CN113831625B - Porous composite material for bottom of high mountain snowboard and processing method thereof - Google Patents
Porous composite material for bottom of high mountain snowboard and processing method thereof Download PDFInfo
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Abstract
The invention provides a porous composite material for the bottom of a high mountain snowboard, which comprises porous oil storage particles, a two-dimensional material and ultrahigh molecular weight polyethylene. The composite material has excellent wear resistance and lubricating property, simple processing technology and lower cost.
Description
Technical Field
The invention relates to the technical field of sports equipment, in particular to a porous composite material for a bottom of a high mountain snowboard and a processing method thereof.
Background
Sports equipment is a key element in the development of competitive sports activities. The cross-country skiing project is sports with the help of instruments in a specific environment, in recent years, along with the increasing of the technological content of professional equipment, the selection of related devices such as snowboards, snow sticks and snow wax and auxiliary products greatly influences the competition performance of athletes, and the timely introduction and absorption of related scientific research results become one of the key factors for improving the sports performance of the snowy project and preventing injuries. Research related to sports science has shown that the use of high performance snowboards has become an important factor in winning competitions. The adverse factors of China lacking in related research on the high-performance snowboards become fundamental bottlenecks restricting the rapid development of the project, so that the forward pace of research and development of related materials of the high-performance snowboards is accelerated, the foundation of the project development can be tamped, and the strong promotion can be provided for the benign development of the cross-country skiing project.
The traditional base material of the snowboard is prepared by extruding or sintering polyethylene materials. The bottom of the extrusion plate is made of polyethylene particle materials which are melted at a very high temperature and then are pressed to a proper thickness by a machine, and finally a completely flat polyethylene whole body is formed. The sintered plate bottom is also made of polyethylene, and the polyethylene particles are directly extruded by extremely high pressure, so that a whole body is connected together, and the whole plate bottom contains a large number of small air holes. The conventional snowboard bottom needs to be waxed to provide good lubrication during use. Although the sintered plate bottom is an ideal wax adhesion material compared with the extruded plate bottom due to the porous structure, the adhesion of the snow wax is limited, and the snow wax on the surface layer is gradually consumed in the sliding process, thereby influencing the sliding speed of the snow plate. On the other hand, the wear of the polyethylene in the sliding process enables the texture on the bottom surface of the plate to be shallow and even disappear, and the resistance-reducing and pollution-discharging effects of texture treatment are reduced.
Aiming at the problems of the existing snowboard bottom material, the invention provides a snowboard bottom material prepared by using ultra-high molecular weight polyethylene with excellent wear resistance as a board bottom base material, using porous oil storage particles and a two-dimensional material as additives and adopting a sintering method. According to the plate bottom material provided by the invention, the porous oil storage particles automatically release the lubricant in the sliding process, the lubricant and the two-dimensional material play a lubricating role together, the lubricating role is ensured in the whole sliding process, and the limitation of a product using snow wax alone is effectively avoided.
Disclosure of Invention
The invention aims to provide a porous composite material for the bottom of a high mountain snow board, which has excellent wear resistance and lubricating property, simple processing technology and lower cost.
In order to solve the technical problems, the invention provides a porous composite material for the bottom of a high mountain snowboard, which comprises porous oil storage particles, a two-dimensional material and ultra-high molecular weight polyethylene.
Wherein the mass fraction of the porous oil storage particles in the composite material is 0.01-20%.
Wherein the mass fraction of the two-dimensional material in the composite material is 0-15%.
Wherein, the porous oil storage particles can be one or more of microcapsules containing low-temperature liquid lubricant, expanded graphite and activated carbon.
The two-dimensional material can be one or a combination of several of graphene, black phosphorus and molybdenum disulfide.
Wherein the molecular weight range of the ultra-high molecular weight polyethylene is 150-1000 ten thousand.
Wherein the low-temperature lubricant is one or more of 1-butyl-3-methylimidazole dicyanamide salt, tributyl phosphite, simethicone, polyethylene glycol 400 dioleate, Mobil AN5, liquid paraffin, 1-methyl-3-butylimidazole nitrate and 3-aminopropyltriethoxysilane.
Wherein, pore-forming agent can be added into the composite material, for example, the added mass fraction is 0.01-20%.
The pore-forming agent is one or more of sodium chloride, sodium carbonate, sodium sulfate, potassium chloride, potassium sulfate, potassium carbonate, Arabic gum, sodium alginate, gelatin, polyethylene glycol and polyvinylpyrrolidone in any proportion.
The invention also provides a processing method of the high mountain snow plate bottom composite material, which comprises the following steps:
firstly, weighing oil storage particles, a two-dimensional material, a pore-forming agent and ultrahigh molecular weight polyethylene solid powder in proportion, and mixing by using a ball mill;
secondly, molding the mixed powder in the first step at the temperature of T1 and the pressure of P1;
thirdly, forming a compact solid body at the temperature T2 and the pressure P2;
fourthly, cutting the high mountain snow plate into the required high mountain snow plate bottom slice by a milling machine.
Wherein T1 is room temperature, P1 is 1-10 MPa.
Wherein T2 is 160-260 ℃ and P2 is 2-20 MPa.
The invention has the advantages of
The alpine snowboard bottom porous composite material provided by the invention has excellent wear resistance and lubricating property, on one hand, the mechanical property and the lubricating property of the material are improved by adding the oil storage particles containing the low-temperature lubricant and the two-dimensional material, and on the other hand, the porosity of the composite material is increased by using the pore-forming agent in the processing process, so that the wax absorption property of the board bottom is greatly improved.
In addition, the porous composite material for the bottom of the high mountain snowboard provided by the invention is simple in processing technology and low in cost, and is a snowboard bottom material with good application prospect.
Drawings
FIG. 1 is a schematic representation of a porous composite material prepared in example 1;
FIG. 2 is a graph showing the coefficient of friction of the porous composite material prepared in example 1;
FIG. 3 is a pictorial representation of the oil storing particulate expanded graphite used in porous composite of this invention of example 3;
FIG. 4 is a diagram of a porous composite material object prepared in example 3;
FIG. 5 is a graph of the coefficient of friction of the porous composite of example 3.
Detailed Description
The invention provides a porous composite material for the bottom of a high mountain snowboard, which comprises porous oil storage particles, a two-dimensional material and ultrahigh molecular weight polyethylene.
Wherein the mass fraction of the porous oil storage particles in the composite material is 0.01-20%.
Wherein the mass fraction of the two-dimensional material in the composite material is 0-15%.
Wherein, the porous oil storage particles can be one or more of microcapsules containing low-temperature liquid lubricant, expanded graphite and activated carbon.
The two-dimensional material can be one or a combination of several of graphene, black phosphorus and molybdenum disulfide.
Wherein the molecular weight of the ultra-high molecular weight polyethylene ranges from 150 to 1000 ten thousand.
Wherein the low-temperature lubricant is one or more of 1-butyl-3-methylimidazole dicyanamide salt, tributyl phosphite, simethicone, polyethylene glycol 400 dioleate, Mobil AN5, liquid paraffin, 1-methyl-3-butylimidazole nitrate and 3-aminopropyltriethoxysilane.
The composite material can also be added with pore-forming agent, and the addition mass fraction of the pore-forming agent is 0.01-20%.
The pore-forming agent is one or more of sodium chloride, sodium carbonate, sodium sulfate, potassium chloride, potassium sulfate, potassium carbonate, Arabic gum, sodium alginate, gelatin, polyethylene glycol and polyvinylpyrrolidone in any proportion.
The invention also provides a processing method of the high mountain snow plate bottom composite material, which comprises the following steps:
firstly, weighing oil storage particles, a two-dimensional material, a pore-forming agent and ultrahigh molecular weight polyethylene solid powder in proportion, and mixing by using a ball mill;
secondly, molding the mixed powder in the first step at the temperature of T1 and the pressure of P1;
thirdly, forming a compact solid body at the temperature T2 and the pressure P2;
fourthly, cutting the high mountain snow plate into the required high mountain snow plate bottom slice by a milling machine.
Wherein T1 is room temperature, P1 is 1-10 MPa.
Wherein T2 is 160-260 ℃ and P2 is 2-20 MPa.
The following embodiments are described in detail to solve the technical problems by applying technical means to the present invention, and the implementation process of achieving the technical effects can be fully understood and implemented.
Example 1
The microcapsule containing trimethyl phosphite is prepared by an in-situ polymerization method, and the wall material of the microcapsule is urea-formaldehyde resin. Weighing oil storage particle microcapsules (5 wt.%), two-dimensional material graphene (1 wt.%), pore-forming agent sodium chloride (2 wt.%) and ultrahigh molecular weight polyethylene solid powder (92 wt.%), molecular weight is 900 ten thousand), mixing by using a ball mill, then molding at room temperature and under the pressure of 1PMa for 15min, and then sintering at 200 ℃ and under the pressure of 2MPa for 2h to finally form a compact and solid integral material. In order to verify the lubricating performance of the composite material at low temperature, the composite material is processed into pellets with the diameter of 12.7 mm (figure 1), and the pellets are subjected to a tribological performance test, so that the composite material has the friction coefficient of only 0.019 at minus 10 ℃ and has excellent low-temperature lubricating performance as shown in figure 2.
Comparative example 1
The ultra-high molecular weight polyethylene solid powder (92 wt.%, molecular weight of 900 ten thousand) is firstly molded at room temperature under the pressure of 1PMa, the pressure maintaining time is 15min, and then the powder is sintered for 2h at the temperature of 200 ℃ and the pressure of 2MPa to form a compact and solid material. The material was processed into pellets of 12.7 mm in diameter (fig. 3) and subjected to tribological property testing to give a coefficient of friction of 0.16. By comparison, the substrate material provided by the invention has better lubricating property.
Example 2
The microcapsule containing the dimethyl silicone oil is prepared by an in-situ polymerization method, and the wall material of the microcapsule is urea resin. Weighing oil storage particle microcapsules (7 wt.%), pore-forming agent sodium carbonate (1 wt.%), and ultrahigh molecular weight polyethylene solid powder (92 wt.%, molecular weight is 300 ten thousand), mixing by using a ball mill, molding at room temperature under pressure of 2PMa for 15min, sintering at 220 ℃ under pressure of 4MPa for 2h, and finally forming a compact and solid integral material. To verify the lubricating properties of the composite at low temperatures, we processed the material into pellets of 12.7 mm diameter and subjected it to tribological property tests. The friction coefficient of the composite material is only 0.02 at-10 ℃, and the composite material has excellent low-temperature lubricating property.
Example 3
5g of porous material expanded graphite is weighed, liquid paraffin adsorption treatment is carried out on the material by adopting an impregnation method, and oil storage particles are obtained after drying (figure 4).
Weighing oil storage particles (5 wt.%), two-dimensional material graphene (1 wt.%), pore-forming agent sodium chloride (2 wt.%) and ultrahigh molecular weight polyethylene solid powder (92 wt.% and molecular weight of 700 ten thousand), mixing by using a ball mill, then molding at room temperature and under the pressure of 1PMa for 15min, and sintering at 200 ℃ and 2MPa for 2h to finally form a compact and solid integral material. In order to verify the lubricating performance of the composite material at low temperature, the composite material is cut into small balls with the diameter of 12.7 mm, and the friction performance test is carried out on the small balls, and the result is shown in figure 5, and the composite material has a friction coefficient of about 0.06 at-10 ℃ and has better low-temperature lubricating performance.
Comparative example 2
The ultra-high molecular weight polyethylene solid powder (92 wt.%, molecular weight of 700 ten thousand) is firstly molded at room temperature under the pressure of 1PMa, the pressure maintaining time is 15min, and then the powder is sintered for 2h at the temperature of 200 ℃ and the pressure of 2MPa, and finally the compact and solid integral material is formed. The material was processed into pellets of 12.7 mm in diameter and subjected to tribological property testing to obtain a coefficient of friction of 0.10. By comparison, the substrate material provided by the invention has better lubricating property.
All of the above mentioned intellectual property rights are not intended to be restrictive to other forms of implementing the new and/or new products. Those skilled in the art will appreciate that this important information can be used to modify the above to achieve similar performance. However, all modifications or alterations are based on the new products of the invention and belong to the reserved rights.
The foregoing is directed to preferred embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow. However, any simple modification, equivalent change and modification of the above embodiments according to the technical essence of the present invention are within the protection scope of the technical solution of the present invention.
Claims (7)
1. The utility model provides a porous combined material at bottom of mountain snow board which characterized in that: the composite material comprises porous oil storage particles, a two-dimensional material, ultra-high molecular weight polyethylene and a pore-forming agent;
the porous oil storage particles are particles containing a low-temperature liquid lubricant and are one or a combination of a plurality of microcapsules, expanded graphite and activated carbon;
the oil is a low-temperature liquid lubricant and is selected from one or more of 1-butyl-3-methylimidazole dicyanamide salt, simethicone, polyethylene glycol 400 dioleate, Mobil AN5, liquid paraffin and 1-methyl-3-butylimidazole nitrate;
the addition mass fraction of the pore-forming agent is 0.01-20%.
2. The alpine snowboard bottom porous composite material of claim 1, wherein: the mass fraction of the porous oil storage particles in the composite material is 0.01-20%.
3. The alpine snowboard bottom porous composite material as claimed in claim 1 or 2, wherein: the mass fraction of the two-dimensional material in the composite material is 0-15%.
4. The alpine snowboard bottom porous composite material as claimed in claim 1 or 2, wherein: the two-dimensional material is one or a combination of several of graphene, black phosphorus and molybdenum disulfide.
5. The alpine snowboard bottom porous composite material of claim 1, wherein: the pore-forming agent is one or more of sodium chloride, sodium carbonate, sodium sulfate, potassium chloride, potassium sulfate, potassium carbonate, Arabic gum, sodium alginate, gelatin, polyethylene glycol and polyvinylpyrrolidone in any proportion.
6. The method for processing the alpine snowboard bottom composite material according to any one of claims 1 to 5, comprising:
firstly, weighing porous oil storage particles, a two-dimensional material, a pore-forming agent and ultrahigh molecular weight polyethylene solid powder in proportion, and mixing by using a ball mill;
secondly, molding the mixed powder in the first step at the temperature of T1 and the pressure of P1;
thirdly, forming a compact solid body at the temperature T2 and the pressure P2;
fourthly, cutting the high mountain snow plate into the required high mountain snow plate bottom slice by a milling machine.
7. The method for processing the alpine snowboard bottom composite material of claim 6, wherein: t1 is room temperature, P1 is 1-10MPa, T2 is 160-260 ℃ and P2 is 2-20 MPa.
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