CN105951514A - Waterproof paint for cartons and preparation method of waterproof paint - Google Patents
Waterproof paint for cartons and preparation method of waterproof paint Download PDFInfo
- Publication number
- CN105951514A CN105951514A CN201610336021.XA CN201610336021A CN105951514A CN 105951514 A CN105951514 A CN 105951514A CN 201610336021 A CN201610336021 A CN 201610336021A CN 105951514 A CN105951514 A CN 105951514A
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- parts
- repellent paint
- preparation
- water
- carton
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
- D21H19/48—Diolefins, e.g. butadiene; Aromatic vinyl monomers, e.g. styrene; Polymerisable unsaturated acids or derivatives thereof, e.g. acrylic acid
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention provides waterproof paint for cartons and a preparation method of the waterproof paint. The preparation method includes mixing polystyrene foam with ethyl acetate and xylene, stirring the mixture by a magnetic stirrer until the polystyrene foam is dissolved, adding acrylic acid, butyl acrylate, glyceryl triacetate, lactic-acid oligomer, polyoxyethylene lauryl ether, oleic acid polyoxyethylene ester and distilled water, mixing, stirring, adding aqueous ammonia, and stirring the mixture by the magnetic stirrer to obtain a solution A; mixing ammonium persulfate with residual distilled water for dissolution to obtain a solution B; adding the solution A into the solution B slowly after heating, adding waterborne polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mixing, stirring, and finally adding the mixture into a grinder for grinding to obtain the waterproof paint. The waterproof paint for the cartons has the advantages of high coating drying speed and excellent waterproofing effect.
Description
Technical field
The present invention relates to Material Field, be specifically related to a kind of carton water-repellent paint and preparation method thereof.
Background technology
Carton is current most widely used packing articles, is ubiquitous, brings the biggest convenience to us in our productive life.It is different that it presses materials, is broadly divided into corrugated case and single ply board case etc..Meanwhile, Packaging Box, as the indispensable part of modern logistics, carries and contains, protects product, substantial responsibility attractive in appearance, and the physical performance index of Packaging Box also becomes the foundation of its quality evaluation.Carton have easy to use, produce the many merits such as simple and cheap, but have a significant drawback, that is, non-watertight, run into rainy day or wet weather, carton is very easy to moisturize and reduces its mechanical property, even rots.Therefore, improve the performance that the water resistance of carton is overall for improving carton, expand range of application and all have great importance with increasing the service life, and using water-repellent paint is exactly one of method, the performance of water-repellent paint directly determines the water proofing property of carton, therefore, the water-repellent paint developing a kind of good water-proof effect has decisive meaning.
Summary of the invention
Solve the technical problem that:It is an object of the invention to provide a kind of carton water-repellent paint, dried coating film speed, there is extraordinary waterproof effect simultaneously.
Technical scheme:A kind of carton water-repellent paint, is prepared from weight portion by following component: aqueous polyurethane 20-30 part, polystyrene foam plastics 30-50 part, acrylic acid 5-10 part, butyl acrylate 5-10 part, calcium hydroxide 1-3 part, dibutyl phthalate 1-3 part, glyceryl triacetate 2-4 part, lact-acid oligomer 1-3 part, polyoxyethylene lauryl ether 2-5 part, polyoxyethylene oleic acid ester 1-3 part, Ammonium persulfate. 0.1-0.2 part, isopropanol 10-20 part, ethyl acetate 60-80 part, dimethylbenzene 30-50 part, ammonia 3-6 part, distilled water 20-35 part.
Further preferred, described a kind of carton water-repellent paint, it is prepared from weight portion by following component: aqueous polyurethane 22-28 part, polystyrene foam plastics 35-45 part, acrylic acid 6-9 part, butyl acrylate 6-9 part, calcium hydroxide 1.5-2.5 part, dibutyl phthalate 1.5-2.5 part, glyceryl triacetate 2.5-3.5 part, lact-acid oligomer 1.5-2.5 part, polyoxyethylene lauryl ether 3-4 part, polyoxyethylene oleic acid ester 1.5-2.5 part, Ammonium persulfate. 0.12-0.18 part, isopropanol 13-18 part, ethyl acetate 65-75 part, dimethylbenzene 35-45 part, ammonia 4-5 part, distilled water 25-30 part.
The preparation method of above-mentioned carton water-repellent paint comprises the following steps:
Step 1: polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stirs to polystyrene foam plastics dissolving with magnetic stirrer under rotating speed 80-100r/min;
Step 2: add acrylic acid, butyl acrylate, glyceryl triacetate, lact-acid oligomer, polyoxyethylene lauryl ether, polyoxyethylene oleic acid ester and 15-25 part distilled water mix and blend 3-5 minute;
Step 3: add ammonia, stirs 10-30 minute to obtain solution A with magnetic stirrer at temperature 30-35 DEG C;
Step 4: by Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;
Step 5: solution A is heated to 40-50 DEG C, slowly instills solution B;
Step 6: add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 10-20 minute;
Step 7: add and be ground 10-20 minute in grinder and get final product.
It is further preferred that step 1 medium speed is 85-95r/min.
It is further preferred that mixing time is 3.5-4.5 minute in step 2.
It is further preferred that temperature is 31-34 DEG C in step 3, mixing time is 15-25 minute.
It is further preferred that temperature is 45 DEG C in step 5.
It is further preferred that mixing time is 15 minutes in step 6.
It is further preferred that milling time is 15 minutes in step 7.
Beneficial effect:The dried coating film time of the carton water-repellent paint of the present invention is 6 minutes, and rate of drying is very fast, and its water resisting time may be up to 17.7 hours, has extraordinary waterproof effect.
Detailed description of the invention
Embodiment 1
A kind of carton water-repellent paint, is prepared from weight portion by following component: aqueous polyurethane 20 parts, polystyrene foam plastics 30 parts, 5 parts of acrylic acid, butyl acrylate 5 parts, calcium hydroxide 1 part, dibutyl phthalate 1 part, glyceryl triacetate 2 parts, lact-acid oligomer 1 part, polyoxyethylene lauryl ether 2 parts, polyoxyethylene oleic acid ester 1 part, Ammonium persulfate. 0.1 part, isopropanol 10 parts, ethyl acetate 60 parts, dimethylbenzene 30 parts, ammonia 3 parts, distilled water 20 parts.
The preparation method of above-mentioned carton water-repellent paint is: first polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stir under rotating speed 80r/min to polystyrene foam plastics dissolving with magnetic stirrer, add acrylic acid, butyl acrylate, glyceryl triacetate, lact-acid oligomer, polyoxyethylene lauryl ether, polyoxyethylene oleic acid ester and 15 parts of distilled water mix and blends 3 minutes, add ammonia, at temperature 30 DEG C, stir 10 minutes to obtain solution A with magnetic stirrer;By Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;Solution A is heated to 40 DEG C, slowly instills solution B, add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 10 minutes, be eventually adding in grinder and be ground 10 minutes and get final product.
Embodiment 2
A kind of carton water-repellent paint, is prepared from weight portion by following component: aqueous polyurethane 22 parts, polystyrene foam plastics 35 parts, 6 parts of acrylic acid, butyl acrylate 6 parts, calcium hydroxide 1.5 parts, dibutyl phthalate 1.5 parts, glyceryl triacetate 2.5 parts, lact-acid oligomer 1.5 parts, polyoxyethylene lauryl ether 3 parts, polyoxyethylene oleic acid ester 1.5 parts, Ammonium persulfate. 0.12 part, isopropanol 13 parts, ethyl acetate 65 parts, dimethylbenzene 35 parts, ammonia 4 parts, distilled water 25 parts.
The preparation method of above-mentioned carton water-repellent paint is: first polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stir under rotating speed 85r/min to polystyrene foam plastics dissolving with magnetic stirrer, add acrylic acid, butyl acrylate, glyceryl triacetate, lact-acid oligomer, polyoxyethylene lauryl ether, polyoxyethylene oleic acid ester and 17 parts of distilled water mix and blends 3.5 minutes, add ammonia, at temperature 31 DEG C, stir 15 minutes to obtain solution A with magnetic stirrer;By Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;Solution A is heated to 45 DEG C, slowly instills solution B, add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 15 minutes, be eventually adding in grinder and be ground 15 minutes and get final product.
Embodiment 3
A kind of carton water-repellent paint, is prepared from weight portion by following component: aqueous polyurethane 25 parts, polystyrene foam plastics 40 parts, 7.5 parts of acrylic acid, butyl acrylate 7.5 parts, calcium hydroxide 2 parts, dibutyl phthalate 2 parts, glyceryl triacetate 3 parts, lact-acid oligomer 2 parts, polyoxyethylene lauryl ether 3.5 parts, polyoxyethylene oleic acid ester 2 parts, Ammonium persulfate. 0.15 part, isopropanol 15 parts, ethyl acetate 70 parts, dimethylbenzene 40 parts, ammonia 4.5 parts, distilled water 27 parts.
The preparation method of above-mentioned carton water-repellent paint is: first polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stir under rotating speed 90r/min to polystyrene foam plastics dissolving with magnetic stirrer, add acrylic acid, butyl acrylate, glyceryl triacetate, lact-acid oligomer, polyoxyethylene lauryl ether, polyoxyethylene oleic acid ester and 20 parts of distilled water mix and blends 4 minutes, add ammonia, at temperature 32 DEG C, stir 20 minutes to obtain solution A with magnetic stirrer;By Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;Solution A is heated to 45 DEG C, slowly instills solution B, add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 15 minutes, be eventually adding in grinder and be ground 15 minutes and get final product.
Embodiment 4
A kind of carton water-repellent paint, is prepared from weight portion by following component: aqueous polyurethane 28 parts, polystyrene foam plastics 45 parts, 9 parts of acrylic acid, butyl acrylate 9 parts, calcium hydroxide 2.5 parts, dibutyl phthalate 2.5 parts, glyceryl triacetate 3.5 parts, lact-acid oligomer 2.5 parts, polyoxyethylene lauryl ether 4 parts, polyoxyethylene oleic acid ester 2.5 parts, Ammonium persulfate. 0.18 part, isopropanol 18 parts, ethyl acetate 75 parts, dimethylbenzene 45 parts, ammonia 5 parts, distilled water 30 parts.
The preparation method of above-mentioned carton water-repellent paint is: first polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stir under rotating speed 95r/min to polystyrene foam plastics dissolving with magnetic stirrer, add acrylic acid, butyl acrylate, glyceryl triacetate, lact-acid oligomer, polyoxyethylene lauryl ether, polyoxyethylene oleic acid ester and 23 parts of distilled water mix and blends 4.5 minutes, add ammonia, at temperature 34 DEG C, stir 25 minutes to obtain solution A with magnetic stirrer;By Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;Solution A is heated to 45 DEG C, slowly instills solution B, add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 15 minutes, be eventually adding in grinder and be ground 15 minutes and get final product.
Embodiment 5
A kind of carton water-repellent paint, is prepared from weight portion by following component: aqueous polyurethane 30 parts, polystyrene foam plastics 50 parts, 10 parts of acrylic acid, butyl acrylate 5-10 part, calcium hydroxide 3 parts, dibutyl phthalate 3 parts, glyceryl triacetate 4 parts, lact-acid oligomer 3 parts, polyoxyethylene lauryl ether 5 parts, polyoxyethylene oleic acid ester 3 parts, Ammonium persulfate. 0.2 part, isopropanol 20 parts, ethyl acetate 80 parts, dimethylbenzene 50 parts, ammonia 6 parts, distilled water 35 parts.
The preparation method of above-mentioned carton water-repellent paint is: first polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stir under rotating speed 100r/min to polystyrene foam plastics dissolving with magnetic stirrer, add acrylic acid, butyl acrylate, glyceryl triacetate, lact-acid oligomer, polyoxyethylene lauryl ether, polyoxyethylene oleic acid ester and 25 parts of distilled water mix and blends 5 minutes, add ammonia, at temperature 35 DEG C, stir 30 minutes to obtain solution A with magnetic stirrer;By Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;Solution A is heated to 50 DEG C, slowly instills solution B, add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 20 minutes, be eventually adding in grinder and be ground 20 minutes and get final product.
Comparative example 1
The present embodiment is to replace polyoxyethylene oleic acid ester with polyoxyethylene lauryl ether with the difference of embodiment 5.Specifically:
A kind of carton water-repellent paint, is prepared from weight portion by following component: aqueous polyurethane 30 parts, polystyrene foam plastics 50 parts, 10 parts of acrylic acid, butyl acrylate 5-10 part, calcium hydroxide 3 parts, dibutyl phthalate 3 parts, glyceryl triacetate 4 parts, lact-acid oligomer 3 parts, polyoxyethylene lauryl ether 5 parts, Ammonium persulfate. 0.2 part, isopropanol 20 parts, ethyl acetate 80 parts, dimethylbenzene 50 parts, ammonia 6 parts, distilled water 35 parts.
The preparation method of above-mentioned carton water-repellent paint is: first polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stir under rotating speed 100r/min to polystyrene foam plastics dissolving with magnetic stirrer, add acrylic acid, butyl acrylate, glyceryl triacetate, lact-acid oligomer, polyoxyethylene lauryl ether and 25 parts of distilled water mix and blends 5 minutes, add ammonia, at temperature 35 DEG C, stir 30 minutes to obtain solution A with magnetic stirrer;By Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;Solution A is heated to 50 DEG C, slowly instills solution B, add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 20 minutes, be eventually adding in grinder and be ground 20 minutes and get final product.
Comparative example 2
The present embodiment is not contain lact-acid oligomer with the difference of embodiment 5.Specifically:
A kind of carton water-repellent paint, is prepared from weight portion by following component: aqueous polyurethane 30 parts, polystyrene foam plastics 50 parts, 10 parts of acrylic acid, butyl acrylate 5-10 part, calcium hydroxide 3 parts, dibutyl phthalate 3 parts, glyceryl triacetate 4 parts, polyoxyethylene lauryl ether 5 parts, polyoxyethylene oleic acid ester 3 parts, Ammonium persulfate. 0.2 part, isopropanol 20 parts, ethyl acetate 80 parts, dimethylbenzene 50 parts, ammonia 6 parts, distilled water 35 parts.
The preparation method of above-mentioned carton water-repellent paint is: first polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stir under rotating speed 100r/min to polystyrene foam plastics dissolving with magnetic stirrer, add acrylic acid, butyl acrylate, glyceryl triacetate, polyoxyethylene lauryl ether, polyoxyethylene oleic acid ester and 25 parts of distilled water mix and blends 5 minutes, add ammonia, at temperature 35 DEG C, stir 30 minutes to obtain solution A with magnetic stirrer;By Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;Solution A is heated to 50 DEG C, slowly instills solution B, add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 20 minutes, be eventually adding in grinder and be ground 20 minutes and get final product.
The water resistance of carton water-repellent paint prepared by the present invention is as follows, it may be seen that the dried coating film time of the present invention is 6 minutes, rate of drying is very fast, and its water resisting time may be up to 17.7 hours, has extraordinary waterproof effect.
The performance of embodiment and comparative example is as follows:
Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 | Comparative example 2 | |
The dried coating film time (min) | 6 | 6 | 6 | 6 | 6 | 6 | 6.5 |
Water resisting time (h) | 17.3 | 17.4 | 17.5 | 17.7 | 17.6 | 16.8 | 16.5 |
Claims (9)
1. a carton water-repellent paint, it is characterised in that: it is prepared from weight portion by following component: aqueous polyurethane 20-30 part, polystyrene foam plastics 30-50 part, acrylic acid 5-10 part, butyl acrylate 5-10 part, calcium hydroxide 1-3 part, dibutyl phthalate 1-3 part, glyceryl triacetate 2-4 part, lact-acid oligomer 1-3 part, polyoxyethylene lauryl ether 2-5 part, polyoxyethylene oleic acid ester 1-3 part, Ammonium persulfate. 0.1-0.2 part, isopropanol 10-20 part, ethyl acetate 60-80 part, dimethylbenzene 30-50 part, ammonia 3-6 part, distilled water 20-35 part.
A kind of carton water-repellent paint the most according to claim 1, it is characterized in that: be prepared from weight portion by following component: aqueous polyurethane 22-28 part, polystyrene foam plastics 35-45 part, acrylic acid 6-9 part, butyl acrylate 6-9 part, calcium hydroxide 1.5-2.5 part, dibutyl phthalate 1.5-2.5 part, glyceryl triacetate 2.5-3.5 part, lact-acid oligomer 1.5-2.5 part, polyoxyethylene lauryl ether 3-4 part, polyoxyethylene oleic acid ester 1.5-2.5 part, Ammonium persulfate. 0.12-0.18 part, isopropanol 13-18 part, ethyl acetate 65-75 part, dimethylbenzene 35-45 part, ammonia 4-5 part, distilled water 25-30 part.
3. the preparation method of a kind of carton water-repellent paint described in any one of claim 1 to 2, it is characterised in that: comprise the following steps:
Step 1: polystyrene foam plastics, ethyl acetate and dimethylbenzene are mixed, stirs to polystyrene foam plastics dissolving with magnetic stirrer under rotating speed 80-100r/min;
Step 2: add acrylic acid, butyl acrylate, glyceryl triacetate, lact-acid oligomer, polyoxyethylene lauryl ether, polyoxyethylene oleic acid ester and 15-25 part distilled water mix and blend 3-5 minute;
Step 3: add ammonia, stirs 10-30 minute to obtain solution A with magnetic stirrer at temperature 30-35 DEG C;
Step 4: by Ammonium persulfate. and residue distilled water mixed dissolution, obtain solution B;
Step 5: solution A is heated to 40-50 DEG C, slowly instills solution B;
Step 6: add aqueous polyurethane, calcium hydroxide, dibutyl phthalate and isopropanol, mix and blend 10-20 minute;
Step 7: add and be ground 10-20 minute in grinder and get final product.
The preparation method of a kind of carton water-repellent paint the most according to claim 3, it is characterised in that: described step 1 medium speed is 85-95r/min.
The preparation method of a kind of carton water-repellent paint the most according to claim 3, it is characterised in that: in described step 2, mixing time is 3.5-4.5 minute.
The preparation method of a kind of carton water-repellent paint the most according to claim 3, it is characterised in that: in described step 3, temperature is 31-34 DEG C, and mixing time is 15-25 minute.
The preparation method of a kind of carton water-repellent paint the most according to claim 3, it is characterised in that: in described step 5, temperature is 45 DEG C.
The preparation method of a kind of carton water-repellent paint the most according to claim 3, it is characterised in that: in described step 6, mixing time is 15 minutes.
The preparation method of a kind of carton water-repellent paint the most according to claim 3, it is characterised in that: in described step 7, milling time is 15 minutes.
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CN201610336021.XA CN105951514A (en) | 2016-05-20 | 2016-05-20 | Waterproof paint for cartons and preparation method of waterproof paint |
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CN201610336021.XA CN105951514A (en) | 2016-05-20 | 2016-05-20 | Waterproof paint for cartons and preparation method of waterproof paint |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN106917323A (en) * | 2017-03-29 | 2017-07-04 | 合肥天沃能源科技有限公司 | A kind of cardboard waterproof finishing agent and preparation method thereof |
CN109322212A (en) * | 2018-07-20 | 2019-02-12 | 蚌埠市奥特纸箱机械有限公司 | A method of improving the sun-proof performance of Packaging Box waterproof |
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WO2013151050A1 (en) * | 2012-04-03 | 2013-10-10 | 関西ペイント株式会社 | Aqueous paint composition and method for forming coating |
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CN106917323A (en) * | 2017-03-29 | 2017-07-04 | 合肥天沃能源科技有限公司 | A kind of cardboard waterproof finishing agent and preparation method thereof |
CN109322212A (en) * | 2018-07-20 | 2019-02-12 | 蚌埠市奥特纸箱机械有限公司 | A method of improving the sun-proof performance of Packaging Box waterproof |
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Application publication date: 20160921 |