CN113944564B - Variable-aperture device based on 4D printing technology and preparation method thereof - Google Patents

Variable-aperture device based on 4D printing technology and preparation method thereof Download PDF

Info

Publication number
CN113944564B
CN113944564B CN202111094424.5A CN202111094424A CN113944564B CN 113944564 B CN113944564 B CN 113944564B CN 202111094424 A CN202111094424 A CN 202111094424A CN 113944564 B CN113944564 B CN 113944564B
Authority
CN
China
Prior art keywords
pipe body
printing technology
aperture
variable
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202111094424.5A
Other languages
Chinese (zh)
Other versions
CN113944564A (en
Inventor
周燕
甘杰
马国财
李霏
文世峰
蔡志娟
段隆臣
史玉升
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China University of Geosciences
Beijing Institute of Electronic System Engineering
Original Assignee
China University of Geosciences
Beijing Institute of Electronic System Engineering
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China University of Geosciences, Beijing Institute of Electronic System Engineering filed Critical China University of Geosciences
Priority to CN202111094424.5A priority Critical patent/CN113944564B/en
Publication of CN113944564A publication Critical patent/CN113944564A/en
Application granted granted Critical
Publication of CN113944564B publication Critical patent/CN113944564B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02KJET-PROPULSION PLANTS
    • F02K1/00Plants characterised by the form or arrangement of the jet pipe or nozzle; Jet pipes or nozzles peculiar thereto
    • F02K1/78Other construction of jet pipes
    • F02K1/82Jet pipe walls, e.g. liners
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/20Direct sintering or melting
    • B22F10/28Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/10Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
    • B22F5/106Tube or ring forms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02KJET-PROPULSION PLANTS
    • F02K1/00Plants characterised by the form or arrangement of the jet pipe or nozzle; Jet pipes or nozzles peculiar thereto
    • F02K1/78Other construction of jet pipes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Abstract

The invention relates to the technical field of additive manufacturing and advanced manufacturing, in particular to a variable-aperture device based on a 4D printing technology and a preparation method thereof. The variable-aperture device based on the 4D printing technology comprises a cylindrical tube body and a conical tube body, the cylindrical tube body is used for connecting other parts, a plurality of wrinkle units are uniformly arranged on the tube wall of the conical tube body along the circumference, the cross section of each wrinkle unit is of a sine curve structure, the cylindrical tube body and the conical tube body are integrally formed by nickel-titanium shape memory alloy materials through the 4D printing technology, and the 4D printing technology is a selective laser melting technology. The two-part structure is integrally formed by a 4D printing technology, the printed state of the conical pipe body is an extension state, external force is adopted to contract each wrinkle unit after forming, the shrinkage state with the diameter same as that of the cylindrical pipe body is achieved, and after heating, each wrinkle unit is immediately converted into the extension state from the shrinkage state, so that the aperture is changed.

Description

Variable-aperture device based on 4D printing technology and preparation method thereof
Technical Field
The invention relates to the technical field of additive manufacturing and advanced manufacturing, in particular to a variable-aperture device based on a 4D printing technology and a preparation method thereof.
Background
The 4D printing technology is used as a new material-structure-function integrated forming technology of an intelligent component, combines the characteristics of the 3D printing technology, can reduce three-dimensional manufacturing into simple two-dimensional manufacturing, can form any part with a complex structure, and is one of the current domestic and foreign research hotspots. Due to the great application prospect in the aspect of high-end intelligent structure preparation, the 4D printing technology is rapidly developed in the field of additive manufacturing.
Nickel titanium shape memory alloys are becoming popular candidate intelligent materials in various fields such as aerospace, medical devices and flexible electronics due to their excellent shape memory and superelastic properties. In recent years, the 4D printing technology of intelligent component material-structure-function integrated molding is rapidly developed, the application of the nickel-titanium shape memory alloy is expected to be further expanded on the basis of combining the 4D printing technology, and the method has great significance for development requirements of various fields in the aspect of high-end intelligent structures.
The tail gas nozzle is one of important power auxiliary devices in the aerospace field, the variable structure-variable function of the tail gas nozzle is mainly designed by a mechanical structure at present, the deformation efficiency and the response sensitivity are still to be improved, and the structure design and the preparation method for realizing the structure-function integration are urgently needed to be researched aiming at the further requirements of the aerospace field on intelligent variable-aperture components.
Disclosure of Invention
The invention aims to provide a variable-aperture device based on a 4D printing technology and a preparation method thereof, aiming at the existing technical situation, the variable-aperture device is applied to a tail nozzle of an aerospace auxiliary power device, and the variable-aperture device can realize the variable aperture to adjust the spraying amount.
In order to achieve the purpose, the invention adopts the following technical scheme:
the utility model provides a become aperture device based on 4D printing technique, includes cylindric body and coniform body, cylindric body is used for connecting other parts, evenly be equipped with a plurality of fold units along the circumference on the pipe wall of coniform body, the cross section of each fold unit is sinusoidal column structure, cylindric body and coniform body adopt nickel titanium shape memory alloy material to pass through 4D printing technique integrated into one piece, 4D printing technique is the selective laser melting technique.
Further, when the corrugated unit is in a contracted state, the cosine angle of the sinusoidal structure of the cross section is 30 degrees, and when the corrugated unit is in an expanded state, the cosine angle of the sinusoidal structure of the cross section is 60 degrees.
Furthermore, the inner diameter of the cylindrical pipe body is 25mm-35mm, the outer diameter is 28mm-38mm, the height is 20mm-30mm, the height of the conical pipe body is 40mm-50mm, the bottom diameter is 56mm-76mm, and the thickness is 1mm-3 mm.
A preparation method of a variable-aperture device based on a 4D printing technology comprises the following steps:
s1, building a variable aperture device model by using three-dimensional modeling software, storing and inputting the model into selective laser melting equipment;
s2, enabling the powder material of the selective laser melting equipment to be nickel-titanium alloy material powder, taking a nickel-titanium alloy material plate as a substrate, grinding the substrate to be flat, then carrying out sand blasting treatment, and then uniformly paving a layer of nickel-titanium alloy material powder on the substrate;
s3, closing a cabin door of the selective laser melting equipment, opening a gas circulation system, injecting protective gas to ensure that the oxygen content in the forming cavity of the selective laser melting equipment is lower than 200ppm, and simultaneously preheating the substrate to 100-200 ℃;
s4, when the oxygen content in the forming cavity of the laser melting equipment of the area to be selected and the preheating temperature of the substrate reach set values, forming the aperture-variable device, wherein the laser power is 100W-300W, the scanning speed is 400mm/S-700mm/S, the powder layer thickness is 30 microns, and the scanning interval is 120 microns;
and S5, cutting the aperture-changing device from the substrate after the aperture-changing device is molded, and performing sand blasting to remove surface defects to finish the preparation.
The invention has the beneficial effects that:
1. the two parts of the structure are integrally formed by a 4D printing technology, the printed state of the conical pipe body is an extension state, external force is adopted to contract each wrinkle unit after forming, the contraction state with the same diameter as the cylindrical pipe body is achieved, and each wrinkle unit is immediately converted into the extension state from the contraction state after heating, so that the aperture is changed;
2. the invention is applied to the tail nozzle of the aerospace auxiliary power device, the spraying amount of the tail nozzle is increased due to the temperature rise and extension in the traveling process, and the spraying amount of the tail nozzle is reduced due to the temperature reduction and shrinkage when the traveling is finished;
3. the invention adopts the 4D printing advanced manufacturing technology, solves the problem of integrated molding of a complex fold structure in the variable-aperture device, and has the advantages of high molding efficiency and low cost.
Drawings
FIG. 1 is a perspective view of a variable aperture device of the present invention;
figure 2 is a comparison of the pleated element of the present invention in a contracted state and an expanded state.
Description of the labeling: 1. cylindrical tube, 2, conical tube.
Detailed Description
The invention will be further explained with reference to the drawings.
Referring to fig. 1-2, an aperture-changing device based on 4D printing technology includes a cylindrical tube 1 and a conical tube 2, the cylindrical tube 1 is used for connecting other components, a plurality of corrugated units are uniformly arranged on the tube wall of the conical tube 2 along the circumference, the corrugated units are similar to a tail skirt, and the cross section of each corrugated unit is of a sinusoidal structure.
The cylindrical pipe body 1 and the conical pipe body 2 are integrally formed by a nickel-titanium shape memory alloy material through a 4D printing technology, a rich nickel-titanium shape memory alloy with a nearly equal atomic ratio is generally selected, and the 4D printing technology is a Selective Laser Melting (SLM) technology.
Above-mentioned technical scheme, two part structures are through 4D printing technology integrated into one piece, and the state after conical body 2 prints is the extension state, adopts external force to make each fold unit shrink after the shaping, reaches the shrink state with cylindric body 1 diameter, and each fold unit truns into the extension state from the shrink state immediately after the heating to realize becoming the aperture.
When the pleat unit is in a contracted state, the cosine included angle of the sine curve-shaped structure of the cross section of the pleat unit is 30 degrees, and when the pleat unit is in an expanded state, the cosine included angle of the sine curve-shaped structure of the cross section of the pleat unit is 60 degrees.
The inner diameter of the cylindrical pipe body 1 is 25mm-35mm, the outer diameter is 28mm-38mm, the height is 20mm-30mm, the height of the conical pipe body 2 is 40mm-50mm, the bottom diameter is 56mm-76mm, and the thickness is 1mm-3 mm.
The present invention is further described in detail in examples 1 to 3 below.
Example 1:
become aperture device based on 4D printing technique, including cylindric body 1 and coniform body 2, the internal diameter of cylindric body 1 is 25mm, the external diameter is 28mm, highly is 20mm, and the height of coniform body 2 is 40mm, the bottom diameter is 56mm, thickness is 1 mm.
The preparation method of the variable-aperture device based on the 4D printing technology comprises the following steps:
s1, building a variable aperture device model by using three-dimensional modeling software, wherein the three-dimensional modeling software comprises Magics, UG, SolidWorks and the like, and is stored in an STL format and then input into selective laser melting equipment;
s2, the powder material of the selective laser melting equipment is nickel-titanium alloy material powder, a nickel-titanium alloy material plate is used as a substrate, sand blasting is carried out after the substrate is ground to be flat, the nickel-titanium alloy material powder can be uniformly paved on the substrate, and then a layer of nickel-titanium alloy material powder is uniformly paved on the substrate, wherein the thickness is about 30 mu m, and the particle size range is 15-53 mu m;
s3, closing a cabin door of the selective laser melting equipment, opening a gas circulation system, injecting argon protective gas to ensure that the oxygen content in the forming cavity of the selective laser melting equipment is lower than 200ppm, and simultaneously preheating the substrate to 200 ℃;
s4, when the oxygen content in the forming cavity of the laser melting equipment of the area to be selected and the preheating temperature of the substrate reach set values, forming the aperture-variable device, wherein the laser power is 300W, the scanning speed is 700mm/S, the powder layer thickness is 30 microns, and the scanning interval is 120 microns;
and S5, cutting the aperture-changing device from the substrate by adopting linear cutting after the aperture-changing device is molded, and carrying out sand blasting to remove surface defects to finish the preparation.
Example 2:
become aperture device based on 4D printing technique, including cylindric body 1 and coniform body 2, the internal diameter of cylindric body 1 is 30mm, the external diameter is 33mm, highly is 25mm, and the height of coniform body 2 is 50mm, the bottom diameter is 60mm, thickness is 2 mm.
The preparation method of the variable-aperture device based on the 4D printing technology comprises the following steps:
s1, establishing a variable aperture device model by using three-dimensional modeling software, wherein the three-dimensional modeling software comprises Magics, UG, SolidWorks and the like, and is stored in STL format and then input into selective laser melting equipment;
s2, the powder material of the selective laser melting equipment is nickel-titanium alloy material powder, a nickel-titanium alloy material plate is used as a substrate, sand blasting is carried out after the substrate is ground to be flat, the nickel-titanium alloy material powder can be uniformly paved on the substrate, and then a layer of nickel-titanium alloy material powder is uniformly paved on the substrate, wherein the thickness is about 30 mu m, and the particle size range is 15-53 mu m;
s3, closing a cabin door of the selective laser melting equipment, opening a gas circulation system, injecting argon protective gas to ensure that the oxygen content in the forming cavity of the selective laser melting equipment is lower than 200ppm, and simultaneously preheating the substrate to 200 ℃;
s4, when the oxygen content in the forming cavity of the laser melting equipment of the region to be selected and the preheating temperature of the substrate reach set values, forming the aperture-variable device, wherein the laser power is 200W, the scanning speed is 400mm/S, the powder layer thickness is 30 microns, and the scanning interval is 120 microns;
and S5, cutting the aperture-changing device from the substrate by adopting linear cutting after the aperture-changing device is molded, and carrying out sand blasting to remove surface defects to finish the preparation.
Example 3:
become aperture device based on 4D printing technique, including cylindric body 1 and coniform body 2, the internal diameter of cylindric body is 35mm, the external diameter is 38mm, highly is 40mm, and the height of coniform body 2 is 60mm, bottom diameter is 56mm, thickness is 1 mm.
The preparation method of the variable-aperture device based on the 4D printing technology comprises the following steps:
s1, building a variable aperture device model by using three-dimensional modeling software, wherein the three-dimensional modeling software comprises Magics, UG, SolidWorks and the like, and is stored in an STL format and then input into selective laser melting equipment;
s2, the powder material of the selective laser melting equipment is nickel-titanium alloy material powder, a nickel-titanium alloy material plate is used as a substrate, sand blasting is carried out after the substrate is ground to be flat, the nickel-titanium alloy material powder can be uniformly paved on the substrate, and then a layer of nickel-titanium alloy material powder is uniformly paved on the substrate, wherein the thickness is about 30 mu m, and the particle size range is 15-53 mu m;
s3, closing a cabin door of the selective laser melting equipment, opening a gas circulation system, injecting argon protective gas to ensure that the oxygen content in the forming cavity of the selective laser melting equipment is lower than 200ppm, and simultaneously preheating the substrate to 200 ℃;
s4, when the oxygen content in the forming cavity of the laser melting equipment of the area to be selected and the preheating temperature of the substrate reach set values, forming the aperture-variable device, wherein the laser power is 250W, the scanning speed is 500mm/S, the powder layer thickness is 30 microns, and the scanning interval is 120 microns;
and S5, cutting the aperture-changing device from the substrate by adopting linear cutting after the aperture-changing device is molded, and carrying out sand blasting to remove surface defects to finish the preparation.
The invention has the advantages that:
1. the two-part structure is integrally formed by a 4D printing technology, the printed state of the conical pipe body 2 is an extension state, external force is adopted to contract each fold unit after forming, the contraction state with the diameter same as that of the cylindrical pipe body 1 is achieved, and each fold unit is immediately converted into the extension state from the contraction state after heating, so that the aperture is changed;
2. the invention is applied to the tail nozzle of the aerospace auxiliary power device, the spraying amount of the tail nozzle is increased due to the temperature rise and extension in the advancing process, and the spraying amount of the tail nozzle is reduced due to the temperature reduction and shrinkage when the advancing is finished;
3. the invention adopts the 4D printing advanced manufacturing technology, solves the problem of integrated molding of a complex fold structure in the variable-aperture device, and has the advantages of high molding efficiency and low cost.
It should be understood that the above-mentioned embodiments are merely preferred embodiments of the present invention, and not intended to limit the scope of the invention, therefore, all equivalent changes in the principle of the present invention should be included in the protection scope of the present invention.

Claims (4)

1. The utility model provides a become aperture device based on 4D printing technique which characterized in that: the cylindrical pipe body is used for being connected with other parts, a plurality of fold units are uniformly arranged on the pipe wall of the conical pipe body along the circumference, the cross section of each fold unit is of a sine curve structure, the cylindrical pipe body and the conical pipe body are integrally formed by a nickel-titanium shape memory alloy material through a 4D printing technology, and the 4D printing technology is a selective laser melting technology.
2. The variable aperture device based on the 4D printing technology as claimed in claim 1, wherein: when the pleat unit is in a contracted state, the cosine included angle of the sine curve-shaped structure of the cross section of the pleat unit is 30 degrees, and when the pleat unit is in an expanded state, the cosine included angle of the sine curve-shaped structure of the cross section of the pleat unit is 60 degrees.
3. The variable-aperture device based on the 4D printing technology is characterized in that: the inner diameter of the cylindrical pipe body is 25mm-35mm, the outer diameter of the cylindrical pipe body is 28mm-38mm, the height of the cylindrical pipe body is 20mm-30mm, the height of the conical pipe body is 40mm-50mm, the bottom diameter of the conical pipe body is 56mm-76mm, and the thickness of the conical pipe body is 1mm-3 mm.
4. A method for manufacturing a variable aperture device based on 4D printing technology according to any of claims 1-3, characterized in that: the method comprises the following steps:
s1, building a variable aperture device model by using three-dimensional modeling software, storing and inputting the model into selective laser melting equipment;
s2, enabling the powder material of the selective laser melting equipment to be nickel-titanium alloy material powder, taking a nickel-titanium alloy material plate as a substrate, grinding the substrate to be flat, then carrying out sand blasting treatment, and then uniformly paving a layer of nickel-titanium alloy material powder on the substrate;
s3, closing a cabin door of the selective laser melting equipment, opening a gas circulation system, injecting protective gas to ensure that the oxygen content in the forming cavity of the selective laser melting equipment is lower than 200ppm, and simultaneously preheating the substrate to 100-200 ℃;
s4, when the oxygen content in the forming cavity of the laser melting equipment of the area to be selected and the preheating temperature of the substrate reach set values, forming the aperture-variable device, wherein the laser power is 100W-300W, the scanning speed is 400mm/S-700mm/S, the powder layer thickness is 30 microns, and the scanning interval is 120 microns;
and S5, cutting the aperture-changing device from the substrate after the aperture-changing device is molded, and performing sand blasting to remove surface defects to finish the preparation.
CN202111094424.5A 2021-09-17 2021-09-17 Variable-aperture device based on 4D printing technology and preparation method thereof Active CN113944564B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111094424.5A CN113944564B (en) 2021-09-17 2021-09-17 Variable-aperture device based on 4D printing technology and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111094424.5A CN113944564B (en) 2021-09-17 2021-09-17 Variable-aperture device based on 4D printing technology and preparation method thereof

Publications (2)

Publication Number Publication Date
CN113944564A CN113944564A (en) 2022-01-18
CN113944564B true CN113944564B (en) 2022-09-20

Family

ID=79328326

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111094424.5A Active CN113944564B (en) 2021-09-17 2021-09-17 Variable-aperture device based on 4D printing technology and preparation method thereof

Country Status (1)

Country Link
CN (1) CN113944564B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114572408B (en) * 2022-03-03 2024-03-19 华中科技大学 Variable flow channel device and preparation method thereof
CN114857300B (en) * 2022-04-26 2023-06-16 华中科技大学 Self-adaptive temperature-sensing flow regulating valve device and 3D printing method thereof
CN115366221B (en) * 2022-09-14 2023-07-04 中国地质大学(武汉) Electrodrive variable-aperture drill bit and manufacturing method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105003359A (en) * 2015-07-14 2015-10-28 西北工业大学 Deformable swing spraying pipe based on intelligent composite material
CN105658183A (en) * 2013-05-23 2016-06-08 Sts医疗有限公司 Shape change structure
CN109528352A (en) * 2019-01-15 2019-03-29 哈尔滨工业大学 A kind of shape-memory polymer carries medicine intestinal stent and preparation method thereof
CN109567668A (en) * 2018-11-30 2019-04-05 南安市尚赢机械科技有限公司 A kind of ferroalloy mold dust catcher that the multidirectional deformation of reducing fits closely
CN111842888A (en) * 2020-06-18 2020-10-30 华中科技大学 4D printing method of nickel titanium based ternary shape memory alloy
WO2021027300A1 (en) * 2019-08-09 2021-02-18 华南理工大学 4d printing method for in-situ regulation of functional properties of nickel-titanium alloy and use thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105658183A (en) * 2013-05-23 2016-06-08 Sts医疗有限公司 Shape change structure
CN105003359A (en) * 2015-07-14 2015-10-28 西北工业大学 Deformable swing spraying pipe based on intelligent composite material
CN109567668A (en) * 2018-11-30 2019-04-05 南安市尚赢机械科技有限公司 A kind of ferroalloy mold dust catcher that the multidirectional deformation of reducing fits closely
CN109528352A (en) * 2019-01-15 2019-03-29 哈尔滨工业大学 A kind of shape-memory polymer carries medicine intestinal stent and preparation method thereof
WO2021027300A1 (en) * 2019-08-09 2021-02-18 华南理工大学 4d printing method for in-situ regulation of functional properties of nickel-titanium alloy and use thereof
CN111842888A (en) * 2020-06-18 2020-10-30 华中科技大学 4D printing method of nickel titanium based ternary shape memory alloy

Also Published As

Publication number Publication date
CN113944564A (en) 2022-01-18

Similar Documents

Publication Publication Date Title
CN113944564B (en) Variable-aperture device based on 4D printing technology and preparation method thereof
Chen et al. The research status and development trend of additive manufacturing technology
CN104175417B (en) A kind of spheronization process of PEEK superfine powder
CN106166617A (en) A kind of preparation method of 3D printing titanium alloy powder
CN103395973B (en) A kind of glass high temperature melting melt forming shower nozzle based on 3D printing technique
CN105710377A (en) Hybrid additive manufacturing methods using hybrid additively manufactured features for hybrid components
EP3593998A1 (en) Methods and thin walled reinforced structures for additive manufacturing
CN106825542A (en) Negative poisson's ratio high-magnetostriction material and its increasing material manufacturing method
Bourell et al. Powder densification maps in selective laser sintering
Ratsimba et al. Densification behaviour and three-dimensional printing of Y2O3 ceramic powder by selective laser sintering
CN105414549A (en) Metal powder injection molding method for product with inverted buckle structure
CN104084594A (en) Method for preparing microfine spherical niobium powder
CN106113501A (en) One has metal-like or ceramic texture composite increases material preparation method
CN103433492B (en) Blow molding method for powder of metal hollow product
CN107855523A (en) A kind of quick near clean shaping preparation method of tungsten alloy parts
CN101230472B (en) Method for manufacturing airtight cavity structure
CN107649684A (en) A kind of 3D printing method
Jiao et al. Experimental research of drop‐on‐demand droplet jetting 3D printing with molten polymer
Imam et al. Cost effective developments for fabrication of titanium components
CN204035571U (en) A kind of device preparing metal molybdenum ball-shaped micro powder or Ultramicro-powder
Xiong et al. Directly manufacturing mouse mold by plasma deposition manufacturing
CN206145974U (en) Gaseous heating device of atomizing and pulverizing equipment
CN108129150A (en) A kind of manufacturing method of easy structure fiber connector
CN101745566B (en) Preparation method and device of high-precision metal amorphous tube
CN206543881U (en) A kind of 3D printing annular distance type aerosolization nozzle

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant