CN108610029A - A kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller - Google Patents

A kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller Download PDF

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Publication number
CN108610029A
CN108610029A CN201611133365.7A CN201611133365A CN108610029A CN 108610029 A CN108610029 A CN 108610029A CN 201611133365 A CN201611133365 A CN 201611133365A CN 108610029 A CN108610029 A CN 108610029A
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annealing furnace
glass horizontal
quartz ceramic
horizontal annealing
ceramic roller
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王永江
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Xuzhou Connor Hi-Tech Materials Science And Technology Co Ltd
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Xuzhou Connor Hi-Tech Materials Science And Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B35/00Transporting of glass products during their manufacture, e.g. hot glass lenses, prisms
    • C03B35/14Transporting hot glass sheets or ribbons, e.g. by heat-resistant conveyor belts or bands
    • C03B35/16Transporting hot glass sheets or ribbons, e.g. by heat-resistant conveyor belts or bands by roller conveyors
    • C03B35/18Construction of the conveyor rollers ; Materials, coatings or coverings thereof
    • C03B35/181Materials, coatings, loose coverings or sleeves thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/6261Milling
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3821Boron carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3873Silicon nitrides, e.g. silicon carbonitride, silicon oxynitride
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
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  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Ceramic Products (AREA)

Abstract

The invention discloses a kind of production methods of glass horizontal annealing furnace Quartz Ceramic Roller, the invention belongs to fused quartz ceramic production of articles field, produce composition of raw materials that the product uses count by weight percentage:50 80 mesh vitreous silica silicon powders 30 32%, 120 140 mesh vitreous silica silicon powders 36 38%, 180 200 mesh vitreous silica silicon powders 26%, boron carbide 4%, silicon nitride 1%, nanometre glue 0.40%, ammonium persulfate 0.20%, tetramethylethylenediamine 0.20%, polyethylene glycol 200 0.20%;The production method has using series of advantages such as few, simple for process, the pollution-free waste discharge of equipment, good product qualities;Product glass horizontal annealing furnace Quartz Ceramic Roller has excellent hot property, chemical stability and electrical insulation capability at 1200 DEG C or less, is used mainly as glass horizontal annealing furnace transmission product.

Description

A kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller
Technical field
The invention belongs to fused quartz ceramic production of articles fields, more particularly to one kind is using vitreous silica silicon powder as raw material The method for producing glass horizontal annealing furnace Quartz Ceramic Roller.
Background technology
Fused quartz ceramic be one kind using vitreous silica as raw material, using vitreous silica material made of ceramic production technology Material, its main feature is that:Coefficient of thermal expansion is small, thermal stability is good, electrical insulating property is good, chemerosiveness resistent is good;Quartz-ceramics are maximum Advantage is at l1O0 DEG C or less, and intensity increases with the raising of temperature, and when from room temperature to 1100 DEG C, intensity can increase Add 33%, product still can normal use at 1250 DEG C.The major product type of fused quartz ceramic is various, such as glass horizontal steel Change stove Quartz Ceramic Roller, float glass furnace damper block, Float Glass Annealing stove hollow roll, cast steel water nozzle, metal tape Material heat-treatment furnace hollow roll, glass and metallurgical furnace water nozzle, punch, crucible, furnace body, section's sulphur, even section cylinder, stirring rod, material Basin, rotation pipe, coke oven door and tedge liner and insulative inserts, microwave screen, arc-extinguish chamber, efficient batch furnace thermal insulation Device, laser reflector and other optical elements, quartz light sources light reflection and the such as part are absorbed in addition, in guided missile, rocket, thunder Up to etc. also have a small amount of application.The primary raw material that these products use all is vitreous silica silicon powder, and difference is only that silicon is micro- The granularity of powder is different, auxiliary material is different, product shape is different.The present invention is a kind of glass horizontal annealing furnace quartz-ceramics Roller is exclusively used in the transmission of glass horizontal annealing furnace product, and product requirement intensity height, high temperature resistant, the temperature in use are up to 1000 DEG C Left and right, it is necessary to have have stable high-temperature performance indeformable, thermals expansion is small, chemical stability is good, surface it is smooth exquisiteness, wearability it is good, The features such as not easy to wear by long-term use.The key technical problem that product of the present invention intends to solve in production has four, first, molten The optimum proportioning of the granularity of fused silica ceramic powder;Second is that the shadow of quartz-ceramics additives on sintering property of fused quartz ceramics It rings;Third, the optimal combination of auxiliary material, the combination of auxiliary material will directly influence the conjugation of fused quartz ceramic powder particles, to reducing Gap, the quality for improving product are most important;Fourth, the determination of large-scale shuttle kiln sintering temperature and sintering time, the prior art It is first through 2-3 hours time that sintering temperature is slowly warm by sintering after 0 DEG C rises to 400 DEG C, then within 10 hour time Degree quickly rises to 1150-1200 DEG C from 400 DEG C, stops heating means after maintaining this temperature 6-10 hours.
Invention content
Present invention mainly solves the problem of be to provide a kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller, it is raw Producing the raw material weight proportioning of soup processed that the product uses is:50-80 mesh vitreous silica silicon powder 30-32%, 120-140 mesh vitreous silica silicon Micro mist 36-38%, 180-200 mesh vitreous silica silicon powder 26%, boron carbide 4%, silicon nitride 1%, nanometre glue 0.40%, ammonium persulfate 0.20%, tetramethylethylenediamine 0.20%, polyethylene glycol 200 0.20%.
The present invention can be achieved through the following technical solutions:
(1)Stirring first is added in the nanometre glue of formula ratio, ammonium persulfate, tetramethylethylenediamine, polyethylene glycol 200 in agitator tank It in tank, is uniformly mixed under room temperature, then by the 50-80 mesh vitreous silicas silicon powder of formula ratio, 120-140 mesh vitreous silica silicon Micro mist, 180-200 mesh vitreous silicas silicon powder, boron carbide, silicon nitride are sent into ball mill ball milling 1.8-2.0 hours, by agitator tank In mixture be heated to 30-35 DEG C after be added ball mill, blending is uniform;
(2)Material in ball mill is filled into glass horizontal annealing furnace quartz-ceramics roller mould, is shaken using in casting Method cast molding, then pressurization sloughs mold after placing 24-26 hours, then naturally dry 38-40 hours;
(3)The glass horizontal annealing furnace dried is sent into kiln with Quartz Ceramic Roller and begins to warm up heating, first through 2.2-2.8 hours Time by sintering temperature slowly after 0 DEG C rises to 400 DEG C, then sintering temperature is risen to from 400 DEG C within 5 hour time It 1180-1200 DEG C, maintains this temperature to stop heating after 26-27 hours, glass horizontal annealing furnace is obtained after being gradually cooled to room temperature With the blank material of Quartz Ceramic Roller;
(4)The blank material of glass horizontal annealing furnace Quartz Ceramic Roller is sent into cylindrical grinder, outer circle is milled to predetermined size i.e. Obtain finished product.
The present invention further technical solution be:
Step(3)The kiln is that shuttle kiln occurs for coal gas.
Step(3)Sintering temperature in the kiln is 1190 DEG C, and the total time of sintering is 26.5 hours.
The beneficial effects of the invention are as follows:A kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller is provided, it should Production method has using series of advantages such as few, simple for process, the pollution-free waste discharge of equipment, good product qualities;Product Glass horizontal annealing furnace Quartz Ceramic Roller has excellent hot property, chemical stability and electrical insulating property at 1200 DEG C or less Can, it is used mainly as glass horizontal annealing furnace transmission product.
Specific implementation mode
The present invention is further described by following embodiment.
Embodiment 1:
It is 0.40% nanometre glue, 0.20% ammonium persulfate, 0.20% tetramethyl second two that total amount will will be first accounted in agitator tank Amine, 0.20% polyethylene glycol 200 are added in agitator tank, are uniformly mixed under room temperature, then will account for 50-80 mesh of the total amount for 30% Vitreous silica silicon powder accounts for that 120-140 mesh vitreous silicas silicon powder that total amount is 38%, to account for the 180-200 mesh that total amount is 26% molten Fused silica silicon powder accounts for boron carbide that total amount is 4%, accounts for the silicon nitride that total amount is 1% and be sent into ball mill ball milling 1.8 hours, will stir It mixes and ball mill is added after the mixture in tank is heated to 30 DEG C, blending is uniform;Material in ball mill is filled into glass horizontal Annealing furnace quartz-ceramics roller mould is taken off using the method cast molding shaken in casting after then pressurization is placed 24 hours Remove mold, then naturally dry 40 hours;The glass horizontal annealing furnace dried is sent into kiln with Quartz Ceramic Roller and begins to warm up liter Temperature, it is first through 2.2 hours time that sintering temperature is slowly warm by sintering after 0 DEG C rises to 400 DEG C, then within 5 hour time Degree rises to 1180 DEG C from 400 DEG C, maintains this temperature to stop heating after 27 hours, glass horizontal steel is obtained after being gradually cooled to room temperature Change the blank material of stove Quartz Ceramic Roller;The blank material of glass horizontal annealing furnace Quartz Ceramic Roller is sent into cylindrical grinder, it will Outer circle is milled to predetermined size and gets product.
Embodiment 2:
It is 0.40% nanometre glue, 0.20% ammonium persulfate, 0.20% tetramethyl second two that total amount will will be first accounted in agitator tank Amine, 0.20% polyethylene glycol 200 are added in agitator tank, are uniformly mixed under room temperature, then will account for 50-80 mesh of the total amount for 31% Vitreous silica silicon powder accounts for that 120-140 mesh vitreous silicas silicon powder that total amount is 37%, to account for the 180-200 mesh that total amount is 26% molten Fused silica silicon powder accounts for boron carbide that total amount is 4%, accounts for the silicon nitride that total amount is 1% and be sent into ball mill ball milling 1.9 hours, will stir It mixes and ball mill is added after the mixture in tank is heated to 32.5 DEG C, blending is uniform;Material in ball mill is filled into bath of glass Flat annealing furnace quartz-ceramics roller mould, using the method cast molding shaken in casting, then pressurization is placed 24-26 hours After slough mold, then naturally dry 39 hours;The glass horizontal annealing furnace Quartz Ceramic Roller dried feeding kiln is started to add Heat heating, first through 2.5 hours time by sintering temperature slowly after 0 DEG C rises to 400 DEG C, then will be burnt within 5 hour time Junction temperature rises to 1190 DEG C from 400 DEG C, maintains this temperature to stop heating after 26.5 hours, glass is obtained after being gradually cooled to room temperature The blank material of horizontal annealing furnace Quartz Ceramic Roller;The blank material of glass horizontal annealing furnace Quartz Ceramic Roller is sent into peripheral milling Bed, is milled to predetermined size by outer circle and gets product.
Embodiment 3:
It is 0.40% nanometre glue, 0.20% ammonium persulfate, 0.20% tetramethyl second two that total amount will will be first accounted in agitator tank Amine, 0.20% polyethylene glycol 200 are added in agitator tank, are uniformly mixed under room temperature, then will account for 50-80 mesh of the total amount for 32% Vitreous silica silicon powder accounts for that 120-140 mesh vitreous silicas silicon powder that total amount is 36%, to account for the 180-200 mesh that total amount is 26% molten Fused silica silicon powder accounts for boron carbide that total amount is 4%, accounts for the silicon nitride that total amount is 1% and be sent into ball mill ball milling 2.0 hours, will stir It mixes and ball mill is added after the mixture in tank is heated to 35 DEG C, blending is uniform;Material in ball mill is filled into glass horizontal Annealing furnace quartz-ceramics roller mould, using the method cast molding shaken in casting, after then pressurization is placed 24-26 hours Slough mold, then naturally dry 40 hours;The glass horizontal annealing furnace dried is sent into kiln with Quartz Ceramic Roller to begin to warm up Heating, first through 2.2-2.8 hour time by sintering temperature slowly after 0 DEG C rises to 400 DEG C, then the general within 5 hour time Sintering temperature rises to 1200 DEG C from 400 DEG C, maintains this temperature to stop heating after 26 hours, glass is obtained after being gradually cooled to room temperature The blank material of horizontal annealing furnace Quartz Ceramic Roller;The blank material of glass horizontal annealing furnace Quartz Ceramic Roller is sent into peripheral milling Bed, is milled to predetermined size by outer circle and gets product.

Claims (3)

1. a kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller, composition of raw materials is count by weight percentage:50- 80 mesh vitreous silica silicon powder 30-32%, 120-140 mesh vitreous silica silicon powder 36-38%, 180-200 mesh vitreous silica silicon are micro- Powder 26%, boron carbide 4%, silicon nitride 1%, nanometre glue 0.40%, ammonium persulfate 0.20%, tetramethylethylenediamine 0.20%, polyethylene glycol 200 0.20%;It is characterized in that:
(1)Stirring first is added in the nanometre glue of formula ratio, ammonium persulfate, tetramethylethylenediamine, polyethylene glycol 200 in agitator tank It in tank, is uniformly mixed under room temperature, then by the 50-80 mesh vitreous silicas silicon powder of formula ratio, 120-140 mesh vitreous silica silicon Micro mist, 180-200 mesh vitreous silicas silicon powder, boron carbide, silicon nitride are sent into ball mill ball milling 1.8-2.0 hours, by agitator tank In mixture be heated to 30-35 DEG C after be added ball mill, blending is uniform;
(2)Material in ball mill is filled into glass horizontal annealing furnace quartz-ceramics roller mould, is shaken using in casting Method cast molding, then pressurization sloughs mold after placing 24-26 hours, then naturally dry 38-40 hours;
(3)The glass horizontal annealing furnace dried is sent into kiln with Quartz Ceramic Roller and begins to warm up heating, first through 2.2-2.8 hours Time by sintering temperature slowly after 0 DEG C rises to 400 DEG C, then sintering temperature is risen to from 400 DEG C within 5 hour time It 1180-1200 DEG C, maintains this temperature to stop heating after 26-27 hours, glass horizontal annealing furnace is obtained after being gradually cooled to room temperature With the blank material of Quartz Ceramic Roller;
(4)The blank material of glass horizontal annealing furnace Quartz Ceramic Roller is sent into cylindrical grinder, outer circle is milled to predetermined size i.e. Obtain finished product.
2. a kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller according to claim 1, it is characterized in that:Step Suddenly(3)The kiln is that shuttle kiln occurs for coal gas.
3. a kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller according to claim 1, it is characterized in that:Step Suddenly(3)Sintering temperature in the kiln is 1190 DEG C, and the total time of sintering is 26.5 hours.
CN201611133365.7A 2016-12-10 2016-12-10 A kind of production method of glass horizontal annealing furnace Quartz Ceramic Roller Pending CN108610029A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111377720A (en) * 2020-02-28 2020-07-07 徐州华焰特种陶瓷有限公司 High-temperature-resistant low-expansion ceramic material and preparation method thereof
CN112919891A (en) * 2021-03-02 2021-06-08 徐州亚苏尔高新材料有限公司 Environment-friendly high-new powder material for ceramic roller and preparation method thereof
CN114031384A (en) * 2021-11-16 2022-02-11 徐州康纳高新材料科技有限公司 Preparation method of quartz ceramic hollow roller for toughened glass heating furnace

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111377720A (en) * 2020-02-28 2020-07-07 徐州华焰特种陶瓷有限公司 High-temperature-resistant low-expansion ceramic material and preparation method thereof
CN112919891A (en) * 2021-03-02 2021-06-08 徐州亚苏尔高新材料有限公司 Environment-friendly high-new powder material for ceramic roller and preparation method thereof
CN114031384A (en) * 2021-11-16 2022-02-11 徐州康纳高新材料科技有限公司 Preparation method of quartz ceramic hollow roller for toughened glass heating furnace

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