CN113845808A - Acrylic container finish paint for repairing and preparation method thereof - Google Patents
Acrylic container finish paint for repairing and preparation method thereof Download PDFInfo
- Publication number
- CN113845808A CN113845808A CN202111031326.7A CN202111031326A CN113845808A CN 113845808 A CN113845808 A CN 113845808A CN 202111031326 A CN202111031326 A CN 202111031326A CN 113845808 A CN113845808 A CN 113845808A
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- Prior art keywords
- percent
- stirring
- container finish
- chlorinated paraffin
- acrylic
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- 239000003973 paint Substances 0.000 title claims abstract description 26
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 239000012188 paraffin wax Substances 0.000 claims abstract description 20
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 18
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 18
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 16
- 239000010703 silicon Substances 0.000 claims abstract description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 14
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 12
- OIAUFEASXQPCFE-UHFFFAOYSA-N formaldehyde;1,3-xylene Chemical compound O=C.CC1=CC=CC(C)=C1 OIAUFEASXQPCFE-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 4
- 239000000460 chlorine Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 42
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 24
- 239000004952 Polyamide Substances 0.000 claims description 14
- 239000000440 bentonite Substances 0.000 claims description 14
- 229910000278 bentonite Inorganic materials 0.000 claims description 14
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 14
- 239000002270 dispersing agent Substances 0.000 claims description 14
- 239000000049 pigment Substances 0.000 claims description 14
- 229920002647 polyamide Polymers 0.000 claims description 14
- 239000002002 slurry Substances 0.000 claims description 14
- 239000001993 wax Substances 0.000 claims description 14
- 238000000227 grinding Methods 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 9
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract description 12
- 238000000576 coating method Methods 0.000 abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 239000011248 coating agent Substances 0.000 abstract description 9
- 239000011347 resin Substances 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- 239000000945 filler Substances 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 11
- 229920002635 polyurethane Polymers 0.000 description 10
- 239000004814 polyurethane Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 4
- ZCJGPLOQDMFGAR-UHFFFAOYSA-N formaldehyde;1,2-xylene Chemical compound O=C.CC1=CC=CC=C1C ZCJGPLOQDMFGAR-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a finish paint for a repairing acrylic container and a preparation method thereof, wherein the finish paint comprises the following components: the organic silicon modified acrylic resin replaces the traditional acrylic resin, so that the hydrophobicity of the whole coating is increased; the BCS solvent can be used for quickly dissolving moisture entering the coating, so that the adsorption of the 3A molecular sieve is facilitated, the moisture entering the system is adsorbed by introducing the 3A molecular sieve, and the contact of water and resin is reduced; talc powder with silicon content of more than 60% is selected as a main filler to replace conventional barium sulfate, so that hydrophobicity is improved; the chlorinated paraffin with chlorine content over 70% is matched with xylene formaldehyde resin to replace common chlorinated paraffin 52 to raise hydrophobicity.
Description
Technical Field
The invention relates to the field of coatings, in particular to a finish paint for a repairable acrylic container and a preparation method thereof.
Background
Under the promotion of national environmental protection requirements, the water-based container coating is basically realized, the box discharging speed is increased from 100TU to 160TU in a single shift along with the improvement of field technology and the increase of the proficiency of workers, certain moisture still exists in a paint film although a film is formed on the surface when boxes arrive at a stacking factory in many times, the water-based paint cannot be repaired due to technological reasons, and the water-based paint is usually whitened due to the existence of moisture after being repaired, has obvious color difference and is not attractive, so that the water-based container coating is a problem commonly existing in many box factories at present.
Disclosure of Invention
In order to solve the problems, the invention discloses acrylic container finish paint for repairing and a preparation method thereof, which effectively solve the problems of whitening of the surface of a container and color difference.
The technical scheme of the invention is as follows: the acrylic container finish paint for repairing comprises the following raw material components in percentage by mass:
40.0 to 50.0 percent of organic silicon modified acrylic resin
Polyacrylate dispersant 1.0-2.5%
1.5 to 2.0 percent of organic bentonite
Xylene 15.0-20.0%
BCS solvent 3.0-5.0%
5.0-8.0% of 3A molecular sieve
10.0 to 15.0 percent of 800-mesh talcum powder
Pigment 8.0-15.0%
703.0-5.0% of chlorinated paraffin
Xylene formaldehyde resin 1.0-2.5%
1.5 to 3.0 percent of polyamide wax slurry;
the silicon content of the 800-mesh talcum powder is more than 60 percent, and the chlorine content of the chlorinated paraffin is more than 70 percent.
A preparation method of acrylic acid container finish paint for repairing comprises the following steps:
step 1) adding organic silicon modified hydroxy acrylic resin, polyacrylate dispersant, xylene and BCS solvent into a feeding tank, and adding organic bentonite under stirring;
step 2) adding a 3A molecular sieve, 800-mesh talcum powder, pigment and 70 parts of chlorinated paraffin under a stirring state;
step 3), adding polyamide wax slurry and continuing stirring;
and 4) adding xylene formaldehyde resin and stirring until stirring is finished.
Wherein the stirring speed in the step 1) is 300-500 r/min.
Wherein the rotating speed in the step 2) is 600-800r/min, the stirring is carried out for 10-15min, and the grinding fineness of the sand mill is not more than 30 u.
Wherein the rotating speed in the step 3) is 800-1000r/min, and the stirring is carried out for 10-15 min.
Wherein the stirring speed in the step 4) is 10-15min, and the rotation speed is 300-500 r/min.
The invention has the advantages that: the organic silicon modified acrylic resin replaces the traditional acrylic resin, so that the hydrophobicity of the whole coating is increased, the water resistance is improved, and the phenomenon that the coating turns white when meeting water is effectively reduced; the BCS solvent can be used for quickly dissolving moisture entering the coating, so that the 3A molecular sieve can be conveniently adsorbed, the moisture entering a system is adsorbed by introducing the 3A molecular sieve, the contact of water and resin is reduced, and the problem that the coating turns white when meeting water can be effectively solved; talc powder with silicon content of more than 60% is selected as a main filler to replace conventional barium sulfate, so that hydrophobicity is improved; the chlorinated paraffin with chlorine content over 70% is matched with xylene formaldehyde resin to replace common chlorinated paraffin 52 to raise hydrophobicity.
Detailed Description
For the purpose of enhancing the understanding of the present invention, the following description is given in conjunction with the embodiments of the present invention, which are provided for the purpose of illustration only and are not intended to limit the scope of the present invention.
Example 1
The acrylic acid container finish paint for repairing comprises the following components in percentage by mass:
35.0 percent of organic silicon modified acrylic resin,
1 percent of polyurethane dispersant,
1.5 percent of organic bentonite,
19 percent of dimethylbenzene,
4.0 percent of BCS solvent,
7.0 percent of 3A molecular sieve,
11.0 percent of 800-mesh talcum powder,
13.5 percent of pigment,
704.0 percent of chlorinated paraffin,
2.0 percent of dimethylbenzene formaldehyde resin,
2.0% of polyamide wax slurry;
a preparation method of acrylic acid container finish paint for repairing comprises the following steps:
step 1: adding organic silicon modified acrylic resin, a polyurethane dispersant, dimethylbenzene and a BCS solvent into a feeding tank, adding bentonite under stirring, and rotating at 300 r/min;
step 2: adding 3A molecular sieve, 800 mesh talcum powder, pigment and chlorinated paraffin under stirring at 70 rotation speed of 600r/min, stirring for 10min, and grinding to fineness of 40u by a sand mill;
and step 3: adding polyamide wax slurry, stirring at 8000r/min for 10 min;
and 4, step 4: adding xylene formaldehyde resin and stirring for 10min at the rotating speed of 300 r/min.
Example 2
The acrylic acid container finish paint for repairing comprises the following components in percentage by mass:
40.0 percent of organic silicon modified acrylic resin,
1.0 percent of polyurethane dispersant,
1.5 percent of organic bentonite,
15.0 percent of dimethylbenzene,
5.0 percent of BCS solvent,
6.0 percent of 3A molecular sieve,
12.5 percent of 800-mesh talcum powder,
12.0 percent of pigment is added,
704.0 percent of chlorinated paraffin,
1.5 percent of dimethylbenzene formaldehyde resin,
1.5% of polyamide wax slurry;
a preparation method of acrylic acid container finish paint for repairing comprises the following steps:
step 1: adding organic silicon modified acrylic resin, a polyurethane dispersant, dimethylbenzene and a BCS solvent into a feeding tank, adding bentonite under stirring, and rotating at 500 r/min;
step 2: adding 3A molecular sieve, 800 mesh talcum powder, pigment and chlorinated paraffin under stirring at 70 rotation speed of 800r/min, stirring for 15min, and grinding to fineness of 40u by a sand mill;
and step 3: adding polyamide wax slurry, stirring at the rotation speed of 1000r/min for 15 min;
and 4, step 4: adding xylene formaldehyde resin, and stirring at 500r/min for 15 min.
Example 3
The acrylic acid container finish paint for repairing comprises the following components in percentage by mass:
45.0 percent of organic silicon modified acrylic resin,
1.0 percent of polyurethane dispersant,
2.0 percent of organic bentonite,
15.5 percent of dimethylbenzene,
3.5 percent of BCS solvent,
5.0 percent of 3A molecular sieve,
10.0 percent of 800-mesh talcum powder,
10.0 percent of pigment,
705.0 percent of chlorinated paraffin,
1.5 percent of dimethylbenzene formaldehyde resin,
1.5 percent of polyamide wax slurry,
a preparation method of acrylic acid container finish paint for repairing comprises the following steps:
step 1: adding organic silicon modified acrylic resin, a polyurethane dispersant, dimethylbenzene and a BCS solvent into a feeding tank, adding bentonite under stirring, and rotating at 400 r/min;
step 2: adding 3A molecular sieve, 800 mesh talcum powder, pigment and chlorinated paraffin under stirring at a rotation speed of 700r/min, stirring for 13min, and grinding to a fineness of 40u by a sand mill;
and step 3: adding polyamide wax slurry, stirring at the rotation speed of 900r/min for 13 min;
and 4, step 4: adding xylene formaldehyde resin and stirring for 13min at the rotating speed of 400 r/min.
Comparative example 1
The common acrylic acid container finish paint comprises the following components in percentage by mass:
45.0 percent of common acrylic resin,
0.5 percent of polyurethane dispersant,
1.0 percent of organic bentonite,
16.5 percent of dimethylbenzene,
15.0 percent of precipitated barium sulfate,
15.0 percent of pigment,
52 to 15.0 percent of chlorinated paraffin,
2.0 percent of polyamide wax slurry,
a preparation method of acrylic acid container finish paint for repairing comprises the following steps:
step 1: adding common acrylic resin, a polyurethane dispersant and dimethylbenzene into a feeding tank, adding bentonite under stirring, and rotating at 500 r/min;
step 2: adding precipitated barium sulfate and pigment at a rotating speed of 800r/min under stirring, stirring for 15min, and grinding to obtain a fineness of 40u by a sand mill;
and step 3: adding polyamide wax slurry, stirring at the rotation speed of 1000r/min for 15 min;
and 4, step 4: adding 52-1 parts of chlorinated paraffin, stirring for 10min at the rotating speed of 400 r/min.
Comparative example 2
The common acrylic acid container finish paint comprises the following components in percentage by mass:
38.0 percent of common acrylic resin,
1.0 percent of polyurethane dispersant,
2.0 percent of organic bentonite,
23.0 percent of dimethylbenzene,
15.0 percent of precipitated barium sulfate,
15.0 percent of pigment,
52 to 14.0 percent of chlorinated paraffin
2.0 percent of polyamide wax slurry,
a preparation method of acrylic acid container finish paint for repairing comprises the following steps:
step 1: adding common acrylic resin, a polyurethane dispersant and dimethylbenzene into a feeding tank, adding bentonite under stirring, and rotating at 500 r/min;
step 2: adding precipitated barium sulfate and pigment at a rotating speed of 800r/min under stirring, stirring for 15min, and grinding to obtain a fineness of 40u by a sand mill;
and step 3: adding polyamide wax slurry, stirring at the rotation speed of 1000r/min for 15 min;
and 4, step 4: adding 52-1 parts of chlorinated paraffin, stirring for 10min at the rotating speed of 400 r/min.
Preparing water-based acrylic finish paint, coating the examples and the comparative examples after touch drying, comparing the color change condition and the color difference after drying, and comparing the specific data:
as can be seen from the table, after the finish paint is used, the surface of the container has no obvious color change after the finish paint is applied to the container and dried, and the comparative example has obvious color change, so that the acrylic container finish paint for repairing can avoid the phenomena of whitening and obvious unattractive color difference.
Claims (6)
1. The acrylic container finish paint for repairing is characterized by comprising the following raw material components in percentage by mass:
40.0 to 50.0 percent of organic silicon modified acrylic resin
Polyacrylate dispersant 1.0-2.5%
1.5 to 2.0 percent of organic bentonite
Xylene 15.0-20.0%
BCS solvent 3.0-5.0%
5.0-8.0% of 3A molecular sieve
10.0 to 15.0 percent of 800-mesh talcum powder
Pigment 8.0-15.0%
703.0-5.0% of chlorinated paraffin
Xylene formaldehyde resin 1.0-2.5%
1.5 to 3.0 percent of polyamide wax slurry;
the silicon content of the 800-mesh talcum powder is more than 60%, and the chlorine content of the chlorinated paraffin is more than 70%.
2. The method for preparing a refinishable acrylic container finish according to claim 1, comprising the steps of:
step 1) adding organic silicon modified hydroxy acrylic resin, polyacrylate dispersant, xylene and BCS solvent into a feeding tank, and adding organic bentonite under stirring;
step 2) adding a 3A molecular sieve, 800-mesh talcum powder, pigment and 70 parts of chlorinated paraffin under a stirring state;
step 3), adding polyamide wax slurry and continuing stirring;
and 4) adding xylene formaldehyde resin and stirring until stirring is finished.
3. The method for preparing a refinishable acrylic container finish according to claim 2, wherein the method comprises the following steps: the stirring speed in the step 1) is 300-500 r/min.
4. The method for preparing a refinishable acrylic container finish according to claim 2, wherein the method comprises the following steps: the rotating speed in the step 2) is 600-800r/min, the stirring is carried out for 10-15min, and the grinding fineness of the sand mill is not more than 30 u.
5. The method for preparing a refinishable acrylic container finish according to claim 2, wherein the method comprises the following steps: the rotating speed in the step 3) is 800-.
6. The method for preparing a refinishable acrylic container finish according to claim 2, wherein the method comprises the following steps: the stirring speed in the step 4) is 10-15min, and the rotation speed is 300-500 r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111031326.7A CN113845808A (en) | 2021-09-03 | 2021-09-03 | Acrylic container finish paint for repairing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111031326.7A CN113845808A (en) | 2021-09-03 | 2021-09-03 | Acrylic container finish paint for repairing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113845808A true CN113845808A (en) | 2021-12-28 |
Family
ID=78973197
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111031326.7A Pending CN113845808A (en) | 2021-09-03 | 2021-09-03 | Acrylic container finish paint for repairing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113845808A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845129A (en) * | 2010-05-21 | 2010-09-29 | 中科院广州化学有限公司 | Silicone (methyl)acrylate ABA-type block copolymer, and preparation method and application thereof |
| CN102453417A (en) * | 2011-12-14 | 2012-05-16 | 陈锐群 | Wall surface coating |
| CN108699382A (en) * | 2016-02-25 | 2018-10-23 | 中国涂料株式会社 | Anticorrosive coating composition, anticorrosion film, the base material with anticorrosion film and its manufacturing method |
-
2021
- 2021-09-03 CN CN202111031326.7A patent/CN113845808A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845129A (en) * | 2010-05-21 | 2010-09-29 | 中科院广州化学有限公司 | Silicone (methyl)acrylate ABA-type block copolymer, and preparation method and application thereof |
| CN102453417A (en) * | 2011-12-14 | 2012-05-16 | 陈锐群 | Wall surface coating |
| CN108699382A (en) * | 2016-02-25 | 2018-10-23 | 中国涂料株式会社 | Anticorrosive coating composition, anticorrosion film, the base material with anticorrosion film and its manufacturing method |
Non-Patent Citations (2)
| Title |
|---|
| 北京市职工技术协会 等: "《涂装工实用技术问答》", 30 April 2000, 机械工业出版社 * |
| 黄喜雨: "《家装失误308例》", 30 September 2006, 江西科学技术出版社 * |
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Application publication date: 20211228 |