CN113788617B - Super-wear-resistant high-permeability diamond microcrystalline glaze and production process thereof - Google Patents
Super-wear-resistant high-permeability diamond microcrystalline glaze and production process thereof Download PDFInfo
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- CN113788617B CN113788617B CN202111132015.XA CN202111132015A CN113788617B CN 113788617 B CN113788617 B CN 113788617B CN 202111132015 A CN202111132015 A CN 202111132015A CN 113788617 B CN113788617 B CN 113788617B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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Abstract
The embodiment of the invention discloses an ultra-wear-resistant high-permeability diamond microcrystalline glaze and a production process thereof, belongs to an upgraded glaze material, and can simultaneously solve the problems of non-wear-resistant and non-transparent glaze surface of a full-polished glaze. The production process comprises the following steps: (1) Taking 7000 parts by weight of microcrystalline glaze, 8-15 parts by weight of methyl methacrylate, 25-30 parts by weight of sodium tripolyphosphate, 3-5 parts by weight of ammonium chloride and 4 parts by weight of preservative, crushing and homogenizing; adding 2500-3000 parts by weight of water, and ball-milling for 10 hours until: the water content of glaze material is 36-37%, the fineness of glaze material is less than or equal to 0.3%, the flow rate of glaze slurry is 55-70m/s, and the specific gravity of glaze slurry is 1.83-1.88g/cm 3 (ii) a (3) And sieving the diamond microcrystalline glaze with a 300-mesh sieve, and removing impurities to obtain the diamond microcrystalline glaze.
Description
Technical Field
The invention relates to the field of ceramic tile glaze, in particular to super-wear-resistant high-permeability diamond microcrystalline glaze and a production process thereof.
Background
The full-glazed ceramic tile is polished after glazing on the surface of a traditional polished tile, and compared with the polished tile, the full-glazed ceramic tile is richer in color and luster.
However, the conventional full-polishing glaze has two problems, namely, the glaze is not wear-resistant, scratches are easy to appear on the glaze surface after long-term use, and the aesthetic effect and the practicability are greatly reduced; secondly, the transparency and the color development are insufficient, so that the hierarchical details and the texture patterns of the product cannot be presented perfectly.
The prior art solves the problem of abrasion resistance, but the transparency and color development of the glazed surface of the ceramic tile have to be sacrificed; if the transparency and color development are to be maintained at a high level, only the abrasion resistance and the workability are lowered.
Therefore, solving the problems of abrasion resistance and transparency of the glaze is one of the problems that the skilled person needs to solve.
Disclosure of Invention
The embodiment of the invention provides an ultra-wear-resistant high-permeability diamond microcrystalline glaze and a production process thereof, belongs to an upgraded glaze material, and can simultaneously solve the problems of non-wear-resistant and non-transparent glaze surface of a full-polishing glaze.
In order to solve the problems, the formula of the super-wear-resistant high-permeability diamond microcrystalline glaze provided by the invention comprises, by weight, 7000 parts of microcrystalline glaze, 8-15 parts of methyl methacrylate, 25-30 parts of sodium tripolyphosphate, 3-5 parts of ammonium chloride, 4 parts of a preservative and 2500-3000 parts of water.
Preferably, the microcrystalline glaze comprises the following components in parts by weight: 50-55 parts of modified frit, 8-10 parts of strontium carbonate, 8-10 parts of kaolin, 8-10 parts of white corundum, 15-20 parts of feldspar and 2-8 parts of zinc oxide.
Preferably, the modified frit comprises the following components in parts by weight: 45-50 parts of silicon dioxide, 15-20 parts of aluminum oxide, 10-15 parts of calcium oxide, 3-5 parts of magnesium oxide, 0.1-0.5 part of potassium oxide, 5-5.5 parts of sodium oxide, 10-12 parts of barium oxide, 0.1-0.5 part of titanium dioxide and 0.1-0.5 part of iron dioxide.
Preferably, the modified frit comprises the following components in parts by weight: 49-50 parts of silicon dioxide, 19-20 parts of aluminum oxide, 10-11 parts of calcium oxide, 3-3.1 parts of magnesium oxide, 0.4-0.5 part of potassium oxide, 5.4 parts of sodium oxide, 10-11 parts of barium oxide, 0.25 part of titanium dioxide and 0.3-0.4 part of iron dioxide.
Preferably, the glaze material comprises the microcrystalline glaze material 7000, methyl methacrylate 8-10, sodium tripolyphosphate 25-28, ammonium chloride 3, preservative 4 and water 2700 in parts by weight.
The invention also provides a production process of the super-wear-resistant high-permeability diamond microcrystalline glaze, which comprises the following steps:
(1) Taking 7000 parts by weight of microcrystalline glaze, 8-15 parts by weight of methyl methacrylate, 25-30 parts by weight of sodium tripolyphosphate, 3-5 parts by weight of ammonium chloride and 4 parts by weight of preservative, crushing and homogenizing,
(2) Adding 2500-3000 parts by weight of water, and ball-milling for 10 hours until: the water content of glaze material is 36-37%, the fineness of glaze material is less than or equal to 0.3%, the flow rate of glaze slurry is 55-70m/s, and the specific gravity of glaze slurry is 1.83-1.88g/cm 3 ；
(3) And sieving the diamond microcrystalline glaze with a 300-mesh sieve, and removing impurities to obtain the diamond microcrystalline glaze.
Preferably, the microcrystalline glaze is prepared by the following steps:
taking 50-55 parts of modified frit, 8-10 parts of strontium carbonate, 8-10 parts of kaolin, 8-10 parts of white corundum, 15-20 parts of feldspar and 2-8 parts of zinc oxide, and carrying out ball milling for 40-60 minutes.
Preferably, the preparation method of the modified frit comprises the following steps:
taking 45-50 parts by weight of silicon dioxide, 15-20 parts by weight of aluminum oxide, 10-15 parts by weight of calcium oxide, 3-5 parts by weight of magnesium oxide, 0.1-0.2 part by weight of potassium oxide, 5-5.5 parts by weight of sodium oxide, 10-12 parts by weight of barium oxide, 0.1-0.5 part by weight of titanium dioxide and 0.1-0.5 part by weight of iron dioxide, grinding and sieving.
The invention further provides a glaze spraying process of the super-wear-resistant high-permeability diamond microcrystalline glaze, wherein the diamond microcrystalline glaze is sprayed on a green brick and sintered, and the glaze thickness of the glazed brick is 0.3-0.6mm.
According to the technical scheme, the implementation mode of the invention has the following advantages: the invention keeps the wear-resistant characteristic of the ceramic tile and also meets the requirements of the ceramic tile on transparency and bright color development and visual attractiveness.
The formula of the modified frit is matched with other raw materials of the microcrystalline glaze, and the size of ground slurry is controlled, so that the glaze is coated on a green brick, and the glaze permeates into tiny pores of the green brick in the firing process to form a structure capable of holding the green brick, and the modified frit has extremely high transparency and can greatly embody high-level color development under the condition of light irradiation.
Detailed Description
The embodiment of the invention provides an ultra-wear-resistant high-permeability diamond microcrystalline glaze and a production process thereof, belongs to an upgraded glaze material, and can simultaneously solve the problems of non-wear-resistant and non-transparent glaze surface of a full-polishing glaze.
The formula of the super-wear-resistant high-permeability diamond microcrystalline glaze comprises, by weight, 7000 parts of microcrystalline glaze, 8-15 parts of methyl methacrylate, 25-30 parts of sodium tripolyphosphate, 3-5 parts of ammonium chloride, 4 parts of a preservative and 2500-3000 parts of water.
Preferably, the microcrystalline glaze comprises the following components in parts by weight: 50-55 parts of modified frit, 8-10 parts of strontium carbonate, 8-10 parts of kaolin, 8-10 parts of white corundum, 15-20 parts of feldspar and 2-8 parts of zinc oxide.
Preferably, the modified frit comprises the following components in parts by weight: 45-50 parts of silicon dioxide, 15-20 parts of aluminum oxide, 10-15 parts of calcium oxide, 3-5 parts of magnesium oxide, 0.1-0.5 part of potassium oxide, 5-5.5 parts of sodium oxide, 10-12 parts of barium oxide, 0.1-0.5 part of titanium dioxide and 0.1-0.5 part of iron dioxide.
Preferably, the modified frit comprises the following components in parts by weight: 49-50 parts of silicon dioxide, 19-20 parts of aluminum oxide, 10-11 parts of calcium oxide, 3-3.1 parts of magnesium oxide, 0.4-0.5 part of potassium oxide, 5.4 parts of sodium oxide, 10-11 parts of barium oxide, 0.25 part of titanium dioxide and 0.3-0.4 part of iron dioxide.
Preferably, the microcrystalline glaze 7000, the methyl methacrylate 8-10, the sodium tripolyphosphate 25-28, the ammonium chloride 3, the preservative 4 and the water 2700 are included according to the parts by weight.
The invention also provides a production process of the super-wear-resistant high-permeability diamond microcrystalline glaze, which comprises the following steps:
(1) Taking 7000 parts by weight of microcrystalline glaze, 8-15 parts by weight of methyl methacrylate, 25-30 parts by weight of sodium tripolyphosphate, 3-5 parts by weight of ammonium chloride and 4 parts by weight of preservative, crushing and homogenizing,
(2) Adding 2500-3000 parts by weight of water, and ball-milling for 10 hours until: the water content of glaze material is 36-37%, the fineness of glaze material is less than or equal to 0.3%, the flow rate of glaze slurry is 55-70m/s, and the specific gravity of glaze slurry is 1.83-1.88g/cm 3 ；
(3) And sieving the diamond microcrystalline glaze with a 300-mesh sieve, and removing impurities to obtain the diamond microcrystalline glaze.
Preferably, the microcrystalline glaze is prepared by the following steps:
taking 50-55 parts of modified frit, 8-10 parts of strontium carbonate, 8-10 parts of kaolin, 8-10 parts of white corundum, 15-20 parts of feldspar and 2-8 parts of zinc oxide, and carrying out ball milling for 40-60 minutes.
Preferably, the preparation method of the modified frit comprises the following steps:
taking 45-50 parts by weight of silicon dioxide, 15-20 parts by weight of aluminum oxide, 10-15 parts by weight of calcium oxide, 3-5 parts by weight of magnesium oxide, 0.1-0.2 part by weight of potassium oxide, 5-5.5 parts by weight of sodium oxide, 10-12 parts by weight of barium oxide, 0.1-0.5 part by weight of titanium dioxide and 0.1-0.5 part by weight of iron dioxide, grinding and sieving.
The invention provides a glaze spraying process of an ultra-wear-resistant high-permeability diamond microcrystalline glaze, which comprises the steps of spraying the diamond microcrystalline glaze on a green brick, and sintering to obtain a glazed tile with the glaze thickness of 0.3-0.6mm.
The invention relates to an ultra-wear-resistant high-permeability diamond microcrystalline glaze, which belongs to an upgrading glaze in a full-polishing glaze process, and is characterized in that a modified frit is prepared by modifying the internal structure of the glaze.
DETAILED DESCRIPTION OF EMBODIMENT (S) OF INVENTION
A production process of super-wear-resistant high-permeability diamond microcrystalline glaze comprises the following steps:
(1) Taking 49-50 parts by weight of silicon dioxide, 19-20 parts by weight of aluminum oxide, 10-11 parts by weight of calcium oxide, 3-3.1 parts by weight of magnesium oxide, 0.4-0.5 part by weight of potassium oxide, 5.4 parts by weight of sodium oxide, 10-11 parts by weight of barium oxide, 0.25 part by weight of titanium dioxide and 0.3-0.4 part by weight of iron dioxide, grinding and sieving to obtain modified frit;
(2) Taking 50-55 parts by weight of modified frit, 8-10 parts by weight of strontium carbonate, 8-10 parts by weight of kaolin, 8-10 parts by weight of white corundum, 15-20 parts by weight of feldspar and 2-8 parts by weight of zinc oxide, and carrying out ball milling for 40-60 minutes to obtain a microcrystalline glaze;
(3) Taking 7000 parts by weight of microcrystalline glaze, 8-10 parts by weight of methyl methacrylate, 25-28 parts by weight of sodium tripolyphosphate, 3 parts by weight of ammonium chloride and 4 parts by weight of preservative, crushing and homogenizing;
(4) Adding 2700 parts of water by weight, and ball-milling for 10 hours until: the water content of glaze material is 36-37%, the fineness of glaze material is less than or equal to 0.3%, the flow rate of glaze slip is 55-70m/s, and the specific gravity of glaze slip is 1.83-1.88g/cm 3 ；
(5) And sieving the diamond microcrystalline glaze with a 300-mesh sieve, and removing impurities to obtain the diamond microcrystalline glaze.
(6) And spraying diamond microcrystalline glaze on the green brick according to a conventional glaze spraying mode, and firing according to production requirements to obtain a finished product brick glaze surface with the thickness of 0.3-0.6mm.
Example 1
A production process of super-wear-resistant high-permeability diamond microcrystalline glaze comprises the following steps:
(1) Taking 4.95kg of silicon dioxide, 1.95kg of aluminum oxide, 1kg of calcium oxide, 0.3kg of magnesium oxide, 0.045kg of potassium oxide, 0.54kg of sodium oxide, 0.15kg of barium oxide, 0.025kg of titanium dioxide and 0.035kg of iron dioxide, grinding and sieving to obtain modified clinker;
(2) Taking 5kg of modified frit, 1kg of strontium carbonate, 1kg of kaolin, 1kg of white corundum, 1.5kg of feldspar and 0.5kg of zinc oxide, and carrying out ball milling for 60 minutes to obtain a microcrystalline glaze material;
(3) Taking 700kg of microcrystalline glaze, 1kg of methyl methacrylate, 2.7kg of sodium tripolyphosphate, 0.3kg of ammonium chloride and 0.4kg of preservative, crushing and homogenizing;
(4) Adding 270kg of water, and ball-milling for 10 hours until: the water content of glaze material is 37%, the fineness of glaze material is less than or equal to 0.3%, the flow rate of glaze slip is 60-62m/s, and the specific gravity of glaze slip is 1.83-1.88g/cm 3 ；
(5) And sieving the diamond microcrystalline glaze with a 300-mesh sieve, and removing impurities to obtain the diamond microcrystalline glaze.
(6) And spraying diamond microcrystalline glaze on the green brick according to a conventional glaze spraying mode, and firing according to production requirements to obtain a finished product brick glaze surface with the thickness of 0.5mm.
Example 2
A production process of super-wear-resistant high-permeability diamond microcrystalline glaze comprises the following steps:
(1) Taking 4.9kg of silicon dioxide, 1.9kg of aluminum oxide, 1kg of calcium oxide, 0.3kg of magnesium oxide, 0.04kg of potassium oxide, 0.54kg of sodium oxide, 0.1kg of barium oxide, 0.025kg of titanium dioxide and 0.03kg of iron dioxide, grinding and sieving to obtain modified clinker;
(2) Taking 5kg of modified frit, 0.8kg of strontium carbonate, 0.8kg of kaolin, 0.8kg of white corundum, 1.5kg of feldspar and 0.2kg of zinc oxide, and carrying out ball milling for 60 minutes to obtain a microcrystalline glaze;
(3) Taking 700kg of microcrystalline glaze, 0.8kg of methyl methacrylate, 2.5kg of sodium tripolyphosphate, 0.3kg of ammonium chloride and 0.4kg of preservative, crushing and homogenizing;
(4) Adding 270kg of water, and ball-milling for 10 hours until: the glaze material has water content of 37%, glaze fineness not more than 0.3%, glaze slurry flow rate of 60-62m/s, and glaze slurry specific gravity of 1.83-1.88g/cm 3 ；
(5) And sieving the diamond microcrystalline glaze with a 300-mesh sieve, and removing impurities to obtain the diamond microcrystalline glaze.
(6) Spraying diamond microcrystalline glaze to the green brick according to a conventional glaze spraying mode, and firing according to production requirements to obtain a finished product brick with the glaze surface thickness of 0.5mm.
Example 3
A production process of super-wear-resistant high-permeability diamond microcrystalline glaze comprises the following steps:
(1) Taking 5kg of silicon dioxide, 2kg of aluminum oxide, 1.1kg of calcium oxide, 0.31kg of magnesium oxide, 0.05kg of potassium oxide, 0.54kg of sodium oxide, 0.11kg of barium oxide, 0.025kg of titanium dioxide and 0.04kg of iron dioxide, grinding and sieving to obtain modified frit;
(2) Taking 5.5kg of modified frit, 1kg of strontium carbonate, 1kg of kaolin, 1kg of white corundum, 2kg of feldspar and 0.8kg of zinc oxide, and carrying out ball milling for 60 minutes to obtain a microcrystalline glaze material;
(3) Taking 700kg of microcrystalline glaze, 1kg of methyl methacrylate, 2.8kg of sodium tripolyphosphate, 0.3kg of ammonium chloride and 0.4kg of preservative, crushing and homogenizing;
(4) Adding 270kg of water, and ball-milling for 10 hours until: the water content of glaze material is 37%, the fineness of glaze material is less than or equal to 0.3%, the flow rate of glaze slip is 60-62m/s, and the specific gravity of glaze slip is 1.83-1.88g/cm 3 ；
(5) And sieving the diamond microcrystalline glaze with a 300-mesh sieve, and removing impurities to obtain the diamond microcrystalline glaze.
(6) And spraying diamond microcrystalline glaze on the green brick according to a conventional glaze spraying mode, and firing according to production requirements to obtain a finished product of the ceramic tile glaze with the thickness of 0.5mm.
The ceramic tiles prepared in the embodiments 1 to 3 are detected, and based on the condition that the thicknesses of green bricks are the same, the hardness of the glaze reaches 6 grades, and the wear resistance of the ceramic tiles reaches 3900-4600 turns; the transparency is observed by naked eyes, the permeability is strong, and the light refractive index is good.
The super wear-resistant high-permeability diamond microcrystalline glaze and the production process thereof provided by the invention are described above, and the above embodiment and examples are only used for illustrating the technical scheme of the invention, but not for limiting the same; although the present invention has been described in detail with reference to the foregoing embodiments and examples, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments and examples of the present invention.
Claims (4)
1. The formula of the super-wear-resistant high-permeability diamond microcrystalline glaze is characterized by comprising, by weight, 7000 parts of microcrystalline glaze, 8-15 parts of methyl methacrylate, 25-30 parts of sodium tripolyphosphate, 3-5 parts of ammonium chloride, 4 parts of a preservative and 2500-3000 parts of water;
the microcrystalline glaze comprises the following components: 50-55 parts of modified frit, 8-10 parts of strontium carbonate, 8-10 parts of kaolin, 8-10 parts of white corundum, 15-20 parts of feldspar and 2-8 parts of zinc oxide;
the modified frit comprises the following components: 45-50 parts of silicon dioxide, 15-20 parts of aluminum oxide, 10-15 parts of calcium oxide, 3-5 parts of magnesium oxide, 0.1-0.5 part of potassium oxide, 5-5.5 parts of sodium oxide, 10-12 parts of barium oxide, 0.1-0.5 part of titanium dioxide and 0.1-0.5 part of ferric oxide.
2. The ultra-wear-resistant high-permeability diamond microcrystalline glaze formula according to claim 1, wherein the modified frit comprises the following components in parts by weight: 49-50 parts of silicon dioxide, 19-20 parts of aluminum oxide, 10-11 parts of calcium oxide, 3-3.1 parts of magnesium oxide, 0.4-0.5 part of potassium oxide, 5.4 parts of sodium oxide, 10-11 parts of barium oxide, 0.25 part of titanium dioxide and 0.3-0.4 part of ferric oxide.
3. The ultra-wear-resistant high-permeability diamond microcrystalline glaze formula according to claim 1, wherein the formula comprises, by weight, 7000 parts of microcrystalline glaze, 8-10 parts of methyl methacrylate, 25-28 parts of sodium tripolyphosphate, 3 parts of ammonium chloride, 4 parts of preservative and 2700 parts of water.
4. A production process of the super-wear-resistant high-permeability diamond microcrystalline glaze is characterized by comprising the following steps:
(1) Taking 7000 parts by weight of microcrystalline glaze, 8-15 parts by weight of methyl methacrylate, 25-30 parts by weight of sodium tripolyphosphate, 3-5 parts by weight of ammonium chloride and 4 parts by weight of preservative, crushing and homogenizing;
(2) Adding 2500-3000 parts by weight of water, and ball-milling for 10 hours until: the water content of glaze material is 36-37%, the fineness of glaze material is less than or equal to 0.3%, and the flow rate of glaze slipIs 55-70m/s, and the specific gravity of the glaze slip is 1.83-1.88g/cm 3 ；
(3) Sieving with a 300-mesh sieve, and removing impurities to obtain the diamond microcrystalline glaze;
the preparation method of the microcrystalline glaze material comprises the following steps:
taking 50-55 parts by weight of modified frit, 8-10 parts by weight of strontium carbonate, 8-10 parts by weight of kaolin, 8-10 parts by weight of white corundum, 15-20 parts by weight of feldspar and 2-8 parts by weight of zinc oxide, and carrying out ball milling for 40-60 minutes;
the preparation method of the modified frit comprises the following steps:
taking 45-50 parts by weight of silicon dioxide, 15-20 parts by weight of aluminum oxide, 10-15 parts by weight of calcium oxide, 3-5 parts by weight of magnesium oxide, 0.1-0.2 part by weight of potassium oxide, 5-5.5 parts by weight of sodium oxide, 10-12 parts by weight of barium oxide, 0.1-0.5 part by weight of titanium dioxide and 0.1-0.5 part by weight of ferric oxide, grinding and sieving.
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