08-23 | 2016-11-23 | 河海大学 | 一种下凹式绿地的缓释氧材料层及其制备方法 |
CN205874160U (zh) * | 2016-08-08 | 2017-01-11 | 湖南环达环保有限公司 | 一种用于地下水污染修复的可渗透反应墙装置 |
CN106365329A (zh) * | 2016-10-27 | 2017-02-01 | 辽宁石油化工大学 | 一种用于修复石油烃污染地下水的生物反应墙介质材料 |
CN106975653A (zh) * | 2017-04-19 | 2017-07-25 | 合肥工业大学 | 一种防止含水层污染的可渗透反应墙原位修复方法 |
CN107739083A (zh) * | 2017-10-31 | 2018-02-27 | 爱土工程环境科技有限公司 | 一种含氰地下水可渗透反应墙原位修复的方法 |
CN108217919A (zh) * | 2017-12-28 | 2018-06-29 | 上海市政工程设计研究总院(集团)有限公司 | 一种用于有机污染地下水修复的多效复合修复材料 |
CN109012740A (zh) * | 2018-08-22 | 2018-12-18 | 国家能源投资集团有限责任公司 | 用于微波催化氧化处理有机废水的分子筛催化剂、其制备方法及应用 |
CN208327744U (zh) * | 2018-05-11 | 2019-01-04 | 陈晓建 | 一种地下水污染修复的可渗透反应墙 |
CN109354217A (zh) * | 2018-12-21 | 2019-02-19 | 江西省科学院 | 一种河道水体及底泥综合处理剂及制备方法 |
CN109912045A (zh) * | 2019-03-22 | 2019-06-21 | 河海大学 | 一种可渗透反应墙 |
CN209222868U (zh) * | 2018-11-30 | 2019-08-09 | 广东佳德土壤修复技术有限公司 | 一种修复有机污染土壤的可渗透反应墙装置 |
CN110201632A (zh) * | 2019-05-15 | 2019-09-06 | 王子韩 | 一种锰掺杂的4a分子筛的制备方法及其用途 |
CN111377520A (zh) * | 2018-12-28 | 2020-07-07 | 中国石油化工股份有限公司 | 一种有机废水处理工艺 |
-
2020
- 2020-07-31 CN CN202010761065.3A patent/CN114054484B/zh active Active
Patent Citations (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5041408A (en) * | 1989-05-09 | 1991-08-20 | Imperial Chemical Industries Plc | Catalyst comprising calcium aluminate cement and at least one oxide of nickel or cobalt |
US20090090677A1 (en) * | 2007-10-09 | 2009-04-09 | National Cheng Kung University | Method of treating organic compounds in groundwater |
CN101698537A (zh) * | 2009-11-05 | 2010-04-28 | 吉林大学 | 泥炭作为添加介质用于石油烃污染地下水的原位修复方法 |
CN101973610A (zh) * | 2010-04-22 | 2011-02-16 | 吉林大学 | 以电气石作为添加介质原位修复石油烃污染地下水的方法 |
CN102583827A (zh) * | 2012-03-01 | 2012-07-18 | 中国环境科学研究院 | 一种双层可渗透反应墙修复体系及制法和应用 |
GB201219329D0 (en) * | 2012-03-01 | 2012-12-12 | Chinese Res Academy Of Enviromental Sciences | Double-layer permeable reactive barrier remediation system and its constructive method and application |
CN102826632A (zh) * | 2012-07-22 | 2012-12-19 | 大连理工大学 | 一种原位吸附-微电解-催化氧化的污水处理设备及方法 |
US20150018196A1 (en) * | 2012-10-29 | 2015-01-15 | China Petroleum & Chemical Corporation | 5A Molecular Sieve Adsorbent and Method for Preparation of the Same |
CN103170304A (zh) * | 2013-03-11 | 2013-06-26 | 常州大学 | 采用凹凸棒土制备直链烷烃吸附用5a分子筛的方法 |
CN103241792A (zh) * | 2013-05-10 | 2013-08-14 | 中山大学 | 一种可渗透反应墙墙体材料及其制备方法 |
CN104438312A (zh) * | 2014-11-14 | 2015-03-25 | 华中科技大学 | 一种重度复合污染场地的修复方法 |
CN104478071A (zh) * | 2014-11-25 | 2015-04-01 | 东华大学 | 一种稀土-凹凸棒土生物催化污泥的制备方法 |
CN105668689A (zh) * | 2016-04-11 | 2016-06-15 | 华东理工大学 | 一种应用于地下水原位修复的多功能缓释修复剂 |
CN205874160U (zh) * | 2016-08-08 | 2017-01-11 | 湖南环达环保有限公司 | 一种用于地下水污染修复的可渗透反应墙装置 |
CN106142318A (zh) * | 2016-08-23 | 2016-11-23 | 河海大学 | 一种下凹式绿地的缓释氧材料层及其制备方法 |
CN106365329A (zh) * | 2016-10-27 | 2017-02-01 | 辽宁石油化工大学 | 一种用于修复石油烃污染地下水的生物反应墙介质材料 |
CN106975653A (zh) * | 2017-04-19 | 2017-07-25 | 合肥工业大学 | 一种防止含水层污染的可渗透反应墙原位修复方法 |
CN107739083A (zh) * | 2017-10-31 | 2018-02-27 | 爱土工程环境科技有限公司 | 一种含氰地下水可渗透反应墙原位修复的方法 |
CN108217919A (zh) * | 2017-12-28 | 2018-06-29 | 上海市政工程设计研究总院(集团)有限公司 | 一种用于有机污染地下水修复的多效复合修复材料 |
CN208327744U (zh) * | 2018-05-11 | 2019-01-04 | 陈晓建 | 一种地下水污染修复的可渗透反应墙 |
CN109012740A (zh) * | 2018-08-22 | 2018-12-18 | 国家能源投资集团有限责任公司 | 用于微波催化氧化处理有机废水的分子筛催化剂、其制备方法及应用 |
CN209222868U (zh) * | 2018-11-30 | 2019-08-09 | 广东佳德土壤修复技术有限公司 | 一种修复有机污染土壤的可渗透反应墙装置 |
CN109354217A (zh) * | 2018-12-21 | 2019-02-19 | 江西省科学院 | 一种河道水体及底泥综合处理剂及制备方法 |
CN111377520A (zh) * | 2018-12-28 | 2020-07-07 | 中国石油化工股份有限公司 | 一种有机废水处理工艺 |
CN109912045A (zh) * | 2019-03-22 | 2019-06-21 | 河海大学 | 一种可渗透反应墙 |
CN110201632A (zh) * | 2019-05-15 | 2019-09-06 | 王子韩 | 一种锰掺杂的4a分子筛的制备方法及其用途 |
Non-Patent Citations (1)
Title |
---|
刘登义 主编, 合肥工业大学出版社, pages: 133 - 135 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113979508A (zh) * | 2021-11-19 | 2022-01-28 | 中国石油化工股份有限公司 | 一种可渗透反应墙的填充材料、制备方法和应用 |
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