CN113773116A - Production process for printing on ceramic product and printed ceramic product - Google Patents

Production process for printing on ceramic product and printed ceramic product Download PDF

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Publication number
CN113773116A
CN113773116A CN202010533606.7A CN202010533606A CN113773116A CN 113773116 A CN113773116 A CN 113773116A CN 202010533606 A CN202010533606 A CN 202010533606A CN 113773116 A CN113773116 A CN 113773116A
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CN
China
Prior art keywords
printing
paste mixture
ceramic
mixture
airing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010533606.7A
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Chinese (zh)
Inventor
许斌
张丹
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Tangshan Kun Kiln Ceramics Co ltd
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Tangshan Kun Kiln Ceramics Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN202010533606.7A priority Critical patent/CN113773116A/en
Publication of CN113773116A publication Critical patent/CN113773116A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Printing Methods (AREA)

Abstract

The invention discloses a production process for printing on a ceramic product and the printed ceramic product. The production process comprises the following steps: a. mixing the semitransparent matting powder and the printing varnish according to the mass ratio of 5: 3, and grinding for at least 3 times by using a grinder to form a paste mixture A; b. mixing the semitransparent relief powder, the relief cooling agent and the printing varnish according to the mass ratio of 5: 6, and grinding into a paste mixture B by a grinder; c. printing the paste mixture A on the special stained paper for ceramics by using a silk screen, and airing; d. covering and printing the paste mixture B on the paste mixture A by using a silk screen, completely covering the paste mixture A by the paste mixture B, and then airing; e. covering the pasty mixture B with special ceramic surface oil, and then airing; f. soaking the special stained paper for the ceramic, transferring the pattern to the surface of the glazed ceramic body after the pattern formed by the pasty mixture A and the pasty mixture B is separated from the special stained paper for the ceramic, and airing; g. and putting the ceramic body into a kiln for firing. The glazed porcelain product manufactured by the production process has the visual effect of unglazed printing.

Description

Production process for printing on ceramic product and printed ceramic product
Technical Field
The invention relates to a production process of a ceramic product and the ceramic product, in particular to a production process of printing on the ceramic product and the ceramic product produced by the production process.
Background
The ceramic is a popular material for containers and artworks, and has the advantages of beautiful appearance, corrosion resistance, high temperature resistance, high hardness and the like. In order to increase the mechanical strength, thermal stability, dielectric strength and liquid corrosion resistance of the ceramic vessel, the inner and outer surfaces of the ceramic vessel, which are generally used daily, are subjected to glazing treatment. The surface of the ceramic product after glazing is smoother, and the glossiness is obviously improved.
In some designs, designers need to design containers such as cups and trays with partial glazing, and the contrast between glazed and unglazed portions forms patterns, so as to achieve the visual effect of making the porcelain more beautiful and changeable. At present, the common method for porcelain needing partial glazing is that a porcelain body is placed in a kiln at about 1230 ℃ to be fired, glazing is carried out after firing is finished, and in order to express the surface pattern of the porcelain, the part which is not glazed is wiped off by sponge or soft cloth. Alternatively, the glazing is carried out by masking the portion that does not need to be glazed. After glazing, placing the porcelain body in a kiln at about 1130 ℃ for glaze firing, and finishing the manufacturing. The process has the defects that on one hand, the part which is not glazed is easy to seep water and seep dirt, is easy to leave scratches and is difficult to clean, and on the other hand, in the glazing process, because the glaze is water-soluble, the glaze is easy to fall off easily after being dried by slight rubbing, and is not beneficial to performing fine treatment to express fine patterns, the production difficulty is improved, and the yield is low, so that the design of local glazing does not open the door of the market under the condition that the porcelain is more beautiful.
Disclosure of Invention
Based on the background, the invention discloses a production process for printing on ceramic products and printed ceramic products produced by the production process. The printed part of the porcelain product manufactured by the production process is 'pseudo-unglazed', namely the printed part has the unglazed visual effect, and meanwhile, the printed part has the advantages of difficult water seepage and dirt seepage, difficult scratch leaving, easy cleaning and the like of the glazed porcelain product, thereby solving the technical problem that the unglazed part cannot have the same difficult water seepage and dirt seepage and difficult scratch as the glazed part to express the patterns of the porcelain in the prior art.
The invention discloses a production process for printing on a ceramic product, which comprises the following steps:
a. mixing the semitransparent matting powder (1) and the printing varnish (2) according to the mass ratio of 5: 3, and grinding for at least 3 times by using a grinder to form a paste mixture A (3);
b. mixing the semitransparent embossment powder (4), the embossment cooling agent (5) and the printing varnish (2) according to the mass ratio of 5: 6, and grinding into a paste mixture B (6) by a grinder;
c. printing the paste mixture A (3) on special stained paper for ceramics by using a silk screen under the conditions that the ambient temperature is 25-26 ℃ and the humidity is 50-60%, and airing;
d. under the conditions that the ambient temperature is 25-26 ℃ and the humidity is 50-60%, covering and printing the paste mixture B (6) on the paste mixture A (3) by using a silk screen, completely covering the paste mixture A (3) by using the paste mixture B (6), and then airing;
e. covering the pasty mixture B (6) with special ceramic surface oil (7), and then airing;
f. soaking the special stained paper for ceramics, transferring the pattern to the surface of a glazed ceramic body after the pattern formed by the paste mixture A (3) and the paste mixture B (6) is separated from the special stained paper for ceramics, and airing;
g. and putting the ceramic body into a kiln for firing.
Preferably, the screen is a 250-mesh S-type screen.
Preferably, in the step g, the firing temperature is about 800 degrees celsius, and the firing time is about 120 minutes.
The invention also describes a printed ceramic product produced according to the production process.
The color of the printed part of the porcelain produced by the process is extremely close to that of the porcelain body, the color difference is less than 3%, the thickness of the coating is low, the visual effect reaches unglazed, and whether the surface of the porcelain has the coating or not can not be distinguished by naked eyes.
The printed coating has high hardness, and scratches are not easy to leave after metal is scratched.
The process is simple and flexible, and can be used for printing by any screen printing equipment.
By utilizing the process, fine patterns can be represented on the surface of the porcelain, the thickness of the printed patterns can reach 0.12 mm, and the fine and complex patterns can be more conveniently represented compared with the traditional pattern sketching mode of glazing and erasing.
The firing temperature is about 800 ℃, which is much lower than the traditional 1130 ℃ firing temperature, thus being beneficial to saving energy and reducing cost.
Detailed Description
The technical means of the present invention will be described in detail with reference to examples.
The printing part of the porcelain product manufactured by the production process can realize the visual effect of 'pseudo-unglazed', and the production process needs the following raw materials: glazed porcelain to be printed, semitransparent matting powder, semitransparent relief powder, relief cooling agent, printing varnish and sealing oil. The semi-transparent matting powder, the semi-transparent relief powder, the printing varnish and the seal oil are all specially used for ceramics, and specifically, the semi-transparent matting powder with a Froude brand model of 197815, the semi-transparent relief powder with a German Hesley brand model of 60904, the relief cooling agent with a Japanese izawa brand model of 31181 and the printing varnish with a Reqiong brand model of 8608 can be selected.
The specific production process comprises the following steps:
firstly, mixing translucent matting powder and printing varnish according to the mass ratio of 5: 3, and grinding for at least 3 times by using a grinder to form a paste mixture A. The grinder can be a three-roller grinder.
And secondly, mixing the semitransparent embossment powder, the embossment cooling agent and the printing varnish according to the mass ratio of 5: 6, and grinding the mixture into a pasty mixture B by a grinder. When mixing, the translucent embossment powder and the embossment cooling agent can be mixed firstly, and the mixture is mixed with the printing varnish. The grinder can be a three-roller grinder.
And thirdly, controlling the indoor temperature of the printing chamber to be 25-26 ℃ and controlling the humidity to be 50-60%. And (3) printing the paste mixture A on the special stained paper for the ceramic by using a silk screen to serve as a base layer of printing. And then drying. The drying time was about 2 hours.
Fourthly, controlling the indoor temperature of the printing chamber to be 25-26 ℃ and controlling the humidity to be 50-60%. The paste mixture B is printed on the paste mixture a using a screen, and the paste mixture B is completely covered on the paste mixture a when printing. And then drying. The drying time was about 4 hours.
The third step and the fourth step are screen printing steps. The screen used in both steps is preferably a 250 mesh S-shaped screen.
And fifthly, covering the paste mixture B with cover oil. And then drying. In this step, the airing time was about 6 hours.
And sixthly, soaking the special stained paper for the ceramic printed with the patterns in water, and transferring the patterns to the surface of the glazed ceramic product after the patterns are separated from the special stained paper for the ceramic. And then drying. In this step, the airing time was about 2 hours.
And seventhly, putting the ceramic product with the printed patterns in a kiln for firing. The firing temperature is about 800 degrees celsius and the firing time is about 120 minutes. After the firing is finished, the printed part on the surface of the porcelain product presents an unglazed visual effect.
The color of the printed part of the porcelain produced by the process is extremely close to the color of the porcelain body, the color difference is less than 3%, the thickness of the coating is low, the visual effect reaches unglazed, whether the surface of the porcelain is coated or not can not be distinguished by naked eyes, and the visual effect is very attractive.
The printed coating has high hardness, and the scratch is not easy to leave after the metal is scraped, so that the manufactured porcelain product is beautiful and has high practicability.
The process is simple and flexible, and can be used for printing by any screen printing equipment. The hand printing table, the semi-automatic printing machine and the full-automatic printing machine can be selected according to actual conditions.
By utilizing the process, fine patterns can be represented on the surface of the porcelain, the thickness of the printed patterns can reach 0.12 mm, and the fine and complex patterns can be more conveniently represented compared with the traditional pattern sketching mode of glazing and erasing.
The embodiments described above are merely exemplary of the invention and are not intended to limit the invention in any way, so that those skilled in the art may make modifications and changes to the embodiments equivalent to those disclosed above. However, any simple modification, equivalent change and modification of the above embodiments according to the present invention shall fall within the protection scope of the present invention without departing from the technical principle of the present invention.

Claims (4)

1. The production process of printing on ceramic products is characterized by comprising the following steps of:
a. mixing the semitransparent matting powder (1) and the printing varnish (2) according to the mass ratio of 5: 3, and grinding for at least 3 times by using a grinder to form a paste mixture A (3);
b. mixing the semitransparent embossment powder (4), the embossment cooling agent (5) and the printing varnish (2) according to the mass ratio of 5: 6, and grinding for at least 3 times by using a grinder to form a paste mixture B (6);
c. printing the paste mixture A (3) on special stained paper for ceramics by using a silk screen under the conditions that the ambient temperature is 25-26 ℃ and the humidity is 50-60%, and airing;
d. under the conditions that the ambient temperature is 25-26 ℃ and the humidity is 50-60%, covering and printing the paste mixture B (6) on the paste mixture A (3) by using a silk screen, completely covering the paste mixture A (3) by using the paste mixture B (6), and then airing;
e. covering the pasty mixture B (6) with special ceramic surface oil (7), and then airing;
f. soaking the special stained paper for ceramics, transferring the pattern to the surface of a glazed ceramic body after the pattern formed by the paste mixture A (3) and the paste mixture B (6) is separated from the special stained paper for ceramics, and airing;
g. and putting the ceramic body into a kiln for firing.
2. The process of claim 1, wherein the screen is a 250 mesh S-screen.
3. The process according to claim 1 or 2, wherein in step g, the firing temperature is about 800 ℃ and the firing time is about 120 minutes.
4. A printed ceramic article, characterized in that it is produced by the production process as claimed in claim 1 or 2 or 3.
CN202010533606.7A 2020-06-10 2020-06-10 Production process for printing on ceramic product and printed ceramic product Pending CN113773116A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010533606.7A CN113773116A (en) 2020-06-10 2020-06-10 Production process for printing on ceramic product and printed ceramic product

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Application Number Priority Date Filing Date Title
CN202010533606.7A CN113773116A (en) 2020-06-10 2020-06-10 Production process for printing on ceramic product and printed ceramic product

Publications (1)

Publication Number Publication Date
CN113773116A true CN113773116A (en) 2021-12-10

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0999070A2 (en) * 1998-11-06 2000-05-10 dmc2 Degussa Metals Catalysts Cerdec AG Process of manufacturing coloured ceramic decorations with relief srtucture
CN1865591A (en) * 2006-06-01 2006-11-22 潮州市西湖瓷花纸有限公司 Method for making paper for used in embossed and patterned gold porcelain
CN102690553A (en) * 2012-06-05 2012-09-26 江苏劲嘉新型包装材料有限公司 Method for printing double smooth surfaces at one time and matting agent for printing ink
CN103435374A (en) * 2013-08-09 2013-12-11 上海高诚艺术包装有限公司 Preparation method of ceramic wine bottle with printing
CN105946427A (en) * 2015-10-10 2016-09-21 四川省长宁县天成印务有限公司 Transparent relief decoration firing process
CN106274109A (en) * 2016-08-31 2017-01-04 唐山市琨窑陶瓷有限公司 On ceramic, marble paper pattern presents the production technology of three dimensional change
CN108396588A (en) * 2018-01-31 2018-08-14 醴陵市精陶瓷业有限公司 Inorganic material combination marble paper and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0999070A2 (en) * 1998-11-06 2000-05-10 dmc2 Degussa Metals Catalysts Cerdec AG Process of manufacturing coloured ceramic decorations with relief srtucture
CN1865591A (en) * 2006-06-01 2006-11-22 潮州市西湖瓷花纸有限公司 Method for making paper for used in embossed and patterned gold porcelain
CN102690553A (en) * 2012-06-05 2012-09-26 江苏劲嘉新型包装材料有限公司 Method for printing double smooth surfaces at one time and matting agent for printing ink
CN103435374A (en) * 2013-08-09 2013-12-11 上海高诚艺术包装有限公司 Preparation method of ceramic wine bottle with printing
CN105946427A (en) * 2015-10-10 2016-09-21 四川省长宁县天成印务有限公司 Transparent relief decoration firing process
CN106274109A (en) * 2016-08-31 2017-01-04 唐山市琨窑陶瓷有限公司 On ceramic, marble paper pattern presents the production technology of three dimensional change
CN108396588A (en) * 2018-01-31 2018-08-14 醴陵市精陶瓷业有限公司 Inorganic material combination marble paper and preparation method thereof

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