CN113813216B

CN113813216B - Water-out honey powder composition and preparation method thereof

Info

Publication number: CN113813216B
Application number: CN202111238381.3A
Authority: CN
Inventors: 曹洪彬; 师国康
Original assignee: Zhejiang Biyouti Cosmetics Co ltd
Current assignee: Zhejiang Biyouti Cosmetics Co ltd
Priority date: 2021-10-25
Filing date: 2021-10-25
Publication date: 2023-05-09
Anticipated expiration: 2041-10-25
Also published as: CN113813216A

Abstract

The invention discloses a water-out honey powder composition and a preparation method thereof, wherein the water-out honey powder composition comprises the following components: thickeners, colorants, surfactants, solvents, humectants, skin conditioning agents, preservatives, emollients, fillers. The preparation method comprises the following steps: weighing CI77891, CI77492, CI77491, CI77499, CI77007, CI77288, bis-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine, isopropyl titanium triisostearate and triethoxy octyl silane according to a proportion, and mixing to obtain a phase A; stirring and crushing the phase A and the silica dimethyl silyl to obtain a phase B; heating, mixing and dissolving water, butanediol, glycerol, glyceroglycoside and p-hydroxyacetophenone to obtain a C phase; cooling the phase C, adding phenoxyethanol, herba Dendrobii extract, hydrolyzed Margarita, and 1, 2-hexanediol to obtain phase D; and adding the phase D into the phase B to obtain a finished product. The invention has the characteristic of effectively improving the effects of moistening, cooling and softening focus.

Description

Water-out honey powder composition and preparation method thereof

Technical Field

The invention relates to a honey powder cosmetic, in particular to a water-yielding honey powder composition and a preparation method thereof.

Background

The cosmetic powder, commonly called honey powder and powder, is a cosmetic applied to the face. Generally contains fine talcum powder, has the function of absorbing excessive facial grease and reducing facial oil, and can make the makeup more durable, smooth and fine. In addition, the cosmetic powder has the effect of covering flaws on the face, so that the cosmetic looks softer, and a hazy cosmetic state is presented, and the cosmetic powder is particularly suitable for daily life cosmetics. Therefore, it is indispensable to make the makeup delicate and durable, and to use a powder for making up. At present, honey powder cosmetics are generally divided into three types of powder, block and liquid; the conventional market is divided into two dosage forms of powder and block, and liquid dosage forms rarely exist; however, powdered and lump honey products have poor moisturizing, cooling and soft-focus effects, which can affect the consumer's experience and thus the overall popularity and sales of the product. Therefore, the prior art has the problem of poor moisturizing, cooling and soft-focus effects.

Disclosure of Invention

The invention aims to provide a water-out honey powder composition and a preparation method thereof. The invention has the characteristic of effectively improving the effects of moistening, cooling and softening focus.

The technical scheme of the invention is as follows: the water-out honey powder composition comprises the following components in parts by weight: 10-30 parts of thickening agent; 0.5-2 parts of coloring agent; 0.5-5 parts of surfactant; 10-20 parts of a solvent; 10-30 parts of humectant; 0.02-3 parts of skin conditioning agent; 0.2-2 parts of preservative; 0.2-2 parts of an emollient; 10-30 parts of filler.

In the above-mentioned water-out honey powder composition, the thickener is dimethyl silyl silica.

In one of the foregoing water-yielding powdered honey compositions, the coloring agent comprises CI77891, CI77492, CI77491, CI77499, CI77007 and CI77288.

In the water-out honey powder composition, the surfactant comprises a bis-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine, triisostearate isopropoxide titanium salt and triethoxy octyl silane.

In the above-mentioned water-out honey powder composition, the humectant comprises butanediol, glycerol and glyceroglycosides.

In the above water-yielding honey powder composition, the skin conditioning agent comprises Dendrobium officinale Kimura et Migo extract and hydrolyzed pearl.

In the above-mentioned water-out honey powder composition, the decay agent includes phenoxyethanol and p-hydroxyacetophenone.

In the water-out honey powder composition, the emollient is 1, 2-hexanediol; the filler is silica and the solvent is water.

The preparation method of the water-out honey powder composition comprises the following specific steps:

firstly, weighing CI77891, bis-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine and triisostearate isopropoxide titanium salt according to the weight ratio, mixing and stirring uniformly at the stirring speed of 1500-1800rpm, spraying and putting into a high-pressure reaction kettle for reaction, and drying at the temperature of 90-120 ℃ to obtain an A1 phase;

weighing CI77492, di-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine and triisostearate isopropoxide titanium salt according to the weight ratio, mixing and stirring uniformly at the stirring speed of 1500-1800rpm, spraying and putting into a high-pressure reaction kettle for reaction, and drying at the high temperature of 90-120 ℃ to obtain an A2 phase;

weighing CI77491, a bis-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine and triisostearate isopropoxide titanium salt according to the weight ratio, mixing and stirring uniformly at the stirring speed of 1500-1800rpm, spraying and putting into a high-pressure reaction kettle for reaction, and drying at the high temperature of 90-120 ℃ to obtain an A3 phase;

weighing CI77499, bis-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine and triisostearate isopropoxide titanium salt according to the weight ratio, mixing and stirring uniformly at the stirring speed of 1500-1800rpm, spraying and putting into a high-pressure reaction kettle for reaction, and drying at the high temperature of 90-120 ℃ to obtain an A4 phase;

weighing CI77007 and triethoxy octyl silane according to the weight ratio, mixing and stirring uniformly at the stirring speed of 1500-1800rpm, spraying and putting into a high-pressure reaction kettle for reaction, and drying at the high temperature of 90-120 ℃ to obtain a phase A5;

weighing CI77288 and triethoxy octyl silane according to the weight ratio, mixing and stirring uniformly at the stirring speed of 1500-1800rpm, spraying and putting into a high-pressure reaction kettle for reaction, and drying at the high temperature of 90-120 ℃ to obtain phase A6;

uniformly stirring the A1-A6 phases at a stirring speed of 1500-1800rpm, and putting into a high-speed pulverizer to pulverize for 3-5 times at a speed of 3000-3500rpm to obtain the A phase;

weighing phase A with corresponding weight, adding dimethyl silyl silica and silica, stirring uniformly at 1200-1500rpm, and then feeding into a high-speed pulverizer, and repeatedly pulverizing at 3000-3500rpm for 3-5 times to obtain phase B;

thirdly, weighing water, butanediol, glycerol, glyceroglycosides and p-hydroxyacetophenone, mixing and stirring uniformly at the speed of 700-900rpm, and heating to 65-70 ℃ until the mixture is completely dissolved to obtain a C phase;

fourthly, cooling the phase C to 30-35 ℃, adding phenoxyethanol, dendrobium candidum extract, hydrolyzed pearl and 1, 2-hexanediol, and uniformly stirring at a speed of 900-1200rpm to obtain a phase D;

and fifthly, slowly stirring the phase B and adding the phase D, and continuously and uniformly stirring after the addition is completed to obtain a finished product.

In the fifth step, in the adding process of the D phase, the stirring speed of the B phase is 400-600RPM; after the addition of phase D was completed, phase B was uniformly and rapidly added to 1100-1400RPM at 300RPM per minute with stirring time of 18-20min.

Compared with the prior art, the water-out honey powder composition consists of a thickening agent, a coloring agent, a surfactant, a solvent, a humectant, a skin conditioning agent, a preservative, an emollient and a filler, the proportion of the components is strictly limited, the powdery and liquid dosage forms are combined together, the basic characteristics of honey powder are maintained, the honey powder composition has the effects of moistening skin, cooling (because the honey powder composition contains 10-30 parts of humectant, the water is squeezed by beating in the use process, the cooling effect is brought to the skin), and the soft-focus effect, the face of the honey powder composition can feel water after the face of the honey powder composition, and the honey powder composition is in the state of powder and does not have the feeling of dry powder. The invention selects the multiple surface treatments, namely the toner containing the di-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine, triisostearate isopropoxide titanium salt and triethoxy octyl silane, so as to ensure that the product can not quickly be clustered and sunk while the solvent and the humectant are stirred in. In addition, the stirring rotation speed and time of each step are controlled by strictly controlling each step and specific technological parameters of each step in the preparation process of the water-out honey powder composition, so that the powder and liquid dosage forms can be combined, and the effects of moistening skin, cooling and softening focus are achieved while the basic characteristics of the honey powder are maintained. In conclusion, the invention has the characteristic of effectively improving the effects of moistening, cooling and softening.

Drawings

FIG. 1 is a view showing the state of water drops observed under a microscope of the product prepared in example 2 of the present invention;

FIG. 2 is a view showing the state of water drops when the products prepared in comparative examples 1 and 3 are observed under a microscope;

FIG. 3 is a view showing the state of water drops when the products prepared in comparative examples 2 and 4 were observed under a microscope.

Detailed Description

The invention is further illustrated by the following figures and examples, which are not intended to be limiting.

Example 1. The water-out honey powder composition comprises the following components in parts by weight: 10-30 parts of thickening agent; 0.5-2 parts of coloring agent; 0.5-5 parts of surfactant; 10-20 parts of a solvent; 10-30 parts of humectant; 0.02-3 parts of skin conditioning agent; 0.2-2 parts of preservative; 0.2-2 parts of an emollient; 10-30 parts of filler.

The thickener is dimethylsilylated silica.

The colorant includes CI77891 (0.3-1 parts), CI77492 (0.1-0.5 parts), CI77491 (0.1-0.5 parts), CI77499 (0.1-0.5 parts), CI77007 (0.1-0.5 parts), and CI77288 (0.1-0.5 parts).

The surfactant comprises bis-PEG-15 polydimethylsiloxane/IPDI copolymer (0.7-3.5 parts), PEG-2 soybean amine (O.1-0.5 parts), triisostearate isopropoxide titanium salt (0.8-3 parts) and triethoxy octyl silane (1-3 parts).

The humectant comprises butanediol (5-15 parts), glycerol (5-15 parts) and glyceroglycosides (5-15 parts).

The skin preparation comprises Dendrobium officinale extract (0.01-3 parts) and hydrolyzed pearl (0.01-3 parts).

The preservative comprises phenoxyethanol (0.1-0.8 part) and p-hydroxyacetophenone (0.1-0.8 part).

The emollient is 1, 2-hexanediol; the filler is silica and the solvent is water.

In the fifth step, in the adding process of the D phase, the stirring rotating speed of the B phase is 400-600RPM; after the addition of phase D was completed, phase B was uniformly and rapidly added to 1100-1400RPM at 300RPM per minute with stirring time of 18-20min.

Example 2. The composition of the water-out honey powder comprises the following components in parts by weight: 30g of thickener, 1.5g of colorant, 3 g of surfactant, 15g of solvent, 15g of humectant, 3 g of skin conditioning agent, 0.8 g of preservative, 2g of emollient and 29.7g of filler.

Thickeners include dimethylsilylated silica, which function to improve the stability, rheological state of the product.

Colorants include CI77891 (titanium dioxide), CI77492 (iron oxides), CI77491 (iron oxides), CI77499 (iron oxides), CI77007 (ultramarine), CI77288 (chrome oxide green), the primary function being to impart color to the product.

The skin preparation comprises Dendrobium officinale extract and hydrolyzed pearl, has the main effects of promoting permeation and moisturizing, and has the effect of resisting oxidation.

The preservative comprises phenoxyethanol and p-hydroxyacetophenone, and has the main effects of inhibiting the growth and reproduction of microorganisms and keeping the stability of the properties of the cosmetics.

Emollients include 1, 2-hexanediol, which primarily serves to provide lubrication and protection to the skin surface.

The filler is silica, and the main function is to improve the stability of the product.

The humectant comprises butanediol, glycerol and glyceroglycosides, and has the main effect of moisturizing skin.

The solvent is water, and has the main function of bringing about a moistening effect on the skin.

Surfactants include bis-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine, isopropyl titanyl triisostearate, triethoxy octyl silane, which have the main effect of increasing the hydrophobicity of the colorant surface.

In the preparation process of the invention, multiple surface treatments, namely, the toner containing the di-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine, triisostearate isopropoxide titanium salt and triethoxy octyl silane are selected. Ensures that the product can not be quickly agglomerated and sunk while the solvent and the humectant are stirred in. When the toner which is not subjected to surface treatment is selected to prepare the product, the toner which is not subjected to surface treatment has better compatibility with a solvent and a humectant in a formula, so that the toner can be quickly agglomerated and sunk.

The thickener used is mentioned in the product formulation as silica. The specific surface area of the silica is 195-245m2/g, and the density is 0.0588 +/-0.01 g/ml. When a silica having a higher density is selected, the suspension effect is not achieved.

Preparation method

Firstly, weighing CI77891 (96 g), bis-PEG-15 polydimethylsiloxane/IPDI copolymer (1.75 g), PEG-2 soybean amine (0.25 g) and triisostearate isopropoxide titanium salt (2 g) and uniformly stirring at a stirring speed of 1600rpm, spraying and putting the mixture into a high-pressure reaction kettle for reaction, and drying at a high temperature of 105 ℃ to obtain an A1 phase; CI77492 (96 g), bis-PEG-15 polydimethylsiloxane/IPDI copolymer (1.75 g), PEG-2 soybean amine (0.25 g) and triisostearate isopropoxide titanium salt (2 g) are weighed, evenly stirred and sprayed into a high-pressure reaction kettle for reaction at a stirring speed of 1600rpm, and are dried at a high temperature of 105 ℃ to obtain A2 phase; CI77491 (96 g), bis-PEG-15 polydimethylsiloxane/IPDI copolymer (1.75 g), PEG-2 soybean amine (0.25 g) and triisostearate isopropoxide titanium salt (2 g) are weighed, evenly stirred and sprayed into a high-pressure reaction kettle for reaction at a stirring speed of 1600rpm, and are dried at a high temperature of 105 ℃ to obtain A3 phase; CI77499 (96 g), bis-PEG-15 polydimethylsiloxane/IPDI copolymer (1.75 g), PEG-2 soybean amine (0.25 g) and triisostearate isopropoxide titanium salt (2 g) are weighed, evenly stirred and sprayed into a high-pressure reaction kettle at a stirring speed of 1600rpm to react, and the mixture is dried at a high temperature to 105 ℃ to be A4 phase; weighing CI77007 (98 g) and triethoxyoctylsilane (2 g), uniformly stirring at a stirring speed of 1600rpm, spraying, putting into a high-pressure reaction kettle, and performing high-temperature drying to 105 ℃ to obtain A5 phase; weighing CI77288 (98 g) and triethoxyoctylsilane (2 g), uniformly stirring at a stirring speed of 1600rpm, spraying, putting into a high-pressure reaction kettle, and performing high-temperature drying to 105 ℃ to obtain A6 phase; phases A1 to A6 were stirred uniformly at a stirring speed of 1600rpm and fed into a high-speed pulverizer (at a speed of 3300 rpm) to pulverize 4 times, to be phase A.

In the second step, 1.55g of dimethylsilylated silica (30 g) and 29.7g of silica were taken out of the phase A, stirred uniformly at 1350rpm, and fed into a high-speed pulverizer, and pulverized repeatedly 4 times at 3300rpm without white particles. Is phase B.

And thirdly, weighing 15g of water, 5g of butanediol, 5g of glycerol, 5g of glyceroglycosides and 0.4g of p-hydroxyacetophenone, mixing and stirring uniformly at the speed of 800rpm, and heating to 68 ℃ until the mixture is completely dissolved to form a C phase.

Fourth, cooling the phase C to 33 ℃, adding 0.4g of phenoxyethanol, 1.5g of dendrobium candidum extract, 1.5g of hydrolyzed pearl and 2g of 1, 2-hexanediol, and uniformly stirring at 1050rpm to obtain phase D.

And fifthly, slowly stirring the phase B and adding the phase D. Adding phase D during the first 55 seconds of stirring at 500RPM; then the stirring time was 19min, which was increased to 1200RPM at a constant speed of 300RPM per minute. When the selected rotating speed is too high, the phenomenon that water drops are stuck and sunk is caused, the product becomes a viscous state and loses the basic form of the honey powder, and when the selected rotating speed is too low, the phenomenon that water drops are not stirred is caused.

Comparative examples 1-4 procedure:

comparative column 1: the other steps are the same as in example 2, except that the specific process selected in the fourth step of the preparation method is different: specifically, the phase B is slowly stirred and added into the phase D, and the phase D is stirred and added for the first 55 seconds, and the rotating speed is 200RPM; then the stirring time was 19min, which was increased to 1200RPM at a constant speed of 300RPM per minute.

Comparative column 2: the other steps are the same as in example 2, except that the specific process selected in the fourth step of the preparation method is different: specifically, the phase B is slowly stirred and added into the phase D, and the phase D is stirred and added for the first 55 seconds, and the rotating speed is 700RPM; then the stirring time was 19min, which was increased to 1200RPM at a constant speed of 300RPM per minute.

Comparative column 3: the other steps are the same as in example 2, except that the specific process selected in the fourth step of the preparation method is different: specifically, the phase B is slowly stirred and added into the phase D, and the phase D is stirred and added for the first 55 seconds, and the rotating speed is 500RPM; then the stirring time was 19min, which was increased to 900RPM at a constant speed of 300RPM per minute.

Comparative column 4: the other steps are the same as in example 2, except that the specific process selected in the fourth step of the preparation method is different: specifically, the phase B is slowly stirred and added into the phase D, and the phase D is stirred and added for the first 55 seconds, and the rotating speed is 500RPM; then the stirring time was 19min, which was increased to 1600RPM at a constant speed of 300RPM per minute.

Example 2 and 4 comparison table of stability during the course of the experiment

	Comparative column 1	Comparative column 2	Comparative column 3	Comparative column 4
					During the experiment	The water drops can not be stirred	Water drop holding ball	The water drops can not be stirred	Water drop holding ball

From the above stability comparison table, in comparative examples 1 and 3, there were cases where the water droplets were not stirred, and in comparative examples 2 and 4, there were cases where the water droplets were stuck. The best process option is to implement the rotational speed and time in column 2.

The products of example 2 and comparative examples 1 to 4 were observed under a microscope for the water drop state, and the results are shown in fig. 1 to 3: as shown in fig. 1, the product of example 2 showed uniform dispersion of water droplets in the product under a microscope; as shown in fig. 2, the products prepared in comparative examples 1 and 3 show that water drops cannot be stirred in under a microscope; as shown in fig. 3, comparative examples 2 and 4 showed that the water droplets were stuck in a viscous state under the microscope, and lost the form of the honey powder itself.

Claims

1. The water-out honey powder composition is characterized by comprising the following components in parts by weight: 10-30 parts of thickening agent; 0.5-2 parts of coloring agent; 0.5-5 parts of surfactant; 10-20 parts of a solvent; 10-30 parts of humectant; 0.02-3 parts of skin conditioning agent; 0.2-2 parts of preservative; 0.2-2 parts of an emollient; 10-30 parts of filler;

the thickener is dimethyl silyl silica;

the colorants include CI77891, CI77492, CI77491, CI77499, CI77007, and CI 77288;

the surfactant comprises a bis-PEG-15 polydimethylsiloxane/IPDI copolymer, PEG-2 soybean amine, triisostearate isopropoxide titanium salt and triethoxy octyl silane;

the humectant comprises butanediol, glycerol and glyceroglycosides;

the skin conditioner comprises dendrobium candidum extract and hydrolyzed pearl;

the preservative comprises phenoxyethanol and p-hydroxyacetophenone;

2. The method for preparing the water-out honey powder composition according to claim 1, which is characterized by comprising the following specific steps:

3. The method for preparing the water-out honey powder composition according to claim 2, which is characterized in that: in the fifth step, in the adding process of the D phase, the stirring rotating speed of the B phase is 400-600RPM; after the addition of phase D was completed, phase B was uniformly and rapidly added to 1100-1400RPM at 300RPM per minute with stirring time of 18-20min.