CN113978065A - 增强型玻璃钢拉挤型材 - Google Patents
增强型玻璃钢拉挤型材 Download PDFInfo
- Publication number
- CN113978065A CN113978065A CN202111113009.XA CN202111113009A CN113978065A CN 113978065 A CN113978065 A CN 113978065A CN 202111113009 A CN202111113009 A CN 202111113009A CN 113978065 A CN113978065 A CN 113978065A
- Authority
- CN
- China
- Prior art keywords
- curing agent
- glass fiber
- reinforced plastic
- parts
- section bar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003365 glass fiber Substances 0.000 title claims abstract description 30
- 229920002430 Fibre-reinforced plastic Polymers 0.000 title claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 40
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 32
- 239000011152 fibreglass Substances 0.000 claims abstract description 21
- 239000011159 matrix material Substances 0.000 claims abstract description 21
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003063 flame retardant Substances 0.000 claims abstract description 20
- 239000003822 epoxy resin Substances 0.000 claims abstract description 19
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 19
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 16
- 239000012170 montan wax Substances 0.000 claims abstract description 16
- 239000011241 protective layer Substances 0.000 claims abstract description 16
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 16
- 239000012790 adhesive layer Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 13
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004593 Epoxy Substances 0.000 claims abstract description 12
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 11
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004744 fabric Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 10
- 239000000758 substrate Substances 0.000 abstract description 7
- 230000036541 health Effects 0.000 abstract description 4
- 230000001172 regenerating effect Effects 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 4
- 239000011347 resin Substances 0.000 abstract description 4
- 238000005452 bending Methods 0.000 abstract description 3
- 230000001902 propagating effect Effects 0.000 abstract description 3
- 239000003292 glue Substances 0.000 description 15
- 230000006872 improvement Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/04—Wing frames not characterised by the manner of movement
- E06B3/06—Single frames
- E06B3/08—Constructions depending on the use of specified materials
- E06B3/20—Constructions depending on the use of specified materials of plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/536—Hardness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
本发明公开了增强型玻璃钢拉挤型材，其特征在于，包括基体、粘接层和保护层，所述保护层通过粘接层粘接在基体的外表面上；所述基体的重量组分为：饱和环氧树脂8‑12、固化剂7‑13、玻璃纤维60‑70、褐煤蜡0.1‑0.3、阻燃剂6‑8，其余为碳酸钙。本发明该型材不需要采用进口的表面毡，并且甲基四氢苯酐和体环氧固化剂K54组合的固化剂成本更低，降低了型材的价格，采用了环氧树脂材料的型材的弯曲强度和巴氏硬度等指标优于不饱和树脂材料的型材，同时设置了银离子抗菌面料的保护层1可防止细菌在基体3上再生和繁殖，避免人们使用门窗时接触到较多细菌，危害人体健康，进而使得该型材具有较好的稳定性，硬度，韧性、阻燃性和抗菌性。
Description
技术领域
本发明涉及拉挤型玻璃钢技术领域，尤其涉及增强型玻璃钢拉挤型材。
背景技术
拉挤型玻璃钢是以玻璃纤维为主要增强材料，树脂作为粘接剂，经拉挤成型加工而制成复合材料，连续拉挤成型加工出玻璃钢拉挤格栅、棒材、条板、管材、角钢、槽钢等各种型材。
现有技术中，拉挤型玻璃钢一般都是采用不饱和聚酯树脂通过拉挤制成，但该玻璃钢型材脆性较大、韧性不够、横向强度低且价格较高，同时拉挤型玻璃钢一般作为门窗使用的材料，表面容易堆积灰尘，进而容易滋生细菌。
发明内容
本发明提供了增强型玻璃钢拉挤型材，以解决上述背景技术中提出的现有技术中，拉挤型玻璃钢一般都是采用不饱和聚酯树脂通过拉挤制成，但该玻璃钢型材脆性较大、韧性不够、横向强度低且价格较高，同时拉挤型玻璃钢一般作为门窗使用的材料，表面容易堆积灰尘，进而容易滋生细菌问题。
为了实现上述目的，本发明采用了如下技术方案：
增强型玻璃钢拉挤型材，其特征在于，包括基体、粘接层和保护层，所述保护层通过粘接层粘接在基体的外表面上；
所述基体的重量组分为：饱和环氧树脂8-12、固化剂7-13、玻璃纤维60-70、褐煤蜡0.1-0.3、阻燃剂6-8，其余为碳酸钙。
作为本技术方案的进一步改进方案：所述基体的重量组分为：饱和环氧树脂8、固化剂7、玻璃纤维60、褐煤蜡0.1、阻燃剂6，其余为碳酸钙。
作为本技术方案的进一步改进方案：所述基体的重量组分为：饱和环氧树脂10、固化剂10、玻璃纤维65、褐煤蜡0.2、阻燃剂7，其余为碳酸钙。
作为本技术方案的进一步改进方案：所述基体的重量组分为：饱和环氧树脂12、固化剂13、玻璃纤维70、褐煤蜡0.3、阻燃剂4，其余为碳酸钙。
作为本技术方案的进一步改进方案：所述固化剂采用甲基四氢苯酐：体环氧固化剂K54为9:1混合而成。
作为本技术方案的进一步改进方案：所述固化剂采用甲基四氢苯酐：体环氧固化剂K54为8:2混合而成。
作为本技术方案的进一步改进方案：所述固化剂采用甲基四氢苯酐：体环氧固化剂K54为7:3混合而成。
作为本技术方案的进一步改进方案：所述粘接层采用水溶性酚醛树脂粘接剂。
作为本技术方案的进一步改进方案：所述阻燃剂采用氢氧化铝材料。
作为本技术方案的进一步改进方案：所述保护层采用银离子抗菌面料。
与现有技术相比，本发明的有益效果是：
本发明首先将饱和环氧树脂、固化剂、褐煤蜡、阻燃剂和碳酸钙通过搅拌制成胶液，然后将玻璃纤维浸渍在胶液中，使得玻璃纤维和胶液达到很好的凝胶状态，再将浸胶完成的胶液与玻璃纤维混合物进入加热的成型模具中，在拉挤机的牵引下即可得到基体3，最后在基体3的表面上涂刷粘接层2，将银离子抗菌面料粘接固定在基体3的表面即可完成产品的制作，该型材不需要采用进口的表面毡，并且甲基四氢苯酐和体环氧固化剂K54组合的固化剂成本更低，降低了型材的价格，采用了环氧树脂材料的型材的弯曲强度和巴氏硬度等指标优于不饱和树脂材料的型材，同时设置了银离子抗菌面料的保护层1可防止细菌在基体3上再生和繁殖，避免人们使用门窗时接触到较多细菌，危害人体健康，进而使得该型材具有较好的稳定性，硬度，韧性、阻燃性和抗菌性。
上述说明仅是本发明技术方案的概述，为了能够更清楚了解本发明的技术手段，并可依照说明书的内容予以实施，以下以本发明的较佳实施例并配合附图详细说明如后。本发明的具体实施方式由以下实施例及其附图详细给出。
附图说明
此处所说明的附图用来提供对本发明的进一步理解，构成本申请的一部分，本发明的示意性实施例及其说明用于解释本发明，并不构成对本发明的不当限定。在附图中：
图1为本发明提出的增强型玻璃钢拉挤型材的结构示意图。
附图中，各标号所代表的部件列表如下：
1基体、2粘接层、3保护层。
具体实施方式
以下结合附图对本发明的原理和特征进行描述，所举实例只用于解释本发明，并非用于限定本发明的范围。在下列段落中参照附图以举例方式更具体地描述本发明。根据下面说明和权利要求书，本发明的优点和特征将更清楚。需说明的是，附图均采用非常简化的形式且均使用非精准的比例，仅用以方便、明晰地辅助说明本发明实施例的目的。
需要说明的是，当组件被称为“固定于”另一个组件，它可以直接在另一个组件上或者也可以存在居中的组件。当一个组件被认为是“连接”另一个组件，它可以是直接连接到另一个组件或者可能同时存在居中组件。当一个组件被认为是“设置于”另一个组件，它可以是直接设置在另一个组件上或者可能同时存在居中组件。本文所使用的术语“垂直的”、“水平的”、“左”、“右”以及类似的表述只是为了说明的目的。
除非另有定义，本文所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同。本文中在本发明的说明书中所使用的术语只是为了描述具体的实施例的目的，不是旨在于限制本发明。本文所使用的术语“及/或”包括一个或多个相关的所列项目的任意的和所有的组合。
请参阅图1，本发明实施例中，增强型玻璃钢拉挤型材，包括基体3、粘接层2和保护层1，保护层1通过粘接层2粘接在基体3的外表面上；
基体3的重量组分为：饱和环氧树脂8-12、固化剂7-13、玻璃纤维60-70、褐煤蜡0.1-0.3、阻燃剂6-8，其余为碳酸钙，制作基体3首先将饱和环氧树脂、固化剂、褐煤蜡、阻燃剂和碳酸钙通过搅拌制成胶液，然后将玻璃纤维浸渍在胶液中，使得玻璃纤维和胶液达到很好的凝胶状态，再将浸胶完成的胶液与玻璃纤维混合物进入加热的成型模具中，在拉挤机的牵引下即可得到基体3，最后在基体3的表面上涂刷粘接层2，将银离子抗菌面料粘接固定在基体3的表面即可完成产品的制作。
优选地，基体3的重量组分为：饱和环氧树脂8、固化剂7、玻璃纤维60、褐煤蜡0.1、阻燃剂6，其余为碳酸钙。
优选地，基体3的重量组分为：饱和环氧树脂10、固化剂10、玻璃纤维65、褐煤蜡0.2、阻燃剂7，其余为碳酸钙。
优选地，基体3的重量组分为：饱和环氧树脂12、固化剂13、玻璃纤维70、褐煤蜡0.3、阻燃剂4，其余为碳酸钙。
优选地，固化剂采用甲基四氢苯酐：体环氧固化剂K54为9:1混合而成。
优选地，固化剂采用甲基四氢苯酐：体环氧固化剂K54为8:2混合而成。
优选地，固化剂采用甲基四氢苯酐：体环氧固化剂K54为7:3混合而成。
具体的，粘接层2采用水溶性酚醛树脂粘接剂，可更加牢固的将保护层1固定在基体3上。
具体的，阻燃剂采用氢氧化铝材料，可增加型材的阻燃性能。
具体的，保护层1采用银离子抗菌面料，银离子极易同其它物质相结合,使得细菌细胞膜内外的蛋白质凝固,从而阻断细菌细胞的呼吸和繁殖过，进而可防止细菌在基体3上再生和繁殖，避免人们使用门窗时接触到较多细菌，危害人体健康。
本发明的工艺成型过程是：
本发明首先将饱和环氧树脂、固化剂、褐煤蜡、阻燃剂和碳酸钙通过搅拌制成胶液，然后将玻璃纤维浸渍在胶液中，使得玻璃纤维和胶液达到很好的凝胶状态，再将浸胶完成的胶液与玻璃纤维混合物进入加热的成型模具中，在拉挤机的牵引下即可得到基体3，最后在基体3的表面上涂刷粘接层2，将银离子抗菌面料粘接固定在基体3的表面即可完成产品的制作，该型材不需要采用进口的表面毡，并且甲基四氢苯酐和体环氧固化剂K54组合的固化剂成本更低，降低了型材的价格，采用了环氧树脂材料的型材的弯曲强度和巴氏硬度等指标优于不饱和树脂材料的型材，同时设置了银离子抗菌面料的保护层1可防止细菌在基体3上再生和繁殖，避免人们使用门窗时接触到较多细菌，危害人体健康，进而使得该型材具有较好的稳定性，硬度，韧性、阻燃性和抗菌性。
以上所述，仅为本发明的较佳实施例而已，并非对本发明作任何形式上的限制；凡本行业的普通技术人员均可按说明书附图所示和以上所述而顺畅地实施本发明；但是,凡熟悉本专业的技术人员在不脱离本发明技术方案范围内，利用以上所揭示的技术内容而做出的些许更动、修饰与演变的等同变化，均为本发明的等效实施例；同时,凡依据本发明的实质技术对以上实施例所作的任何等同变化的更动、修饰与演变等，均仍属于本发明的技术方案的保护范围之内。
Claims (10)
1.增强型玻璃钢拉挤型材，其特征在于，包括基体(3)、粘接层(2)和保护层(1)，所述保护层(1)通过粘接层(2)粘接在基体(3)的外表面上；
所述基体(3)的重量组分为：饱和环氧树脂8-12、固化剂7-13、玻璃纤维60-70、褐煤蜡0.1-0.3、阻燃剂6-8，其余为碳酸钙。
2.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述基体(3)的重量组分为：饱和环氧树脂8、固化剂7、玻璃纤维60、褐煤蜡0.1、阻燃剂6，其余为碳酸钙。
3.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述基体(3)的重量组分为：饱和环氧树脂10、固化剂10、玻璃纤维65、褐煤蜡0.2、阻燃剂7，其余为碳酸钙。
4.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述基体(3)的重量组分为：饱和环氧树脂12、固化剂13、玻璃纤维70、褐煤蜡0.3、阻燃剂4，其余为碳酸钙。
5.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述固化剂采用甲基四氢苯酐：体环氧固化剂K54为9:1混合而成。
6.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述固化剂采用甲基四氢苯酐：体环氧固化剂K54为8:2混合而成。
7.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述固化剂采用甲基四氢苯酐：体环氧固化剂K54为7:3混合而成。
8.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述粘接层(2)采用水溶性酚醛树脂粘接剂。
9.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述阻燃剂采用氢氧化铝材料。
10.根据权利要求1所述的增强型玻璃钢拉挤型材，其特征在于，所述保护层(1)采用银离子抗菌面料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111113009.XA CN113978065A (zh) | 2021-09-23 | 2021-09-23 | 增强型玻璃钢拉挤型材 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111113009.XA CN113978065A (zh) | 2021-09-23 | 2021-09-23 | 增强型玻璃钢拉挤型材 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113978065A true CN113978065A (zh) | 2022-01-28 |
Family
ID=79736383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111113009.XA Pending CN113978065A (zh) | 2021-09-23 | 2021-09-23 | 增强型玻璃钢拉挤型材 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113978065A (zh) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105570657A (zh) * | 2014-10-09 | 2016-05-11 | 南京建辉复合材料有限公司 | 增强型玻璃钢拉挤型材 |
| CN106808762A (zh) * | 2015-12-02 | 2017-06-09 | 株洲时代新材料科技股份有限公司 | 一种高强度拉挤型材及其制备方法 |
| CN107083037A (zh) * | 2017-05-14 | 2017-08-22 | 南通德瑞森复合材料有限公司 | 一种新型无卤阻燃的玻璃钢模塑料制备方法 |
| CN107663365A (zh) * | 2017-11-17 | 2018-02-06 | 成都双瑞暖通设备有限公司 | 一种具有抗菌功能的玻璃钢 |
| CN107778802A (zh) * | 2017-11-17 | 2018-03-09 | 成都双瑞暖通设备有限公司 | 一种高强度玻璃钢配方 |
| CN109722058A (zh) * | 2017-10-31 | 2019-05-07 | 江苏创曦复合材料科技有限公司 | 一种玻璃钢拉挤阻燃树脂及其制备方法 |
| US20190270263A1 (en) * | 2016-06-15 | 2019-09-05 | Sp Advanced Engineering Materials Pvt. Ltd. | A composites product; a pultrusion continuous method for manufacturing thereof |
-
2021
- 2021-09-23 CN CN202111113009.XA patent/CN113978065A/zh active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105570657A (zh) * | 2014-10-09 | 2016-05-11 | 南京建辉复合材料有限公司 | 增强型玻璃钢拉挤型材 |
| CN106808762A (zh) * | 2015-12-02 | 2017-06-09 | 株洲时代新材料科技股份有限公司 | 一种高强度拉挤型材及其制备方法 |
| US20190270263A1 (en) * | 2016-06-15 | 2019-09-05 | Sp Advanced Engineering Materials Pvt. Ltd. | A composites product; a pultrusion continuous method for manufacturing thereof |
| CN107083037A (zh) * | 2017-05-14 | 2017-08-22 | 南通德瑞森复合材料有限公司 | 一种新型无卤阻燃的玻璃钢模塑料制备方法 |
| CN109722058A (zh) * | 2017-10-31 | 2019-05-07 | 江苏创曦复合材料科技有限公司 | 一种玻璃钢拉挤阻燃树脂及其制备方法 |
| CN107663365A (zh) * | 2017-11-17 | 2018-02-06 | 成都双瑞暖通设备有限公司 | 一种具有抗菌功能的玻璃钢 |
| CN107778802A (zh) * | 2017-11-17 | 2018-03-09 | 成都双瑞暖通设备有限公司 | 一种高强度玻璃钢配方 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Fiore et al. | Effect of sodium bicarbonate treatment on mechanical properties of flax-reinforced epoxy composite materials | |
| Sanjay et al. | The hybrid effect of Jute/Kenaf/E-glass woven fabric epoxy composites for medium load applications: impact, inter-laminar strength, and failure surface characterization | |
| Mittal et al. | Biodegradability and mechanical properties of pineapple leaf/coir Fiber reinforced hybrid epoxy composites | |
| Kushwaha et al. | Effect of silanes on mechanical properties of bamboo fiber-epoxy composites | |
| ATE527220T1 (de) | Geschlichtetes versträrkungsmaterial und materiale verstärkt mit diesen verstärkiungsmaterialen | |
| EP2229421B1 (de) | Textiles halbzeug mit wengistens einer mit einem kleber versehenen oberfläche | |
| Abd El-Baky et al. | Mechanical properties evaluation of sugarcane bagasse-glass/polyester composites | |
| CN107641242B (zh) | 一种注塑材料 | |
| Bengtsson et al. | Profile extrusion and mechanical properties of crosslinked wood–thermoplastic composites | |
| Krishnan et al. | Tensile, flexural, impact, and hardness properties of alkaline-treated Sunnhemp fiber reinforced polyester composites | |
| CN110283399A (zh) | 一种竹木纤维墙板及其制备方法 | |
| CA2457728A1 (en) | Matrix resin composition for fiber reinforced plastic and process for producing fiber reinforced plastic | |
| Rajan et al. | Effect of viscose fabric modification on the mechanical and water absorption properties of composites prepared through vacuum infusion | |
| CN113978065A (zh) | 增强型玻璃钢拉挤型材 | |
| CN107521203A (zh) | 一种超细碳酸钙改性苎麻纤维毡增强pu的汽车顶棚材料及其制备方法 | |
| Manh Vu et al. | Influence of silanized bacterial cellulose on the mode I interlaminar fracture toughness of glass fiber filled with epoxy resin | |
| EP0318616B1 (en) | Fiber-reinforced composite materials and resin composition therefor | |
| Tsukamoto et al. | Evaluation of the tensile strength of polypropylene-based composites containing glass wool | |
| CN205364741U (zh) | 一种连续纤维增强板材 | |
| Rao et al. | Study of hardness and flexural strength of banyan and peepal fibre reinforced hybrid composites | |
| Mirza et al. | Lyocell fiber reinforced polypropylene composites: effect of matrix modification | |
| CN113022041B (zh) | 一种具有抗病毒功能的层压板及其制备方法 | |
| JPS5962639A (ja) | 耐食性多層成形体の製造方法 | |
| CN108129829A (zh) | 一种柔韧聚氨酯鞋底材料及其制备方法 | |
| Rout | Fabrication of transesterified cured coir reinforced composites and evaluation of their properties |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220128 |
|
| RJ01 | Rejection of invention patent application after publication |