CN113864906A - Dehumidifier - Google Patents
Dehumidifier Download PDFInfo
- Publication number
- CN113864906A CN113864906A CN202111085027.1A CN202111085027A CN113864906A CN 113864906 A CN113864906 A CN 113864906A CN 202111085027 A CN202111085027 A CN 202111085027A CN 113864906 A CN113864906 A CN 113864906A
- Authority
- CN
- China
- Prior art keywords
- filter element
- film
- shell
- dehumidifier
- condenser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 11
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 50
- 238000010438 heat treatment Methods 0.000 claims description 17
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 16
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 238000009210 therapy by ultrasound Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 230000009467 reduction Effects 0.000 description 6
- 239000013505 freshwater Substances 0.000 description 5
- 238000005057 refrigeration Methods 0.000 description 5
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003507 refrigerant Substances 0.000 description 3
- 238000010793 Steam injection (oil industry) Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000003775 Density Functional Theory Methods 0.000 description 1
- 208000032912 Local swelling Diseases 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
- F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
- F24F3/14—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/54—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms
- B01D46/543—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms using membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/265—Drying gases or vapours by refrigeration (condensation)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/122—Separate manufacturing of ultra-thin membranes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/28—Arrangement or mounting of filters
Abstract
The invention discloses a dehumidifier, which comprises a shell, a water tank, a rotating disc, a filter element, a condenser, a heater and a fan, wherein the water tank is arranged in the shell; the water tank is arranged below the shell, the fan is arranged above the shell, the rotating disc is arranged above the water tank, and the filter element is arranged inside the shell and on the rotating disc; the condenser is arranged on the outer side of the shell, a guide pipe is arranged between the condenser and the water tank, and the heater is arranged on one side of the filter element close to the condenser; wherein, the filter element adopts HEPA material, and a layer of Fe-SHC film is covered on the surface of the HEPA material; the invention provides the dehumidifier which is simple in structure, convenient to use and energy-saving.
Description
Technical Field
The invention relates to the field of medical instruments, in particular to a dehumidifier.
Background
The refrigeration systems adopted at present are mainly compression type, absorption type, adsorption type and steam injection type refrigeration systems. The basic thermodynamic principles of the refrigeration system are reverse Carnot cycle, low boiling point refrigerants, binary solutions and the like are selected as refrigeration working media, and continuous refrigeration cycle is realized through the heat absorption process of refrigerant evaporation/desorption and the heat release process of condensation/absorption. The cooled working medium (water, air, etc.) exchanges heat with the refrigerating working medium in the evaporator to reduce the temperature, thereby obtaining the cold energy.
However, the traditional air conditioning means has high requirements on power consumption, and in the process of obtaining cold energy, irreversible heat loss is inevitably generated by the heat exchange temperature difference between the refrigerant and the cooled working medium. Meanwhile, a compression type refrigerating system needs special compression equipment, and absorption type, adsorption type and steam injection type refrigerating systems are greatly limited in application due to the problems of large equipment volume, low energy efficiency ratio and the like caused by heat exchange. In addition, the currently adopted absorption type air dehumidifying device is mainly a lithium chloride solution dehumidifying device, and when the device is used, air needs to be filtered and purified, otherwise, the lithium chloride solution is polluted, and the performance of the device is affected.
Disclosure of Invention
The invention overcomes the defects of the prior art and provides the dehumidifier which has a simple structure, is convenient to use and saves energy.
The technical scheme of the invention is as follows:
the dehumidifier comprises a shell, a water tank, a rotating disk, a filter element, a condenser, a heater and a fan; the water tank is arranged below the shell, the fan is arranged above the shell, the rotating disc is arranged above the water tank, and the filter element is arranged inside the shell and on the rotating disc; the condenser is arranged on the outer side of the shell, a guide pipe is arranged between the condenser and the water tank, and the heater is arranged on one side of the filter element close to the condenser;
wherein, the filter element adopts HEPA material, and a layer of Fe-SHC film is covered on the surface of the HEPA material.
Further, the specific preparation process of the Fe-SHC film is as follows: dissolving ferric trichloride in alcohol, performing ultrasonic treatment for 10 minutes to form a ferric chloride solution, dropwise adding ethanolamine into the solution, continuously heating and stirring on a heater until no precipitate exists, pouring the mixed solution into a glassware, heating to form a smooth film, namely a Fe-SHC film, and finally attaching the film on the surface of a filter element by a process.
Further, the specific preparation process of the Fe-SHC film is as follows: dissolving ferric trichloride in alcohol, performing ultrasonic treatment for 10 minutes to form a ferric chloride solution, dropwise adding ethanolamine into the solution, continuously heating and stirring on a heater until no precipitate exists, soaking a filter element in the mixed solution, taking out the filter element, and putting the filter element into a vacuum oven until a film, namely an Fe-SHC film, is formed on the surface of the filter element.
Further, the oven temperature is set at 70 ℃ and the heating time is more than 10 hours, so that the film is formed.
Further, the molar ratio of anhydrous ferric chloride to ethanolamine is 4: 3.
compared with the prior art, the invention has the advantages that:
the invention provides the dehumidifier which is simple in structure, convenient to use and energy-saving. The dehumidifier of the scheme of the invention not only removes the compressor in the traditional dehumidifier, realizes effective reduction of energy consumption, has the effect of heat absorption and temperature reduction, has the temperature reduction function which other dehumidifiers do not have, but also achieves the effect of collecting liquefied fresh water by using the condenser. The overall cost is far lower than that of the traditional dehumidifier.
Drawings
FIG. 1 is a schematic view of an overall dehumidifier of the present invention;
FIG. 2 is a schematic diagram of a dehumidifier with a partial explosion according to the present invention;
FIG. 3 is an exploded view of the filter element of the present invention;
FIG. 4 is a schematic view of a body portion of a filter cartridge according to the present invention;
FIG. 5 is a schematic view of a fan according to the present invention;
FIG. 6 is a schematic view of the housing and the fan of the present invention;
FIG. 7 is a graph of comparative endothermic experiments with Fe-SHC membranes according to the present invention;
FIG. 8 is a schematic diagram of the Fe-SHC film preparation process of the present invention.
Reference numerals: the air conditioner comprises a shell 1, an air inlet 11, a notch 12, a water tank 2, a notch 21, a connecting rod 22, a rotary disk 3, a rotary disk 31, a rotary clamping groove 32, a filter element 4, an upper cover 41, a lower cover 42, a filter element body 43, a condenser 5 and a fan 6.
Detailed Description
The invention is further described with reference to the following figures and detailed description.
As shown in fig. 1 to 8, the dehumidifier includes a case 1, a water tank 2, a rotary disk 313, a cartridge 4, a condenser 5, a heater, and a fan 6; the water tank 2 is arranged below the shell 1, the fan 6 is arranged above the shell 1, the rotating disc 313 is arranged above the water tank 2, and the filter element 4 is arranged inside the shell 1 and on the rotating disc 313; the condenser 5 is arranged outside the housing 1, a guide pipe is arranged between the condenser 5 and the water tank 2, and the heater is arranged on one side (not shown) of the filter element 4 close to the condenser 5. Shell 1 sets up air inlet 11 with condenser 5 relative one side, sets up latticed dustproof construction on air inlet 11, and general direct shell 1 of selecting a regional evenly distributed on an organic whole sets up the aperture, and the latticed of monolithic is convenient for block certain dust, also can open an air inlet 11, sets up the dustproof frame of detachable on the air inlet 11, as long as can realize the circulation that the air got into promptly, can block certain dust again can.
The specific principle is that moist air is continuously sucked into the filter element 4 from the air inlet 11, and after being filtered by the filter element 4, dry air is conveyed out from the fan 6, wherein the ventilation with the air inlet 11 can be realized through the rotation of the fan 6, and the moist air in the environment is continuously sucked. Wherein, the filter element 4 absorbs moisture passing through the open indoor environment to realize the dehumidification function. Meanwhile, when the dehumidifying filter element 4 rotates through the heater, the adsorbed moisture is released and transferred to the condenser 5 for condensation. Finally, the condensed liquid water is collected into the water tank 2 through a guide pipe to perform the function of fresh water production.
In a specific structure, the water tank 2 and the shell 1 are designed in a split mode and can be detached independently, and fresh water is poured out for other purposes. Set up breach 21 on the one side that water tank 2 is close to shell 1, and this breach 21 all is close to shell 1 and sets up the part of condenser 5, is convenient for collect fresh water, sets up connecting rod 22 in the intermediate position of this breach 21, and the corresponding part of shell 1 sets up notch 12 to the cooperation is used, plays the fixed stay effect.
The filter element 4 is fixedly connected with the water tank 2 through the rotating disc 313, the rotating disc 313 comprises the rotating disc 31 and the rotating clamping groove 32, the filter element 4 is integrally annular, and the filter element can rotate along with the rotating clamping groove 32 when being placed on the rotating clamping groove 32. The rotary plate 31 controls the rotation of the rotary slot 32. The filter element 4 comprises an upper cover 41, a lower cover 42 and a filter element body 43, the filter element body 43 is designed in a wave folding mode to improve the contact area, and the upper cover 41 and the lower cover 42 are only fixed to facilitate connection and installation.
In the specific material, the filter element 4 is made of a HEPA material (HEPA English is called High-Efficiency Particulate Air, namely a High-Efficiency Air Particulate filter screen for short), and a layer of Fe-SHC film is covered on the surface of the HEPA material. The specific preparation process of the Fe-SHC film is as follows: dissolving ferric trichloride in alcohol, performing ultrasonic treatment for 10 minutes to form a ferric chloride solution, dropwise adding ethanolamine into the solution, continuously heating and stirring on a heater until no precipitate exists, pouring the mixed solution into a glassware, heating to form a smooth film, namely a Fe-SHC film, and finally attaching the film to the surface of the filter element 4 by a corresponding process, wherein the covering process adopts a conventional technical means.
Aiming at the covering process, the scheme also provides a simpler mode, and the specific preparation process of the Fe-SHC film can be as follows: dissolving ferric trichloride in alcohol, and carrying out ultrasonic treatment for 10 minutes to form a ferric chloride solution. And then the ethanolamine is dropwise added into the solution, and the solution is stirred on a heater continuously under heating until no precipitate exists. Then, the filter element 4 is immersed in the mixed liquid for several minutes, actually, the liquid is adhered to the filter element. Then taking out the filter element 4 and putting the filter element into a vacuum oven until a film, namely an Fe-SHC film, is formed on the surface of the filter element 4. The temperature of the oven is generally set at 70 ℃ and the heating time is more than 10 hours, so that the film is formed. The heating time is generally about 12 hours according to experiments.
Specifically, in the formed mixed solution, the molar ratio of anhydrous ferric chloride to ethanolamine is 4: 3. FeCl3Unsaturated ligand with ethanolaminePreparing Fe-SHC. Through experimental observation and calculation of the insertion energy of water molecules, the density functional theory is carried out to optimize FeCl3And ethanolamine. First, ethanolamine and FeCl are obtained3Then one, two, three and four ethanolamine molecules are inserted into FeCl3In a unit cell corresponding to FeCl3And ethanolamine at a molar ratio of 4:1, 4:2, 4:3, and 4: 4. Intercalation into ethanolamine molecule as FeCl3And ethanolamine at a 4:1 molar ratio, the Cl-Fe bond length increases only slightly, where Fe is bonded to the ethanolamine molecule through N and O atoms. Thus, the gaps between the super cells are reduced at this time. When another ethanolamine molecule is introduced into FeCl3In the matrix (i.e. FeCl)3With ethanolamine C2H7NO at a 4:2 molar ratio), Fe-Cl bonds continue to increase in length slightly, and gaps between superunits become smaller and more crowded. Interestingly, the resulting structure is highly symmetrical and the Fe-Cl bonds are driven to local swelling. When one ethanolamine molecule is added (i.e., FeCl)3A 4:3 molar ratio to ethanolamine) results in a larger central cavity, and this unique central cavity-enlarging structure facilitates water intercalation. But when one ethanolamine molecule is added, i.e. when FeCl is added3When the molar ratio to ethanolamine is further increased to 4:4, the ethanolamine molecules occupy the voids and leave less water-embeddable space, which is detrimental to the absorption of water by the material. Thus according to experimental observations FeCl3And ethanolamine is critical to improve Fe-SHC water vapor absorption performance. FeCl that this scheme adopted3And ethanolamine at a molar ratio of 4: 3.
According to experiments, the obtained Fe-SHC film not only can absorb atmospheric water automatically, but also can release water automatically due to the change of heating temperature (namely water molecules are separated out from the Fe-SHC film when heated to a certain degree), and the released water molecules achieve the effects of absorbing heat and reducing the ambient temperature. Therefore, the heater of the dehumidifier only needs to adopt equipment with about 10W of power. The dehumidifier has the important application that local heating is adopted for heating, the heat insulation plate is arranged in the area to reduce the influence of the heating function on the external temperature and save energy, and the dehumidifier has the cooling effect when the ambient temperature exceeds 22 ℃. As shown in FIG. 7, the material of the scheme has better heat absorption effect and better cooling effect compared with commercial materials.
In conclusion, the dehumidifier of the scheme eliminates the compressor in the traditional dehumidifier, realizes effective reduction of energy consumption, has the effect of heat absorption and temperature reduction, has the temperature reduction function which other dehumidifiers do not have, and achieves the function of collecting liquefied fresh water by using the condenser 5. The whole cost is far lower than that of the traditional dehumidifier
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and decorations can be made without departing from the spirit of the present invention, and these modifications and decorations should also be regarded as being within the scope of the present invention.
Claims (5)
1. The dehumidifier is characterized by comprising a shell, a water tank, a rotating disc, a filter element, a condenser, a heater and a fan; the water tank is arranged below the shell, the fan is arranged above the shell, the rotating disc is arranged above the water tank, and the filter element is arranged inside the shell and on the rotating disc; the condenser is arranged on the outer side of the shell, a guide pipe is arranged between the condenser and the water tank, and the heater is arranged on one side of the filter element close to the condenser;
wherein, the filter element adopts HEPA material, and a layer of Fe-SHC film is covered on the surface of the HEPA material.
2. The dehumidifier of claim 1, wherein: the specific preparation process of the Fe-SHC film is as follows: dissolving ferric trichloride in alcohol, performing ultrasonic treatment for 10 minutes to form a ferric chloride solution, dropwise adding ethanolamine into the solution, continuously heating and stirring on a heater until no precipitate exists, pouring the mixed solution into a glassware, heating to form a smooth film, namely a Fe-SHC film, and finally attaching the film on the surface of a filter element by a process.
3. The dehumidifier of claim 1, wherein: the specific preparation process of the Fe-SHC film is as follows: dissolving ferric trichloride in alcohol, performing ultrasonic treatment for 10 minutes to form a ferric chloride solution, dropwise adding ethanolamine into the solution, continuously heating and stirring on a heater until no precipitate exists, soaking a filter element in the mixed solution, taking out the filter element, and putting the filter element into a vacuum oven until a film, namely an Fe-SHC film, is formed on the surface of the filter element.
4. The dehumidifier of claim 1, wherein: the oven temperature is set at 70 ℃ and the heating time is more than 10 hours, so that the film is formed.
5. The dehumidifier of claim 2 or 3, wherein: the molar ratio of anhydrous ferric chloride to ethanolamine is 4: 3.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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CN202111085027.1A CN113864906B (en) | 2021-09-16 | 2021-09-16 | Dehumidifier |
CN202311274989.0A CN117073087A (en) | 2021-09-16 | 2021-09-16 | Novel dehumidifier |
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CN202111085027.1A CN113864906B (en) | 2021-09-16 | 2021-09-16 | Dehumidifier |
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CN202311274989.0A Division CN117073087A (en) | 2021-09-16 | 2021-09-16 | Novel dehumidifier |
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CN113864906A true CN113864906A (en) | 2021-12-31 |
CN113864906B CN113864906B (en) | 2023-10-27 |
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CN202111085027.1A Active CN113864906B (en) | 2021-09-16 | 2021-09-16 | Dehumidifier |
CN202311274989.0A Pending CN117073087A (en) | 2021-09-16 | 2021-09-16 | Novel dehumidifier |
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CN202311274989.0A Pending CN117073087A (en) | 2021-09-16 | 2021-09-16 | Novel dehumidifier |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB536776A (en) * | 1939-12-13 | 1941-05-27 | William Laird | Improvements in or relating to apparatus for drying air or other gases |
GB675099A (en) * | 1949-04-29 | 1952-07-02 | Stewart King Ind Ltd | Improvements in or relating to air-conditioning apparatus |
US20130092622A1 (en) * | 2011-04-01 | 2013-04-18 | Millipore Corporation | Nanofiber containing composite membrane structures |
CN105603400A (en) * | 2016-01-21 | 2016-05-25 | 深圳市国华光电科技有限公司 | Preparation method of ZnO transparent conductive film |
CN106390909A (en) * | 2016-11-03 | 2017-02-15 | 孙顺秋 | Ferroferric-oxide magnetic heavy-metal-ion adsorbent being of double-shell hollow structure and preparation method thereof |
US20180236398A1 (en) * | 2015-12-04 | 2018-08-23 | Haldex Brake Products Aktiebolag | Air dryer cartridge, air dryer and commercial vehicle comprising an air dryer cartridge |
US20190002841A1 (en) * | 2015-12-11 | 2019-01-03 | The Trustees Of The University Of Pennsylvania | Scalable purification method for aavrh10 |
-
2021
- 2021-09-16 CN CN202111085027.1A patent/CN113864906B/en active Active
- 2021-09-16 CN CN202311274989.0A patent/CN117073087A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB536776A (en) * | 1939-12-13 | 1941-05-27 | William Laird | Improvements in or relating to apparatus for drying air or other gases |
GB675099A (en) * | 1949-04-29 | 1952-07-02 | Stewart King Ind Ltd | Improvements in or relating to air-conditioning apparatus |
US20130092622A1 (en) * | 2011-04-01 | 2013-04-18 | Millipore Corporation | Nanofiber containing composite membrane structures |
US20180236398A1 (en) * | 2015-12-04 | 2018-08-23 | Haldex Brake Products Aktiebolag | Air dryer cartridge, air dryer and commercial vehicle comprising an air dryer cartridge |
US20190002841A1 (en) * | 2015-12-11 | 2019-01-03 | The Trustees Of The University Of Pennsylvania | Scalable purification method for aavrh10 |
CN105603400A (en) * | 2016-01-21 | 2016-05-25 | 深圳市国华光电科技有限公司 | Preparation method of ZnO transparent conductive film |
CN106390909A (en) * | 2016-11-03 | 2017-02-15 | 孙顺秋 | Ferroferric-oxide magnetic heavy-metal-ion adsorbent being of double-shell hollow structure and preparation method thereof |
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Publication number | Publication date |
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CN113864906B (en) | 2023-10-27 |
CN117073087A (en) | 2023-11-17 |
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