CN117127219B - Electrolytic copper device convenient to retrieve anode mud - Google Patents
Electrolytic copper device convenient to retrieve anode mud Download PDFInfo
- Publication number
- CN117127219B CN117127219B CN202311380941.8A CN202311380941A CN117127219B CN 117127219 B CN117127219 B CN 117127219B CN 202311380941 A CN202311380941 A CN 202311380941A CN 117127219 B CN117127219 B CN 117127219B
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- plate
- fixedly connected
- electrolytic
- anode
- sealing
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000010949 copper Substances 0.000 title claims abstract description 45
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 44
- 238000007789 sealing Methods 0.000 claims abstract description 46
- 238000004062 sedimentation Methods 0.000 claims abstract description 34
- 238000005192 partition Methods 0.000 claims abstract description 21
- 239000012528 membrane Substances 0.000 claims description 15
- 238000009434 installation Methods 0.000 claims description 14
- 230000000694 effects Effects 0.000 claims description 12
- 238000001125 extrusion Methods 0.000 claims description 12
- 238000011084 recovery Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 6
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 6
- 241001330002 Bambuseae Species 0.000 claims description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 6
- 239000011425 bamboo Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 244000309464 bull Species 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 230000000149 penetrating effect Effects 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 abstract description 17
- 238000004064 recycling Methods 0.000 abstract description 9
- 238000000926 separation method Methods 0.000 abstract description 3
- 239000002002 slurry Substances 0.000 abstract description 3
- 238000003723 Smelting Methods 0.000 abstract description 2
- 238000005868 electrolysis reaction Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 241000883990 Flabellum Species 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- -1 platinum group metals Chemical class 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/007—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells comprising at least a movable electrode
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
The invention discloses an electrolytic copper device convenient for recycling anode slime, which belongs to the technical field of electrolytic equipment and aims to solve the problem that when the existing electrolytic equipment is used for electrolytic copper smelting, the anode slime generated by the existing electrolytic equipment is directly deposited at the bottom of an electrolytic cell and is difficult to be pumped and sucked by a slurry pump for recycling; according to the invention, the L-shaped partition plate is matched with the sedimentation tube, the collection tank is uniformly arranged at the bottom of the L-shaped partition plate at the hollow groove of the electrolytic cell, the collection tank is used for collecting the naturally sedimentary anode slime, and meanwhile, the adjustment disk is matched with the squeezing drive of the collected anode slime, so that the automatic control of the adjustment disk on the sealing shifting piece and the positioning shifting piece to the top port of the sealing collection tank in a staggered manner is realized, the partition of the collected anode slime and electrolyte in the collection tank is realized, the rapid collection and separation of the collected anode slime and electrolyte in the electrolytic cell are realized, and only the collection tank at the bottom of the sedimentation tube is needed to be replaced regularly, so that the operation is easy and rapid.
Description
Technical Field
The invention relates to the technical field of electrolysis equipment, in particular to an electrolytic copper device convenient for recycling anode slime.
Background
Electrolytic copper is prepared by preparing thick plate of coarse copper as anode, preparing thin sheet of pure copper as cathode, and adding sulfuric acid (H) 2 SO 4 ) And copper sulfate (CuSO) 4 ) The mixed solution is used as electrolyte. After the power is applied, copper dissolves from the anode to copper ions (Cu) and moves to the cathode, and electrons are obtained after reaching the cathode, and pure copper (also called electrolytic copper) is precipitated at the cathode. For copper hydrometallurgy (i.e. electrolytic copper), copper sludge is the product of the copper electrorefining process and contains major elements including gold, silver, platinum group metals, copper, selenium, tellurium, arsenic, antimony, bismuth, nickel, tin, lead, silicon dioxide, and the like. The valuable metals such as gold, silver, platinum, palladium, selenium, tellurium, antimony, bismuth, tin and the like in the anode slime are treated, so that the recycling value is extremely high.
The patent with the publication number of CN218880087U discloses an alkaline etching solution circulation regeneration electrolytic copper device, which comprises an electrolytic cell and is characterized in that a discharging pipe is arranged on the side wall of the electrolytic cell, an adjusting device is arranged on the side wall of the electrolytic cell and comprises a fixing frame, the fixing frame is fixedly connected with two sides of the electrolytic cell, a driving rod is inserted into the fixing frame through internal threads, the lower end of the driving rod is rotationally connected with a connecting plate, one side, close to the driving rod, of the connecting plate is fixedly connected with a fixing plate, a reverse screw is rotationally connected with the fixing plate, two supporting blocks are connected with the arc surface of the reverse screw through threads, and two sliding holes are formed in the surface of the connecting plate, so that a plurality of copper-containing plates can be electrolyzed simultaneously at one time conveniently. However, in the conventional electrolysis equipment, the anode slime is mostly naturally settled, but the anode slime precipitated at the bottom of the electrolytic cell is difficult to be filtered and recovered by a mud pump to a filter press, so that the anode slime is inconvenient to recover.
Therefore, an electrolytic copper device convenient for recycling anode slime is provided.
Disclosure of Invention
The invention aims to provide an electrolytic copper device convenient for recycling anode slime, and aims to solve the problem that the anode slime produced by the conventional electrolytic equipment is difficult to be pumped and sucked by a slurry pump for recycling after being deposited at the bottom of an electrolytic cell when the electrolytic copper is smelted in the prior art.
In order to achieve the above purpose, the present invention provides the following technical solutions: the electrolytic copper device comprises an electrolytic cell and a liquid injection pipe arranged on the side wall of one end of the electrolytic cell, wherein an ionic membrane is fixedly connected between the inner walls of the two sides of the electrolytic cell, a hollow tank is formed in the bottom of the electrolytic cell on one side of the ionic membrane, an L-shaped partition plate is fixedly connected between the inner walls of the top of the hollow tank, vertical plates of the L-shaped partition plate are attached to the ionic membrane, collecting tanks are uniformly arranged on the top plate of the L-shaped partition plate at intervals, a sedimentation pipe is fixedly connected at the bottom of the collecting tanks, and a collecting tank is movably connected at the bottom of the sedimentation pipe;
the fixed location plectrum of card between collection tank top department port inner wall, the lower extreme activity of location plectrum is run through and is provided with the locating sleeve pipe, the locating sleeve pipe top runs through and extends to the location plectrum top, its end fixedly connected with seals the plectrum, sealed plectrum laminating location plectrum top sets up, the flexible cutting ferrule in locating sleeve's bottom has the connecting axle, the bottom fixedly connected with of connecting axle is in regulating plate top middle part department, the bottom fixedly connected with of regulating plate removes the closing plate, remove closing plate activity block in between collection tank top port department inner wall.
Further, the regulating plate includes fixed plate and the annular section of thick bamboo of fixed connection in the connecting axle bottom in fixed plate bottom, annular section of thick bamboo lower extreme activity cutting ferrule is in the annular spacing intracavity at fixed section of thick bamboo top, and set up the regulation thread groove on the inner wall of fixed section of thick bamboo, fixed section of thick bamboo lower extreme fixed connection is in the removal closing plate top, removal closing plate top both sides activity block is provided with elastomeric element, elastomeric element top fixedly connected with in fixed plate lower extreme, fixed plate bottom one side fixedly connected with L type gag lever post, the terminal activity block of L gag lever post bottom straight-bar is in the regulation thread groove.
Further, the diameter of the fixed plate is smaller than that of the movable sealing plate, when the elastic component keeps a normal diastole state, the lower end of the annular cylinder is positioned at the top port of the annular limiting cavity, at the moment, the tail end of the bottom straight rod of the L-shaped limiting rod is positioned in the adjusting thread groove at the top port of the fixed cylinder, and the connecting shaft is completely contracted in the inner cavity at the bottom of the positioning sleeve.
Further, the both ends of collecting vessel bottom are fixed continuous with the top both ends of U type frame respectively, and the bottom plate middle part department activity of U type frame runs through and is provided with the regulation bull stick, and the top of adjusting the bull stick runs through and extends to the fixed cylinder inner chamber after moving the closing plate, and fixedly connected with connecting strip on the outer wall of one side that the collecting vessel is close to top department, the terminal fixedly connected with of connecting strip strain Kong Dinggai.
Further, the top of the movable sealing plate on two sides of the adjusting rotating rod is fixedly connected with a pressure sensor respectively, the pressure sensor is arranged on the inner side of the elastic component, the two sides of the bottom of the fixed plate between the elastic components are fixedly connected with an extrusion rod respectively, and the extrusion rod corresponds to the pressure sensor.
Further, the composition structure of the positioning plectrum and the sealing plectrum is the same, and positioning plectrum and sealing plectrum are flabellum structure, and its fan-shaped blade quantity is corresponding, and positioning plectrum and the fan-shaped blade terminal radian of sealing plectrum all suits with collection tank inner wall radian, and the fan-shaped blade of positioning plectrum and sealing plectrum is crisscross when each other totally shutoff collection tank top port.
Further, the collecting tank is of a funnel-shaped structure, a sedimentation pipe is arranged in the middle of the bottom plate in a penetrating mode, the top end opening of the sedimentation pipe is flush with the upper end of the bottom plate of the collecting tank, an electric telescopic rod is fixedly connected to the outer wall of one side of the sedimentation pipe at the lower end of the bottom plate of the collecting tank, a movable plugboard is fixedly connected to the bottom of the tail end of the electric telescopic rod, and the tail end of the movable plugboard penetrates through the side wall of the sedimentation pipe and extends to the inside of the sedimentation pipe.
Further, remove the picture peg and include fixed connection in the installation casing of electric telescopic link terminal bottom and fixed connection in the installation casing flexible pad, the lateral wall card around the flexible pad is fixed in the through-hole on the installation casing lateral wall, and fixed connection has the sealing ring on the inner wall of installation casing top port department, fixedly connected with flexible piece between the sealing ring intermediate hole inner wall.
Further, limit sliding grooves are formed in the side walls of the electrolytic cells on two sides of the L-shaped partition plate, movable blocks are movably clamped in the limit sliding grooves, lifting support rods are fixedly connected to the top ends of the movable blocks, the tail ends of the lifting support rods are fixedly connected to the side walls of two ends of the anode plate, the anode plate is suspended in the electrolytic cell above the L-shaped partition plate, a cathode plate is fixedly connected to the inner wall of the electrolytic cell, which is far away from one end of the anode plate, and the cathode plate is suspended in the electrolytic cell, which is far away from one side of the anode plate, of the ionic membrane.
Further, the positive pole plate includes fixed connection in the terminal L type buckle of lift bracing piece and fixed connection in the installation gallows at L type buckle both ends top, installation gallows top straight-bar activity cup joints in the terminal fixed cover of lift bracing piece, and the activity is provided with the screw thread loop pole on the riser bottom department lateral wall of installation gallows one side, the terminal fixed connection of screw thread loop pole is on moving splint lateral wall, it electrolyzes the copper to press from both sides between moving splint and the L type buckle riser lateral wall, and L type buckle top both sides fixedly connected with conductive post, conductive post lower extreme laminating electrolysis copper sets up, and the ring cover sets up connecting cable on the outer wall of conductive post.
Compared with the prior art, the invention has the following beneficial effects:
according to the electrolytic copper device convenient for recycling anode slime, the collecting tank is uniformly arranged at the bottom of the L-shaped baffle plate at the hollow groove of the electrolytic tank through the cooperation of the L-shaped baffle plate and the sedimentation pipe, the collecting tank is used for collecting liquid discharged from the naturally sedimentated anode slime, and meanwhile, the adjusting disk is matched for collecting the extrusion driving of the anode slime, so that the automatic control of the adjusting disk on the top port of the sealing shifting disk and the positioning shifting disk in a staggered sealing manner of the collecting tank is realized, the separation of the collected anode slime and electrolyte in the collecting tank is realized, the collected anode slime is prevented from overflowing due to the disturbance of the electrolyte, at the moment, the collecting tank is unscrewed from the hollow groove at the bottom of the electrolytic tank, the anode slime generated by electrolytic copper can be recycled, and the collecting tank at the bottom of the sedimentation pipe is only needed to be replaced regularly, so that the electrolytic copper device is convenient and practical.
Drawings
FIG. 1 is a schematic diagram of the overall structure of the present invention;
FIG. 2 is a schematic cross-sectional view of an electrolytic cell of the present invention;
FIG. 3 is a schematic view of the structure of the L-shaped partition and collection tank of the present invention;
FIG. 4 is a schematic cross-sectional view of the collection tank of the present invention in an open state;
FIG. 5 is a schematic cross-sectional view of the collection tank of the present invention in a closed state;
FIG. 6 is a schematic view of the assembly of the positioning paddles and sealing paddles of the present invention;
FIG. 7 is an enlarged schematic view of the structure of FIG. 5A according to the present invention;
FIG. 8 is a cross-sectional view of a conditioning disk of the present invention;
FIG. 9 is a cross-sectional view of a settling tube of the present invention;
FIG. 10 is a cross-sectional view of a mobile insert plate of the present invention;
fig. 11 is a schematic view of the structure of an anode plate member according to the present invention.
In the figure: 1. an electrolytic cell; 2. a liquid injection pipe; 3. an ionic membrane; 4. a hollow groove; 5. an L-shaped partition; 6. a material collecting groove; 7. a sedimentation tube; 71. an electric telescopic rod; 72. moving the plugboard; 721. a mounting shell; 722. a flexible pad; 723. a seal ring; 724. a flexible sheet; 8. a collection tank; 81. positioning a poking piece; 82. positioning the sleeve; 83. sealing the poking piece; 84. a connecting shaft; 85. an adjusting plate; 851. a fixing plate; 852. an annular cylinder; 853. a fixed cylinder; 854. an annular limiting cavity; 855. adjusting the thread groove; 856. an elastic member; 857. an L-shaped limiting rod; 858. an extrusion rod; 86. moving the sealing plate; 861. a U-shaped frame; 862. adjusting the rotating rod; 863. a pressure sensor; 87. a connecting strip; 88. filtering Kong Dinggai; 9. limiting sliding grooves; 91. a moving block; 10. lifting the support rod; 11. an anode plate member; 111. an L-shaped buckle plate; 112. installing a hanging bracket; 113. a threaded sleeve rod; 114. moving the clamping plate; 115. electrolytic copper plate; 116. a conductive post; 117. a connecting cable; 12. and (5) a cathode plate.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Referring to fig. 1, an electrolytic copper device convenient for recycling anode mud comprises an electrolytic cell 1 with a square structure and a liquid injection pipe 2 fixedly connected to the side wall of one end of the electrolytic cell 1, wherein the liquid injection pipe 2 is used for injecting electrolyte into the electrolytic cell 1, a controller is arranged on the outer wall of the other side of the electrolytic cell 1, an ion membrane 3 is fixedly connected between the inner walls of the two sides of the electrolytic cell 1, the lower end of the ion membrane 3 is fixedly connected with the bottom plate of the electrolytic cell 1, and the ion membrane 3 is used for enriching cations to an electrolytic cathode.
In order to solve the problem that the anode slime generated by the existing electrolysis equipment is difficult to be pumped and sucked by a slurry pump for recovery treatment after being directly precipitated at the bottom of the electrolytic cell 1 when the electrolytic copper smelting is carried out by the existing electrolysis equipment, referring to fig. 1-8 and 11, the following preferable technical scheme is provided:
a hollow tank 4 is arranged at the bottom of the electrolytic cell 1 at one side of the ionic membrane 3, vertical plates fixedly connected with an L-shaped partition board 5,L type partition board 5 between the inner walls at the top of the hollow tank 4 are attached to the ionic membrane 3, collecting tanks 6 are uniformly arranged on the top plate of the L-shaped partition board 5 at intervals, sedimentation pipes 7 are fixedly connected at the bottom of the collecting tanks 6, and cylindrical collecting tanks 8 are connected at the bottom of the sedimentation pipes 7 in a threaded manner;
the even interval fixed connection L type projection on the port inner wall of collection jar 8 top department, sleeve hole on the cutting ferrule location plectrum 81 on the L type projection outer wall, the lower extreme activity of location plectrum 81 runs through and is provided with positioning sleeve 82, positioning sleeve 82 top runs through and extends to location plectrum 81 top, its end fixedly connected with seals plectrum 83, the sealed plectrum 83 laminating location plectrum 81 top sets up, the bottom activity cutting ferrule of positioning sleeve 82 has connecting axle 84, the bottom fixedly connected with of connecting axle 84 is in regulating plate 85 top middle part department, the bottom fixedly connected with of regulating plate 85 removes closing plate 86, remove closing plate 86 activity block in between the inner wall of collection jar 8 top port department.
The adjusting disk 85 comprises a fixed plate 851 fixedly connected to the bottom of the connecting shaft 84 and an annular cylinder 852 fixedly connected to the bottom of the fixed plate 851, the lower end of the annular cylinder 852 is movably clamped in an annular limiting cavity 854 at the top of the fixed cylinder 853, an adjusting thread groove 855 is formed in the inner wall of the fixed cylinder 853, the lower end of the fixed cylinder 853 is fixedly connected to the top of the movable sealing plate 86, elastic components 856 are movably clamped on two sides of the top of the movable sealing plate 86, the top of the elastic components 856 is fixedly connected to the lower end of the fixed plate 851, one side of the bottom of the fixed plate 851 is fixedly connected with an L-shaped limiting rod 857, and the tail end of a straight rod at the bottom of the L-shaped limiting rod 857 is movably clamped in the adjusting thread groove 855.
The positioning poking piece 81 and the sealing poking piece 83 are identical in composition structure, the positioning poking piece 81 and the sealing poking piece 83 are of fan blade type structures, the number of fan-shaped blades of the positioning poking piece 81 is corresponding, trepanning is formed in the edge of the tail end of the fan-shaped blade of the positioning poking piece 81 so as to clamp and fix the L-shaped convex column, the radian of the tail ends of the fan-shaped blades of the positioning poking piece 81 and the sealing poking piece 83 are matched with the radian of the inner wall of the collecting tank 8, and the top port of the collecting tank 8 is completely plugged when the fan-shaped blades of the positioning poking piece 81 and the sealing poking piece 83 are mutually staggered.
The diameter of the fixed plate 851 is smaller than that of the movable sealing plate 86, when the elastic member 856 keeps a normal and relaxed state, the lower end of the annular cylinder 852 is positioned at the top port of the annular limiting cavity 854, at this time, the tail end of the bottom straight rod of the L-shaped limiting rod 857 is positioned in the adjusting thread groove 855 at the top port of the fixed cylinder 853, and the connecting shaft 84 is completely contracted in the bottom inner cavity of the positioning sleeve 82.
Limiting sliding grooves 9 are formed in the side walls of the electrolytic cell 1 on two sides of the L-shaped partition plate 5, movable blocks 91 are movably clamped in the limiting sliding grooves 9, lifting support rods 10 are fixedly connected to the top ends of the movable blocks 91, the tail ends of the lifting support rods 10 are fixedly connected to the side walls of two ends of the anode plate 11, the anode plate 11 is suspended in the electrolytic cell 1 above the L-shaped partition plate 5, multiple groups of anode plate 11 can be suspended in the electrolytic cell 1 by matching with the lifting support rods 10 through the arrangement of multiple groups of movable blocks 91 in the limiting sliding grooves 9, simultaneous electrolysis of copper plates of the multiple groups of anode plate 11 is achieved, cathode plates 12 are fixedly connected to the inner wall, away from one end of the anode plate 11, of the electrolytic cell 1, and the cathode plates 12 are suspended in the electrolytic cell 1, away from one side of the anode plate 11, of the ionic membrane 3.
The anode plate 11 comprises an L-shaped buckle 111 fixedly connected to the tail end of the lifting support rod 10 and an installation hanging bracket 112 fixedly connected to the tops of two ends of the L-shaped buckle 111, a straight rod at the top end of the installation hanging bracket 112 is movably sleeved in a fixed sleeve at the tail end of the lifting support rod 10, a threaded sleeve rod 113 is movably arranged on the side wall of the bottom of a vertical plate on one side of the installation hanging bracket 112, the tail end of the threaded sleeve rod 113 is fixedly connected to the side wall of a movable clamping plate 114 (the threaded sleeve rod 113 consists of a rotary sleeve and a threaded column, the threaded column is fixedly connected with the movable clamping plate 114, the rotary sleeve on the outer wall of the threaded column is movably connected with a vertical plate on one side of the installation hanging bracket 112), an electrolytic copper plate 115 is clamped between the movable clamping plate 114 and the side wall of the vertical plate 111, two sides of the top of the L-shaped buckle 111 are fixedly connected with conductive columns 116, the lower ends of the conductive columns 116 are attached to the electrolytic copper plate 115, and conductive rings connected with the ends of the cable 117 are sleeved on the outer walls of the conductive columns 116.
Specifically, in the initial stage, the positioning pulling piece 81 and the sealing pulling piece 83 are completely overlapped, so that the top port of the collecting tank 8 is communicated with the sedimentation tube 7, when the blister copper plate is suspended in the electrolytic cell 1 for electrolysis, anode mud generated by the electrolysis of the blister copper plate is settled in the collecting tank 6 on the L-shaped partition plate 5, slides and intensively falls into the sedimentation tube 7 along the collecting tank 6, so as to enter the collecting tank 8 at the bottom of the sedimentation tube 7, anode mud entering the collecting tank 8 is accumulated above the fixed plate 851 and the movable sealing plate 86 of the adjusting plate 85, meanwhile, the accumulated anode mud is reversely extruded and removed from electrolyte entering the collecting tank 8, when the weight of the anode mud on the fixed plate 851 counteracts the elastic supporting force of the elastic component 856 at the bottom of the fixed plate 851, the elastic component 856 is extruded by the gravity of the anode mud to be compressed, so that the fixed plate 851 starts to slowly move downwards, the fixed plate 851 slowly moves downwards and drives the L-shaped limiting rod 857 to slide downwards along the adjusting thread groove 855 on the inner wall of the fixed barrel 853, so that the fixed plate 851 rotates, the positioning sleeve 82 and the connecting shaft 84 are matched to drive the sealing stirring piece 83 to start rotating when the fixed plate 851 rotates, until the annular barrel 852 is contracted in the annular limiting cavity 854 of the fixed barrel 853, when the collecting tank 8 is full of anode mud, the sealing stirring piece 83 and the positioning stirring piece 81 automatically misplaced to seal the top port of the collecting tank 8, the collected anode mud is prevented from overflowing due to disturbance of electrolyte, at the moment, the anode mud fully deposited in the collecting tank 8 is screwed off from the hollow groove 4 at the bottom of the electrolytic cell 1, the collecting tank 8 can be completely recovered, and the collecting tank 8 at the bottom of the sedimentation tube 7 only needs to be replaced regularly, so that the device is convenient and practical.
As shown in fig. 4 to 8, in order to facilitate rapid treatment of the anode slime collected in the collection tank 8, the following scheme is provided in this embodiment:
the two ends of the bottom of the collecting tank 8 are fixedly connected with the two ends of the top of the U-shaped frame 861 respectively, an adjusting rotating rod 862 is movably arranged in the middle of the bottom plate of the U-shaped frame 861 in a penetrating mode, the top end of the adjusting rotating rod 862 penetrates through the movable sealing plate 86 and then extends to the inner cavity of the fixed cylinder 853, a connecting strip 87 is fixedly connected to the outer wall of one side of the collecting tank 8, which is close to the top, and a filter Kong Dinggai 88 is fixedly connected to the tail end of the connecting strip 87.
The top of the movable sealing plate 86 on two sides of the adjusting rotating rod 862 is fixedly connected with a pressure sensor 863 respectively, the pressure sensor 863 is arranged on the inner side of the elastic component 856, two sides of the bottom of the fixed plate 851 between the elastic components 856 are fixedly connected with an extrusion rod 858 respectively, the extrusion rod 858 is arranged corresponding to the pressure sensor 863, the pressure sensor 863 is connected with a controller through a built-in wireless module, when the inner cavity of the collecting tank 8 is filled with anode mud accumulated on the top of the fixed plate 851, the fixed plate 851 moves downwards to enable the extrusion rod 858 to move and attach with the pressure sensor 863, wireless signals are generated by extrusion of the extrusion rod 858 to the pressure sensor 863, and the wireless signals are transmitted to the controller to alarm the collecting tank 8 to collect the anode mud fully, so that the collected anode mud is conveniently cleaned out for centralized treatment.
Specifically, twist the collecting vessel 8 from the settling tube 7 bottom and take off the back, will fix a position the plectrum 81 and take off from the L type projection on the collecting vessel 8 port department inner wall, fix a position the plectrum 81 and take out from the connecting axle 84 outer wall with sealed plectrum 83 through locating sleeve 82 jointly, make it take out collecting vessel 8 top port, collecting vessel 8 top port is opened completely, produce the interference that blocks when avoiding collecting anode mud to pour out, the anode mud that conveniently will collect in the collecting vessel 8 pours out fast, at this moment with straining Kong Dinggai 88 and twist on collecting vessel 8 port outer wall, utilize straining Kong Dinggai to seal up collecting vessel 8 top port, make collecting vessel 8 port invert downwards, rotatory adjusting lever 862, adjusting lever 862 drives and removes closing plate 86 and to strain Kong Dinggai 88, promote simultaneously that adjusting plate 85 extrudees the anode mud in the collecting vessel 8, make its inside electrolyte extrusion discharge, realize carrying out the quick dehumidification operation to the anode mud of collection, can pour out the anode mud after straining Kong Dinggai and store.
As shown in fig. 3 and fig. 8 to fig. 10, in order to achieve rapid detachment of the collected anode slime from the electrolyte, the following scheme is provided in this embodiment:
the collecting tank 6 is of a funnel-shaped structure, the middle part of the bottom plate of the collecting tank 6 is penetrated and provided with a sedimentation pipe 7, the top port of the sedimentation pipe 7 is flush with the upper end of the bottom plate of the collecting tank 6, an electric telescopic rod 71 is fixedly connected to the outer wall of one side of the sedimentation pipe 7 at the lower end of the bottom plate of the collecting tank 6, the bottom of the tail end of the electric telescopic rod 71 is fixedly connected with a movable plugboard 72, and the tail end of the movable plugboard 72 penetrates through the side wall of the sedimentation pipe 7 and extends to the inside of the sedimentation pipe.
The movable plugboard 72 comprises a mounting shell 721 fixedly connected to the bottom of the tail end of the electric telescopic rod 71 and a flexible pad 722 fixedly connected to the mounting shell 721, the peripheral side wall of the flexible pad 722 is clamped and fixed in a through hole on the side wall of the mounting shell 721, a sealing ring 723 is fixedly connected to the inner wall of the top port of the mounting shell 721, and a flexible sheet 724 is fixedly connected between the inner walls of the middle holes of the sealing ring 723.
Specifically, when the collecting tank 8 is full of anode mud and an alarm signal is sent to the controller, the controller controls the electric telescopic rod 71 to retract, so that the movable plugboard 72 is inserted back into the sedimentation pipe 7, the sedimentation pipe 7 and the electrolytic cell 1 are blocked by closing to the top port of the collecting tank 8, the electrolyte in the electrolytic cell 1 is prevented from continuously intersecting with the collecting tank 8, the automatic separation of the anode mud and the electrolyte in the electrolytic cell 1 is realized, the electrolyte content in the collected anode mud is greatly reduced, the anode mud is convenient to filter and dry, the electrolyte in the electrolytic cell 1 is conveniently filtered and dried, after the movable plugboard 72 is inserted back into the sedimentation pipe 7, the electrolyte contacts the flexible sheet 724 in the middle hole of the sealing ring 723 at the top of the movable plugboard 72, the electrolyte extrudes the flexible sheet 724 downwards to deform the flexible sheet 722 through gravity, the flexible sheet 724 deforms and stretches out along the through holes on the side wall of the mounting shell 721, the gap middle part of the movable plugboard 72 and the inner wall of the sedimentation pipe 7 is filled in the gap of the movable plugboard 72, and the leakage of the electrolyte in the electrolytic cell 1 is further enhanced.
It is noted that relational terms such as first and second, and the like are used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Moreover, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (9)
1. Electrolytic copper device convenient to retrieve anode mud, including electrolytic cell (1) and annotate liquid pipe (2) of setting on electrolytic cell (1) one end lateral wall, fixedly connected with ion membrane (3), its characterized in that between the both sides inner wall of electrolytic cell (1): a hollow groove (4) is formed in the bottom of the electrolytic cell (1) on one side of the ionic membrane (3), an L-shaped partition plate (5) is fixedly connected between inner walls at the top of the hollow groove (4), vertical plates of the L-shaped partition plate (5) are attached to the ionic membrane (3) and are arranged, collecting tanks (6) are uniformly arranged on top plates of the L-shaped partition plate (5) at intervals, sedimentation pipes (7) are fixedly connected to the bottom of the collecting tanks (6), and collecting tanks (8) are movably connected to the bottoms of the sedimentation pipes (7);
the device comprises a collecting tank (8), wherein a positioning stirring sheet (81) is fixedly clamped between inner wall parts of ports at the top of the collecting tank, a positioning sleeve (82) is movably arranged at the lower end of the positioning stirring sheet (81) in a penetrating manner, the top end of the positioning sleeve (82) is penetrated and extended to the top of the positioning stirring sheet (81), a sealing stirring sheet (83) is fixedly connected to the tail end of the positioning sleeve, the sealing stirring sheet (83) is attached to the top of the positioning stirring sheet (81), a connecting shaft (84) is movably clamped at the bottom of the positioning sleeve (82), the bottom of the connecting shaft (84) is fixedly connected to the middle part of the top end of an adjusting disc (85), a movable sealing plate (86) is fixedly connected to the bottom of the adjusting disc (85), and the movable sealing plate (86) is movably clamped between inner wall parts at the top ports of the collecting tank (8);
the adjusting disc (85) comprises a fixed plate (851) fixedly connected to the bottom of the connecting shaft (84) and an annular cylinder (852) fixedly connected to the bottom of the fixed plate (851), the lower end of the annular cylinder (852) is movably clamped in an annular limiting cavity (854) at the top of the fixed cylinder (853), an adjusting thread groove (855) is formed in the inner wall of the fixed cylinder (853), the lower end of the fixed cylinder (853) is fixedly connected to the top of the movable sealing plate (86), elastic components (856) are movably clamped on two sides of the top of the movable sealing plate (86), the top of the elastic components (856) is fixedly connected to the lower end of the fixed plate (851), one side of the bottom of the fixed plate (851) is fixedly connected with an L-shaped limiting rod (857), and the tail end of a straight rod at the bottom of the L-shaped limiting rod (857) is movably clamped in the adjusting thread groove (855).
2. An electrolytic copper device for facilitating the recovery of anode slime as claimed in claim 1, wherein: the diameter of the fixed plate (851) is smaller than that of the movable sealing plate (86), when the elastic component (856) keeps a normal diastole state, the lower end of the annular cylinder (852) is positioned at the top port of the annular limiting cavity (854), at the moment, the tail end of the bottom straight rod of the L-shaped limiting rod (857) is positioned in the adjusting thread groove (855) at the top port of the fixed cylinder (853), and the connecting shaft (84) is completely contracted in the bottom inner cavity of the positioning sleeve (82).
3. An electrolytic copper device for facilitating the recovery of anode slime as claimed in claim 1, wherein: the bottom both ends of collection jar (8) are fixed continuous with the top both ends of U type frame (861) respectively, and the bottom plate middle part department activity of U type frame (861) runs through and is provided with regulation bull stick (862), and the top of regulation bull stick (862) runs through and extends to fixed section of thick bamboo (853) inner chamber after moving closing plate (86), and fixedly connected with connecting strip (87) on the outer wall of one side that collection jar (8) is close to top department, the terminal fixedly connected with of connecting strip (87) strain Kong Dinggai (88).
4. An electrolytic copper device for facilitating the recovery of anode slime as claimed in claim 3, wherein: the top of the movable sealing plate (86) on two sides of the adjusting rotating rod (862) is fixedly connected with a pressure sensor (863) respectively, the pressure sensor (863) is arranged on the inner side of the elastic components (856), the two sides of the bottom of the fixed plate (851) between the elastic components (856) are fixedly connected with an extrusion rod (858) respectively, and the extrusion rod (858) is arranged corresponding to the pressure sensor (863).
5. An electrolytic copper device for facilitating the recovery of anode slime as claimed in claim 1, wherein: the positioning poking piece (81) and the sealing poking piece (83) are identical in composition structure, the positioning poking piece (81) and the sealing poking piece (83) are of fan blade structures, the number of fan-shaped blades of the positioning poking piece (81) and the sealing poking piece (83) is corresponding, the radian of the tail ends of the fan-shaped blades of the positioning poking piece (81) and the sealing poking piece (83) are matched with the radian of the inner wall of the collecting tank (8), and the top ports of the collecting tank (8) are completely plugged when the fan-shaped blades of the positioning poking piece (81) and the sealing poking piece (83) are mutually staggered.
6. An electrolytic copper device for facilitating the recovery of anode slime as claimed in claim 1, wherein: the collecting tank (6) is of a funnel-shaped structure, the middle part of the bottom plate of the collecting tank is penetrated and provided with a sedimentation pipe (7), the top port of the sedimentation pipe (7) is flush with the upper end of the bottom plate of the collecting tank (6), an electric telescopic rod (71) is fixedly connected to the outer wall of one side of the sedimentation pipe (7) at the lower end of the bottom plate of the collecting tank (6), the bottom of the tail end of the electric telescopic rod (71) is fixedly connected with a movable plugboard (72), and the tail end of the movable plugboard (72) penetrates through the side wall of the sedimentation pipe (7) and extends to the inside of the sedimentation pipe.
7. An electrolytic copper device for facilitating the recovery of anode slime as claimed in claim 6, wherein: the movable plugboard (72) comprises a mounting shell (721) fixedly connected to the bottom of the tail end of the electric telescopic rod (71) and a flexible pad (722) fixedly connected to the inside of the mounting shell (721), the peripheral side wall of the flexible pad (722) is clamped and fixed in a through hole on the side wall of the mounting shell (721), a sealing ring (723) is fixedly connected to the inner wall of a top port of the mounting shell (721), and flexible sheets (724) are fixedly connected between the inner walls of middle holes of the sealing ring (723).
8. An electrolytic copper device for facilitating the recovery of anode slime as claimed in claim 1, wherein: limiting sliding grooves (9) are formed in the side walls of the electrolytic cells (1) on two sides of the L-shaped partition plate (5), moving blocks (91) are movably clamped in the limiting sliding grooves (9), lifting support rods (10) are fixedly connected to the top ends of the moving blocks (91), the tail ends of the lifting support rods (10) are fixedly connected to the side walls of two ends of an anode plate (11), the anode plate (11) is suspended in the electrolytic cells (1) above the L-shaped partition plate (5), cathode plates (12) are fixedly connected to the inner walls of one ends of the electrolytic cells (1) away from the anode plate (11), and the cathode plates (12) are suspended in the electrolytic cells (1) on one sides of the ion membranes (3) away from the anode plate (11).
9. An electrolytic copper device for facilitating the recovery of anode slime as claimed in claim 8, wherein: the anode plate (11) comprises an L-shaped buckle plate (111) fixedly connected to the tail end of the lifting support rod (10) and an installation hanging frame (112) fixedly connected to the tops of two ends of the L-shaped buckle plate (111), a straight rod at the top end of the installation hanging frame (112) is movably sleeved in a fixed sleeve at the tail end of the lifting support rod (10), a threaded sleeve rod (113) is movably arranged on the side wall of the bottom of a vertical plate on one side of the installation hanging frame (112), the tail end of the threaded sleeve rod (113) is fixedly connected to the side wall of a movable clamp plate (114), an electrolytic copper plate (115) is clamped between the movable clamp plate (114) and the side wall of the vertical plate of the L-shaped buckle plate (111), conductive columns (116) are fixedly connected to two sides of the top of the L-shaped buckle plate (111), the lower ends of the conductive columns (116) are attached to the electrolytic copper plate (115), and connecting cables (117) are arranged on the outer wall of the conductive columns (116) in a ring mode.
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| CN202311380941.8A CN117127219B (en) | 2023-10-24 | 2023-10-24 | Electrolytic copper device convenient to retrieve anode mud |
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| CN202311380941.8A CN117127219B (en) | 2023-10-24 | 2023-10-24 | Electrolytic copper device convenient to retrieve anode mud |
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