CN113784837A - Composite panel, method for manufacturing the same and use of the same - Google Patents

Composite panel, method for manufacturing the same and use of the same Download PDF

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Publication number
CN113784837A
CN113784837A CN202180000957.4A CN202180000957A CN113784837A CN 113784837 A CN113784837 A CN 113784837A CN 202180000957 A CN202180000957 A CN 202180000957A CN 113784837 A CN113784837 A CN 113784837A
Authority
CN
China
Prior art keywords
layer
panel
polymer film
composite
intermediate layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202180000957.4A
Other languages
Chinese (zh)
Inventor
张慧星
S·舒尔泽
J·多罗萨里奥
F·贝尔特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Original Assignee
Saint Gobain Glass France SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS filed Critical Saint Gobain Glass France SAS
Publication of CN113784837A publication Critical patent/CN113784837A/en
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10082—Properties of the bulk of a glass sheet
    • B32B17/1011—Properties of the bulk of a glass sheet having predetermined tint or excitation purity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B32B17/10256—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
    • B32B17/10275—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on interlayer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B32B17/10256—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
    • B32B17/10284—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on intermediate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
    • B32B17/10348—Specific parts of the laminated safety glass or glazing being colored or tinted comprising an obscuration band
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10431—Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
    • B32B17/10467—Variable transmission
    • B32B17/10495—Variable transmission optoelectronic, i.e. optical valve
    • B32B17/10504—Liquid crystal layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10541—Functional features of the laminated safety glass or glazing comprising a light source or a light guide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10651—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising colorants, e.g. dyes or pigments
    • B32B17/1066—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising colorants, e.g. dyes or pigments imparting a tint in certain regions only, i.e. shade band
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
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    • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J3/00—Antiglare equipment associated with windows or windscreens; Sun visors for vehicles
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/67—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light
    • E06B3/6715—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/67—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light
    • E06B3/6715—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light
    • E06B3/6722—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light with adjustable passage of light
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    • B32B2250/00—Layers arrangement
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    • B32B2605/00—Vehicles

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  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

The invention relates to a composite panel (1) comprising a first panel (2) having an outer side surface (I) and an inner side surface (II), a second panel (4) having an outer side surface (III) and an inner side surface (IV), and an intermediate layer (5), in particular a functional layer (6), which is arranged between the inner side surface (II) of the first panel (2) and the outer side surface (III) of the second panel (4), wherein the second panel (4) is designed as an inner panel, the first panel (2) is designed as an outer panel, furthermore comprising a first polymer film (8) and a second polymer film (10), wherein the first polymer film (8) is arranged between the inner side surface (II) of the first panel (2) and the intermediate layer (5), and the second polymer film (10) is arranged between the outer side surface (III) of the second panel (4) and the intermediate layer (5), characterized in that, in the edge region of the composite panel, a printed opaque layer (12, 14) is applied on the first polymer film (8) and/or the second polymer film (10). Furthermore, the invention relates to a method for producing said composite panel and to the use of said composite panel.

Description

Composite panel, method for manufacturing the same and use of the same
The present invention relates to a composite panel, a method of manufacturing the composite panel and use of the composite panel.
A composite panel with a masking strip is known from WO 2014/174308 a 1. The masking strip extends in a peripheral region of the plate and is made of an opaque ceramic ink applied to the plate. However, in the case of surface coating of glass, it is difficult or impossible to apply the ceramic to the glass plate. Furthermore, in the production of composite glass, if separate pressure devices are provided for the plates of the composite plate, this leads to an increase in costs and thus to an increase in costs.
DE 19927683C 1 discloses a composite glass pane composed of at least two glass panes and a transparent composite layer connecting them and having a sunscreen layer which substantially reflects solar radiation, in particular infrared radiation, except for radiation in the visible spectrum. The composite pane has a further transparent coating (low-E layer) which is substantially reflective for thermal radiation and is spatially separated from the sun protection layer on its surface facing the interior space.
As is known, glazings, such as those used in sunroofs and sliding skylights, require a light transmission of 2% to 10%, and certain sunshades, which are characterized by a TTS value, which is a measure of the total solar thermal radiation transmitted through the panel and is measured, for example, according to ISO 9050. At a higher light transmission, on the one hand, too much heat radiation is transmitted and, on the other hand, the person behind the glazing may be visually disturbed due to too much light entering. At a lower light transmission, the glazing as a whole is too dark, so that a person behind the glazing can no longer see through it.
From WO 2017/103032 a1 a composite panel is known, which comprises an outer panel having an outer side surface and an inner side surface, an inner panel having an outer side surface and an inner side surface, and a thermoplastic intermediate layer connecting the inner side surface of the outer panel with the outer side surface of the inner panel. The composite pane has at least one sun protection coating between the outer pane and the inner pane, which sun protection coating substantially reflects or absorbs radiation of the solar radiation outside the visible spectrum, in particular infrared radiation, and wherein the composite pane has a coating reflecting thermal radiation on the inner side surface of the inner pane. The composite plate has a transmission index A of 0.02 to 0.08, wherein the transmission index A (A value) is determined according to the following formula (I): a ═ TLComposite glass plate/（TLLow E-coated panels* TE）（I），
Where TL is the light transmission and TE is the energy transfer rate measured according to ISO 9050 respectively.
Windshields in which a sun visor in the form of a functional element having electrically controllable optical properties, in particular electrically controllable transmission or scattering properties, is integrated are also known, for example, from WO 2019/166155 a 1. The driver can thus control the transmission properties of the windscreen itself with respect to solar radiation, and the conventional mechanical sun visor can be dispensed with. This makes it possible to reduce the weight of the vehicle and to obtain space in the roof region. Furthermore, electrical control of the sun visor is more convenient for the driver than manually turning down a mechanical sun visor. Such a windscreen may also be provided with an image pick-up area. In such areas, it is necessary to avoid bending of the glass sheet that may be caused by the application of the ceramic tape to the glass sheet.
Electrically controllable sun visors are also used in glass roofs of motor vehicles. Especially in the case of large-area panoramic glass panels, it is necessary to variably control the transmission of the panels. In this case, depending on the position of the sun, it is only necessary to shield a portion of the panel from light or to switch the entire area to opaque as a privacy protection in parking the vehicle.
Such a possible electrically switchable functional element for realizing a controllable sun visor is a so-called PDLC functional element (polymer dispersed liquid crystal). In this case, the active layer comprises a liquid crystal, which is embedded in a polymer matrix. If no voltage is applied, the liquid crystals are disorderly aligned, which causes strong scattering of light passing through the active layer. If a voltage is applied to the planar electrodes, the liquid crystals are aligned in a common direction and the transmission of light through the active layer is increased. PDLC functions work less by reducing the total transmission, but by increasing the scattering to ensure glare protection.
Windscreens with electrically controllable sun visors are known, for example, from DE 102013001334 a1, DE 102005049081B 3, DE 102005007427 a1 and DE 102007027296 a 1. DE 102010021563a1 describes a windshield with an electrically controllable sun visor which is switchable in partial regions, wherein the dimming of the individual elements can be controlled by capacitive sensor devices in the edge regions of the sun visor.
DE 202005014791U 1 discloses an interior lighting device for a motor vehicle. For this purpose, the OLED screen is designed as a light source, which radiates into the interior of the vehicle. The OLED screen can be arranged in particular in an interior ceiling of a motor vehicle, for example in a roof module. In this case, the roof module can be formed as a transparent or partially transparent roof module, wherein the OLED screen is transparent or partially transparent in the closed state, so that the roof module can be used as a transparent or partially transparent sunroof despite the provision of the OLED screen.
The electrical contacting of the electrically controllable functional elements is usually carried out by means of busbars (also called "busbars") which are applied to the planar electrodes in the edge regions of the functional elements and are in electrically conductive contact therewith. By connecting the busbar to an external voltage source, for example via a flat conductor mounted on the busbar, a voltage is applied to the planar electrode and the active layer of the functional element is switched.
US 2016/243796 a1 and DE 102011004500 a1 disclose laminated vehicle glazing having glass panes connected by a plastic layer, wherein the shaded region is created by printing on the plastic layer of the laminate.
The object of the present invention is to provide a composite panel having a masked area, which is compatible with at least one of the aforementioned coatings or functional elements (functional ä ten). Another object of the invention is to provide a cost-effective manufacturing method that can be easily used.
The composite panel according to the present invention comprises: a first plate having an outer side surface and an inner side surface; a second plate having an outer side surface and an inner side surface; and an intermediate layer, in particular a functional layer, which is arranged between the inner side surface of the first plate and the outer side surface of the second plate, wherein the second plate is designed as an inner plate, wherein the first plate is designed as an outer plate. The outer side is understood to mean the side of the first or outer plate and the inner side is understood to mean the side of the second or inner plate. Thus, when used as a vehicle glazing or a building glazing, the interior side is in the interior space of the vehicle or building.
Further, the composite panel includes a first polymer film disposed between the inside surface of the first panel and the intermediate layer and a second polymer film disposed between the outside surface of the second panel and the intermediate layer.
In the edge region of the composite plate, a printed opaque layer is applied on the first polymer film and/or the second polymer film.
The opaque layer printed on the polymer film is in particular an opaque enamel substitute layer, which is applied by means of a printing method. The opaque layer is in particular black and may comprise enamel.
The advantage of applying the first and/or second polymer film is that it can be produced more cost-effectively. In addition, it can also be used in combination with coated glass.
In one embodiment, a printed first opaque layer is applied on the first polymer film on the surface facing the intermediate layer or the surface facing the inside surface of the first plate.
In an alternative embodiment, a printed first opaque layer is applied to the inner side surface of the first plate. In this case, the printed opaque layer is in particular an enamel layer, which is also fired after the printing process.
The first opaque layer advantageously and thus preferably forms a circumferential edge of the composite plate. Optionally, the first opaque layer may have one or more stripes or patterns that are offset from the center of the composite panel.
In a further embodiment, a printed second opaque layer is applied on the second polymer film on the surface facing the intermediate layer or on the surface facing the outer side surface of the second plate.
The second opaque layer advantageously and thus preferably forms the peripheral edge of the composite panel. Optionally, the second opaque layer may have one or more stripes or patterns that are offset from the center of the composite panel.
The first opaque layer and/or the second opaque layer cover at least the electrically connected edge regions in which the intermediate layer formed as a functional layer is arranged.
The intermediate layer formed as a functional layer advantageously and therefore preferably comprises a liquid crystal layer, in particular a PDLC layer or an OLED layer, which is connected to at least one busbar at least along one side edge, in particular two opposite side edges. Contact at two opposite side edges is possible, for example, in the case of a rectangular or trapezoidal planar shape of the functional layer. The busbars serve for the electrical contacting of the functional layers.
The functional layer advantageously and therefore preferably also comprises a first and a second sealing layer. Such sealing layers are formed in particular from polymer films, in particular thermoplastic polymer films, for example polyethylene terephthalate (PET).
In one embodiment, a third and/or fourth polymer film is arranged adjacent to the intermediate layer, which is arranged at least in a part of the edge region. The third and/or fourth polymer film is in particular formed from a thermoplastic polymer film, for example PET.
In a further embodiment, a further polymer film or polymer intermediate layer is arranged between the first plate and the intermediate layer.
The composite plate advantageously and therefore preferably comprises a thickness compensator. Such thickness compensators are designed to compensate for the thickness of the functional layer and of the electrical connections, in particular of the busbars.
In a further embodiment, the first polymer film and/or the second polymer film and/or the further polymer film comprises polyvinyl butyral, ethylene vinyl acetate, polyurethane and/or mixtures and/or copolymers thereof, or is polyvinyl butyral (PVB).
In a further embodiment, the first and/or second plate is a colored or transparent glass or plastic plate, which is provided, in particular, with a coating that reflects thermal radiation.
Such coatings are known, for example, from WO2013/131667A 1. Coatings that reflect thermal radiation may also be referred to as low emissivity coatings, reduced emissivity coatings, low E coatings or low E layers. The task is to reflect thermal radiation, i.e. in particular IR radiation of a longer wavelength than the IR part of the solar radiation. At low external temperatures, the low E coating reflects heat back into the interior space and reduces cooling of the interior space. At high external temperatures, the low E coating reflects the thermal radiation of the heated composite panel outward and reduces heating of the interior space. On the inside of the inner panel, the coating according to the invention reduces the emission of thermal radiation of the panel into the interior space particularly effectively in summer and reduces the emission of thermal radiation into the external environment particularly effectively in winter.
The coating that reflects thermal radiation preferably comprises a functional layer that contains a Transparent Conductive Oxide (TCO), preferably indium tin oxide, tin oxide doped with antimony or fluorine, and/or zinc oxide doped with gallium and/or aluminum (ZnO: Ga, or ZnO: Al), of which indium tin oxide is preferred. However, the functional layer may also comprise other conductive oxides, for example fluorine-doped tin oxide (SnO)2F), antimony doped tin oxide (SnO)2Sb), indium zinc mixed oxide (IZO), gallium-doped or aluminum-doped zinc oxide, niobium-doped titanium oxide, cadmium stannate and/or zinc stannate. Particularly good results are thus obtained in terms of emissivity and bendability of the coating according to the invention. The refractive index of the material of the functional layer is preferably 1.7 to 2.5.
The heat-radiation-reflecting coating furthermore usually comprises a dielectric layer, in particular a dielectric layer formed from a dielectric oxide or nitride, such as ZnO, SnZnO, AlN, TiO2、SiO2Or Si3N4. The layer formed of reflective conductive oxide is anti-reflective above and below by using additional dielectric layers to ensure sufficiently low reflection at the inner side.
Alternatively or additionally, the first polymer film and/or the second polymer film has a polymer intermediate layer, which is or comprises, in particular, a coating that reflects thermal radiation.
The method according to the invention for manufacturing a composite panel according to the invention comprises:
providing the first and second sheets and the intermediate layer, in particular the functional layer
-printing a first opaque layer on the first polymer film or on the inner side surface of the first plate, and optionally subsequently firing, and/or
-printing a second opaque layer on the second polymer film,
-laminating the first sheet with the functional layer and the second sheet, wherein a first polymer film is arranged between the first sheet and the functional layer and a second polymer film is arranged between the second sheet and the functional layer.
If the opaque layer is printed only on the polymer film, the above method allows all of the films to be printed on the same printer and then combined together, thereby reducing manufacturing costs.
According to the invention, the composite panel according to the invention can be used as a vehicle glazing, in particular a sunroof, a windshield and/or a side window. Alternatively, the composite panel according to the invention can also be used in building glazing.
The invention is explained in more detail below with regard to further features and advantages by the description of exemplary embodiments and with reference to the drawings. Each shows in a schematic diagram:
figure 1 shows a first design of a composite plate,
figure 2 shows a second design of a composite plate,
figure 3 shows a third design of a composite plate,
FIG. 4 shows a fourth embodiment of the composite panel along the first edge, and
fig. 5 shows a fourth embodiment of the composite plate along the second edge.
Fig. 1 shows a first embodiment of a composite plate. The composite panel 1 comprises a first panel 2, said first panel 2 having an outer side surface I and an inner side surface II. The first plate is designed as an outer plate. In contrast, the composite panel 1 comprises a second panel 4 having an outer side surface III and an inner side surface IV. The second plate is designed as an inner plate. An intermediate layer 5 is arranged between the first plate 2 and the second plate 4, which intermediate layer 5 is a functional layer 6. The intermediate layer 5 is arranged between the inner side surface II of the first plate 2 and the outer side surface III of the second plate 4.
The intermediate layer 5 is designed as a functional layer 6. In the embodiment shown, it comprises a PDLC layer 30. Alternatively, however, designs as OLEDs or as combinations of these functional elements are also possible. The PDLC layer 30 is disposed in an interlayer comprised of two sealing layers, namely a first sealing layer 32 and a second sealing layer 34. In the vicinity of the functional layer 6 and in particular for electrical connection, there are also arranged busbars 36, by means of which the functional layer can be brought into at least two different states, namely transparent and translucent in the case of a PDLC layer or light-emitting and non-light-emitting in the case of an OLED. In the region of the busbar, a third polymer film 18 is arranged towards the two plates and a fourth polymer film 20 is arranged opposite.
Furthermore, the composite plate 1 comprises a first polymer film 8 and a second polymer film 10. A first polymer film 8 is arranged between the inner side surface II of the first sheet 2 and the intermediate layer 5 and a second polymer film 10 is arranged between the outer side surface III of the second sheet 4 and the intermediate layer 5.
On the first 8 and second 10 polymer films, printed opaque layers 12, 14 are applied in the edge regions of the composite panel. The opaque layers 10, 12 cover the bus bars and the edge regions of the PDLC layer. In particular, a first opacifying layer 12 is arranged on the side of the first polymer film 8 facing the intermediate layer 5, while a second opacifying layer 14 is arranged on the outer lateral surface III of the second plate.
Furthermore, this embodiment comprises a thickness compensator 16, which thickness compensator 16 compensates the thickness of the functional layer 6 and the busbar 36.
Fig. 2 shows a second embodiment of a composite plate 1'. This design differs from design 1 shown in fig. 1 in that the first polymer film 8 is not printed with an opaque layer, but only the second polymer film is printed with a second opaque layer 14. In this case, an opaque layer 12' is printed on the inner side surface II of the first plate 2. The opaque layer 12' is in particular an enamel layer.
Fig. 3 shows a third embodiment of a composite plate 1 ″. This third design differs from design 1 shown in fig. 1 in that only the first polymer film 8 is printed with a first opacifying layer 12. In this design, neither the second sheet 4 nor the second polymer film 10 is printed with the second opaque layer 14.
Fig. 4 and 5 show a fourth embodiment of a composite plate 1' ″. The side with the busbars 36 is shown in fig. 4 and the side without busbars of a composite plate (verbundshiene) is shown in fig. 5. The side shown in fig. 5 shows in particular the side of the composite plate (verbundshiene) which is perpendicular to the side present in fig. 4. Unlike the composite panel 1 shown in fig. 1, the first polymer film 8 is not printed and the first panel is printed with an opaque layer 12' on the inner side surface II. The opaque layer 12' is in particular an enamel layer. On the side facing away from the first plate 2, the first polymer film 8 has a polymer intermediate layer 9. The first polymer film 8 may be formed with a polymer interlayer 9 as a first bilayer 40. The polymer intermediate layer 9 is in particular a heat-reflective layer. The polymer intermediate layer 9 is in turn arranged between the first polymer film 8 and the further polymer film 11, which further polymer film 11 in turn forms a second bilayer 42 with the third polymer film 18. The second polymer film 10 may also form a third bilayer 44 with the fourth polymer film 20. In this embodiment, the second plate can be an uncoated or coated glass plate, as in the previous embodiment.
List of reference numerals
1, 1', 1' ', 1' '', 1'' '' composite board
2 first plate
4 second plate
5 intermediate layer
6 functional layer
8 first Polymer film
9 Polymer interlayer
10 second polymer film
11 additional Polymer films
12, 12' first opaque layer
14 second opaque layer
16 thickness compensator
18 third Polymer film
20 fourth Polymer film
30 PDLC
32 first sealing layer
34 second sealing layer
33 Polymer film
34 fourth plate
36 bus bar
40 first bilayer
42 second bilayer
44 third bilayer
I outer side surface of first plate
II inside surface of first plate
III outside surface of second plate
IV inside surface of the second plate.

Claims (13)

1. Composite panel (1) comprising a first panel (2) having an outer side surface (I) and an inner side surface (II), a second panel (4) having an outer side surface (III) and an inner side surface (IV), and an intermediate layer (5), the intermediate layer (5) being in particular a functional layer (6) which is arranged between the inner side surface (II) of the first panel (2) and the outer side surface (III) of the second panel (4), wherein the second panel (4) is designed as an inner panel and the first panel (2) is designed as an outer panel,
further comprising a first polymer film (8) and a second polymer film (10), wherein the first polymer film (8) is arranged between the inner side surface (II) of the first plate (2) and the intermediate layer (5), the second polymer film (10) is arranged between the outer side surface (III) of the second plate (4) and the intermediate layer (5),
it is characterized in that the preparation method is characterized in that,
applying a printed opaque layer (12, 14) on the first polymer film (8) and/or the second polymer film (10) in an edge region of the composite plate.
2. The composite panel (1) according to claim 1, wherein on the first polymer film (8), a printed first opaque layer (12) is applied on the surface facing the intermediate layer (5) or on the surface facing the inside surface (II) of the first panel (2), or
Wherein a first printed opaque layer (12') is applied on the inner side surface (II) of the first plate (2),
wherein the first opacifying layer (12, 12') preferably forms a peripheral edge of the composite sheet (1) and optionally can have one or more stripes or patterns offset from the center of the composite sheet (1).
3. The composite panel (1) according to claim 1 or 2, wherein on the second polymer film (10) a printed second opaque layer (14) is applied on the surface facing the intermediate layer (5) or on the surface facing the outer side surface (III) of the second panel (4),
wherein the second opacifying layer (14) preferably forms the peripheral edge of the composite sheet (1) and optionally can have one or more stripes or patterns offset from the centre of the composite sheet (1).
4. Composite plate (1) according to any one of the preceding claims, wherein the first and/or second opaque layer (10, 12) covers at least the edge region in which the electrical connection of the intermediate layer (5) formed as a functional layer (6) is arranged.
5. Composite plate (1) according to any one of the preceding claims, wherein the intermediate layer (5) formed as a functional layer (6) comprises a liquid crystal layer (30) or an OLED layer, which liquid crystal layer (30) or OLED layer is connected with at least one bus bar (36) at least along one side, in particular along two opposite sides.
6. A composite plate (1) according to claim 5, wherein said functional layer (6) further comprises a first and a second sealing layer (32, 34).
7. The composite plate (1) according to any one of the preceding claims, wherein a third and/or a fourth polymer film is arranged adjacent to the intermediate layer (5), which is arranged at least in a part of the edge region.
8. A composite sheet (1) according to any one of the preceding claims, wherein an additional polymer film or polymer intermediate layer is arranged between the first sheet (2) and the intermediate layer (5).
9. The composite plate (1) according to any one of the preceding claims, wherein the composite plate (1) comprises a thickness compensator (16).
10. A composite sheet (1) according to any of the preceding claims, wherein said first (8) and/or second (10) and/or further (11) polymer film comprises polyvinyl butyral, ethylene vinyl acetate, polyurethane and/or mixtures and/or copolymers thereof, preferably polyvinyl butyral.
11. The composite panel (1) according to any one of the preceding claims, wherein the first panel (2) and/or the second panel (4) is a tinted or transparent glass or plastic panel, in particular having a coating reflecting thermal radiation, and/or
Wherein the first polymer film (8) and/or the second polymer film (10) has a polymer intermediate layer (9), the polymer intermediate layer (9) being in particular a coating that reflects thermal radiation.
12. Method of manufacturing a composite panel (1) according to any of claims 1 to 12, comprising
-providing a first sheet (2) and a second sheet (4) and an intermediate layer (5), in particular a functional layer (6),
-printing a first opaque layer (12) on the inside surface (II) of the first polymeric film (8) or first sheet, and/or
-printing a second opaque layer (14) on the second polymer film (10),
-laminating the first sheet (2) with the functional layer (6) and the second sheet (8), wherein the first polymer film (8) is arranged between the first sheet (2) and the functional layer (6) and the second polymer film (10) is arranged between the second sheet (4) and the functional layer (6).
13. Use of a composite panel (1) according to any one of claims 1 to 12 as a vehicle glazing or a building glazing.
CN202180000957.4A 2020-03-13 2021-03-10 Composite panel, method for manufacturing the same and use of the same Pending CN113784837A (en)

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EP20162907 2020-03-13
PCT/EP2021/056035 WO2021180779A1 (en) 2020-03-13 2021-03-10 Composite pane, method for producing the composite pane and use of the composite pane

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DE19927683C1 (en) 1999-06-17 2001-01-25 Sekurit Saint Gobain Deutsch Laminated glass pane reflecting sun and heat rays
DE102005007427A1 (en) 2005-02-18 2006-08-31 Volkswagen Ag Motor vehicle e.g. land vehicle, has controller providing automatic adjustment of transparency of segment such as sun visor of window pane in dependence of output signal of glare sensor
DE202005014791U1 (en) 2005-09-19 2005-12-22 Webasto Ag Lighting device for roof interior of motor vehicle, has laminar organic light emitting diode display formed for light source, which is designed for emitting light into internal space, and including layer with OLED-cells
DE102005049081B3 (en) 2005-10-13 2007-06-06 Webasto Ag Layer arrangement for darkening a transparent pane
DE102007027296A1 (en) 2007-06-11 2008-12-18 Volkswagen Ag Automatic sun visor for a motor vehicle
DE102010021563A1 (en) 2010-05-26 2011-12-01 Gm Global Technology Operations Llc (N.D.Ges.D. Staates Delaware) Window pane assembly for motor vehicle, particularly passenger car, comprises rear, front, side or panoramic disk which comprises surface portion, which is electrically adjusted, according to its transmittance
DE102011004500A1 (en) 2011-02-22 2012-08-23 Bayerische Motoren Werke Aktiengesellschaft Method for producing printed composite plate for, e.g. sliding roof of vehicle, involves laminating composite sheet that is printed using inkjet printer before performing lamination process, between outer and inner panes
CN104159861B (en) 2012-03-05 2018-04-03 法国圣戈班玻璃厂 Glass pane with heat radiation reflectance coating
DE102013001334A1 (en) 2013-01-26 2014-07-31 Audi Ag Method for operating a window pane of motor vehicle, involves detecting operating-contact gesture of occupant with respect to window pane, so as to adjust light transmittance using adjustment element
GB201307495D0 (en) 2013-04-25 2013-06-12 Pilkington Group Ltd Laminated glazing
US9623634B2 (en) 2015-02-19 2017-04-18 Agp America S.A. Obscuration having superior strength and optical quality for a laminated automotive windshield
CA3005510C (en) 2015-12-16 2020-05-05 Saint-Gobain Glass France Heatable laminated glass having a thin inner pane and a thin outer pane
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