CN113801494A - High-fastness black disperse dye composition - Google Patents
High-fastness black disperse dye composition Download PDFInfo
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- CN113801494A CN113801494A CN202111174345.5A CN202111174345A CN113801494A CN 113801494 A CN113801494 A CN 113801494A CN 202111174345 A CN202111174345 A CN 202111174345A CN 113801494 A CN113801494 A CN 113801494A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
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Abstract
The invention belongs to the field of disperse dyes, and particularly relates to a high-fastness black disperse dye composition which comprises a component A, a component B, a component C and a component D; wherein, the component A accounts for 15 to 20 percent, the component B accounts for 10 to 15 percent, the component C accounts for 40 to 50 percent, and the component D accounts for 10 to 15 percent; the high-fastness black disperse dye composition is added with a filling aid E; the filling aid E comprises the following components: naphthalenesulfonic acid formaldehyde condensates (e.g., dispersant NNO), alkylnaphthalenesulfonic acid formaldehyde condensates (e.g., dispersant MF), benzylnaphthalenesulfonic acid formaldehyde condensates (e.g., dispersant CNF), lignosulfonates (e.g., commercially available dispersant Reax 83A, Reax 85A, Reax 89L, etc.); the dye has good deep dyeing property, easy washing of loose color, excellent organic solvent fastness, sublimation fastness and washing fastness, and is particularly suitable for dyeing and printing of fabrics with dry cleaning and gluing and laminating requirements, such as shoe materials, suit coats and the like.
Description
Technical Field
The invention belongs to the field of disperse dyes, and particularly relates to a black disperse dye composition with high fastness.
Background
Landslide, sideslip, collapse of side slope.
A chinese patent publication No. CN107652710A discloses a high-fastness disperse black dye composition, which comprises a component a, a component B, a component C and a component D, wherein the component a is selected from at least one of compounds represented by formula (I), the component B is selected from at least one of compounds represented by formula (II), the component C is selected from at least one of compounds represented by formula (III) and/or formula (IV), and the component D is selected from at least one of compounds represented by formula (V).
The conventional dye has poor fastness to organic solvents, and when the conventional dye is used for glue adhesion of shoe materials, the dye can be dissolved and transferred out by the solvent of the glue, so that the contamination and color fastness of the fabric are reduced; in addition, organic solvents such as tetrachloroethylene and the like are used when the suit fabric is dry-cleaned, and dyes are also transferred and stained.
Therefore, the invention provides a high-fastness black disperse dye composition.
Disclosure of Invention
To remedy the deficiencies of the prior art, at least one of the technical problems set forth in the background is addressed.
The technical scheme adopted by the invention for solving the technical problems is as follows: the invention relates to a high-fastness black disperse dye composition which comprises a component A, a component B, a component C and a component D; wherein
The structural formula of the component A is as follows:
in the formula R1：-CH3，-C2H5，-C4H7；
The structural formula of the component B is as follows:
in the formula R2：-NHCOCH3，
R3、R4：-CH2COOCH3，-C2H4COOCH3，-C2H4CN；
The structural formula of the component C is as follows:
in the formula R5：-BR，-CN，-NO2；
R6：-H，-COH3，-OCH2OH3；
R7、R8：-CH2COOCH3，-CH2CH2COOCH3，-C2H4CN，
The structural formula of the component D is as follows:
in the formula R9：-H，-CH3；
R10、R11：-C2H5，-C2H4OH，C2H4OCOCH3。
Further, a filling aid E is added into the high-fastness black disperse dye composition; the filling aid E comprises the following components: naphthalene sulfonic acid formaldehyde condensates (e.g., dispersant NNO), alkyl naphthalene sulfonic acid formaldehyde condensates (e.g., dispersant MF), benzyl naphthalene sulfonic acid formaldehyde condensates (e.g., dispersant CNF), lignosulfonates (e.g., the commercially available dispersant Reax 83A, Reax 85A, Reax 89L, etc.).
Further, the high-fastness black disperse dye composition is filled in a storage device for storage; the storage device comprises a tank body; the top of the tank body is provided with a sealing cover; a glue scraping plate is fixedly connected to the opening part of the inner side wall of the tank body, which is close to the opening part; the rubber scraping plate is arranged annularly; the scraping plate is made of rubber; the diameter of the top opening of the glue scraping plate is larger than that of the bottom opening; when the dye composition collecting device is used, when an operator needs to use the dye composition in the tank body, the collecting device extends into the tank body, then the collecting device is lifted, so that the dye composition in the tank body can be taken out by the operator, and the dye composition is brushed or dripped at the position where the dye composition needs to be used, through the glue scraping plate arranged in the tank body, part of the dye composition can be dripped in the process that the collecting device is lifted from the tank body, at the moment, when the collecting device is lifted, the side wall of the collecting device is scraped at the bottom of the glue scraping plate for multiple times, so that the dye composition on the surface of the collecting device is scraped, a large amount of the dye composition cannot be dripped at the port of the tank body when the collecting device is taken out of the tank body, the waste problem of the collecting device in the process of collecting the dye composition is further reduced, and the dye composition is simultaneously reduced in the port of the tank body, the problem that the dye composition can cause pollution to the port of the tank body can be reduced.
Furthermore, an elastic arc-shaped cleaning plate is fixedly connected to the inner side wall of the top of the sealing cover; the elastic arc-shaped sweeping plate is arranged annularly; the elastic arc-shaped sweeping plate is made of rubber; the diameter of the middle part of the elastic arc-shaped cleaning plate is larger than that of the middle part of the rubber scraping plate; the diameter of the top of the rubber scraping plate is larger than that of the bottom of the rubber scraping plate; an elastic scraping piece is fixedly connected to the end part of the elastic arc-shaped sweeping plate; the bottom of the sealing cover is provided with the elastic arc-shaped cleaning plate, so that in the process that the sealing cover covers the tank body, the elastic arc-shaped cleaning plate can push down the dye composition on the glue scraping plate, the dye composition on the side wall of the glue scraping plate is gathered into a drop shape when being pushed together, and then the dye composition drops into the tank body under the self gravity, so that the dye composition remained on the glue scraping plate drops into the tank body, the waste caused by the residue of the dye composition on the glue scraping plate is reduced, and the sealing performance of the sealing cover on the tank body can be increased by the extrusion of the elastic arc-shaped cleaning plate and the glue scraping plate.
Furthermore, an elastic bag is fixedly connected to the inner side wall of the elastic arc-shaped cleaning plate; the outer side of the elastic arc-shaped sweeping plate is provided with a friction ball; a first elastic pull rope is connected between the friction ball and the elastic bag; the first elastic pull rope penetrates through the elastic arc-shaped sweeping plate; a second elastic pull rope is connected between the friction ball and the side wall of the elastic scraping blade; through being equipped with the friction ball on elasticity arc cleans the board, can clean the board and scrape the offset plate contact in elasticity arc, upwards promote the friction ball, the friction ball will pass through second elasticity stay cord pulling elasticity doctor-bar this moment, make elasticity doctor-bar to scraping the offset plate and incline, the tip of elasticity doctor-bar can contact with scraping the offset plate this moment, scrape the offset plate, will scrape remaining dyestuff composition on the offset plate and wipe the part, further reduce the residual amount of dyestuff composition on scraping the offset plate, further reduce when opening and shutting sealed lid many times, there is the dyestuff composition quantity of remaining on scraping the offset plate, reduce the waste of dyestuff composition.
Furthermore, a sub-magic tape is fixedly connected to the side wall of the second elastic pull rope, which is close to the elastic arc-shaped cleaning plate; a plurality of groups of female magic tapes are fixedly connected to one side of the elastic arc-shaped sweeping plate close to the male magic tapes; by arranging the sub magic tape between the second elastic pull rope and the elastic arc-shaped cleaning plate, when the elastic arc-shaped cleaning plate is attached to the rubber scraping plate, the sub magic tape can be contacted with the female magic tape, then under the continuous pulling of the friction ball, when the pulling force of the friction ball is greater than the bonding force of the female magic tape and the sub magic tape, the sub magic tape and the female magic tape can slide, at the moment, the second elastic pull rope can be contacted with the rubber scraping plate to erase part of the dye composition on the rubber scraping plate, then when the elastic arc-shaped cleaning plate leaves the rubber scraping plate, the elastic scraping blade can be elastically reset by itself, then the sub magic tape can be separated from the female magic tape under the support of the elastic scraping blade and the friction ball, when the sub magic tape is separated from the female magic tape, a plurality of small-amplitude vibrations can be generated, at the moment, part of the dye composition adhered on the second elastic pull rope can be shaken off by the vibrations, the residual quantity of the dye composition on the second elastic pull rope is reduced, the waste of the dye composition is further reduced, and the surface neatness degree of the second elastic pull rope after repeated use is kept.
Further, a first magnet is fixedly connected to the end part of the elastic arc-shaped sweeping plate; a hollow flexible cylindrical vibrating rod is fixedly connected to the side wall of the glue scraping plate; a magnetic ball is arranged inside the hollow flexible cylindrical vibrating rod; a third elastic pull rope is arranged between the magnetic ball and the inner side wall of the hollow flexible cylindrical vibrating rod; one end of the third elastic pull rope is connected with the magnetic ball, and the other end of the third elastic pull rope is connected with the inner side wall, close to the glue scraping plate, of the hollow flexible cylindrical vibrating bar; a plurality of groups of rubber strips are fixedly connected to the inner side wall of the hollow flexible cylindrical vibrating rod; through be equipped with first magnet and the inside magnetic ball mutual exclusion of hollow flexible cylindricality vibrating spear at elasticity arc cleaning plate tip, can be when sealed lid is on the jar body, first magnet can be close to the magnetic ball, this moment because of the mutual exclusion of first magnet and magnetic ball, can promote the magnetic ball to the bottom of hollow flexible cylindricality vibrating spear, at the in-process that the magnetic ball removed in hollow flexible cylindricality vibrating spear is inside, can collide with a plurality of rubber strips, contact, will produce slight vibration this moment, this vibrations can be conducted to scraping on the offset plate, make and scrape remaining dyestuff composition on the offset plate and be fallen, further reduce the amount of remaining of scraping dyestuff composition on the offset plate, keep scraping the clean degree of offset plate, and reduce the extravagant problem of dyestuff composition.
Further, a second magnet is fixedly connected inside the hollow flexible cylindrical vibrating rod; the second magnet is arranged on one side, far away from the glue scraping plate, of the interior of the hollow flexible cylindrical vibrating spear; through being equipped with the second magnet inside the hollow flexible cylindricality vibrating spear and can adsorb with the magnetic ball, can be when the magnetic ball is promoted by the repulsion of first magnet, the magnetic ball after having accomplished a plurality of rubber strips, adsorb with the second magnet at last, can produce stronger impact slightly this moment, just this moment can produce great shake with hollow flexible cylindricality vibrating spear, will scrape the dyestuff composition shake that is collected by above-mentioned rubber strip on the offset plate and shake and fall, further reduce the dyestuff composition residue on the offset plate, reduce extravagantly.
Further, an iron block is fixedly connected inside the rubber strip; an elastic stabilizer bar is fixedly connected inside the rubber strip; the elastic stabilizer bar is connected between the iron block and the inner side wall of the hollow flexible cylindrical vibrating rod; through being equipped with the stabilizer bar in rubber strip inside, multiplicable rubber strip is when being strikeed by the magnetic ball, the dynamics of rocking that self produced, make the range increase of hollow flexible cylindricality vibrating spear vibration, the inside iron plate that is equipped with of rubber strip simultaneously, can make the rubber strip by the magnetic ball striking back, self also can produce slight rocking, and then increase the frequency of rocking of hollow flexible cylindricality vibrating spear, can make more dyestuff compositions on the frictioning board shaken off this moment, reduce the residue of dyestuff composition on the frictioning board.
Further, the bottom end of the rubber scraping plate is fixedly connected with an arc-shaped elastic sheet; a plurality of groups of charging chutes are formed in the arc-shaped elastic sheet; the end part of the arc-shaped elastic piece is arranged towards the inner side wall of the tank body; through being equipped with the arc flexure strip at the frictioning board tip, can be when collection system scrapes the frictioning board tip, collection system and the area of contact of frictioning board and arc flexure strip are bigger for the dyestuff composition on the collection system is scraped more, reduces collection system and when lifting up from jar internal portion, the dyestuff composition volume that can drip, further reduces the waste of dyestuff composition and to the pollution of jar body port.
The invention has the following beneficial effects:
1. the high-fastness black disperse dye composition has the advantages of good deep dyeing property, easiness in washing of loose color, excellent organic solvent fastness, sublimation fastness and washing fastness, and is particularly suitable for dyeing and printing of fabrics with dry cleaning and gluing and fitting requirements, such as shoe materials, suit coats and the like.
2. According to the high-fastness black disperse dye composition, the glue scraping plate is arranged in the tank body, so that part of the dye composition can drip off when the collecting device is lifted from the tank body, at the moment, the side wall of the collecting device can be scraped at the bottom of the glue scraping plate for multiple times when the collecting device is lifted, the dye composition on the surface of the collecting device is scraped for a part, a large amount of dye composition cannot drip on the port of the tank body when the collecting device is taken out of the tank body, and the waste problem of the collecting device in collecting the dye composition is reduced.
Drawings
The invention will be further explained with reference to the drawings.
FIG. 1 is a perspective view of the present invention;
FIG. 2 is a cross-sectional view of the present invention;
FIG. 3 is a cross-sectional view of a doctor blade;
FIG. 4 is a cross-sectional view of the resilient arcuate sweeping shoe;
FIG. 5 is an enlarged view of a portion of FIG. 4 at A;
FIG. 6 is a schematic cross-sectional view of a rubber strip;
FIG. 7 is a schematic structural diagram of a second embodiment of the present invention;
in the figure: 1. a tank body; 11. a sealing cover; 12. scraping a rubber plate; 2. an elastic arc-shaped cleaning plate; 21. an elastic wiper blade; 3. an elastic bag; 31. a friction ball; 32. a first elastic pull rope; 33. a second elastic pull rope; 4. a sub-magic tape; 41. female magic tape; 5. a first magnet; 51. a hollow flexible cylindrical vibrating rod; 52. a magnetic ball; 53. a third elastic pull rope; 54. a rubber strip; 6. a second magnet; 7. an iron block; 71. an elastic stabilizer bar; 8. an arc-shaped elastic sheet; 81. and a feeding chute.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
The invention relates to a high-fastness black disperse dye composition which comprises a component A, a component B, a component C and a component D; wherein
The structural formula of the component A is as follows:
in the formula R1：-CH3，-C2H5，-C4H7；
The structural formula of the component B is as follows:
in the formula R2：-NHCOCH3，
R3、R4：-CH2COOCH3，-C2H4COOCH3，-C2H4CN；
The structural formula of the component C is as follows:
in the formula R5：-BR，-CN，-NO2；
R6：-H，-COH3，-OCH2OH3；
R7、R8：-CH2COOCH3，-CH2CH2COOCH3，-C2H4CN，
The structural formula of the component D is as follows:
in the formula R9：-H，-CH3；
R10、R11：-C2H5，-C2H4OH，C2H4OCOCH3。
The high-fastness black disperse dye composition is added with a filling aid E; the filling aid E comprises the following components: naphthalene sulfonic acid formaldehyde condensates (e.g., dispersant NNO), alkyl naphthalene sulfonic acid formaldehyde condensates (e.g., dispersant MF), benzyl naphthalene sulfonic acid formaldehyde condensates (e.g., dispersant CNF), lignosulfonates (e.g., the commercially available dispersant Reax 83A, Reax 85A, Reax 89L, etc.).
Example one
As shown in fig. 1 to 2, the high-fastness black disperse dye composition is filled in a storage device for storage; the storage device comprises a tank body 1; the top of the tank body 1 is provided with a sealing cover 11; a glue scraping plate 12 is fixedly connected to the opening part of the inner side wall of the tank body 1, which is close to the opening part; the scraping plate 12 is arranged annularly; the scraping plate 12 is made of rubber; the diameter of the top opening of the rubber scraping plate 12 is larger than that of the bottom opening; when the dye composition collecting device is used, when an operator needs to use the dye composition in the tank body 1, the collecting device extends into the tank body 1, then the collecting device is lifted, so that the dye composition in the tank body 1 can be taken out by the operator, the dye composition is brushed or dripped at a position where the dye composition needs to be used, a part of the dye composition can be dripped in the process that the collecting device is lifted from the tank body 1 by arranging the glue scraping plate 12 in the tank body 1, at the moment, the side wall of the collecting device can be scraped at the bottom of the glue scraping plate 12 for multiple times when the collecting device is lifted, so that the part of the dye composition on the surface of the collecting device is scraped, a large amount of the dye composition cannot drip at the port of the tank body 1 when the collecting device is taken out of the tank body 1, the waste problem of the collecting device in collecting the dye composition is reduced, and the dripping of the dye composition at the port of the tank body 1 is reduced, the problem that the dye composition causes pollution to the port of the can body 1 can be reduced.
An elastic arc-shaped sweeping plate 2 is fixedly connected to the inner side wall of the top of the sealing cover 11; the elastic arc-shaped sweeping plate 2 is arranged annularly; the elastic arc-shaped sweeping plate 2 is made of rubber; the diameter of the middle part of the elastic arc-shaped sweeping plate 2 is larger than that of the middle part of the rubber scraping plate 12; the diameter of the top of the rubber scraping plate 12 is larger than that of the bottom; an elastic scraping blade 21 is fixedly connected to the end part of the elastic arc-shaped cleaning plate 2; by arranging the elastic arc-shaped cleaning plate 2 at the bottom of the sealing cover 11, the dye composition on the rubber scraping plate 12 can be pushed downwards by the elastic arc-shaped cleaning plate 2 in the process that the sealing cover 11 is covered on the tank body 1, when the dye composition on the side wall of the rubber scraping plate 12 is pushed together, the dye composition is gathered into a drop shape and then drops into the tank body 1 under the self gravity, so that the dye composition remained on the rubber scraping plate 12 drops into the tank body 1, the waste caused by the residue of the dye composition on the rubber scraping plate 12 is reduced, moreover, the sealing performance of the sealing cover 11 to the tank body 1 can be increased by the extrusion of the elastic arc-shaped cleaning plate 2 and the glue scraping plate 12, so that when the sealing cover 11 is covered on the tank body 1, the gas circulation inside and outside the tank body 1 is reduced, so that the dye composition can be stored in the tank body 1 for a longer time, while reducing the problem of contamination of the surface of the doctor blade 12 due to extensive drying of the dye composition on the doctor blade 12.
As shown in fig. 4, the inner side wall of the elastic arc-shaped sweeping plate 2 is fixedly connected with an elastic bag 3; the outer side of the elastic arc-shaped cleaning plate 2 is provided with a friction ball 31; a first elastic pull rope 32 is connected between the friction ball 31 and the elastic bag 3; the first elastic pull rope 32 penetrates through the elastic arc-shaped cleaning plate 2; a second elastic pull rope 33 is connected between the friction ball 31 and the side wall of the elastic wiper 21; through being equipped with friction ball 31 on elasticity arc cleans board 2, can clean board 2 and scrape the offset plate 12 contact in elasticity arc, upwards promote friction ball 31, friction ball 31 will pass through second elasticity stay cord 33 pulling elasticity doctor-bar 21 this moment, make elasticity doctor-bar 21 to scraping offset plate 12 and incline, the tip of elasticity doctor-bar 21 can contact with scraping offset plate 12 this moment, scrape offset plate 12, will scrape the part of wiping remaining dyestuff composition on offset plate 12, further reduce the amount of residue of dyestuff composition on scraping offset plate 12, further reduce when the sealed lid 11 that opens and shuts many times, there is the amount of dyestuff composition remaining on scraping offset plate 12, reduce dyestuff composition's waste.
A sub magic tape 4 is fixedly connected to the side wall of the second elastic pull rope 33 close to the elastic arc-shaped sweeping plate 2; a plurality of groups of female magic tapes 41 are fixedly connected to one side of the elastic arc-shaped sweeping plate 2 close to the female magic tapes 4; by arranging the sub magic tape 4 between the second elastic pulling rope 33 and the elastic arc-shaped cleaning plate 2, when the elastic arc-shaped cleaning plate 2 is adhered to the rubber scraping plate 12, the sub magic tape 4 can be contacted with the female magic tape 41, then under the continuous pulling of the friction ball 31, when the pulling force of the friction ball 31 is greater than the adhering force of the female magic tape 41 and the sub magic tape 4, the sub magic tape 4 and the female magic tape 41 can slide, at the moment, the second elastic pulling rope 33 can be contacted with the rubber scraping plate 12, part of the dye composition on the rubber scraping plate 12 can be erased, then when the elastic arc-shaped cleaning plate 2 is separated from the rubber scraping plate 12, the elastic scraping blade 21 can be reset due to the self elasticity, then the sub magic tape 4 can be separated from the female magic tape 41 under the support of the elastic scraping blade 21 and the friction ball 31, when the sub magic tape 4 is separated from the female magic tape 41, a plurality of small vibrations can be generated, at the moment, part of the dye composition adhered to the second elastic pulling rope 33 can be shaken off by the vibrations, the residual amount of the dye composition on the second elastic cord 33 is reduced, the waste of the dye composition is further reduced, and the surface cleanliness of the second elastic cord 33 after repeated use is maintained.
As shown in fig. 3 and 4, a first magnet 5 is fixedly connected to an end of the elastic arc-shaped sweeping board 2; a hollow flexible cylindrical vibrating rod 51 is fixedly connected to the side wall of the glue scraping plate 12; a magnetic ball 52 is arranged inside the hollow flexible cylindrical vibrating rod 51; a third elastic pull rope 53 is arranged between the magnetic ball 52 and the inner side wall of the hollow flexible cylindrical vibrating rod 51; one end of the third elastic pull rope 53 is connected with the magnetic ball 52, and the other end is connected with the inner side wall of the hollow flexible cylindrical vibrating bar 51 close to the rubber scraping plate 12; a plurality of groups of rubber strips 54 are fixedly connected to the inner side wall of the hollow flexible cylindrical vibrating rod 51; through being equipped with first magnet 5 and the inside magnetic ball 52 mutual exclusion of hollow flexible cylindricality vibrating spear 51 at elasticity arc cleaning plate 2 tip, can be when sealed lid 11 is covered on jar body 1, first magnet 5 can be close to magnetic ball 52, at this moment because of the mutual exclusion of first magnet 5 and magnetic ball 52, can push magnetic ball 52 to the bottom of hollow flexible cylindricality vibrating spear 51, in the process that magnetic ball 52 moves in hollow flexible cylindricality vibrating spear 51, can collide with a plurality of rubber strips 54, contact, will produce slight vibration this moment, this vibrations can be conducted to scraping offset 12, make the remaining dyestuff composition on scraping offset 12 shaken off, further reduce the remaining amount of dyestuff composition on scraping offset 12, keep scraping offset 12's clean degree, and reduce the extravagant problem of dyestuff composition.
A second magnet 6 is fixedly connected inside the hollow flexible cylindrical vibrating rod 51; the second magnet 6 is arranged on one side, far away from the rubber scraping plate 12, of the interior of the hollow flexible cylindrical vibrating rod 51; through being equipped with second magnet 6 inside hollow flexible cylindricality vibrating spear 51 and can adsorbing with magnetic ball 52, can be when magnetic ball 52 is promoted by the repulsion of first magnet 5, magnetic ball 52 is through a plurality of rubber strips 54 back, finally adsorbs with second magnet 6, can produce stronger impact this moment, just this moment hollow flexible cylindricality vibrating spear 51 can produce great shake, the dye composition who is shaken the collection by above-mentioned rubber strip 54 on scraping offset plate 12 shakes and falls, further reduce the dye composition residue on scraping offset plate 12, reduce extravagantly.
As shown in fig. 6, an iron block 7 is fixedly connected inside the rubber strip 54; an elastic stabilizer bar 71 is fixedly connected inside the rubber strip 54; the elastic stabilizer bar 71 is connected between the iron block 7 and the inner side wall of the hollow flexible cylindrical vibrating rod 51; through being equipped with the elastic stabilization pole 71 in rubber strip 54 is inside, multiplicable rubber strip 54 is by the striking of magnetic ball 52, the dynamics of rocking that self produced for the range increase of hollow flexible cylindricality vibrating spear 51 vibration, rubber strip 54 is inside to be equipped with iron plate 7 simultaneously, can make rubber strip 54 after by the striking of magnetic ball 52, self also can produce slight rocking, and then increase hollow flexible cylindricality vibrating spear 51's frequency of rocking, can make more dyestuff compositions on the frictioning board 12 shaken off this moment, reduce the residue of dyestuff composition on the frictioning board 12.
Example two
As shown in fig. 7, a first comparative example, in which another embodiment of the present invention is: the bottom end of the rubber scraping plate 12 is fixedly connected with an arc-shaped elastic sheet 8; a plurality of groups of charging chutes 81 are formed in the arc-shaped elastic sheet 8; the end part of the arc-shaped elastic piece 8 is arranged towards the inner side wall of the tank body 1; through being equipped with arc elastic strip 8 at the 12 tip of frictioning board, can be when collection system scrapes at the 12 tip of frictioning board, collection system and the contact area of frictioning board 12 and arc elastic strip 8 are bigger for the dyestuff composition on the collection system is more scraped, reduces collection system when lifting up from jar body 1 inside, and the dyestuff composition volume that can drip further reduces the waste of dyestuff composition and the pollution to jar body 1 port.
When the dye composition collecting device is used, when an operator needs to use the dye composition in the tank body 1, the collecting device extends into the tank body 1, then the collecting device is lifted, so that the dye composition in the tank body 1 can be taken out by the operator, the dye composition is brushed or dripped at a position where the dye composition needs to be used, a part of the dye composition can be dripped in the process that the collecting device is lifted from the tank body 1 by arranging the glue scraping plate 12 in the tank body 1, at the moment, the side wall of the collecting device can be scraped at the bottom of the glue scraping plate 12 for multiple times when the collecting device is lifted, so that the part of the dye composition on the surface of the collecting device is scraped, a large amount of the dye composition cannot drip at the port of the tank body 1 when the collecting device is taken out of the tank body 1, the waste problem of the collecting device in collecting the dye composition is reduced, and the dripping of the dye composition at the port of the tank body 1 is reduced, the problem that the dye composition causes pollution to the port of the can body 1 can be reduced.
By arranging the elastic arc-shaped cleaning plate 2 at the bottom of the sealing cover 11, the dye composition on the rubber scraping plate 12 can be pushed downwards by the elastic arc-shaped cleaning plate 2 in the process that the sealing cover 11 is covered on the tank body 1, when the dye composition on the side wall of the rubber scraping plate 12 is pushed together, the dye composition is gathered into a drop shape and then drops into the tank body 1 under the self gravity, so that the dye composition remained on the rubber scraping plate 12 drops into the tank body 1, the waste caused by the residue of the dye composition on the rubber scraping plate 12 is reduced, moreover, the sealing performance of the sealing cover 11 to the tank body 1 can be increased by the extrusion of the elastic arc-shaped cleaning plate 2 and the glue scraping plate 12, so that when the sealing cover 11 is covered on the tank body 1, the gas circulation inside and outside the tank body 1 is reduced, so that the dye composition can be stored in the tank body 1 for a longer time, while reducing the problem of contamination of the surface of the doctor blade 12 due to extensive drying of the dye composition on the doctor blade 12.
Through being equipped with friction ball 31 on elasticity arc cleans board 2, can clean board 2 and scrape the offset plate 12 contact in elasticity arc, upwards promote friction ball 31, friction ball 31 will pass through second elasticity stay cord 33 pulling elasticity doctor-bar 21 this moment, make elasticity doctor-bar 21 to scraping offset plate 12 and incline, the tip of elasticity doctor-bar 21 can contact with scraping offset plate 12 this moment, scrape offset plate 12, will scrape the part of wiping remaining dyestuff composition on offset plate 12, further reduce the amount of residue of dyestuff composition on scraping offset plate 12, further reduce when the sealed lid 11 that opens and shuts many times, there is the amount of dyestuff composition remaining on scraping offset plate 12, reduce dyestuff composition's waste.
By arranging the sub magic tape 4 between the second elastic pulling rope 33 and the elastic arc-shaped cleaning plate 2, when the elastic arc-shaped cleaning plate 2 is adhered to the rubber scraping plate 12, the sub magic tape 4 can be contacted with the female magic tape 41, then under the continuous pulling of the friction ball 31, when the pulling force of the friction ball 31 is greater than the adhering force of the female magic tape 41 and the sub magic tape 4, the sub magic tape 4 and the female magic tape 41 can slide, at the moment, the second elastic pulling rope 33 can be contacted with the rubber scraping plate 12, part of the dye composition on the rubber scraping plate 12 can be erased, then when the elastic arc-shaped cleaning plate 2 is separated from the rubber scraping plate 12, the elastic scraping blade 21 can be reset due to the self elasticity, then the sub magic tape 4 can be separated from the female magic tape 41 under the support of the elastic scraping blade 21 and the friction ball 31, when the sub magic tape 4 is separated from the female magic tape 41, a plurality of small vibrations can be generated, at the moment, part of the dye composition adhered to the second elastic pulling rope 33 can be shaken off by the vibrations, the residual amount of the dye composition on the second elastic cord 33 is reduced, the waste of the dye composition is further reduced, and the surface cleanliness of the second elastic cord 33 after repeated use is maintained.
The end part of the elastic arc-shaped cleaning plate 2 is provided with the first magnet 5 which is mutually exclusive with the magnetic ball 52 inside the hollow flexible cylindrical vibrating rod 51, when the sealing cover 11 is covered on the tank body 1, the first magnet 5 can approach the magnetic ball 52, at the moment, the magnetic ball 52 can be pushed to the bottom of the hollow flexible cylindrical vibrating rod 51 due to the mutual exclusion of the first magnet 5 and the magnetic ball 52, and the magnetic ball 52 can collide and contact with a plurality of rubber strips 54 in the moving process of the magnetic ball 52 inside the hollow flexible cylindrical vibrating rod 51, so that slight vibration can be generated at the moment, the vibration can be transmitted to the rubber scraping plate 12, so that the residual dye composition on the rubber scraping plate 12 can be shaken off, the residual amount of the dye composition on the rubber scraping plate 12 can be further reduced, the cleanness degree of the rubber scraping plate 12 can be maintained, and the waste problem of the dye composition can be reduced; through being equipped with second magnet 6 inside hollow flexible cylindricality vibrating spear 51 and can adsorbing with magnetic ball 52, can be when magnetic ball 52 is promoted by the repulsion of first magnet 5, magnetic ball 52 is through a plurality of rubber strips 54 back, finally adsorbs with second magnet 6, can produce stronger impact this moment, just this moment hollow flexible cylindricality vibrating spear 51 can produce great shake, the dye composition who is shaken the collection by above-mentioned rubber strip 54 on scraping offset plate 12 shakes and falls, further reduce the dye composition residue on scraping offset plate 12, reduce extravagantly. Through being equipped with the elastic stabilization pole 71 in rubber strip 54 is inside, multiplicable rubber strip 54 is by the striking of magnetic ball 52, the dynamics of rocking that self produced for the range increase of hollow flexible cylindricality vibrating spear 51 vibration, rubber strip 54 is inside to be equipped with iron plate 7 simultaneously, can make rubber strip 54 after by the striking of magnetic ball 52, self also can produce slight rocking, and then increase hollow flexible cylindricality vibrating spear 51's frequency of rocking, can make more dyestuff compositions on the frictioning board 12 shaken off this moment, reduce the residue of dyestuff composition on the frictioning board 12.
Through being equipped with arc elastic strip 8 at the 12 tip of frictioning board, can be when collection system scrapes at the 12 tip of frictioning board, collection system and the contact area of frictioning board 12 and arc elastic strip 8 are bigger for the dyestuff composition on the collection system is more scraped, reduces collection system when lifting up from jar body 1 inside, and the dyestuff composition volume that can drip further reduces the waste of dyestuff composition and the pollution to jar body 1 port.
The front, the back, the left, the right, the upper and the lower are all based on figure 1 in the attached drawings of the specification, according to the standard of the observation angle of a person, the side of the device facing an observer is defined as the front, the left side of the observer is defined as the left, and the like.
In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", etc., indicate orientations or positional relationships based on those shown in the drawings, and are used merely for convenience in describing the present invention and for simplifying the description, but do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the scope of the present invention.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. A high-fastness black disperse dye composition is characterized in that: comprises a component A, a component B, a component C and a component D; wherein
The structural formula of the component A is as follows:
in the formula R1：-CH3，-C2H5，-C4H7；
The structural formula of the component B is as follows:
in the formula R2：-NHCOCH3，
R3、R4：-CH2COOCH3，-C2H4COOCH3，-C2H4CN；
The structural formula of the component C is as follows:
in the formula R5：-BR，-CN，-NO2；
R6：-H，-COH3，-OCH2OH3；
R7、R8：-CH2COOCH3，-CH2CH2COOCH3，-C2H4CN，
The structural formula of the component D is as follows:
in the formula R9：-H，-CH3；
R10、R11：-C2H5，-C2H4OH，C2H4OCOCH3。
2. The high fastness black disperse dye composition according to claim 1, wherein: the high-fastness black disperse dye composition is added with a filling aid E; the filling aid E comprises the following components: naphthalene sulfonic acid formaldehyde condensate, alkyl naphthalene sulfonic acid formaldehyde condensate, and benzyl naphthalene sulfonic acid formaldehyde condensate lignosulfonate.
3. The high fastness black disperse dye composition according to claim 2, wherein: the high-fastness black disperse dye composition is filled in a storage device for storage; the storage device comprises a tank (1); a sealing cover (11) is arranged at the top of the tank body (1); a glue scraping plate (12) is fixedly connected to the opening part of the inner side wall of the tank body (1) close to the port; the glue scraping plate (12) is arranged annularly; the scraping plate (12) is made of rubber; the diameter of the top opening of the glue scraping plate (12) is larger than that of the bottom opening.
4. The high fastness black disperse dye composition according to claim 3, wherein: an elastic arc-shaped cleaning plate (2) is fixedly connected to the inner side wall of the top of the sealing cover (11); the elastic arc-shaped sweeping plate (2) is arranged annularly; the elastic arc-shaped sweeping plate (2) is made of rubber; the diameter of the middle part of the elastic arc-shaped sweeping plate (2) is larger than that of the middle part of the rubber scraping plate (12); the diameter of the top of the rubber scraping plate (12) is larger than that of the bottom; the end part of the elastic arc-shaped cleaning plate (2) is fixedly connected with an elastic scraping blade (21).
5. The high fastness black disperse dye composition according to claim 4, wherein: the inner side wall of the elastic arc-shaped cleaning plate (2) is fixedly connected with an elastic bag (3); a friction ball (31) is arranged on the outer side of the elastic arc-shaped cleaning plate (2); a first elastic pull rope (32) is connected between the friction ball (31) and the elastic bag (3); the first elastic pull rope (32) penetrates through the elastic arc-shaped cleaning plate (2); and a second elastic pull rope (33) is connected between the friction ball (31) and the side wall of the elastic wiper blade (21).
6. The high fastness black disperse dye composition according to claim 5, wherein: a sub-magic tape (4) is fixedly connected to the side wall of the second elastic pull rope (33) close to the elastic arc-shaped cleaning plate (2); one side of the elastic arc-shaped cleaning plate (2) close to the sub magic tape (4) is fixedly connected with a plurality of groups of female magic tapes (41).
7. The high fastness black disperse dye composition according to claim 4, wherein: a first magnet (5) is fixedly connected to the end part of the elastic arc-shaped cleaning plate (2); a hollow flexible cylindrical vibrating rod (51) is fixedly connected to the side wall of the glue scraping plate (12); a magnetic ball (52) is arranged inside the hollow flexible cylindrical vibrating rod (51); a third elastic pull rope (53) is arranged between the magnetic ball (52) and the inner side wall of the hollow flexible cylindrical vibrating rod (51); one end of the third elastic pull rope (53) is connected with the magnetic ball (52), and the other end of the third elastic pull rope is connected with the inner side wall, close to the glue scraping plate (12), of the hollow flexible cylindrical vibrating bar (51); the inner side wall of the hollow flexible cylindrical vibrating rod (51) is fixedly connected with a plurality of groups of rubber strips (54).
8. The high fastness black disperse dye composition according to claim 7, wherein: a second magnet (6) is fixedly connected inside the hollow flexible cylindrical vibrating rod (51); the second magnet (6) is arranged on one side, far away from the rubber scraping plate (12), of the interior of the hollow flexible cylindrical vibrating rod (51).
9. The high fastness black disperse dye composition according to claim 8, wherein: an iron block (7) is fixedly connected inside the rubber strip (54); an elastic stabilizer bar (71) is fixedly connected inside the rubber strip (54); the elastic stabilizer bar (71) is connected between the iron block (7) and the inner side wall of the hollow flexible cylindrical vibrating rod (51).
10. The high fastness black disperse dye composition according to claim 3, wherein: the bottom end of the rubber scraping plate (12) is fixedly connected with an arc-shaped elastic sheet (8); a plurality of groups of charging chutes (81) are formed in the arc-shaped elastic sheet (8); the end part of the arc-shaped elastic piece (8) is arranged towards the inner side wall of the tank body (1).
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| US20110247150A1 (en) * | 2007-08-09 | 2011-10-13 | Dystar Colours Deutschlands Gmbh | Disperse dyes, their preparation and use |
| CN104087019A (en) * | 2013-12-25 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Navy blue or black disperse dye composition |
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| CN105131649A (en) * | 2015-07-27 | 2015-12-09 | 杭州吉华江东化工有限公司 | Composite disperse black-blue dye with high washing fastness |
| CN105176140A (en) * | 2015-08-15 | 2015-12-23 | 上海贝通色彩科技有限公司 | Alkaline discharge printing disperse dye, preparation method and applications |
| CN206201246U (en) * | 2016-08-31 | 2017-05-31 | 太仓市鸿运包装材料有限公司 | A kind of glue making machine Frictioning device |
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- 2021-10-09 CN CN202111174345.5A patent/CN113801494A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110247150A1 (en) * | 2007-08-09 | 2011-10-13 | Dystar Colours Deutschlands Gmbh | Disperse dyes, their preparation and use |
| CN104087019A (en) * | 2013-12-25 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Navy blue or black disperse dye composition |
| CN204208469U (en) * | 2014-08-04 | 2015-03-18 | 张虞旭驹 | A kind of for the Frictioning device in digester |
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Application publication date: 20211217 |
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