CN113929499A - Ceramic tile with mirror surface relief decoration effect and preparation method - Google Patents
Ceramic tile with mirror surface relief decoration effect and preparation method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention discloses a ceramic tile with a mirror surface relief decoration effect and a preparation method thereof. The preparation method comprises the following steps: applying surface glaze on the surface of the green brick; applying high-refractive-index glaze on the surface of the green brick after the surface glaze is applied; printing patterns on the surface of the green brick after the high-refractive-index glaze is applied by ink jet; applying transparent glaze on the surface of the green brick after the pattern is printed by ink jet; and (5) firing. The preparation method promotes the glaze to present relief imaging decoration effects at different angles by matching the transparent glaze layer with high-refractive index substances.
Description
Technical Field
The invention relates to a ceramic tile with a mirror surface relief decoration effect and a preparation method thereof, belonging to the technical field of ceramic tile production and manufacturing.
Background
The ceramic types in the building industry are rare, and along with the improvement of the consumption level, the market demand for the ceramic tiles with decorative effects is increased. In order to meet market demands, relief, three-dimensional and simulation texture surface ceramic products are introduced in the ceramic industry, but most of the products mainly use natural surfaces, lack noble feeling, are easy to store ash and are not clean in later period.
Chinese patent CN108727037A discloses a three-dimensional high-simulation ceramic tile with a matt glaze surface and a preparation method thereof, wherein a small amount of matt glaze is applied at high pressure, dry particles are scattered in combination with ink-jet printing, and redundant dry particle frit is sucked away by adopting a controllable negative pressure dry particle frit sucking device, so that a high-simulation three-dimensional effect is obtained. The preparation method needs a high-precision laser engraving die, has a single decorative effect and high production cost, and the glaze surface is easy to hide and is not beneficial to cleaning.
Disclosure of Invention
Aiming at the problems, the invention provides a ceramic tile with mirror surface relief decoration effect and a preparation method thereof, wherein the glaze surface is promoted to show relief imaging decoration effect at different angles by matching a transparent glaze layer with a high-refractive index substance.
In a first aspect, the present invention provides a method for preparing a ceramic tile with a mirror relief decoration effect. The preparation method comprises the following steps:
applying surface glaze on the surface of the green brick;
applying high-refractive-index glaze on the surface of the green brick after the surface glaze is applied;
printing patterns on the surface of the green brick after the high-refractive-index glaze is applied by ink jet;
applying transparent glaze on the surface of the green brick after the pattern is printed by ink jet;
and (5) firing.
Preferably, the initial melting temperature of the overglaze is 1100-1150 ℃, and the initial melting temperature of the high-refractive-index glaze is 1180-1220 ℃. Preferably, the difference of the initial melting temperature of the overglaze and the high-refractive-index glaze is 70-80 ℃.
Preferably, the refractive index of the high-refractive-index glaze is 1.87 to 1.92, and the refractive index of the transparent glaze is 1.52 to 1.54. Preferably, the difference of the refractive indexes of the high-refraction glaze and the transparent glaze is 0.35-0.38.
Preferably, the chemical composition of the high-refractive-index glaze comprises: by mass percent, SiO2：50～55％、Al2O3: 6.9-7.7%, CaO: 12-14%, MgO: 0.1 to 0.3%, alkali metal oxide: 3.3-5.1% of SnO2：0.8～1.0％、ZrO2：13～16％、Ce2O：3.3～3.8％。
Preferably, the specific gravity of the high-refractive-index glaze is 1.78-1.83 g/cm3The glazing amount is 90-150 g/m2。
Preferably, the chemical composition of the transparent glaze comprises: by mass percent, SiO2：46～52％、Al2O3: 12-14%, CaO: 6.9-7.8%, MgO: 4.8 to 5.5%, alkali metal oxide: 5.6-7.0%, BaO: 6.7-7.4%, ZnO: 2.5 to 3.5 percent.
Preferably, the specific gravity of the transparent glaze is 1.87-1.88 g/cm3The glazing amount is 650-680 g/m2。
Preferably, the high-refractive-index glaze is applied by a screen printing method, and the mesh number of the screen is 120-160 meshes.
Preferably, the maximum firing temperature is 1162-1167 ℃, and the firing period is 93-98 min.
In a second aspect, the invention provides a ceramic tile with mirror relief decoration effect obtained by the preparation method described in any one of the above. The glaze glossiness of the ceramic tile with the mirror surface relief decoration effect is 93-94 degrees.
Drawings
FIG. 1 is a plot of the brick effect of the ceramic tile of comparative example 1.
Detailed Description
The present invention is further illustrated by the following examples, which are to be understood as merely illustrative of, and not restrictive on, the present invention. Unless otherwise specified, each percentage means a mass percentage.
The following is an exemplary illustration of the method for preparing the ceramic tile with mirror relief decoration effect according to the present invention.
Pressing the ceramic base material into a green brick. The chemical composition of the ceramic base material is not limited, and the ceramic base material can be prepared by adopting a common ceramic base material. In some embodiments, the chemical composition of the ceramic base may include: loss on Ignition (IL) in mass percent: 4.9-5.3% of SiO2：64～67％、Al2O3：20～23％、Fe2O3：0.5～1.0％、TiO2：0.1～0.4％、CaO：0.3～0.4％、MgO：0.5～0.9％、K2O：2.2～2.5％、Na2O：2.9～3.2％、P2O5：0.03～0.09％。
And drying the green brick. Drying in a drying kiln may be used. The drying time can be 1-1.2 h. The moisture content of the dried green brick is controlled within 0.5 wt%.
And applying surface glaze on the surface of the dried green brick. The overglaze has the functions of covering the base color and flaws of the blank and promoting the color development of the ink-jet pattern. In some embodiments, the chemical composition of the overglaze may include: by mass percent, SiO2：49～51％、Al2O3：28～31％、K2O：4.8～5.7％、Na2O：2.5～3.4％、ZrO2：5.0～6.5％。
As an example, the chemical composition of the overglaze may include: by mass percent, IL (loss on ignition): 4.0 to 5.0% of SiO2：49～51％、Al2O3：28～31％、Fe2O3：0.22～0.42％、TiO2：0.05～0.07％、CaO：0.5～0.9％、MgO：0.1～0.3％、K2O：4.8～5.7％、Na2O：2.5～3.4％、P2O5：0.2～0.5％、ZrO2：5.0～6.5％。
The overglaze may be applied by spraying glaze. The specific gravity of the overglaze can be 1.40-1.43 g/cm3The glazing amount can be 500-600 g/m2。
And applying high-refractive-index glaze on the surface of the green brick after the overglaze is applied. The chemical composition of the high-refractive-index glaze comprises: by mass percent, SiO2：50～55％、Al2O3: 6.9-7.7%, CaO: 12-14%, MgO: 0.1 to 0.3%, alkali metal oxide: 3.3-5.1% of SnO2：0.8～1.0％、ZrO2：13～16％、Ce2O: 3.3 to 3.8 percent. By controlling ZrO2And CeO2In order to increase the refractive index of the high-refraction glaze slip and regulate ZrO2The content of (A) ensures the stability of the glaze slip at high temperature.
The high refractive index glaze passes through ZrO2、SnO2、Ce2O, etc. having a high refractive index to adjust the refractive index of the glaze. These materials have inherently higher melting points. The excessive content of the substances can cause the melting point temperature of the glaze slip to be too high, and the glaze slip cannot reach a molten state at the highest firing temperature, so that the phenomena of pinholes and openings appear at the positions of the high-refractive-index glaze decorative glaze surface. The gas exhausted from the blank and the overglaze in a high-temperature state passes through the high-refraction glaze slip, and the glaze slip cannot fill pinholes and openings generated by gas exhaust without reaching a molten state, so that the glaze has pinholes. In addition, the ink jet layer is designed above the glaze with high refractive index, and the ink is flushed away by gas, so that white spots occur due to the covering of the ink, and the glaze of the product has defects. In some embodiments, the high refractive index glaze has a refractive index of 1.87 to 1.92.
The initial melting temperature of the overglaze is 1100-1150 ℃, and the initial melting temperature of the high-refractive-index glaze is 1180-1220 ℃. Preferably, the difference of the initial melting temperature of the overglaze and the high-refractive-index glaze is 70-80 ℃. The melting temperature difference of the overglaze and the glaze with high refractive index is controlled within the range, so that the overglaze and the glaze with high refractive index are melted within the same temperature range, and the influence on gas emission caused by overlarge melting temperature difference in a high-temperature state is reduced.
As an example, the chemical composition of the high refractive index glaze may include: by mass percent, IL (loss on ignition): 1.2 to 1.4% of SiO2：50～55％、Al2O3：6.9～7.7％、Fe2O3：0.15～0.22％、TiO2：0.80～0.97％、CaO：12～14％、MgO：0.13～0.28％、K2O：2.1～2.7％、Na2O：1.2～2.4％、SnO2：0.84～0.95％、ZrO2：13～16％、CeO2：3.3～3.8％。
In some embodiments, the mineral composition of the high refractive index glaze may include: the weight percentage of the material is as follows: 4-6% of kaolin, 15-17% of quartz, 15-17% of potassium feldspar, 12-14% of calcite and SnO2 6～8％、CeO2 2～3％、ZrO20.5～1.0％、TiO20.5 to 1.0 percent. The high-refractive-index glaze also comprises 35-42% by mass of (rubber covered roller for glaze) stamp-pad ink. In order to adjust the glaze slip performance of the high-refractive-index glaze, methyl cellulose accounting for 0.2-0.4 wt% of the total weight of all raw materials of the high-refractive-index glaze and sodium tripolyphosphate accounting for 0.1-0.3 wt% of the total weight of all raw materials of the high-refractive-index glaze can also be added. The suspension property of the glaze slip can be adjusted by adding kaolin, and the melting temperature of the glaze slip can be adjusted by potassium feldspar and calcite. In addition, in order to reduce the particle voids of the high refractive index glaze, which causes white spots on the glaze surface after ink jetting, the glaze slip particle size of the high refractive index glaze is preferably 0.05mm or less.
The invention arranges the glaze layer with high refractive index under the ink-jet pattern, which can overcome the limitation of design and color design and adapt to the collocation of various design patterns to a greater extent. And (3) also. TiO 22、CeO2Itself is light yellow, and the glaze surface is made to be TiO by being arranged on the upper layer of the ink-jet pattern2、CeO2The inherent color of the introduced glaze slip greatly limits the development of the design and color of the layout.
The specific gravity of the high-refractive-index glaze is 1.78-1.83 g/cm3The glazing amount is 90-150 g/m2. Preferably, the specific gravity of the high-refractive-index glaze is 1.79-1.83 g/cm3The glazing amount is 120-120 g/m2。
The high refractive index glaze is preferably applied by screen printing. The mesh number of the silk screen can be 120-160 meshes.
And (4) carrying out ink-jet printing on the surface of the green brick after the high-refractive-index glaze is applied. The color and pattern of the ink jet printed pattern are adaptively changed depending on the design effect.
And applying transparent glaze on the surface of the green brick after the pattern is printed by ink jet. The chemical composition of the transparent glaze comprises: by mass percent, SiO2：46～52％、Al2O3: 12-14%, CaO: 6.9-7.8%, MgO: 4.8 to 5.5%, alkali metal oxide: 5.6-7.0%, BaO: 6.7-7.4%, ZnO: 2.5 to 3.5 percent.
As an example, the chemical composition of the transparent glaze may include, in mass percent: IL (loss on ignition): 8.8 to 11.0 percent of SiO2：46～52％、Al2O3：12～14％、Fe2O3：0.16～0.18％、CaO：6.9～7.8％、MgO：4.8～5.5％、K2O：2.3～3.0％、Na2O：3.3～3.7％、P2O5：0.22～0.33％、BaO：6.7～7.4％、ZnO：2.5～3.5％。
The melting temperature of the transparent glaze is 985-1035 ℃. The onset temperature of the transparent glaze is lower than that of the high-refractive-index glaze. The melting temperature difference between the transparent glaze and the high-refractive-index glaze is preferably controlled to be 180-190 ℃, so that the phenomenon that the glaze surface is open-bubble due to the fact that the gas is discharged at a high temperature state at the decorative part of the transparent glaze due to the fact that the temperature difference between the transparent glaze and the high-refractive-index glaze is too large can be avoided.
The application mode of the transparent glaze is glaze pouring. The specific gravity of the transparent glaze is 1.87-1.88 g/cm3The glazing amount is 650-680 g/m2。
The refractive index of the transparent glaze is 1.52-1.54. Preferably, the difference of the refractive indexes of the high-refraction glaze and the transparent glaze is 0.35-0.38. The ink-jet pattern layer has color and has certain shielding effect on the high-refractive-index glaze layer. The refractive index difference value of the high-refraction glaze and the transparent glaze layer can ensure the suspension effect in the range, and different embossment imaging effects can be seen in the glaze layer when the high-refraction glaze and the transparent glaze layer stand at different angles.
In addition, the high-refractive-index glaze has higher melting temperature and is not easy to melt under the high-temperature condition, the difference exists between the refractive index of a glass phase formed by the transparent glaze and the high-refractive-index glaze slurry, and the bulge accumulation effect different from other positions which are not decorated can be observed under the light conditions of different angles, so that the mirror surface relief decoration is realized. The mark of the product can be printed by utilizing the characteristic, and the anti-counterfeiting mark can also be made according to the requirement, so that the integral glaze decoration effect is not influenced, and the anti-counterfeiting function is also realized.
And (5) drying. And drying the green brick after the transparent glaze is applied. Drying in an electric kiln may be employed. The temperature of the drying kiln is controlled to be 110-120 ℃, and the moisture of the dried green bricks is controlled to be within 0.3 wt%.
And (5) firing. Can be quickly fired at low temperature by a roller kiln. The maximum firing temperature can be 1162-1167 ℃, and the firing period can be 93-98 min.
According to the ceramic tile obtained by the preparation method, the high-refractive-index glaze layer and the transparent glaze layer have a refractive index difference after being fired, so that the relief decoration effect is formed in the high-refractive-index glaze layer on the smooth glaze layer at different angles. Meanwhile, the high-refractive-index glaze slip is placed under the ink-jet layer, so that the relief effect is more vivid under the shielding of the patterns of the ink-jet layer. Above because the high refractive index glaze can not take place the reaction with overglaze layer, transparent glaze interlamellar, guaranteed original decorative pattern, and the high refractive index glaze layer is in the inkjet pattern below and makes can not see obvious relief (sculpture) effect when just overlooking, but at other angles, the difference that glass looks refracting index that the transparent glaze formed and high refractive index glaze thick liquid exist makes can observe bellied pile-up effect under different angle light conditions, just as the little hillock that fluctuates, with "the venation" move towards following in the collocation of stone material pattern effect to bring out in good order.
The present invention will be described in detail by way of examples. It is also to be understood that the following examples are illustrative of the present invention and are not to be construed as limiting the scope of the invention, and that certain insubstantial modifications and adaptations of the invention by those skilled in the art may be made in light of the above teachings. The specific process parameters and the like of the following examples are also only one example of suitable ranges, i.e., those skilled in the art can select the appropriate ranges through the description herein, and are not limited to the specific values exemplified below.
Example 1
The preparation method of the ceramic tile with the mirror surface relief decoration effect comprises the following steps:
step 1, pressing a ceramic base material into a green brick;
step 2, drying the green bricks in a drying kiln for 1-1.2 h, and controlling the moisture of the dried green bricks within 0.5 wt%;
step 3, spraying surface glaze on the surface of the dried green brick to form a surface glaze layer, wherein the specific gravity of the surface glaze is 1.40-1.43 g/cm3The glazing amount is 500-600 g/m2；
Step 4, applying high-refractive-index glaze above the overglaze layer through screen printing; the chemical composition of the high-refractive-index glaze comprises: by mass percent, SiO2：50～55％、Al2O3: 6.9-7.7%, CaO: 12-14%, MgO: 0.1 to 0.3%, alkali metal oxide: 3.3-5.1% of SnO2：0.8～1.0％、ZrO2：13～16％、Ce2O: 3.3-3.8%; the specific gravity of the high-refractive-index glaze is 1.78-1.83 g/cm3The glazing amount is 90-150 g/m2；
Step 5, ink-jet printing patterns on the green bricks after screen printing;
step 6, applying transparent glaze on the surface of the green brick after the pattern is printed by ink jet; the chemical composition of the transparent glaze comprises: by mass percent, SiO2：46～52％、Al2O3: 12-14%, CaO: 6.9-7.8%, MgO: 4.8 to 5.5%, alkali metal oxide: 5.6-7.0%, BaO: 6.7-7.4%, ZnO: 2.5-3.5%; the specific gravity of the transparent glaze is 1.87-1.88 g/cm3The glazing amount is 650-680 g/m2；
Step 7, drying in an electric kiln, wherein the temperature of the drying kiln is controlled to be 110-120 ℃, and the moisture of the dried green bricks is controlled to be within 0.3 wt%;
and 8, quickly firing the mixture in the roller kiln at a low temperature, wherein the maximum firing temperature is 1162-1167 ℃, and the firing period is 93-98 min.
The high-refractive-index glaze can not react with the overglaze layer and the transparent glaze layer, so that the original decorative patterns are guaranteed, the high-refractive-index glaze layer is positioned below the ink-jet patterns, so that the obvious embossment effect can not be seen when the front surface is overlooked, but at other angles, the difference value between the glass phase refractive index formed by the transparent glaze and the high-refractive-index glaze slurry enables the convex accumulation effect to be observed under different-angle light conditions, just like a small fluctuated hill, and the high-refractive-index glaze layer can complement each other with the trend of 'venation' under the matching of the stone pattern effect.
Comparative example 1
Essentially the same as example 1, except that:
step 4, ink-jet printing patterns on the green bricks after the surface glaze is sprayed;
step 5, screen printing high-refractive-index glaze on the green brick subjected to the ink-jet pattern printing; the mineral composition of the high-refractive-index glaze comprises: the weight percentage of the material is as follows: 4% of kaolin, 23% of quartz, 22% of potassium feldspar, 12% of calcite and SnO2 5％、CeO23% and ZnO 2%. The high-refractive-index glaze also comprises 29% of rubber roll printing oil for the glaze by mass percent.
As shown in fig. 1, due to the high temperature property of the high refractive index glaze, the high refractive index glaze does not react with the overglaze and the transparent glaze layer, but there is almost no refractive index difference between the high refractive index glaze and the transparent glaze layer, and the appearance is silver gray lines, which not only can not play a role of suspension decoration, but also the layout collocation is very discordant.
Claims (10)
1. A preparation method of ceramic tiles with mirror surface relief decoration effect is characterized by comprising the following steps:
applying surface glaze on the surface of the green brick;
applying high-refractive-index glaze on the surface of the green brick after the surface glaze is applied;
printing patterns on the surface of the green brick after the high-refractive-index glaze is applied by ink jet;
applying transparent glaze on the surface of the green brick after the pattern is printed by ink jet;
and (5) firing.
2. The preparation method according to claim 1, wherein the over glaze has an initial melting temperature of 1100-1150 ℃ and the high refractive index glaze has an initial melting temperature of 1180-1220 ℃; preferably, the difference of the initial melting temperature of the overglaze and the high-refractive-index glaze is 70-80 ℃.
3. The preparation method according to claim 1 or 2, wherein the refractive index of the high refractive index glaze is 1.87 to 1.92, and the refractive index of the transparent glaze is 1.52 to 1.54; preferably, the difference of the refractive indexes of the high-refraction glaze and the transparent glaze is 0.35-0.38.
4. The method according to any one of claims 1 to 3, wherein the chemical composition of the high-refractive-index glaze includes: by mass percent, SiO2：50～55%、Al2O3: 6.9-7.7%, CaO: 12-14%, MgO: 0.1 to 0.3%, alkali metal oxide: 3.3-5.1% of SnO2：0.8～1.0%、ZrO2：13～16%、Ce2O：3.3～3.8%。
5. The method according to any one of claims 1 to 4, wherein the high refractive index glaze has a specific gravity of 1.78 to 1.83g/cm3The glazing amount is 90-150 g/m2。
6. The method according to any one of claims 1 to 5, characterized in that the chemical composition of the transparent glaze comprises: by mass percent, SiO2：46～52%、Al2O3: 12-14%, CaO: 6.9-7.8%, MgO: 4.8 to 5.5%, alkali metal oxide: 5.6-7.0%, BaO: 6.7-7.4%, ZnO: 2.5 to 3.5 percent.
7. The method according to any one of claims 1 to 6, wherein the specific gravity of the transparent glaze is 1.87 to 1.88g/cm3The glazing amount is 650-680 g/m2。
8. The preparation method according to any one of claims 1 to 7, characterized in that the high-refractive-index glaze is applied by screen printing, and the mesh number of the screen is 120-160 meshes.
9. The method according to any one of claims 1 to 8, wherein the maximum firing temperature is 1162 to 1167 ℃ and the firing period is 93 to 98 min.
10. The ceramic tile with the mirror surface relief decoration effect obtained by the preparation method according to any one of claims 1 to 9, wherein the glaze surface glossiness of the ceramic tile with the mirror surface relief decoration effect is 93-94 degrees.
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| CN101659517A (en) * | 2009-09-17 | 2010-03-03 | 广东顺祥陶瓷有限公司 | Daily ceramic glaze with high refractive rate and preparation technique thereof |
| CN101905965A (en) * | 2009-06-03 | 2010-12-08 | 佛山市简一陶瓷有限公司 | Ceramic brick manufacturing process with concave-convex polished in-glaze decoration |
| CN111732453A (en) * | 2020-08-24 | 2020-10-02 | 蒙娜丽莎集团股份有限公司 | Ceramic tile with metallic luster decorative effect and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010121016A2 (en) * | 2009-04-15 | 2010-10-21 | Octi Tech Limited, LLC | Ceramic article imaging process and materials |
| CN104140297B (en) * | 2014-08-26 | 2015-11-18 | 广东宏陶陶瓷有限公司 | The glaze of embossment phantom ornamental brick and preparation |
| CN109834809B (en) * | 2019-03-01 | 2020-08-04 | 江西和美陶瓷有限公司 | Dry particle decorative ceramic tile with strong stereoscopic impression and manufacturing method thereof |
| CN109796224B (en) * | 2019-03-01 | 2021-03-02 | 江西和美陶瓷有限公司 | Ink-jet dry particle decorative ceramic tile and manufacturing method thereof |
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2021
- 2021-09-26 CN CN202111130856.7A patent/CN113929499A/en not_active Withdrawn
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101905965A (en) * | 2009-06-03 | 2010-12-08 | 佛山市简一陶瓷有限公司 | Ceramic brick manufacturing process with concave-convex polished in-glaze decoration |
| CN101659517A (en) * | 2009-09-17 | 2010-03-03 | 广东顺祥陶瓷有限公司 | Daily ceramic glaze with high refractive rate and preparation technique thereof |
| CN111732453A (en) * | 2020-08-24 | 2020-10-02 | 蒙娜丽莎集团股份有限公司 | Ceramic tile with metallic luster decorative effect and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115286243A (en) * | 2022-07-12 | 2022-11-04 | 蒙娜丽莎集团股份有限公司 | Rock plate with shale surface effect and preparation method thereof |
| CN115286243B (en) * | 2022-07-12 | 2023-12-08 | 蒙娜丽莎集团股份有限公司 | Rock plate with shale surface effect and preparation method thereof |
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| CN115521165B (en) | 2023-05-12 |
| CN115521165A (en) | 2022-12-27 |
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