CN114031384A - Preparation method of quartz ceramic hollow roller for toughened glass heating furnace - Google Patents
Preparation method of quartz ceramic hollow roller for toughened glass heating furnace Download PDFInfo
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- CN114031384A CN114031384A CN202111356670.3A CN202111356670A CN114031384A CN 114031384 A CN114031384 A CN 114031384A CN 202111356670 A CN202111356670 A CN 202111356670A CN 114031384 A CN114031384 A CN 114031384A
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 91
- 239000010453 quartz Substances 0.000 title claims abstract description 46
- 239000000919 ceramic Substances 0.000 title claims abstract description 36
- 238000010438 heat treatment Methods 0.000 title claims abstract description 24
- 239000005341 toughened glass Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 64
- 239000002994 raw material Substances 0.000 claims abstract description 40
- 238000001035 drying Methods 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 27
- 238000005245 sintering Methods 0.000 claims abstract description 24
- 238000001238 wet grinding Methods 0.000 claims abstract description 23
- 239000002002 slurry Substances 0.000 claims abstract description 21
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- 239000000084 colloidal system Substances 0.000 claims abstract description 14
- 239000005350 fused silica glass Substances 0.000 claims abstract description 13
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 12
- 238000000465 moulding Methods 0.000 claims abstract description 12
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000010304 firing Methods 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000008187 granular material Substances 0.000 claims description 17
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 12
- 239000008213 purified water Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003638 chemical reducing agent Substances 0.000 claims description 7
- 230000001133 acceleration Effects 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 6
- 235000010333 potassium nitrate Nutrition 0.000 claims description 6
- 239000004323 potassium nitrate Substances 0.000 claims description 6
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- -1 alkyl diphenyl oxide Chemical compound 0.000 claims description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000000280 densification Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- 230000007547 defect Effects 0.000 description 2
- ZIWRUEGECALFST-UHFFFAOYSA-M sodium 4-(4-dodecoxysulfonylphenoxy)benzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCOS(=O)(=O)c1ccc(Oc2ccc(cc2)S([O-])(=O)=O)cc1 ZIWRUEGECALFST-UHFFFAOYSA-M 0.000 description 2
- LGNQGTFARHLQFB-UHFFFAOYSA-N 1-dodecyl-2-phenoxybenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1OC1=CC=CC=C1 LGNQGTFARHLQFB-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000004814 ceramic processing Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
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Abstract
The invention discloses a preparation method of a quartz ceramic hollow roller for a toughened glass heating furnace, which comprises the following steps of S1, selecting quartz mixed raw materials comprising silicon nitride and silicon dioxide; s2, grinding the raw materials; s3, preparing colloidal slurry: putting the slurry after wet grinding, organic colloid, catalyst, surfactant and fused quartz mixed raw materials into a stirrer to be uniformly stirred to prepare colloid slurry; s4, molding, namely building a green body through pressure molding, and adding 1-5% of a sintering aid in the total amount; s5, drying: drying the molded blank body for 4-8h in a normal temperature environment, and then drying in a drying furnace at the drying temperature of 100-120 ℃; s6, sintering: and firing the dried blank body under the conditions of 1180-1220 ℃, and preserving the heat for 2-5 hours to obtain the quartz ceramic hollow roller rod. The treatment process is convenient to operate, the process is simplified, and the product has high breaking strength, low apparent porosity and high densification degree.
Description
Technical Field
The invention relates to the technical field of quartz ceramic processing, in particular to a preparation method of a quartz ceramic hollow roller rod for a toughened glass heating furnace.
Background
The quartz ceramic roller is mainly used for a glass high-temperature transmission mechanism of a glass toughening treatment kiln, and has the main advantages that: 1. the heat conductivity coefficient is low, the heat loss is small, and the uniformity of the furnace temperature is high; 2. the hardness is close to that of glass, and the glass cannot be scratched; 3. the material is light, the rigidity is good, and the flatness of the glass can be ensured. Therefore, the quartz ceramic roller is widely used in a tempered glass furnace. However, the quartz ceramic rolls currently used are all solid rolls. Although the solid roller can meet the use condition of the glass tempering furnace, the solid roller has many defects, such as the heavy weight of the solid roller and inconvenient installation and replacement operation. Particularly, the heat conduction of the solid roller rod is larger than that of the hollow roller rod, so that certain heat loss is caused, and certain influence is also caused on the uniformity of the furnace temperature.
The existing toughened glass heating furnace needs to use a quartz ceramic hollow roller rod in the processing process, and the traditional quartz ceramic hollow roller rod manufacturing process has the advantages that the manufactured product has lower strength, small volume density, low breaking strength, higher apparent porosity and low densification degree, and the using effect is influenced. For this reason, a corresponding technical scheme needs to be designed to solve the existing technical problems.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a preparation method of a quartz ceramic hollow roller rod for a toughened glass heating furnace, which solves the problems that: the existing toughened glass heating furnace needs to use a quartz ceramic hollow roller rod in the processing process, and the traditional quartz ceramic hollow roller rod manufacturing process has the problems of low strength, low volume density, low breaking strength, high apparent porosity, low densification degree and influence on the use effect of the manufactured product.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: a method for preparing a quartz ceramic hollow roller for a toughened glass heating furnace comprises the following steps,
s1, selecting quartz mixed raw materials including 0.5-5.5% of silicon nitride and 94.5-99.5% of silicon dioxide;
s2, grinding the raw materials: adding purified water and a water reducing agent into the granules, putting the granules into a ball mill together, wet-milling the granules for 15-30h, discharging, heating and melting the raw materials, fully stirring the raw materials, and keeping the melting temperature at 1300 ℃ and 1450 ℃ to obtain a fused quartz mixed raw material;
s3, preparing colloidal slurry: putting the slurry after wet grinding, organic colloid, catalyst, surfactant and fused quartz mixed raw materials into a stirrer to be uniformly stirred to prepare colloid slurry;
s4, molding, namely building a green body through pressure molding, and adding 1-5% of a sintering aid in the total amount;
s5, drying: drying the molded blank body for 4-8h in a normal temperature environment, and then drying in a drying furnace at the drying temperature of 100-120 ℃;
s6, sintering: and firing the dried blank body under the conditions of 1180-1220 ℃, and preserving the heat for 2-5 hours to obtain the quartz ceramic hollow roller rod.
As a further preferable mode of the present invention, in step S1, the silica is composed of, in terms of mass percentage of particles to gradation: the granularity is as follows: 0.2-0.4 mm-40-50%, granularity: 0.1-0.2 mm-20-30% of the particle size: less than 0.1mm to 20-30%.
In a more preferred embodiment of the present invention, in step S2, pure water having a concentration of 17% to 68% may be continuously injected during the wet milling, and after the pure water is added, sodium bicarbonate having a concentration of 78% may be added to perform the wet milling.
In a more preferred embodiment of the present invention, in step S3, the catalyst is a mixture of potassium nitrate and silicic acid.
In a further preferred embodiment of the present invention, in step S3, the surfactant is one of sodium dodecyl diphenyl oxide disulfonate and alkyl diphenyl oxide disulfonate.
In a more preferred embodiment of the present invention, in step S3, the rotation speed of stirring is controlled to 120r/min to 160r/min, and the temperature is controlled to 1200 ℃ or higher.
In a further preferred embodiment of the present invention, in step S4, the sintering aid is one of nano yttrium oxide and zinc oxide.
As a further preferred embodiment of the present invention, in step S6, the sintering start rotational speed is 6rpm for 1.5 hours, and then the rotational speed is changed to 8rpm to 24rpm, and the acceleration is maintained uniformly and continuously.
(III) advantageous effects
The invention provides a preparation method of a quartz ceramic hollow roller rod for a toughened glass heating furnace. The method has the following beneficial effects:
the treatment process is convenient to operate and simplified, and the introduction of the silicon nitride has the effect of preparing the gel-casting quartz ceramic. The sintering temperature of the quartz ceramic is not influenced, and the promotion effect is achieved; proper addition does not cause quartz ceramic crystallization; the strength and the volume density of the quartz ceramic increase with the increase of the addition amount of silicon nitride and the increase of the sintering temperature, and the apparent porosity decreases.
The nano yttrium oxide or zinc oxide has the sintering effect on quartz ceramics, can obviously promote the sintering of the quartz ceramics, and has high breaking strength, low apparent porosity and high densification degree.
Drawings
FIG. 1 is a process flow diagram of the oxidative coloration of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, an embodiment of the present invention provides a technical solution: a method for preparing a quartz ceramic hollow roller for a toughened glass heating furnace comprises the following steps,
s1, selecting quartz mixed raw materials including 0.5-5.5% of silicon nitride and 94.5-99.5% of silicon dioxide;
s2, grinding the raw materials: adding purified water and a water reducing agent into the granules, putting the granules into a ball mill together, wet-milling the granules for 15-30h, discharging, heating and melting the raw materials, fully stirring the raw materials, and keeping the melting temperature at 1300 ℃ and 1450 ℃ to obtain a fused quartz mixed raw material;
s3, preparing colloidal slurry: putting the slurry after wet grinding, organic colloid, catalyst, surfactant and fused quartz mixed raw materials into a stirrer to be uniformly stirred to prepare colloid slurry;
s4, molding, namely building a green body through pressure molding, and adding 1-5% of a sintering aid in the total amount;
s5, drying: drying the molded blank body for 4-8h in a normal temperature environment, and then drying in a drying furnace at the drying temperature of 100-120 ℃;
s6, sintering: and firing the dried blank body under the conditions of 1180-1220 ℃, and preserving the heat for 2-5 hours to obtain the quartz ceramic hollow roller rod.
In step S1, the silica is prepared by, in terms of mass percentage of particles to gradation: the granularity is as follows: 0.2-0.4 mm-40-50%, granularity: 0.1-0.2 mm-20-30% of the particle size: less than 0.1mm to 20-30%.
In step S2, pure water with a concentration of 17% to 68% may be continuously injected during the wet milling process, and after the pure water is added, sodium bicarbonate with a concentration of 78% is added for sufficient wet milling.
In step S3, the catalyst is a mixture of potassium nitrate and silicic acid.
In step S3, the surfactant is one of sodium dodecyl diphenyl oxide disulfonate or alkyl diphenyl oxide disulfonate.
In step S3, the rotation speed of stirring is controlled at 120r/min-160r/min, and the temperature is controlled at 1200 ℃ or above.
In step S4, the sintering aid is one of nano yttrium oxide or zinc oxide.
In step S6, the sintering start rotational speed was 6rpm for 1.5 hours, and then the rotational speed was changed to 8rpm to 24rpm, maintaining uniform continuous acceleration.
Example one
Selecting quartz mixed raw materials comprising silicon nitride and silicon dioxide, wherein the silicon nitride accounts for 5.5%, the silicon dioxide accounts for 94.5%, and the particle size of the silicon dioxide is as follows: 0.4 mm-50%, the particle size is: 0.2 mm-30%, the granularity is: less than 0.1mm to 20 percent;
grinding raw materials: adding the particles, purified water and the water reducing agent into a ball mill, wet-milling for 30h, discharging, heating and melting the raw materials, fully stirring, and keeping the melting temperature at 1450 ℃ to obtain a fused quartz mixed raw material;
preparing colloidal slurry: putting the slurry after wet grinding, the mixture consisting of organic colloid, potassium nitrate and silicic acid, sodium dodecyl diphenyl ether disulfonate and the mixed raw material of fused quartz into a stirrer to be uniformly stirred, controlling the rotating speed at 120r/min and the temperature at over 1200 ℃ to prepare colloid slurry;
forming, namely building a green body through pressure forming, and adding zinc oxide accounting for 5 percent of the total weight;
and (3) drying: airing the formed blank body for 6 hours in a normal temperature environment, and then putting the blank body into a drying furnace for drying, wherein the drying temperature is 120 ℃;
and (3) sintering: and (3) firing the dried blank body under the firing condition of 1220 ℃, wherein the initial sintering rotation speed is 6rpm and lasts for 1.5h, then changing the rotation speed to 24rpm, keeping uniform and continuous acceleration, and keeping the temperature for 3.5h to obtain the quartz ceramic hollow roller rod.
Example two
Selecting quartz mixed raw materials, wherein the quartz mixed raw materials comprise silicon nitride and silicon dioxide, the silicon nitride accounts for 0.5-5.5%, the silicon dioxide accounts for 94.5%, and the silicon dioxide comprises the following components in percentage by mass: the granularity is as follows: 0.2 mm-40%, the granularity is: 0.1 mm-30% of the particle size: less than 0.1mm to 30 percent;
grinding raw materials: adding purified water and a water reducing agent into the granules, putting the granules together with the purified water and the water reducing agent into a ball mill, wet-milling the granules for 15h, discharging the granules, heating and melting the raw materials, fully stirring the raw materials, keeping the melting temperature at 1300 ℃ to obtain a fused quartz mixed raw material, continuously injecting the purified water with the concentration of 17 percent in the wet-milling process, adding the sodium bicarbonate with the concentration of 78 percent after adding the purified water, and fully wet-milling the mixture;
preparing colloidal slurry: putting the slurry after wet grinding, a mixture consisting of organic colloid, potassium nitrate and silicic acid, wherein the surfactant is one of sodium dodecyl diphenyl ether disulfonate or alkyl diphenyl ether disulfonate and a fused quartz mixed raw material into a stirrer to be uniformly stirred, the stirring speed is controlled at 160r/min, and the temperature is controlled at over 1200 ℃ to prepare colloid slurry;
molding, namely building a green body through pressure molding, and adding 1% of nano yttrium oxide in total weight percentage;
and (3) drying: airing the formed blank body for 8 hours in a normal temperature environment, and then putting the blank body into a drying furnace for drying, wherein the drying temperature is 100 ℃;
and (3) sintering: and firing the dried blank body under the firing condition of 1180 ℃, wherein the initial sintering rotation speed is 6rpm and lasts for 1.5h, then the rotation speed is changed to 8rpm, the uniform and continuous acceleration is kept, and the heat preservation is carried out for 3h, so that the quartz ceramic hollow roller rod is obtained.
EXAMPLE III
Selecting quartz mixed raw materials, wherein the quartz mixed raw materials comprise silicon nitride and silicon dioxide, the silicon nitride accounts for 4%, the silicon dioxide accounts for 96%, and the silicon dioxide comprises the following components in percentage by mass: the granularity is as follows: 0.4 mm-50%, the particle size is: 0.15 mm-30% of the particle size: less than 0.1mm to 20 percent;
grinding raw materials: adding purified water and a water reducing agent into the granules, putting the granules into a ball mill together, wet-milling the granules for 20h, discharging the granules, heating and melting the raw materials, fully stirring the raw materials, keeping the melting temperature at 1400 ℃ to obtain a fused quartz mixed raw material, continuously injecting purified water with the concentration of 55 percent in the wet milling process, adding purified water, then adding sodium bicarbonate with the concentration of 78 percent, and fully wet-milling the mixture;
preparing colloidal slurry: putting the slurry after wet grinding, the mixture consisting of organic colloid, potassium nitrate and silicic acid, and the surfactant which is dodecyl diphenyl ether sodium disulfonate and the mixed raw material of fused quartz into a stirrer to be uniformly stirred, wherein the stirring speed is controlled at 150r/min, and the temperature is controlled at over 1200 ℃ to prepare colloid slurry;
molding, namely building a green body through pressure molding, and adding 3% of nano yttrium oxide in total weight percentage;
and (3) drying: drying the molded blank body for 8 hours at normal temperature, and then drying in a drying furnace at the drying temperature of 110 ℃;
and (3) sintering: and (3) firing the dried blank body under the firing condition of 1200 ℃, wherein the initial sintering rotation speed is 6rpm and lasts for 1.5h, then changing the rotation speed to 20rpm, keeping uniform and continuous acceleration, and keeping the temperature for 4h to obtain the quartz ceramic hollow roller rod.
The product parameter table is as follows:
while there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be apparent to those skilled in the art that the invention is not limited to the details of the foregoing exemplary embodiments, but is capable of other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (8)
1. A preparation method of a quartz ceramic hollow roller for a toughened glass heating furnace is characterized by comprising the following steps: the specific manufacturing method comprises the following steps of,
s1, selecting quartz mixed raw materials including 0.5-5.5% of silicon nitride and 94.5-99.5% of silicon dioxide;
s2, grinding the raw materials: adding purified water and a water reducing agent into the granules, putting the granules into a ball mill together, wet-milling the granules for 15-30h, discharging, heating and melting the raw materials, fully stirring the raw materials, and keeping the melting temperature at 1300 ℃ and 1450 ℃ to obtain a fused quartz mixed raw material;
s3, preparing colloidal slurry: putting the slurry after wet grinding, organic colloid, catalyst, surfactant and fused quartz mixed raw materials into a stirrer to be uniformly stirred to prepare colloid slurry;
s4, molding, namely building a green body through pressure molding, and adding 1-5% of a sintering aid in the total amount;
s5, drying: drying the molded blank body for 4-8h in a normal temperature environment, and then drying in a drying furnace at the drying temperature of 100-120 ℃;
s6, sintering: and firing the dried blank body under the conditions of 1180-1220 ℃, and preserving the heat for 2-5 hours to obtain the quartz ceramic hollow roller rod.
2. The method for preparing the quartz ceramic hollow roller for the tempered glass heating furnace according to claim 1, wherein the method comprises the following steps: in step S1, the silica is prepared by, in terms of mass percentage of particles to gradation: the granularity is as follows: 0.2-0.4 mm-40-50%, granularity: 0.1-0.2 mm-20-30% of the particle size: less than 0.1mm to 20-30%.
3. The method for preparing the quartz ceramic hollow roller for the tempered glass heating furnace according to claim 1, wherein the method comprises the following steps: in step S2, pure water with a concentration of 17% to 68% may be continuously injected during the wet milling process, and after the pure water is added, sodium bicarbonate with a concentration of 78% is added for sufficient wet milling.
4. The method for preparing the quartz ceramic hollow roller for the tempered glass heating furnace according to claim 1, wherein the method comprises the following steps: in step S3, the catalyst is a mixture of potassium nitrate and silicic acid.
5. The method for preparing the quartz ceramic hollow roller for the tempered glass heating furnace according to claim 1, wherein the method comprises the following steps: in step S3, the surfactant is one of sodium dodecyl diphenyl oxide disulfonate or alkyl diphenyl oxide disulfonate.
6. The method for preparing the quartz ceramic hollow roller for the tempered glass heating furnace according to claim 1, wherein the method comprises the following steps: in step S3, the rotation speed of stirring is controlled at 120r/min-160r/min, and the temperature is controlled at 1200 ℃ or above.
7. The method for preparing the quartz ceramic hollow roller for the tempered glass heating furnace according to claim 1, wherein the method comprises the following steps: in step S4, the sintering aid is one of nano yttrium oxide or zinc oxide.
8. The method for preparing the quartz ceramic hollow roller for the tempered glass heating furnace according to claim 1, wherein the method comprises the following steps: in step S6, the sintering start rotational speed was 6rpm for 1.5 hours, and then the rotational speed was changed to 8rpm to 24rpm, maintaining uniform continuous acceleration.
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