CN113930797A

CN113930797A - Continuous anode electrolytic tank for preparing multiferroic material

Info

Publication number: CN113930797A
Application number: CN202111365054.4A
Authority: CN
Inventors: 万凤
Original assignee: Xianyang Normal University
Current assignee: Xianyang Normal University
Priority date: 2021-11-17
Filing date: 2021-11-17
Publication date: 2022-01-14

Abstract

The invention relates to the technical field of electrolytic cells, and discloses a continuous anode electrolytic cell prepared from a multiferroic material. According to the invention, the anode to be electrolyzed is placed between the side plate and the sliding plate, the pressing plate and the side plate can clamp the anode and can be contacted with the anode guide rod, the whole clamping is convenient, the vertical plate is provided with the net frame which can filter anode mud and is convenient to collect and utilize, the vertical plate can be compressed by rotating the rotating block, the sealing property between the anode tank and the cathode tank is better, and the inserting plate needs to be pulled up or pushed down through the pulling block due to better sealing property, and the solution in the cathode tank can be discharged through the water outlet through the round hole.

Description

Continuous anode electrolytic tank for preparing multiferroic material

Technical Field

The invention relates to the technical field of electrolytic cells, in particular to a continuous anode electrolytic cell prepared from a multiferroic material.

Background

The electrolytic cell consists of a cell body, an anode and a cathode, an anode chamber and a cathode chamber are required to be separated, the electrolytic cell is divided into an aqueous solution electrolytic cell, a molten salt electrolytic cell and a non-aqueous solution electrolytic cell according to the difference of electrolyte, when direct current passes through the electrolytic cell, oxidation reaction occurs at the interface of the anode and the solution, and reduction reaction occurs at the interface of the cathode and the solution, so as to prepare a required product.

The electrolysis trough that commonly uses is when using, often inconvenient material to the positive pole is changed, and the bottom of electrolysis trough can deposit the one deck anode mud, common mode clearance is more troublesome, need regularly handle it, with the cleanliness factor of improvement inside, the inhomogeneous phenomenon of ion distribution also can appear in inside reaction time, need stir, the insoluble anode mud that produces can not filter the recovery, contain noble metal, cause the wasting of resources easily, and can not intercommunicate as required between anode trough and the negative pole groove, it is more troublesome. In response to this situation, those skilled in the art have provided a continuous anode cell for the production of multiferroic materials.

Disclosure of Invention

The invention aims to provide a continuous anode electrolytic cell prepared from a multiferroic material, which aims to solve the problems that the anode material is inconvenient to replace, the ion distribution is uneven during the internal reaction, insoluble anode mud cannot be filtered and recovered, and the anode cell and the cathode cell cannot be communicated as required, which are proposed in the background art.

In order to achieve the purpose, the invention provides the following technical scheme:

the utility model provides a many iron material preparation continuous anode electrolytic cell, includes the electrolysis trough main part, be provided with the positive pole groove and the negative pole groove that link up in the electrolysis trough main part, and one side inner wall fixed mounting of positive pole groove has the centre gripping subassembly, is provided with the baffle structure between positive pole groove and the negative pole groove, and one side of electrolysis trough main part is provided with scrapes the mud structure, and the bottom of electrolysis trough main part is provided with filtering component.

The centre gripping subassembly includes the positive pole guide arm, the positive pole guide arm sets up on the inner wall of positive pole groove, the one end fixed mounting of positive pole guide arm has the fixed plate, the top fixed mounting of fixed plate has the kicking block, it has the slide to peg graft in the kicking block, and the top fixed mounting of slide has two pipes, and all peg graft in two pipes and have spacing post, the common fixed mounting in bottom of two spacing posts has the clamp plate, the top central authorities of clamp plate rotate through the bearing and install the threaded rod, and the side of threaded rod passes through threaded connection with the slide, the top of threaded rod sets up anti-skidding line, one side bottom fixed mounting of fixed plate has the curb plate, and be provided with anti-skidding tooth on the curb plate, one side fixed mounting of slide has the limiting plate.

As a still further scheme of the invention: the bottom of the sliding plate is provided with a bottom groove, and the bottom groove and the pressing plate are matched components.

As a still further scheme of the invention: the mud scraping structure comprises a motor, the motor is fixedly installed at the top of a mounting rack on the side face of the electrolytic bath main body, a gear is fixedly installed at the bottom of an output shaft of the motor, the gear is arranged in the mounting rack, the mounting rack is communicated with an anode tank, a bottom plate is arranged at the bottom of the anode tank, a fixed shaft is fixedly installed at the center of the top of the bottom plate, a fluted disc is rotatably connected onto the fixed shaft, a plurality of connecting plates are arranged on the fluted disc, and the fluted disc is meshed with the gear.

As a still further scheme of the invention: a plurality of the connecting plate is the annular setting, and the top of connecting plate is inserted and is equipped with a plurality of stirring leaves, and the stirring leaf passes through bolt fixed connection with the connecting plate top, and a plurality of stirring leaves are even setting.

As a still further scheme of the invention: and a scraper is fixedly arranged on one side of the connecting plate through a bolt and is in contact with the top of the bottom plate.

As a still further scheme of the invention: the baffle structure includes the picture peg, the picture peg is pegged graft at the inslot between positive pole groove and negative pole groove, fixed mounting has two vertical barrels at the top of electrolysis trough main part symmetrically, and it has the inserted bar to peg graft in two vertical barrels, the cover is equipped with the spring on the inserted bar, the spring sets up in vertical barrel, the top fixed mounting of inserted bar presses the board, peg graft at the top of picture peg according to the board, the downthehole lower surface of the inslot between positive pole groove and the negative pole groove is fixed mounting still has spacing, a plurality of round holes have evenly been seted up on spacing, spacing is pegged graft in the bottom of picture peg, the both sides of picture peg are fixed mounting still has the sealing strip, one side fixed mounting of picture peg has the lacing block.

As a still further scheme of the invention: the filter assembly comprises a guide cylinder, the guide cylinder is communicated and fixedly arranged at the bottom of the anode tank, the guide cylinder is fixedly connected with the bottom plate, the bottom of the guide cylinder is communicated with a filter box, a net rack is inserted in the filter box, a vertical plate is fixedly arranged on one side of the net rack, the bottom of the filter box is communicated with a lower nozzle, and a valve is arranged on the lower nozzle.

As a still further scheme of the invention: two threaded columns are fixedly mounted on one side of the filter box, the threaded columns penetrate through the vertical plate and are provided with rotating blocks through threads, and a handle is fixedly mounted on one side of the vertical plate.

Compared with the prior art, the invention has the beneficial effects that:

1. the anode to be electrolyzed is placed between the side plate and the sliding plate, the threaded rod is rotated, the threaded rod is matched with the sliding plate through threads, the round tube can limit the limiting column, the anode can be fixed, the sliding plate can be folded in the installation process, the top block can not block the movement of the round tube and the threaded rod, the bottom groove can accommodate the pressing plate, the pressing plate and the side plate can clamp the anode and can be contacted with the anode guide rod, and the whole clamping is convenient;

2. the anode mud can fall from the guide cylinder and the filter box and flow out through the drainage port, the vertical plate is provided with a net rack which can filter the anode mud and is convenient to collect and utilize, the vertical plate can be compressed by rotating the rotating block to prevent liquid leakage, and the rotating block can be pulled out through a handle when the net rack is taken out;

3. insert the picture peg between anode slot and negative pole groove, pull up according to the board and make according to the board and insert the top at the picture peg, compress tightly the picture peg under the effect of spring, the both sides of picture peg are provided with and draw the piece, the bottom grafting of picture peg has spacing, can keep good sealed for the leakproofness between anode slot and the negative pole groove is better, because the leakproofness is better, need pull up the picture peg or push down through drawing the piece, the round hole can be discharged the lower mouth of a river of solution accessible in the negative pole inslot.

Drawings

FIG. 1 is a schematic perspective view of the overall structure of a continuous anode electrolytic cell made of a multiferroic material;

FIG. 2 is a schematic view of a clamping assembly for a continuous anode cell made of multiferroic material;

FIG. 3 is a schematic structural view of a sludge scraping structure of a continuous anode electrolytic cell made of a multiferroic material;

FIG. 4 is a schematic structural view of a separator structure of a continuous anode electrolytic cell made of a multiferroic material;

FIG. 5 is a schematic diagram of a filter assembly for a continuous anode electrolytic cell made of a multiferroic material;

FIG. 6 is a schematic cross-sectional view of a filter assembly for a continuous anode cell made of a multiferroic material.

In the figure: 1. an electrolytic cell body; 2. an anode tank; 3. a mud scraping structure; 4. a clamping assembly; 5. a separator structure; 6. a filter assembly; 7. a cathode channel; 31. a motor; 32. a gear; 33. a fluted disc; 34. a base plate; 35. a connecting plate; 36. stirring blades; 37. a fixed shaft; 38. a squeegee; 41. an anode stem; 42. a fixing plate; 43. a slide plate; 44. a bottom groove; 45. a limiting plate; 46. a circular tube; 47. a limiting column; 48. pressing a plate; 49. a threaded rod; 410. a side plate; 411. a top block; 51. inserting plates; 52. a vertical cylinder; 53. inserting a rod; 54. a spring; 55. a limiting strip; 56. a circular hole; 57. pressing a plate; 58. pulling the block; 59. a sealing strip; 61. a draft tube; 62. a filter box; 63. a vertical plate; 64. a threaded post; 65. rotating the block; 66. a water outlet; 67. a net frame; 68. and (4) a handle.

Detailed Description

The technical solution in the embodiment of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiment of the present invention, and with reference to fig. 1 to 6, the embodiment of the present invention is as follows:

the utility model provides a many iron material preparation continuous anode electrolytic cell, includes electrolysis trough main part 1, is provided with the positive pole groove 2 and the negative pole groove 7 that link up in the electrolysis trough main part 1, and one side inner wall fixed mounting of positive pole groove 2 has a centre gripping subassembly 4, is provided with baffle structure 5 between positive pole groove 2 and the negative pole groove 7, and one side of electrolysis trough main part 1 is provided with scrapes mud structure 3, and the bottom of electrolysis trough main part 1 is provided with filter assembly 6.

Centre gripping subassembly 4 includes anode rod 41, anode rod 41 sets up on the inner wall of anode groove 2, anode rod 41's one end fixed mounting has fixed plate 42, fixed plate 42's top fixed mounting has kicking block 411, it has slide 43 to slide peg graft in the kicking block 411, and slide 43's top fixed mounting has two pipes 46, and all peg graft in two pipes 46 and have spacing post 47, the common fixed mounting in bottom of two spacing posts 47 has clamp plate 48, clamp plate 48's top central authorities rotate through the bearing and install threaded rod 49, and threaded rod 49's side and slide 43 pass through threaded connection, the top of threaded rod 49 sets up anti-skidding line, one side bottom fixed mounting of fixed plate 42 has curb plate 410, and be provided with anti-skidding tooth on the curb plate 410, one side fixed mounting of slide 43 has limiting plate 45.

In fig. 1 and 2: the bottom of the slide plate 43 is provided with a bottom groove 44, and the bottom groove 44 and the pressing plate 48 are matched components and can accommodate the pressing plate 48.

In fig. 1 and 3: the mud scraping structure 3 comprises a motor 31, the motor 31 is fixedly installed at the top of an installation frame on the side face of the electrolytic bath main body 1, a gear 32 is fixedly installed at the bottom end of an output shaft of the motor 31, the gear 32 is arranged in the installation frame, the installation frame is communicated with the anode tank 2, a bottom plate 34 is arranged at the bottom of the anode tank 2, a fixed shaft 37 is fixedly installed in the center of the top of the bottom plate 34, a fluted disc 33 is rotatably connected onto the fixed shaft 37, a plurality of connecting plates 35 are arranged on the fluted disc 33, and the fluted disc 33 is meshed with the gear 32, so that anode mud can be removed; the connecting plates 35 are arranged annularly, the stirring blades 36 are inserted into the tops of the connecting plates 35, the stirring blades 36 are fixedly connected with the tops of the connecting plates 35 through bolts, and the stirring blades 36 are uniformly arranged, so that the electrolytes can be uniformly mixed; and a scraper 38 is fixedly arranged on one side of the connecting plate 35 through bolts, and the scraper 38 is contacted with the top of the bottom plate 34 and can scrape the anode mud.

In fig. 1 and 4: the partition board structure 5 comprises an inserting board 51, the inserting board 51 is inserted in the groove between the anode groove 2 and the cathode groove 7, two vertical cylinders 52 are symmetrically and fixedly mounted at the top of the electrolytic bath main body 1, inserting rods 53 are inserted in the two vertical cylinders 52, springs 54 are sleeved on the inserting rods 53, the springs 54 are arranged in the vertical cylinders 52, the top of the inserting rods 53 is fixedly mounted with a pressing board 57, the pressing board 57 is inserted in the top of the inserting board 51, a limiting strip 55 is further fixedly mounted on the lower surface in the groove between the anode groove 2 and the cathode groove 7, a plurality of round holes 56 are uniformly formed in the limiting strip 55, the limiting strip 55 is inserted in the bottom of the inserting board 51, sealing strips 59 are further fixedly mounted on two sides of the inserting board 51, a pull block 58 is fixedly mounted on one side of the inserting board 51, and whether the anode groove 2 and the cathode groove 7 are communicated or not can be controlled, and liquid can be conveniently discharged.

In fig. 1, 5 and 6: the filtering component 6 comprises a guide cylinder 61, the guide cylinder 61 is fixedly arranged at the bottom of the anode tank 2 in a penetrating way, the guide cylinder 61 is fixedly connected with the bottom plate 34, the bottom of the guide cylinder 61 is provided with a filtering box 62 in a penetrating way, a net rack 67 is inserted in the filtering box 62, one side of the net rack 67 is fixedly provided with a vertical plate 63, the bottom of the filtering box 62 is provided with a drainage port 66 in a penetrating way, and the drainage port 66 is provided with a valve which can filter out anode mud; two screw thread posts 64 are fixedly mounted on one side of the filter box 62, the screw thread posts 64 penetrate through the vertical plate 63 and are provided with the rotating block 65 through threads, and a handle 68 is fixedly mounted on one side of the vertical plate 63 to conveniently draw out the net rack 67.

The working principle of the invention is as follows: the anode is placed between the side plate 410 and the sliding plate 43, the threaded rod 49 is rotated, the threaded rod 49 is matched with the sliding plate 43 through threads, the round tube 46 can limit the limiting column 47 and can fix the anode, the sliding plate 43 can be folded when the anode is installed, the top block 411 cannot block the round tube 46 and the threaded rod 49, the bottom groove 44 can accommodate the pressing plate 48 and cannot block the pressing plate 48, and the pressing plate 48 and the side plate 410 can clamp the anode and can be in contact with the anode guide rod 41;

the starting motor 31 drives the gear 32 to rotate, so that the fluted disc 33 is driven to rotate, the scraper 38 is installed on the connecting plate 35 through bolts, the scraper 38 is in contact with the top of the bottom plate 34 and can scrape anode mud from the bottom plate 34 and fall from holes, the stirring blade 36 is arranged on the top of the connecting plate 35 and can stir to a certain extent, so that the solution can be mixed uniformly to promote the speed of electrolysis, the electrolyte can fall from the guide cylinder 61 and the filter box 62 and flows out through the water outlet 66, the vertical plate 63 is provided with the net rack 67 which can filter the anode mud and is convenient to collect and utilize, the vertical plate 63 can be compressed by the rotating block 65 to prevent liquid leakage, and the rotating block can be pulled out through the pull handle 68 when the net rack 67 is taken out;

the inserting plate 51 is inserted into the groove between the anode groove 2 and the cathode groove 7, the pressing plate 57 is pulled up to enable the pressing plate 57 to be inserted into the top of the inserting plate 51, the inserting plate 51 is compressed under the action of the spring 54, the pulling blocks 58 are arranged on two sides of the inserting plate 51, the limiting strip 55 is inserted into the bottom of the inserting plate 51, good sealing can be kept, the sealing performance between the anode groove 2 and the cathode groove 7 is good, the inserting plate 51 needs to be pulled up or pushed down through the pulling blocks 58 due to good sealing performance, and the solution in the cathode groove 7 can be discharged through the water outlet 66 through the round hole 56.

The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention are equivalent to or changed within the technical scope of the present invention.

Claims

1. A continuous anode electrolytic cell for preparing a multiferroic material comprises an electrolytic cell main body (1) and is characterized in that a through anode cell (2) and a cathode cell (7) are arranged in the electrolytic cell main body (1), a clamping assembly (4) is fixedly mounted on the inner wall of one side of the anode cell (2), a partition plate structure (5) is arranged between the anode cell (2) and the cathode cell (7), a mud scraping structure (3) is arranged on one side of the electrolytic cell main body (1), and a filtering assembly (6) is arranged at the bottom of the electrolytic cell main body (1);

the clamping assembly (4) comprises an anode guide rod (41), the anode guide rod (41) is arranged on the inner wall of the anode tank (2), a fixing plate (42) is fixedly arranged at one end of the anode guide rod (41), a top block (411) is fixedly arranged at the top of the fixing plate (42), a sliding plate (43) is inserted in the top block (411) in a sliding manner, two round pipes (46) are fixedly arranged at the top of the sliding plate (43), limiting columns (47) are inserted in the two round pipes (46), a pressing plate (48) is fixedly arranged at the bottoms of the two limiting columns (47) together, a threaded rod (49) is rotatably arranged in the center of the top of the pressing plate (48) through a bearing, the side face of the threaded rod (49) is connected with the sliding plate (43) through threads, anti-skid threads are arranged at the top of the threaded rod (49), a side plate (410) is fixedly arranged at the bottom of one side of the fixing plate (42), and anti-skid teeth are arranged on the side plate (410), a limit plate (45) is fixedly arranged on one side of the sliding plate (43).

2. A multi-iron material continuous anode electrolytic cell according to claim 1, characterized in that the bottom of the slide plate (43) is provided with a bottom groove (44), and the bottom groove (44) and the press plate (48) are matched components.

3. The continuous anode electrolytic tank for preparing the multiferroic material is characterized in that the mud scraping structure (3) comprises a motor (31), the motor (31) is fixedly installed at the top of an installation frame on the side surface of the electrolytic tank body (1), a gear (32) is fixedly installed at the bottom end of an output shaft of the motor (31), the gear (32) is arranged in the installation frame, the installation frame is communicated with the anode tank (2), a bottom plate (34) is arranged at the bottom of the anode tank (2), a fixed shaft (37) is fixedly installed at the center of the top of the bottom plate (34), a fluted disc (33) is rotatably connected onto the fixed shaft (37), a plurality of connecting plates (35) are arranged on the fluted disc (33), and the fluted disc (33) is meshed with the gear (32).

4. A multi-iron material production continuous anode electrolytic cell according to claim 3, characterized in that a plurality of the connecting plates (35) are arranged in a ring shape, a plurality of stirring blades (36) are inserted into the top of the connecting plates (35), the stirring blades (36) are fixedly connected with the top of the connecting plates (35) through bolts, and the plurality of stirring blades (36) are arranged uniformly.

5. A multi-iron material production continuous anode cell according to claim 4, characterized in that the connecting plate (35) is fixed with scrapers (38) on one side by bolts, the scrapers (38) contacting the top of the bottom plate (34).

6. The continuous anode electrolytic cell prepared from the multiferroic material as claimed in claim 1, wherein the partition plate structure (5) comprises an inserting plate (51), the inserting plate (51) is inserted into the cell between the anode cell (2) and the cathode cell (7), two vertical cylinders (52) are symmetrically and fixedly installed at the top of the electrolytic cell main body (1), an inserting rod (53) is inserted into the two vertical cylinders (52), a spring (54) is sleeved on the inserting rod (53), the spring (54) is arranged in the vertical cylinder (52), a pressing plate (57) is fixedly installed at the top of the inserting rod (53), the pressing plate (57) is inserted into the top of the inserting plate (51), a limiting strip (55) is also fixedly installed at the lower surface in the cell between the anode cell (2) and the cathode cell (7), a plurality of round holes (56) are uniformly formed in the limiting strip (55), and the limiting strip (55) is inserted into the bottom of the inserting plate (51), sealing strips (59) are fixedly arranged on two sides of the inserting plate (51), and a pulling block (58) is fixedly arranged on one side of the inserting plate (51).

7. The continuous anode electrolytic cell for multiferroic material preparation according to claim 1, wherein the filter assembly (6) comprises a guide cylinder (61), the guide cylinder (61) is fixedly arranged at the bottom of the anode cell (2) in a penetrating manner, the guide cylinder (61) is fixedly connected with the bottom plate (34), a filter box (62) is arranged at the bottom of the guide cylinder (61) in a penetrating manner, a net rack (67) is inserted in the filter box (62), a vertical plate (63) is fixedly arranged at one side of the net rack (67), a drainage port (66) is arranged at the bottom of the filter box (62) in a penetrating manner, and a valve is arranged on the drainage port (66).

8. The multi-iron material production continuous anode electrolytic cell according to claim 7, wherein two threaded columns (64) are fixedly installed on one side of the filter box (62), the threaded columns (64) penetrate through a vertical plate (63) and are provided with rotating blocks (65) through threads, and a handle (68) is fixedly installed on one side of the vertical plate (63).