CN113979709A - Green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous-resistant adhesive cement and preparation method thereof - Google Patents
Green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous-resistant adhesive cement and preparation method thereof Download PDFInfo
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- 239000004568 cement Substances 0.000 title claims abstract description 27
- 239000000853 adhesive Substances 0.000 title claims abstract description 25
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 25
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000010276 construction Methods 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 239000004576 sand Substances 0.000 claims abstract description 12
- 239000002699 waste material Substances 0.000 claims description 39
- 239000003292 glue Substances 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 229910000831 Steel Inorganic materials 0.000 claims description 15
- 239000010959 steel Substances 0.000 claims description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 14
- 239000004567 concrete Substances 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 239000002893 slag Substances 0.000 claims description 12
- 239000004115 Sodium Silicate Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 10
- 239000010440 gypsum Substances 0.000 claims description 9
- 229910052602 gypsum Inorganic materials 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 8
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 6
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 239000011449 brick Substances 0.000 claims description 6
- 239000001110 calcium chloride Substances 0.000 claims description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 6
- 235000011148 calcium chloride Nutrition 0.000 claims description 6
- 239000004281 calcium formate Substances 0.000 claims description 6
- 229940044172 calcium formate Drugs 0.000 claims description 6
- 235000019255 calcium formate Nutrition 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229920000609 methyl cellulose Polymers 0.000 claims description 6
- 239000001923 methylcellulose Substances 0.000 claims description 6
- 235000010981 methylcellulose Nutrition 0.000 claims description 6
- 229960002900 methylcellulose Drugs 0.000 claims description 6
- 238000005065 mining Methods 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 239000000176 sodium gluconate Substances 0.000 claims description 6
- 235000012207 sodium gluconate Nutrition 0.000 claims description 6
- 229940005574 sodium gluconate Drugs 0.000 claims description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 6
- 235000019794 sodium silicate Nutrition 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- 239000004111 Potassium silicate Substances 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 235000010755 mineral Nutrition 0.000 claims description 4
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 4
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000378 calcium silicate Substances 0.000 claims description 3
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 3
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims description 3
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 3
- 235000019792 magnesium silicate Nutrition 0.000 claims description 3
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000011810 insulating material Substances 0.000 abstract description 8
- 230000032683 aging Effects 0.000 abstract description 3
- 239000002344 surface layer Substances 0.000 abstract description 3
- 229910021487 silica fume Inorganic materials 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 238000000227 grinding Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 239000010881 fly ash Substances 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 5
- 229910000720 Silicomanganese Inorganic materials 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 230000002411 adverse Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011489 building insulation material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 210000000080 chela (arthropods) Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920001821 foam rubber Polymers 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 230000005358 geomagnetic field Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229940023462 paste product Drugs 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/144—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
- C04B2111/00646—Masonry mortars
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/76—Use at unusual temperatures, e.g. sub-zero
Abstract
The invention relates to a green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous-resistant adhesive cement which comprises, by weight, 24-36 parts of an inorganic viscous-resistant coupling agent, 16-24 parts of tailing sand, 16-24 parts of urban construction garbage and 24-36 parts of T-series novel water-based special adhesive. The invention also discloses a preparation method of the adhesive-resistant adhesive cement, which has strong chelating capacity and holding capacity and stable material structure, effectively avoids the aging and falling of the heat-insulating material, and greatly prolongs the service life of the heat-insulating material, thereby realizing the same service life of the heat-insulating material and the decorative surface layer as the building main body.
Description
Technical Field
The invention belongs to the technical field of bonding materials, and particularly relates to green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement and a preparation method thereof.
Background
At present, the design service life of the external wall heat insulation technology at home and abroad is only 25 years, the actual service life is shorter, and the design service life is far away from the service life of a main structure of a building of 50-70 years. Moreover, due to the characteristics of the materials, construction measures and other problems, the external thermal insulation construction process for the external wall generally generates the phenomena of cracking, hollowing and falling in a short time. After 10 years, China faces a large-area energy-saving reconstruction period of external heat preservation of existing buildings, billions of huge maintenance and replacement cost are generated each year, billions of cubic meters of building garbage which is difficult to degrade is generated, and the environment is adversely affected. Therefore, the method has great adverse effects on the development of the civilian and economic aspects and the social harmony. Therefore, the falling safety problem of the thermal insulation material outside the wall body, the fire safety problem, the environmental protection safety problem, and the safety problems of waterproof and seepage-proof wall body and other potential thermal insulation material engineering applications.
In the current social development process, the trends and requirements of novel green environmental protection concepts, environmental protection awareness and environmental protection are gradually enhanced; the new materials and the new processes for the wall insulation of green building, which are safe, fireproof, energy-saving and environment-friendly, and the construction organization measures of the integration of the comprehensive structure are more and more diversified, and are developing towards standardization, normalization and conservation, and the state also puts higher requirements on the industry standards and the standard measures of the green, safe, energy-saving and environment-friendly building insulation materials.
In the prior art, some studies on the adhesive cement, such as the formula of an environment-friendly alkali-resistant adhesive mortar in Chinese patent No. CN201410386071.X and a waterproof adhesive mortar in CN108101423A, have the following problems,
1. the bonding strength is low;
2. the weather resistance is poor;
3. the aging resistance is poor;
4. the freeze-thaw resistance is poor;
5. water-proof and water-proof;
6. the heat insulating material is easy to be hollow, cracked and fall off.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides the green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscose glue, which has strong chelating capacity and holding capacity, stable material structure, effectively avoids the aging and falling of the heat-insulating material, greatly prolongs the service life of the heat-insulating material, and realizes the same service life of the heat-insulating material and the decorative surface layer as the building main body.
The technical scheme adopted by the invention is as follows:
the invention provides a green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement which comprises the following components in parts by weight,
further, the inorganic viscous-resistant coupling agent comprises the following components in percentage by weight,
further, the silicate is two or more of calcium silicate, magnesium silicate, iron silicate, aluminum silicate, sodium silicate and potassium silicate.
Further, the industrial silica fume is waste silica fume from the production of silicomanganese, ferrosilicon or silicocalcium.
Further, the industrial desulfurization gypsum is one of phosphogypsum, sulfur gypsum and salt gypsum.
Further, the tailing sand is waste material in the process of mining iron ore, copper ore or gold ore mineral resources.
Furthermore, the urban construction waste is waste bricks and tiles and concrete materials which are dismantled during urban construction.
Further, the T series novel water-based special glue comprises the following components in percentage by weight,
further, the preparation method of the T series novel water-based special glue comprises the following steps of S1, adding a certain amount of deionized water into a container, adding polyvinyl alcohol, and heating while stirring; s2 adding ethylene glycol, glycerol, sodium silicate, calcium formate, calcium chloride, sodium hexametaphosphate, methyl cellulose, sodium gluconate and the rest deionized water, and stirring while keeping the temperature; and S3, cooling for later use.
The invention also discloses a preparation method of the green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous-resistance adhesive cement, which comprises the following steps of (1) weighing each component according to a preset proportion; (2) preparing T series novel water-based special glue; (3) respectively crushing the tailing sand, the urban construction garbage and the waste steel slag to 200-mesh and 1000-mesh; (4) mixing the T series novel water-based special glue and other components uniformly.
The invention has the beneficial effects that:
the raw materials of the invention adopt green energy-saving low-carbon environment-friendly inorganic viscosity-resistance coupling agent which takes industrial byproducts such as fly ash, waste steel slag and industrial silica fume as main materials and green environment-friendly T series novel water-based special glue which can be used as food additive, and the product has the following characteristics: green and environment-friendly, safe application, high bonding strength, good waterproof and waterproof effects, good weather resistance, good freeze-thaw resistance, simple preparation process, easy operation by common workers, easy control of the temperature of the preparation process, low cost and easy purchase of raw materials.
The invention has the advantages of simple preparation method, easily obtained raw materials, comprehensive reutilization of waste resources, waste material utilization, low cost, high bonding strength and good flame retardant effect.
Drawings
FIG. 1 is a component list of example 1 of the present invention;
FIG. 2 is a component list of example 2 of the present invention;
FIG. 3 is a component list of example 3 of the present invention;
FIG. 4 is a list of components of example 4 of the present invention.
Detailed Description
The invention will be described with reference to fig. 1-4 and the examples.
Example 1
The embodiment provides a green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement which comprises the following components in parts by weight,
the inorganic viscous-resistant coupling agent comprises the following components in percentage by weight,
the silicate is a mixture of calcium silicate and magnesium silicate.
The industrial silica fume is the waste silica fume from the production of silicomanganese, ferrosilicon or silicocalcium.
The tailings are waste materials in the process of mining iron ore resources.
The urban construction garbage is a waste brick and tile and concrete material which are removed during urban construction
The T series novel water-based special glue comprises the following components in percentage by weight,
the preparation method of the viscous drag glue paste comprises the following steps: (1) weighing the components according to a preset proportion; (2) preparing T series novel water-based special glue; (3) respectively crushing the tailing sand, the urban construction waste and the waste steel slag to 800 meshes; (4) mixing the T series novel water-based special glue and other components uniformly.
S1, adding deionized water accounting for 50% of the total deionized amount into a container, adding polyvinyl alcohol, and heating to 93 ℃ while stirring, wherein the stirring speed is 50 r/min; and S2, adding ethylene glycol, glycerol, sodium silicate, calcium formate, calcium chloride, sodium hexametaphosphate, methyl cellulose, sodium gluconate and the rest deionized water, and stirring for 33 minutes at the stirring speed of 40 revolutions per minute. And S3, cooling to 60 ℃ for later use.
The preparation method of the inorganic viscosity-resistance coupling agent comprises the following steps: s1, weighing silicate, fly ash, waste steel slag, industrial silica fume and sulfur gypsum according to a preset proportion; s2 grinding and mixing the components weighed in S1. The grain diameter after grinding is larger than 200 meshes and smaller than 1000 meshes.
Example 2
The embodiment provides a green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement which comprises the following components in parts by weight,
the inorganic viscous-resistant coupling agent comprises the following components in percentage by weight,
the silicate is a mixture of iron silicate and aluminum silicate.
The industrial silica fume is the waste silica fume from the production of silicomanganese, ferrosilicon or silicocalcium.
The tailing sand is waste material in the process of mining copper ore mineral resources.
The urban construction garbage is waste bricks and tiles and concrete materials which are dismantled during urban construction.
The T series novel water-based special glue comprises the following components in percentage by weight,
the preparation method of the viscous drag glue paste comprises the following steps: (1) weighing the components according to a preset proportion; (2) preparing T series novel water-based special glue; (3) respectively crushing the tailing sand, the urban construction waste and the waste steel slag into 200 meshes; (4) mixing the T series novel water-based special glue and other components uniformly.
S1, adding deionized water accounting for 40% of the total deionized amount into a container, adding polyvinyl alcohol, and heating to 91 ℃ while stirring, wherein the stirring speed is 40 r/min; and S2, adding ethylene glycol, glycerol, sodium silicate, calcium formate, calcium chloride, sodium hexametaphosphate, methyl cellulose, sodium gluconate and the rest deionized water, and stirring for 30 minutes at the stirring speed of 45 revolutions per minute. And S3 is cooled to 65 ℃ for standby.
The preparation method of the inorganic viscosity-resistance coupling agent comprises the following steps: s1, weighing silicate, fly ash, waste steel slag, industrial silica fume and phosphogypsum according to a preset proportion; s2 grinding and mixing the components weighed in S1. The grain diameter after grinding is larger than 200 meshes and smaller than 1000 meshes.
Example 3
The embodiment provides a green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement which comprises the following components in parts by weight,
the inorganic viscous-resistant coupling agent comprises the following components in percentage by weight,
the silicate is a mixture of sodium silicate and potassium silicate.
The industrial silica fume is the waste silica fume from the production of silicomanganese, ferrosilicon or silicocalcium.
The tailings sand is the waste material in the mining of gold ore mineral resources.
The urban construction garbage is waste bricks and tiles and concrete materials which are dismantled during urban construction.
The T series novel water-based special glue comprises the following components in percentage by weight,
the preparation method of the viscous drag glue paste comprises the following steps: (1) weighing the components according to a preset proportion; (2) preparing T series novel water-based special glue; (3) respectively crushing the tailing sand, the urban construction waste and the waste steel slag to 1000 meshes; (4) mixing the T series novel water-based special glue and other components uniformly.
S1, adding deionized water accounting for 60% of the total deionized amount into a container, adding polyvinyl alcohol, and heating to 95 ℃ while stirring, wherein the stirring speed is 60 r/min; and S2, adding ethylene glycol, glycerol, sodium silicate, calcium formate, calcium chloride, sodium hexametaphosphate, methyl cellulose, sodium gluconate and the rest deionized water, and stirring for 40 minutes at the stirring speed of 60 revolutions per minute. And S3 is cooled to 63 ℃ for standby.
The preparation method of the inorganic viscosity-resistance coupling agent comprises the following steps: s1, weighing silicate, fly ash, waste steel slag, industrial silica fume and salt gypsum according to a preset proportion; s2 grinding and mixing the components weighed in S1. The grain diameter after grinding is larger than 200 meshes and smaller than 1000 meshes.
Example 4
The embodiment provides a green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement which comprises the following components in parts by weight,
the inorganic viscous-resistant coupling agent comprises the following components in percentage by weight,
the silicate is a mixture of sodium silicate, iron silicate and potassium silicate.
The industrial silica fume is the waste silica fume from the production of silicomanganese, ferrosilicon or silicocalcium.
The tailings are waste materials in the process of mining iron ore resources.
The urban construction garbage is waste bricks and tiles and concrete materials which are dismantled during urban construction.
The T series novel water-based special glue comprises the following components in percentage by weight,
the preparation method of the viscous drag glue paste comprises the following steps: (1) weighing the components according to a preset proportion; (2) preparing T series novel water-based special glue; (3) respectively crushing the tailing sand, the urban construction waste and the waste steel slag into 400 meshes; (4) mixing the T series novel water-based special glue and other components uniformly.
S1, adding deionized water accounting for 43% of the total deionized amount into a container, adding polyvinyl alcohol, and heating to 94 ℃ while stirring, wherein the stirring speed is 52 r/min; and S2, adding ethylene glycol, glycerol, sodium silicate, calcium formate, calcium chloride, sodium hexametaphosphate, methyl cellulose, sodium gluconate and the rest deionized water, and stirring for 37 minutes at the stirring speed of 50 revolutions per minute. And S3 is cooled to 63 ℃ for standby.
The preparation method of the inorganic viscosity-resistance coupling agent comprises the following steps: s1, weighing silicate, fly ash, waste steel slag, industrial silica fume and sulfur gypsum according to a preset proportion; s2 grinding and mixing the components weighed in S1. The grain diameter after grinding is larger than 200 meshes and smaller than 1000 meshes.
The formula mechanism of the invention is as follows: the invention relates to a viscous-resistant adhesive cement, which is prepared from materials such as an inorganic viscous-resistant coupling agent, a T-series novel water-based special adhesive and the like by utilizing a micro-molecular nano chelating bonding technology, and enables a building main body and different types of insulation boards to be bonded in situ. The nanometer chelating binding material with super-strong permeability can quickly permeate, and the homotopic material can be quickly coagulated into a whole just like catching a game object by crab pincers.
The adhesive-resistant adhesive cement is suitable for bonding and flame retarding various heat-insulating materials.
Through tests, the performances of the products of the embodiments 1 to 4 of the invention are as follows, and the bonding strength required by the national standard of the bonding mortar is as follows: greater than 0.6 megapascals (Mpa); the adhesive resistance adhesive cement of the product in the embodiment 1 of the invention is detected by the national building energy conservation quality supervision and inspection center, and the tensile strength result is 1.28 megapascals (Mpa).
The invention adopts the staggered joint bonding installation form during the manufacturing and production, so as to block the air circulation and the cold and hot bridge, the beam column connection and the fastening adopt the bridge-cut type screw joint, and the micro-expansion foam rubber of the engineering is matched, so as to thoroughly block the cold and hot bridge source. The joint of the novel anti-corrosion adhesive paste and the main structure body is bonded by coupling the novel anti-corrosion adhesive paste and the novel material, so that firm bonding is ensured, the steel structure is protected from corrosion and sealing, the building integrity is enhanced, and the service life is prolonged.
The outer wall (inner and outer) surface layers are all made of lightweight concrete as protective layers. The outer wall surface protective layer is made of concrete square T-series lightweight concrete with the thickness of 40 mm, and the inner wall surface protective layer is made of concrete square T-series lightweight concrete with the thickness of 20 mm. The inner and outer wall protective layers are both of a special alkali-resistant and tension-resistant high-strength weighted double-layer glass fiber net reinforcing structure, and the structure is green, safe and environment-friendly. And a steel wire mesh reinforced structure is not used, so that secondary damage to a human body caused by shielding the geomagnetic field by the steel wire mesh reinforced structure is avoided. (note: the concrete square series T series lightweight concrete, can use waste and old waste resources such as fly ash, various desulfurized gypsum, waste steel slag, tailing sand, etc.)
The adhesive-resistant adhesive cement product is widely applicable to the adhesion of the insulation boards of the external wall insulation engineering of newly-built buildings and existing buildings.
The performance indexes of the invention are as follows:
the invention discloses a shape of a viscous resistance adhesive paste product, which is composed of dry powder inorganic viscous resistance coupling agent and liquid T series novel water-based special adhesive material which are premixed and mixed in a factory, and can be used only by uniformly stirring according to the use specification on a construction site.
The performance index of the viscous resistance adhesive paste is shown in table 1.
At present, the technical scheme of the invention has been subjected to a pilot plant test, namely a small-scale test of the product before large-scale mass production; after the pilot test is finished, the investigation for the use of the user is carried out in a small range, and the investigation result shows that the satisfaction degree of the user is higher; the preparation of formal commissioning for industrialization (including intellectual property risk early warning research) has now begun.
The above description is only a preferred embodiment of the present invention, and all equivalent changes or modifications of the structure, characteristics and principles described in the present invention are included in the scope of the present invention.
Claims (9)
1. A green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement is characterized by comprising the following components in parts by weight,
2. the green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous-resistant adhesive cement as claimed in claim 1, characterized in that the inorganic viscous-resistant coupling agent comprises the following components in percentage by weight,
3. the environment-friendly energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement as claimed in claim 2, characterized in that the silicate is two or more of calcium silicate, magnesium silicate, iron silicate, aluminum silicate, sodium silicate and potassium silicate.
4. The green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement as claimed in claim 2, characterized in that the industrial desulfurized gypsum is one of phosphogypsum, thiogypsum and salt gypsum.
5. The environment-friendly energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement as claimed in claim 1, characterized in that the tailing sand is waste material in mining of mineral resources of iron ore, copper ore or gold ore.
6. The environment-friendly energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement as claimed in claim 1, characterized in that the urban construction waste is waste bricks and tiles and concrete materials which are demolished during urban construction.
7. The green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement as claimed in claim 1, characterized in that the T-series novel water-based special cement comprises the following components in percentage by weight,
8. the green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous cement as claimed in claim 7, characterized in that the preparation method of the T-series novel water-based special cement comprises the steps of S1 adding a certain amount of deionized water into a container, adding polyvinyl alcohol while stirring and heating; s2 adding ethylene glycol, glycerol, sodium silicate, calcium formate, calcium chloride, sodium hexametaphosphate, methyl cellulose, sodium gluconate and the rest deionized water, and stirring while keeping the temperature; and S3, cooling for later use.
9. A preparation method of green energy-saving low-carbon environment-friendly T-series innovative multifunctional viscous-resistance adhesive cement is characterized by comprising the following steps of (1) weighing each component according to a preset proportion; (2) preparing T series novel water-based special glue; (3) respectively crushing the tailing sand, the urban construction garbage and the waste steel slag to 200-mesh and 1000-mesh; (4) mixing the T series novel water-based special glue and other components uniformly.
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