CN113908781A - Gel for storing ozone and preparation method thereof - Google Patents
Gel for storing ozone and preparation method thereof Download PDFInfo
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- CN113908781A CN113908781A CN202111293042.5A CN202111293042A CN113908781A CN 113908781 A CN113908781 A CN 113908781A CN 202111293042 A CN202111293042 A CN 202111293042A CN 113908781 A CN113908781 A CN 113908781A
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- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 238000002360 preparation method Methods 0.000 title abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 72
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 72
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000011347 resin Substances 0.000 claims abstract description 45
- 229920005989 resin Polymers 0.000 claims abstract description 45
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 44
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 44
- 239000002994 raw material Substances 0.000 claims abstract description 32
- 238000003756 stirring Methods 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 12
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims abstract description 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 48
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 48
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 16
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 16
- 239000000920 calcium hydroxide Substances 0.000 claims description 16
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 description 11
- 239000012153 distilled water Substances 0.000 description 7
- 238000004659 sterilization and disinfection Methods 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012629 purifying agent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0052—Preparation of gels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0052—Preparation of gels
- B01J13/0056—Preparation of gels containing inorganic material and water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0052—Preparation of gels
- B01J13/0065—Preparation of gels containing an organic phase
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Colloid Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention belongs to the technical field of ozone gel preparation, and discloses a gel for storing ozone and a preparation method thereof, wherein the gel comprises the following raw materials in parts by weight: 3-20 parts of carbon nano tube, 0.1-5 parts of acrylic cross-linked resin, 0.1-15 parts of neutralizer, 0.1-20 parts of ozone and 60-95 parts of water. The preparation method comprises the following steps: mixing carbon nanotubes and water according to parts by weight, and introducing ozone gas according to parts by weight at 0-5 ℃ to form a mixture A; dissolving acrylic crosslinked resin in water according to the parts by weight, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B; adding the mixture B to the mixture A and stirring uniformly to form a mixture C; adding a neutralizing agent into the mixture C in parts by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone. The invention greatly increases the stability of ozone and is convenient for storage.
Description
Technical Field
The invention belongs to the technical field of ozone gel preparation, and particularly relates to a gel for storing ozone and a preparation method thereof.
Background
Ozone is an allotrope of oxygen, has a chemical formula of O3 and a formula weight of 47.998, is light blue gas with fishy smell, has strong oxidizing property, is an oxidant stronger than oxygen, can perform an oxidation reaction at a lower temperature, is a strong bleaching agent when water exists, can easily generate ozonides with unsaturated organic compounds at a low temperature, is used as a strong oxidant, a bleaching agent, a fur deodorizer, an air purifying agent, a sanitizer and the disinfection and deodorization of drinking water, has no dead angle in disinfection and sterilization because ozone has excellent disinfection and sterilization effects, has high disinfection efficiency and has the effect of removing peculiar smell. Therefore, in modern industrial production, ozone is widely prepared, but the stability of ozone is poor, and the preservation of ozone is always a problem in the industry for a long time.
Disclosure of Invention
The invention aims to provide a gel for storing ozone and a preparation method thereof, which aim to solve the problems of insufficient stability and difficult preservation of ozone.
In order to achieve the above object, according to a first aspect, the technical solution adopted is:
a gel for storing ozone, the gel consisting of: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
The invention is further configured to: the gel comprises the following raw materials in parts by weight: 3-20 parts of carbon nano tube, 0.1-5 parts of acrylic cross-linked resin, 0.1-15 parts of neutralizer, 0.1-20 parts of ozone and 60-95 parts of water.
The invention is further configured to: the gel comprises the following raw materials in parts by weight: 5-20 parts of carbon nano tube, 0.5-5 parts of acrylic cross-linked resin, 0.5-15 parts of neutralizer, 0.5-20 parts of ozone and 60-95 parts of water.
The invention is further configured to: the gel comprises the following raw materials in parts by weight: 7-20 parts of carbon nano tube, 1-5 parts of acrylic cross-linked resin, 1-15 parts of neutralizer, 1-20 parts of ozone and 60-95 parts of water.
The invention is further configured to: the gel comprises the following raw materials in parts by weight: 10-20 parts of carbon nano tube, 2-5 parts of acrylic cross-linked resin, 2-15 parts of neutralizer, 2-20 parts of ozone and 60-95 parts of water.
The invention is further configured to: the gel comprises the following raw materials in parts by weight: 15-20 parts of carbon nano tube, 4-5 parts of acrylic cross-linked resin, 4-15 parts of neutralizer, 4-20 parts of ozone and 60-95 parts of water.
The invention is further configured to: the gel comprises the following raw materials in parts by weight: 1-20 parts of carbon nano tube, 0.1-10 parts of acrylic cross-linked resin, 0.1-20 parts of neutralizer, 0.1-30 parts of ozone and 60-95 parts of water.
The invention is further configured to: the gel comprises the following raw materials in parts by weight: 10 parts of carbon nano tube, 5 parts of acrylic cross-linked resin, 10 parts of neutralizer, 1 part of ozone and 80 parts of water.
The invention is further configured to: the neutralizer comprises any one of triethanolamine, sodium hydroxide, potassium hydroxide and calcium hydroxide.
In order to achieve the above object, according to a second aspect, the technical solution adopted is:
a method for preparing a gel for storing ozone, comprising the steps of:
mixing carbon nanotubes and water according to parts by weight, and introducing ozone gas according to parts by weight at 0-5 ℃ to form a mixture A;
dissolving acrylic crosslinked resin in water according to the parts by weight, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B;
adding the mixture B to the mixture A and stirring uniformly to form a mixture C;
adding a neutralizing agent into the mixture C in parts by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
In summary, compared with the prior art, the invention discloses a gel for storing ozone and a preparation method thereof, wherein the gel is composed of the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water. The preparation method comprises the following steps: mixing carbon nanotubes and water according to parts by weight, and introducing ozone gas according to parts by weight at 0-5 ℃ to form a mixture A; dissolving acrylic crosslinked resin in water according to the parts by weight, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B; adding the mixture B to the mixture A and stirring uniformly to form a mixture C; adding a neutralizing agent into the mixture C in parts by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone. Namely, through the arrangement, the stability of the ozone is greatly improved, and the ozone is convenient to store.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and other drawings can be obtained by those skilled in the art without creative efforts.
Fig. 1 is a block flow diagram of a method for preparing a gel for storing ozone according to this embodiment.
Detailed Description
For the purpose of making the objects, technical solutions and advantages of the present invention more apparent, the present invention will be further described in detail with reference to the accompanying drawings and embodiments, it being understood that the specific embodiments described herein are merely illustrative of the present invention and are not intended to limit the present invention.
Furthermore, the technical features mentioned in the different embodiments of the present invention described above may be combined with each other as long as they do not conflict with each other.
Example one
A gel for storing ozone is composed of the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
Further, the gel is prepared from the following raw materials in parts by weight: 3-20 parts of carbon nano tube, 0.1-5 parts of acrylic cross-linked resin, 0.1-15 parts of neutralizer, 0.1-20 parts of ozone and 60-95 parts of water.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
As shown in fig. 1, the method for preparing the gel for storing ozone comprises the following steps:
s101, mixing 10 parts by weight of carbon nano tubes with 30-47 parts by weight of water, and introducing 0.1-20 parts by weight of ozone gas at 0-5 ℃ to form a mixture A.
S102, dissolving 0.1-5 parts by weight of acrylic crosslinked resin in 30-47 parts by weight of water, keeping for 4 hours, and then cooling to 0-5 ℃ to form a mixture B.
S103, adding the mixture B into the mixture A and uniformly stirring to form a mixture C.
And S104, adding 0.1-15 parts of neutralizing agent into the mixture C by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
Wherein 60-95 parts of water is distilled water, and the pH of the gel is adjusted to 7.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
Example two
A gel for storing ozone is composed of the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
Further, the gel is prepared from the following raw materials in parts by weight: 5-20 parts of carbon nano tube, 0.5-5 parts of acrylic cross-linked resin, 0.5-15 parts of neutralizer, 0.5-20 parts of ozone and 60-95 parts of water.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
As shown in fig. 1, the method for preparing the gel for storing ozone comprises the following steps:
s101, mixing 10 parts by weight of carbon nano tubes with 30-47 parts by weight of water, and introducing 0.5-20 parts by weight of ozone gas at 0-5 ℃ to form a mixture A.
S102, dissolving 0.5-5 parts by weight of acrylic crosslinked resin in 30-47 parts by weight of water, keeping for 4 hours, and then cooling to 0-5 ℃ to form a mixture B.
S103, adding the mixture B into the mixture A and uniformly stirring to form a mixture C.
And S104, adding 0.5-15 parts of neutralizing agent into the mixture C by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
Wherein 60-95 parts of water is distilled water, and the pH of the gel is adjusted to 7.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
EXAMPLE III
A gel for storing ozone is composed of the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
Further, the gel is prepared from the following raw materials in parts by weight: 7-20 parts of carbon nano tube, 1-5 parts of acrylic cross-linked resin, 1-15 parts of neutralizer, 1-20 parts of ozone and 60-95 parts of water.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
As shown in fig. 1, the method for preparing the gel for storing ozone comprises the following steps:
s101, mixing 10 parts by weight of carbon nano tubes with 30-47 parts by weight of water, and introducing 1-20 parts by weight of ozone gas at 0-5 ℃ to form a mixture A.
S102, dissolving 1-5 parts by weight of acrylic crosslinked resin in 30-47 parts by weight of water, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B.
S103, adding the mixture B into the mixture A and uniformly stirring to form a mixture C.
And S104, adding 1-15 parts of neutralizing agent into the mixture C by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
Wherein 60-95 parts of water is distilled water, and the pH of the gel is adjusted to 7.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
Example four
A gel for storing ozone is composed of the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
Further, the gel is prepared from the following raw materials in parts by weight: 10-20 parts of carbon nano tube, 2-5 parts of acrylic cross-linked resin, 2-15 parts of neutralizer, 2-20 parts of ozone and 60-95 parts of water.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
As shown in fig. 1, the method for preparing the gel for storing ozone comprises the following steps:
s101, mixing 10 parts by weight of carbon nano tubes with 30-47 parts by weight of water, and introducing 2-20 parts by weight of ozone gas at 0-5 ℃ to form a mixture A.
S102, dissolving 2-5 parts by weight of acrylic crosslinked resin in 30-47 parts by weight of water, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B.
S103, adding the mixture B into the mixture A and uniformly stirring to form a mixture C.
And S104, adding 2-15 parts of neutralizing agent into the mixture C by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
Wherein 60-95 parts of water is distilled water, and the pH of the gel is adjusted to 7.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
EXAMPLE five
A gel for storing ozone is composed of the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
Further, the gel is prepared from the following raw materials in parts by weight: 15-20 parts of carbon nano tube, 4-5 parts of acrylic cross-linked resin, 4-15 parts of neutralizer, 4-20 parts of ozone and 60-95 parts of water.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
As shown in fig. 1, the method for preparing the gel for storing ozone comprises the following steps:
s101, mixing 10 parts by weight of carbon nano tubes with 30-47 parts by weight of water, and introducing 4-20 parts by weight of ozone gas at 0-5 ℃ to form a mixture A.
S102, dissolving 4-5 parts by weight of acrylic crosslinked resin in 30-47 parts by weight of water, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B.
S103, adding the mixture B into the mixture A and uniformly stirring to form a mixture C.
And S104, adding 4-15 parts of neutralizing agent into the mixture C by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
Wherein 60-95 parts of water is distilled water, and the pH of the gel is adjusted to 7.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
EXAMPLE six
A gel for storing ozone is composed of the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
Further, the gel is prepared from the following raw materials in parts by weight: 1-20 parts of carbon nano tube, 0.1-10 parts of acrylic cross-linked resin, 0.1-20 parts of neutralizer, 0.1-30 parts of ozone and 60-95 parts of water.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
As shown in fig. 1, the method for preparing the gel for storing ozone comprises the following steps:
s101, mixing 10 parts by weight of carbon nano tubes with 30-47 parts by weight of water, and introducing 0.1-30 parts by weight of ozone gas at 0-5 ℃ to form a mixture A.
S102, dissolving 0.1-10 parts by weight of acrylic crosslinked resin in 30-47 parts by weight of water, keeping for 4 hours, and then cooling to 0-5 ℃ to form a mixture B.
S103, adding the mixture B into the mixture A and uniformly stirring to form a mixture C.
And S104, adding 0.1-20 parts by weight of neutralizing agent into the mixture C and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
Wherein 60-95 parts of water is distilled water, and the pH of the gel is adjusted to 7.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
EXAMPLE seven
A gel for storing ozone is composed of the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
Further, the gel is prepared from the following raw materials in parts by weight: 10 parts of carbon nano tube, 5 parts of acrylic cross-linked resin, 10 parts of neutralizer, 1 part of ozone and 80 parts of water.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
As shown in fig. 1, the method for preparing the gel for storing ozone comprises the following steps:
s101, mixing 10 parts by weight of carbon nanotubes and 40 parts by weight of water, and introducing 1 part by weight of ozone gas at 0-5 ℃ to form a mixture A.
S102, dissolving 5 parts by weight of acrylic crosslinked resin in 40 parts by weight of water, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B.
S103, adding the mixture B into the mixture A and uniformly stirring to form a mixture C.
And S104, adding 10 parts by weight of neutralizing agent into the mixture C and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
Among them, 80 parts of water was distilled water, and the pH of the gel was adjusted to 7.
Wherein the neutralizer comprises one of triethanolamine, sodium hydroxide, potassium hydroxide, and calcium hydroxide.
In conclusion, the invention has the following beneficial effects: the invention discloses a gel for storing ozone and a preparation method thereof, wherein the gel is prepared from the following raw materials in parts by weight: 0.1-5 parts of acrylic cross-linked resin, 0.1-15 parts of neutralizer, 0.1-20 parts of ozone and 60-95 parts of water. The preparation method comprises the following steps: mixing carbon nanotubes and water according to parts by weight, and introducing ozone gas according to parts by weight at 0-5 ℃ to form a mixture A; dissolving acrylic crosslinked resin in water according to the parts by weight, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B; adding the mixture B to the mixture A and stirring uniformly to form a mixture C; adding a neutralizing agent into the mixture C in parts by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone. And through the arrangement, the stability of the ozone is greatly improved, and the ozone is convenient to store.
It should be understood that the above examples are only for clarity of illustration and are not intended to limit the embodiments. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications therefrom are within the scope of the invention.
Claims (10)
1. A gel for storing ozone, the gel comprising the following raw materials: carbon nano tubes, acrylic cross-linked resin, a neutralizer, ozone and water.
2. The gel for storing ozone as claimed in claim 1, wherein the gel is composed of the following raw materials in parts by weight: 3-20 parts of carbon nano tube, 0.1-5 parts of acrylic cross-linked resin, 0.1-15 parts of neutralizer, 0.1-20 parts of ozone and 60-95 parts of water.
3. The gel for storing ozone as claimed in claim 2, wherein the gel is composed of the following raw materials in parts by weight: 5-20 parts of carbon nano tube, 0.5-5 parts of acrylic cross-linked resin, 0.5-15 parts of neutralizer, 0.5-20 parts of ozone and 60-95 parts of water.
4. The gel for storing ozone as claimed in claim 2, wherein the gel is composed of the following raw materials in parts by weight: 7-20 parts of carbon nano tube, 1-5 parts of acrylic cross-linked resin, 1-15 parts of neutralizer, 1-20 parts of ozone and 60-95 parts of water.
5. The gel for storing ozone as claimed in claim 2, wherein the gel is composed of the following raw materials in parts by weight: 10-20 parts of carbon nano tube, 2-5 parts of acrylic cross-linked resin, 2-15 parts of neutralizer, 2-20 parts of ozone and 60-95 parts of water.
6. The gel for storing ozone as claimed in claim 2, wherein the gel is composed of the following raw materials in parts by weight: 15-20 parts of carbon nano tube, 4-5 parts of acrylic cross-linked resin, 4-15 parts of neutralizer, 4-20 parts of ozone and 60-95 parts of water.
7. The gel for storing ozone as claimed in claim 2, wherein the gel is composed of the following raw materials in parts by weight: 1-20 parts of carbon nano tube, 0.1-10 parts of acrylic cross-linked resin, 0.1-20 parts of neutralizer, 0.1-30 parts of ozone and 60-95 parts of water.
8. The gel for storing ozone as claimed in claim 2, wherein the gel is composed of the following raw materials in parts by weight: 10 parts of carbon nano tube, 5 parts of acrylic cross-linked resin, 10 parts of neutralizer, 1 part of ozone and 80 parts of water.
9. The gel for storing ozone as claimed in any one of claims 1 to 8, wherein the neutralizing agent comprises any one of triethanolamine, sodium hydroxide, potassium hydroxide, calcium hydroxide.
10. A method for preparing gel for storing ozone is characterized by comprising the following steps:
mixing carbon nanotubes and water according to parts by weight, and introducing ozone gas according to parts by weight at 0-5 ℃ to form a mixture A;
dissolving acrylic crosslinked resin in water according to the parts by weight, keeping the solution for 4 hours, and then cooling the solution to 0-5 ℃ to form a mixture B;
adding the mixture B to the mixture A and stirring uniformly to form a mixture C;
adding a neutralizing agent into the mixture C in parts by weight and continuously stirring until the system is gelatinous to obtain the gel for storing ozone.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007061665A (en) * | 2005-08-29 | 2007-03-15 | Nippon Poly-Glu Co Ltd | Water soluble gel in which gas dissolved and retained and frozen substance of water soluble gel in which gas is dissolved and retained |
| CN103461379A (en) * | 2013-09-16 | 2013-12-25 | 北京农学院 | Sustained-release ozone sol and preparation method applications thereof |
| CN103565828A (en) * | 2012-07-24 | 2014-02-12 | 殷豪章 | Chlorine dioxide gel and preparation method thereof |
| CN110028680A (en) * | 2019-04-12 | 2019-07-19 | 燕山大学 | The preparation method of carbon nanotube composite hydrogel |
| CN112625769A (en) * | 2020-11-30 | 2021-04-09 | 青岛科技大学 | Method for promoting rapid generation of methane hydrate by using carbon nano tube composite hydrogel |
-
2021
- 2021-11-03 CN CN202111293042.5A patent/CN113908781A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007061665A (en) * | 2005-08-29 | 2007-03-15 | Nippon Poly-Glu Co Ltd | Water soluble gel in which gas dissolved and retained and frozen substance of water soluble gel in which gas is dissolved and retained |
| CN103565828A (en) * | 2012-07-24 | 2014-02-12 | 殷豪章 | Chlorine dioxide gel and preparation method thereof |
| CN103461379A (en) * | 2013-09-16 | 2013-12-25 | 北京农学院 | Sustained-release ozone sol and preparation method applications thereof |
| CN110028680A (en) * | 2019-04-12 | 2019-07-19 | 燕山大学 | The preparation method of carbon nanotube composite hydrogel |
| CN112625769A (en) * | 2020-11-30 | 2021-04-09 | 青岛科技大学 | Method for promoting rapid generation of methane hydrate by using carbon nano tube composite hydrogel |
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