CN113943530B - 水性uv固化涂料组合物 - Google Patents
水性uv固化涂料组合物 Download PDFInfo
- Publication number
- CN113943530B CN113943530B CN202111404521.XA CN202111404521A CN113943530B CN 113943530 B CN113943530 B CN 113943530B CN 202111404521 A CN202111404521 A CN 202111404521A CN 113943530 B CN113943530 B CN 113943530B
- Authority
- CN
- China
- Prior art keywords
- meth
- pdms
- acrylic oligomer
- coating composition
- polyurethane resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000008199 coating composition Substances 0.000 title claims abstract description 79
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 53
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 46
- 239000000758 substrate Substances 0.000 claims abstract description 33
- 238000000576 coating method Methods 0.000 claims abstract description 30
- 239000011248 coating agent Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 229920000515 polycarbonate Polymers 0.000 claims description 18
- 239000004417 polycarbonate Substances 0.000 claims description 18
- -1 polyoxyethylene Polymers 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 230000009477 glass transition Effects 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004917 carbon fiber Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 3
- 239000006224 matting agent Substances 0.000 description 11
- 239000012855 volatile organic compound Substances 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000002562 thickening agent Substances 0.000 description 6
- 239000005056 polyisocyanate Substances 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 5
- 239000000080 wetting agent Substances 0.000 description 5
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical compound CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- YXRKNIZYMIXSAD-UHFFFAOYSA-N 1,6-diisocyanatohexane Chemical compound O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O YXRKNIZYMIXSAD-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Ex-1 | Ex-2 | Ex-3 | Ex-4 | |
VOC(不含水,g/L) | <150 | <150 | <150 | <150 |
Ex-1 | Ex-2 | Ex-3 | Ex-4 | CE-1 | CE-2 | CE-3 | CE-4 | |
60° | 5.3 | 5.8 | 5.7 | 5.3 | 5.4 | 5.4 | 5.3 | 5.6 |
Ex-1 | Ex-2 | Ex-3 | Ex-4 | CE-1 | CE-2 | CE-3 | CE-4 |
94.3 | 99.6 | 98 | 93.5 | 84.6 | 89 | 105.3 | 94 |
Ex-1 | Ex-2 | Ex-3 | Ex-4 | CE-1 | CE-2 | CE-3 | CE-4 |
7级 | 8级 | 9级 | 7级 | 0级 | 0级 | 1级 | 1级 |
Claims (15)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111404521.XA CN113943530B (zh) | 2021-11-24 | 2021-11-24 | 水性uv固化涂料组合物 |
CA3237519A CA3237519A1 (en) | 2021-11-24 | 2022-11-23 | Waterborne uv curable coating composition |
TW111144817A TW202321389A (zh) | 2021-11-24 | 2022-11-23 | 水性uv固化塗料組合物 |
PCT/CN2022/133669 WO2023093752A1 (en) | 2021-11-24 | 2022-11-23 | Waterborne uv curable coating composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111404521.XA CN113943530B (zh) | 2021-11-24 | 2021-11-24 | 水性uv固化涂料组合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113943530A CN113943530A (zh) | 2022-01-18 |
CN113943530B true CN113943530B (zh) | 2023-09-26 |
Family
ID=79338521
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111404521.XA Active CN113943530B (zh) | 2021-11-24 | 2021-11-24 | 水性uv固化涂料组合物 |
Country Status (4)
Country | Link |
---|---|
CN (1) | CN113943530B (zh) |
CA (1) | CA3237519A1 (zh) |
TW (1) | TW202321389A (zh) |
WO (1) | WO2023093752A1 (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113943530B (zh) * | 2021-11-24 | 2023-09-26 | Ppg涂料(天津)有限公司 | 水性uv固化涂料组合物 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113214735A (zh) * | 2021-06-08 | 2021-08-06 | 广州市雅欧森姆皮革原料有限公司 | 一种皮革用水性uv光油及其制备方法和应用 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5265335B2 (ja) * | 2008-12-24 | 2013-08-14 | ディーエイチ・マテリアル株式会社 | ラジカル重合性組成物 |
CN102863625B (zh) * | 2012-08-22 | 2014-02-26 | 王志军 | 一种辐射固化体系用表面控制助剂及其制备方法和应用 |
CN105038575B (zh) * | 2015-09-21 | 2018-05-11 | 张家港康得新光电材料有限公司 | 一种水性防眩uv涂料、硬化膜及其制备方法 |
JP2017113689A (ja) * | 2015-12-23 | 2017-06-29 | 関西ペイント株式会社 | 基材の親水性被膜形成方法 |
CN108300275A (zh) * | 2017-12-28 | 2018-07-20 | 滁州金桥德克新材料有限公司 | 一种水性uv固化真空电镀底漆、制备方法及其电镀的方法 |
CN113943530B (zh) * | 2021-11-24 | 2023-09-26 | Ppg涂料(天津)有限公司 | 水性uv固化涂料组合物 |
-
2021
- 2021-11-24 CN CN202111404521.XA patent/CN113943530B/zh active Active
-
2022
- 2022-11-23 WO PCT/CN2022/133669 patent/WO2023093752A1/en unknown
- 2022-11-23 TW TW111144817A patent/TW202321389A/zh unknown
- 2022-11-23 CA CA3237519A patent/CA3237519A1/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113214735A (zh) * | 2021-06-08 | 2021-08-06 | 广州市雅欧森姆皮革原料有限公司 | 一种皮革用水性uv光油及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
WO2023093752A1 (en) | 2023-06-01 |
TW202321389A (zh) | 2023-06-01 |
CA3237519A1 (en) | 2023-06-01 |
CN113943530A (zh) | 2022-01-18 |
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PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information |
Inventor after: Xu Xiangling Inventor after: Ruan Daming Inventor after: Yang Yurun Inventor after: Wang Yihua Inventor after: Yang Wenfu Inventor after: Gao Siqi Inventor after: Liu Haifeng Inventor before: Xu Xiangling Inventor before: Ruan Daming Inventor before: Yang Yurun Inventor before: Wang Yihua Inventor before: Yang Wenfu Inventor before: Gao Siqi Inventor before: Liu Haifeng |
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