CN113770100A - Semiconductor part cleaning process - Google Patents

Semiconductor part cleaning process Download PDF

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Publication number
CN113770100A
CN113770100A CN202010680989.0A CN202010680989A CN113770100A CN 113770100 A CN113770100 A CN 113770100A CN 202010680989 A CN202010680989 A CN 202010680989A CN 113770100 A CN113770100 A CN 113770100A
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CN
China
Prior art keywords
parts
cleaning
semiconductor
ultrasonic
cleaned
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010680989.0A
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Chinese (zh)
Inventor
陈如明
陈彩丽
卜庆磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Indinami Xuzhou Semiconductor Technology Co ltd
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Indinami Xuzhou Semiconductor Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Indinami Xuzhou Semiconductor Technology Co ltd filed Critical Indinami Xuzhou Semiconductor Technology Co ltd
Priority to CN202010680989.0A priority Critical patent/CN113770100A/en
Publication of CN113770100A publication Critical patent/CN113770100A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/12Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3942Inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3947Liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/06Hydroxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/14Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3209Amines or imines with one to four nitrogen atoms; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3263Amides or imides
    • C11D2111/22

Abstract

The invention discloses a cleaning process for semiconductor parts, which comprises the following steps: A. firstly, putting the semiconductor parts into warm water and washing the semiconductor parts for 20-30 min by water flow; B. then placing the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 30-50 min; C. then, putting the cleaned parts into cold water for washing for 30-40 min; D. adding hydrofluoric acid with the concentration of 3% and nitric acid with the concentration of 20% into the semiconductor parts cleaned by cold water for carrying out acid etching treatment for 4-8 min; E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment; F. the cleaning process adopted by the invention is simple to operate and good in cleaning effect, can effectively remove dust particles, metal ions, oil stains and dirt, and ensures the performance of the semiconductor parts.

Description

Semiconductor part cleaning process
Technical Field
The invention relates to the technical field of semiconductor part cleaning, in particular to a semiconductor part cleaning process.
Background
The semiconductor is a substance with conductivity between an insulator and a conductor, the conductivity of the semiconductor is easy to control, and the semiconductor can be used as an element material for information processing; semiconductors are very important from the viewpoint of technological or economic development.
After the semiconductor parts are processed, the semiconductor parts need to be cleaned, and the cleaning efficiency of the current cleaning process is low, and the cleaning effect is poor, so that improvement is needed.
Disclosure of Invention
The present invention is directed to a semiconductor component cleaning process to solve the above problems.
In order to achieve the purpose, the invention provides the following technical scheme: a cleaning process for semiconductor parts comprises the following steps:
A. firstly, putting the semiconductor parts into warm water and washing the semiconductor parts for 20-30 min by water flow;
B. then placing the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 30-50 min;
C. then, putting the cleaned parts into cold water for washing for 30-40 min;
D. adding hydrofluoric acid with the concentration of 3% and nitric acid with the concentration of 20% into the semiconductor parts cleaned by cold water for carrying out acid etching treatment for 4-8 min;
E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment;
F. and (5) drying the cleaned parts in a nitrogen atmosphere.
Preferably, the cleaning agent in the step B comprises 20-30 parts by weight of sodium iodide, 10-20 parts by weight of potassium hydroxide, 4-10 parts by weight of N, N-diethylformamide, 5-15 parts by weight of hydrogen peroxide, 3-9 parts by weight of sodium silicate and 4-12 parts by weight of tetraethylammonium hydroxide.
Preferably, the ultrasonic power in the step B is 800-.
Preferably, the ultrasonic power in the step E is 1200-1400W.
Preferably, the blowing flow rate of the nitrogen in the step F is 30-40L/min.
Compared with the prior art, the invention has the beneficial effects that: the cleaning process adopted by the invention is simple to operate and good in cleaning effect, and can effectively remove dust particles, metal ions, oil stains and dirt and ensure the performance of semiconductor parts; the cleaning agent adopted by the invention is environment-friendly, pollution-free, easy to wash and residue-free, and can effectively remove static electricity on the surface of the semiconductor part.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the invention provides the following technical scheme: a cleaning process for semiconductor parts comprises the following steps:
A. firstly, putting semiconductor parts into warm water and washing with water flow for 20 min;
B. then placing the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 30 min;
C. then, putting the cleaned parts into cold water for washing for 30 min;
D. adding hydrofluoric acid with concentration of 3% and nitric acid with concentration of 20% into the semiconductor parts cleaned with cold water for acid etching treatment for 4 min;
E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment;
F. and (5) drying the cleaned parts in a nitrogen atmosphere.
In this embodiment, the components of the cleaning agent in step B include, by weight, 20 parts of sodium iodide, 10 parts of potassium hydroxide, 4 parts of N, N-diethylformamide, 5 parts of hydrogen peroxide, 3 parts of sodium silicate, and 4 parts of tetraethylammonium hydroxide.
In this embodiment, the ultrasonic power in step B is 800W.
In this embodiment, the ultrasonic power in step E is 1200W.
In this example, the flow rate of nitrogen blown out in step F was 30L/min.
Example two:
a cleaning process for semiconductor parts comprises the following steps:
A. firstly, putting semiconductor parts into warm water and washing with water flow for 30 min;
B. then placing the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 50 min;
C. then, putting the cleaned parts into cold water for rinsing with water flow for 40 min;
D. adding hydrofluoric acid with concentration of 3% and nitric acid with concentration of 20% into the semiconductor parts cleaned with cold water for acid etching treatment for 8 min;
E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment;
F. and (5) drying the cleaned parts in a nitrogen atmosphere.
In this embodiment, the components of the cleaning agent in step B include, by weight, 30 parts of sodium iodide, 20 parts of potassium hydroxide, 10 parts of N, N-diethylformamide, 15 parts of hydrogen peroxide, 9 parts of sodium silicate, and 12 parts of tetraethylammonium hydroxide.
In this embodiment, the ultrasonic power in step B is 1000W.
In this embodiment, the ultrasonic power in step E is 1400W.
In this example, the flow rate of nitrogen blown out in step F was 40L/min.
Example three:
a cleaning process for semiconductor parts comprises the following steps:
A. firstly, putting semiconductor parts into warm water and washing with water flow for 22 min;
B. then, putting the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 35 min;
C. then, putting the cleaned parts into cold water for rinsing with water flow for 32 min;
D. adding hydrofluoric acid with concentration of 3% and nitric acid with concentration of 20% into the semiconductor parts cleaned with cold water for acid etching treatment for 5 min;
E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment;
F. and (5) drying the cleaned parts in a nitrogen atmosphere.
In this embodiment, the components of the cleaning agent in step B include, by weight, 22 parts of sodium iodide, 12 parts of potassium hydroxide, 5 parts of N, N-diethylformamide, 6 parts of hydrogen peroxide, 4 parts of sodium silicate, and 6 parts of tetraethylammonium hydroxide.
In this embodiment, the ultrasonic power in step B is 850W.
In this embodiment, the ultrasonic power in step E is 1250W.
In this example, the flow rate of nitrogen blown out in step F was 32L/min.
Example four:
a cleaning process for semiconductor parts comprises the following steps:
A. firstly, putting semiconductor parts into warm water and washing with water flow for 28 min;
B. then placing the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 48 min;
C. then, the cleaned parts are put into cold water to be washed by water flow for 38 min;
D. adding hydrofluoric acid with concentration of 3% and nitric acid with concentration of 20% into the semiconductor parts cleaned with cold water for acid etching treatment for 7 min;
E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment;
F. and (5) drying the cleaned parts in a nitrogen atmosphere.
In this embodiment, the components of the cleaning agent in step B include, by weight, 26 parts of sodium iodide, 14 parts of potassium hydroxide, 8 parts of N, N-diethylformamide, 7 parts of hydrogen peroxide, 8 parts of sodium silicate, and 6 parts of tetraethylammonium hydroxide.
In this embodiment, the ultrasonic power in step B is 920W.
In this embodiment, the ultrasonic power in step E is 1340W.
In this example, the flow rate of nitrogen blown out in step F was 34L/min.
Example five:
a cleaning process for semiconductor parts comprises the following steps:
A. firstly, putting semiconductor parts into warm water and washing with water flow for 29 min;
B. then placing the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 32 min;
C. then, the cleaned parts are placed into cold water for washing for 36 min;
D. adding hydrofluoric acid with concentration of 3% and nitric acid with concentration of 20% into the semiconductor parts cleaned with cold water for acid etching treatment for 6 min;
E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment;
F. and (5) drying the cleaned parts in a nitrogen atmosphere.
In this embodiment, the components of the cleaning agent in step B include, by weight, 28 parts of sodium iodide, 13 parts of potassium hydroxide, 8 parts of N, N-diethylformamide, 5 parts of hydrogen peroxide, 8 parts of sodium silicate, and 6 parts of tetraethylammonium hydroxide.
In this embodiment, the ultrasonic power in step B is 920W.
In this embodiment, the ultrasonic power in step E is 1280W.
In this example, the flow rate of nitrogen blown out in step F was 36L/min.
Example six:
a cleaning process for semiconductor parts comprises the following steps:
A. firstly, putting semiconductor parts into warm water and washing with water flow for 25 min;
B. then placing the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 40 min;
C. then, putting the cleaned parts into cold water for washing for 35 min;
D. adding hydrofluoric acid with concentration of 3% and nitric acid with concentration of 20% into the semiconductor parts cleaned with cold water for acid etching treatment for 6 min;
E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment;
F. and (5) drying the cleaned parts in a nitrogen atmosphere.
In this embodiment, the components of the cleaning agent in step B include, by weight, 25 parts of sodium iodide, 15 parts of potassium hydroxide, 7 parts of N, N-diethylformamide, 10 parts of hydrogen peroxide, 6 parts of sodium silicate, and 8 parts of tetraethylammonium hydroxide.
In this embodiment, the ultrasonic power in step B is 900W.
In this embodiment, the ultrasonic power in step E is 1300W.
In this example, the flow rate of nitrogen blown out in step F was 35L/min.
The cleaning process adopted by the invention is simple to operate and good in cleaning effect, and can effectively remove dust particles, metal ions, oil stains and dirt and ensure the performance of semiconductor parts; the cleaning agent adopted by the invention is environment-friendly, pollution-free, easy to wash and residue-free, and can effectively remove static electricity on the surface of the semiconductor part.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (5)

1. A semiconductor part cleaning process is characterized in that: the method comprises the following steps:
A. firstly, putting the semiconductor parts into warm water and washing the semiconductor parts for 20-30 min by water flow;
B. then placing the semiconductor parts into a cleaning machine, adding a cleaning agent, and cleaning by adopting ultrasonic for 30-50 min;
C. then, putting the cleaned parts into cold water for washing for 30-40 min;
D. adding hydrofluoric acid with the concentration of 3% and nitric acid with the concentration of 20% into the semiconductor parts cleaned by cold water for carrying out acid etching treatment for 4-8 min;
E. finally, placing the parts subjected to the acid etching treatment into an ultrasonic machine for secondary ultrasonic treatment;
F. and (5) drying the cleaned parts in a nitrogen atmosphere.
2. The process of claim 1, wherein the cleaning comprises: the cleaning agent in the step B comprises, by weight, 20-30 parts of sodium iodide, 10-20 parts of potassium hydroxide, 4-10 parts of N, N-diethylformamide, 5-15 parts of hydrogen peroxide, 3-9 parts of sodium silicate and 4-12 parts of tetraethylammonium hydroxide.
3. The process of claim 1, wherein the cleaning comprises: the ultrasonic power in the step B is 800-.
4. The process of claim 1, wherein the cleaning comprises: the ultrasonic power in the step E is 1200-1400W.
5. The process of claim 1, wherein the cleaning comprises: and F, the blowing flow rate of the nitrogen in the step is 30-40L/min.
CN202010680989.0A 2020-07-15 2020-07-15 Semiconductor part cleaning process Pending CN113770100A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010680989.0A CN113770100A (en) 2020-07-15 2020-07-15 Semiconductor part cleaning process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010680989.0A CN113770100A (en) 2020-07-15 2020-07-15 Semiconductor part cleaning process

Publications (1)

Publication Number Publication Date
CN113770100A true CN113770100A (en) 2021-12-10

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Country Status (1)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101465273A (en) * 2007-12-18 2009-06-24 中芯国际集成电路制造(上海)有限公司 Wet-type etching method for reducing wafer surface blemish and device thereof
CN101901743A (en) * 2003-07-24 2010-12-01 应用材料股份有限公司 Cleaning process and apparatus for silicate materials
CN102218410A (en) * 2011-04-19 2011-10-19 浙江露笑光电有限公司 Method for cleaning polished sapphire
CN106062932A (en) * 2014-05-02 2016-10-26 三菱瓦斯化学株式会社 Semiconductor element cleaning liquid and cleaning method
CN110976414A (en) * 2019-12-12 2020-04-10 游利 Ultra-high clean cleaning process for semiconductor aluminum alloy parts
CN111229764A (en) * 2018-11-29 2020-06-05 东莞新科技术研究开发有限公司 Glass cleaning method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101901743A (en) * 2003-07-24 2010-12-01 应用材料股份有限公司 Cleaning process and apparatus for silicate materials
CN101465273A (en) * 2007-12-18 2009-06-24 中芯国际集成电路制造(上海)有限公司 Wet-type etching method for reducing wafer surface blemish and device thereof
CN102218410A (en) * 2011-04-19 2011-10-19 浙江露笑光电有限公司 Method for cleaning polished sapphire
CN106062932A (en) * 2014-05-02 2016-10-26 三菱瓦斯化学株式会社 Semiconductor element cleaning liquid and cleaning method
CN111229764A (en) * 2018-11-29 2020-06-05 东莞新科技术研究开发有限公司 Glass cleaning method
CN110976414A (en) * 2019-12-12 2020-04-10 游利 Ultra-high clean cleaning process for semiconductor aluminum alloy parts

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Application publication date: 20211210