CN113755224A - Semi-coke combustion improver - Google Patents
Semi-coke combustion improver Download PDFInfo
- Publication number
- CN113755224A CN113755224A CN202110960049.1A CN202110960049A CN113755224A CN 113755224 A CN113755224 A CN 113755224A CN 202110960049 A CN202110960049 A CN 202110960049A CN 113755224 A CN113755224 A CN 113755224A
- Authority
- CN
- China
- Prior art keywords
- parts
- semi
- coke
- combustion improver
- combustion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 127
- 239000000571 coke Substances 0.000 title claims abstract description 105
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 52
- 229940116318 copper carbonate Drugs 0.000 claims abstract description 40
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims abstract description 40
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 40
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 39
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 39
- 239000001110 calcium chloride Substances 0.000 claims abstract description 39
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 38
- 238000002156 mixing Methods 0.000 claims abstract description 30
- 229910052799 carbon Inorganic materials 0.000 claims description 30
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract description 95
- 239000007789 gas Substances 0.000 abstract description 31
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 29
- 238000002474 experimental method Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 74
- 238000007873 sieving Methods 0.000 description 27
- 239000003245 coal Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N sulfur dioxide Inorganic materials O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 2
- 239000003830 anthracite Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- MXWZMZKUHWTDHA-UHFFFAOYSA-N cyclopenta-1,3-diene 5-cyclopenta-2,4-dien-1-ylcyclopenta-1,3-diene iron(2+) Chemical compound [Fe++].c1cc[cH-]c1.C1=CC(C=C1)[c-]1cccc1 MXWZMZKUHWTDHA-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000010855 food raising agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
- C10L9/12—Oxidation means, e.g. oxygen-generating compounds
Abstract
The invention provides a semi-coke combustion improver which is prepared by mixing the following components in percentage by weight: 1-3 parts of potassium permanganate, 3-5 parts of ammonium nitrate, 5-9 parts of calcium chloride, 1-5 parts of sodium dodecyl benzene sulfonate, 6-10 parts of basic copper carbonate and 30-50 parts of activated carbon. Each component of the semi-coke combustion improver can pass through a 60-mesh sieve. The semi-coke combustion improver is mixed with the semi-coke according to the weight ratio of 3: 100. Experiments prove that the semi-coke combustion improver can greatly reduce the ignition point of the semi-coke, reduce the burnout time of the semi-coke, ensure the complete and sufficient combustion of the semi-coke, and reduce the discharge amount of nitrogen oxide and sulfide gas generated by the combustion of the semi-coke.
Description
Technical Field
The invention belongs to the technical field of flame retardants, and particularly relates to a semi-coke combustion improver.
Background
The basic characteristics of natural resources in China are rich coal, poor oil and little gas, which determines the important position of coal in primary energy. Coal is relatively abundant in storage compared to oil and natural gas, and accounts for 11.60% of world reserves. The total amount of coal resources in China is 5.6 trillion tons, wherein the proven reserves are 1 trillion tons, which account for 11 percent of the total reserves in the world, and the coal-producing large country in the world is the first coal-producing large country. However, as people continuously mine, the storage capacity of coal is less and less, and coal is a non-renewable resource, so that how to improve the combustion rate and the utilization rate of coal becomes a research focus.
Semi coke is a solid product of low-temperature destructive distillation step conversion in low-metamorphic coal, is determined to be a cleaner energy source, and has the characteristics of high fixed carbon, high chemical activity, low ash content, low aluminum, low sulfur, low phosphorus and the like. The semi-coke has better quality and combustion performance than anthracite, and has lower price than anthracite. The low-rank coal reserves in China are rich, the development of the semi-coke industry is the requirement of the national energy optimization strategy, the semi-coke has wide prospect and sufficient market. Based on the above excellent characteristics, the semi-coke has attracted high attention as an alternative fuel for domestic and foreign enterprises, and the semi-coke with low price is always explored as an alternative fuel. Although various coal additives and combustion improvers are available on the market, combustion improvers capable of really solving the problem of burning of semi-coke are not available, the semi-coke has a high burning ignition point, is extremely easy to burn incompletely and insufficiently in the burning process, and has high content of nitrogen oxides and sulfides generated by burning, so that environmental pollution is extremely easy to cause.
The invention patent with publication number CN102229835A provides an environment-friendly energy-saving combustion improver for coal, which can prolong the combustion time by adding various high-hardness solid metal oxides to ensure more complete combustion(ii) a The invention patents with publication numbers of CN106336929A, CN105132076A and CN111534356A use nano materials for combustion supporting, but the formulation components of the three patents are relatively complex, part of the substances are easy to generate toxic substances, the substances are easy to explode in the combustion process, and the industrial application effect is very limited; the invention patents with publication numbers of CN102453583A, CN102888260A and CN103146456A simplify the combustion improver of the industrial formula into four components, and although the invention patents have the characteristics of simple and convenient process, low cost and the like, the combustion improver has very limited combustion-supporting effect on the semi coke; the invention patent with publication number CN104987913A discloses a combustion improver added with activated carbon as a leavening agent and an adsorbent, wherein CaCl is added2Can improve the calcium-sulfur ratio and effectively reduce SO2The emission amount is reduced, but the formula cannot reduce the burning ignition point of the semi-coke; the invention patents with publication numbers CN104774671A, CN106753683A and CN108611155A add more than one oxidant in the combustion improver formula, but economically limit the application of the combustion improver in industry; in the invention patent with publication number CN 102517119A, sodium dodecyl benzene sulfonate with emulsification is added in the formula of combustion improver, but the industrial applicability of diesel oil and cyclopentadienylferrocene is not great in the formula.
Disclosure of Invention
In order to solve the problems in the background art, the invention provides a semi-coke combustion improver.
The semi-coke combustion improver is prepared by mixing the following components in percentage by weight: 1-3 parts of potassium permanganate, 3-5 parts of ammonium nitrate, 5-9 parts of calcium chloride, 1-5 parts of sodium dodecyl benzene sulfonate, 6-10 parts of basic copper carbonate and 30-50 parts of activated carbon.
Furthermore, the particle size of each component of the semi-coke combustion improver can pass through a 60-mesh sieve.
Further, the potassium permanganate accounts for 3 parts, the ammonium nitrate accounts for 5 parts, the calcium chloride accounts for 9 parts, the sodium dodecyl benzene sulfonate accounts for 5 parts, the basic copper carbonate accounts for 8-10 parts, and the activated carbon accounts for 30-50 parts.
Further, 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30-50 parts of active carbon.
Furthermore, the potassium permanganate accounts for 3 parts, the ammonium nitrate accounts for 5 parts, the calcium chloride accounts for 9 parts, the sodium dodecyl benzene sulfonate accounts for 5 parts, the basic copper carbonate accounts for 10 parts, and the activated carbon accounts for 30 parts.
When the semi-coke combustion improver is used, the semi-coke combustion improver and the semi-coke are mixed according to the weight ratio of 3: 100.
Compared with the prior art, the semi-coke combustion improver has the advantages that the types of the formula components are less, the formula component products are easy to obtain, and the cost is low; potassium permanganate added into the combustion improver has the characteristic of generating oxygen by decomposition, so that the peroxy combustion is realized during the burning of the semi coke, the proportion of incomplete burning of the semi coke is reduced, and the burnout rate is improved; calcium chloride and ammonium nitrate are added into the combustion improver, so that the ignition point of the semi-coke can be reduced, the ignition time can be shortened, and the calcium chloride can also combine with sulfur dioxide to play a role in reducing the emission of sulfides; basic copper carbonate is added into the combustion improver, and the basic copper carbonate is decomposed at high temperature to generate copper oxide, so that the reduction of nitric oxide into nitrogen and oxygen can be promoted, and the emission of nitrogen oxides is reduced; the combustion improver is added with sodium dodecyl benzene sulfonate and active carbon, and the sodium dodecyl benzene sulfonate is used as a surfactant to provide more adsorption sites for the active carbon to adsorb redundant nitric oxides and sulfides. Experiments prove that the semi-coke combustion improver can greatly reduce the ignition point of the semi-coke, reduce the burnout time of the semi-coke, ensure the complete and sufficient combustion of the semi-coke, and reduce the discharge amount of nitrogen oxide and sulfide gas generated by the combustion of the semi-coke.
Drawings
FIG. 1 is a TG curve of semi-coke combustion.
Detailed Description
The embodiments of the present invention will be described in detail with reference to the accompanying drawings, but the embodiments are not limited to the invention, and the advantages of the invention will be understood more clearly by the description. All modifications which can be derived or suggested by a person skilled in the art from the disclosure of the present invention are to be considered within the scope of the invention. The positional relationships described in the embodiments are all the same as those shown in the drawings, and other portions not described in detail in the embodiments are all the related art.
Example 1
The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 3 parts by weight of ammonium nitrate, 5 parts by weight of calcium chloride, 1 part by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of basic copper carbonate and 30 parts by weight of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The ignition point of the combustion is averagely reduced by 63 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 22 min.
Example 2
The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 3 parts by weight of ammonium nitrate, 7 parts by weight of calcium chloride, 3 parts by weight of sodium dodecyl benzene sulfonate, 8 parts by weight of basic copper carbonate and 30 parts by weight of active carbon. Adding into a pulverizer, pulverizing, and sieving with 60 mesh sieve to obtain powdered mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 66 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 4 percent, and the burnout time is averagely reduced by 22 min.
Example 3
The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 3 parts by weight of ammonium nitrate, 9 parts by weight of calcium chloride, 5 parts by weight of sodium dodecyl benzene sulfonate, 10 parts by weight of basic copper carbonate and 30 parts by weight of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 2 percent, and the burnout time is averagely reduced by 25 min.
Example 4
The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 4 parts by weight of ammonium nitrate, 5 parts by weight of calcium chloride, 1 part by weight of sodium dodecyl benzene sulfonate, 8 parts by weight of basic copper carbonate and 30 parts by weight of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point of the fuel is averagely reduced by 68 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 27 min.
Example 5
The semi-coke combustion improver consists of the following components in percentage by mass: adding 1 part by weight of potassium permanganate, 4 parts by weight of ammonium nitrate, 7 parts by weight of calcium chloride, 3 parts by weight of sodium dodecyl benzene sulfonate, 10 parts by weight of basic copper carbonate and 30 parts by weight of active carbon into a pulverizer, pulverizing, and sieving with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 69 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 2 percent, and the burnout time is averagely reduced by 25 min.
Example 6
The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 4 parts by weight of ammonium nitrate, 9 parts by weight of calcium chloride, 5 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of basic copper carbonate and 30 parts by weight of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 62 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 28 min.
Example 7
The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 5 parts by weight of ammonium nitrate, 5 parts by weight of calcium chloride, 1 part by weight of sodium dodecyl benzene sulfonate, 10 parts by weight of basic copper carbonate and 40 parts by weight of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 60 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 25 min.
Example 8
The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 5 parts by weight of ammonium nitrate, 7 parts by weight of calcium chloride, 3 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of basic copper carbonate and 30 parts by weight of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 32 min.
Example 9
The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 5 parts by weight of ammonium nitrate, 9 parts by weight of calcium chloride, 5 parts by weight of sodium dodecyl benzene sulfonate, 8 parts by weight of basic copper carbonate and 30 parts by weight of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 62 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 27 min.
Example 10
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 3 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 40 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 70 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 3 percent, and the burnout time is averagely reduced by 27 min.
Example 11
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 3 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 3 percent, and the burnout time is averagely reduced by 30 min.
Example 12
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 3 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point of the gas burner is averagely reduced by 71 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 33 min.
Example 13
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 4 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The ignition point of the combustion is averagely reduced by 63 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 2 percent, and the burnout time is averagely reduced by 32 min.
Example 14
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 4 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 32 min.
Example 15
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 4 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 50 parts of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 30 min.
Example 16
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 5 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point of the burner is averagely reduced by 68 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 2 percent, and the burnout time is averagely reduced by 31 min.
Example 17
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 5 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 69 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 5 percent, and the burnout time is averagely reduced by 34 min.
Example 18
The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 40 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 65 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 34 min.
Example 19
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 3 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point of the burner is averagely reduced by 68 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 30 min.
Example 20
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 3 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 2 percent, and the burnout time is averagely reduced by 33 min.
Example 21
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 3 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 5 percent, and the burnout time is averagely reduced by 28 min.
Example 22
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 4 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 6 percent, and the burnout time is averagely reduced by 28 min.
Example 23
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 4 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 73 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 33 min.
Example 24
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 74 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 34 min.
Example 25
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 62 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 34 min.
Example 26
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 40 parts of active carbon. Adding into a pulverizer, pulverizing, and sieving with 60 mesh sieve to obtain powdered mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 69 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 2 percent, and the burnout time is averagely reduced by 34 min.
Example 27
The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30 parts of active carbon. Adding into a pulverizer, pulverizing, and sieving with 60 mesh sieve to obtain powdered mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 75 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 6%, and the burnout time is averagely reduced by 35 min.
As described in the above-mentioned examples 24 and 27, when the components in the combustion improver are: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 8-10 parts of basic copper carbonate and 30 parts of active carbon, and particularly when the basic copper carbonate is 10 parts by weight, the burning effect of the semi coke is best.
The burning test is carried out on the semi-coke added with the combustion improver of the embodiment 27 and the semi-coke, the experimental group is the semi-coke added with the combustion improver of the embodiment 27, the comparison group is the semi-coke, the TG curve is shown in figure 1, the ignition point of the semi-coke added with the combustion improver is reduced by about 74 ℃, the burn-up rate is improved by about 6 percent, and the burning effect of the semi-coke is obviously improved.
The preferred embodiments of the present invention have been described in detail with reference to the accompanying drawings and specific examples, however, the present invention is not limited to the specific details of the above embodiments, and various simple modifications can be made to the technical solution of the present invention within the technical idea of the present invention, and these simple modifications are within the protective scope of the present invention.
Claims (5)
1. The semi-coke combustion improver is characterized by being prepared by mixing the following components in percentage by weight: 1-3 parts of potassium permanganate, 3-5 parts of ammonium nitrate, 5-9 parts of calcium chloride, 1-5 parts of sodium dodecyl benzene sulfonate, 6-10 parts of basic copper carbonate and 30-50 parts of activated carbon.
2. The semi-coke combustion improver as set forth in claim 1, wherein: the granularity of each component of the semi-coke combustion improver can pass through a 60-mesh sieve.
3. The semi-coke combustion improver as set forth in claim 2, wherein: the potassium permanganate is 3 parts, the ammonium nitrate is 5 parts, the calcium chloride is 9 parts, the sodium dodecyl benzene sulfonate is 5 parts, the basic copper carbonate is 8-10 parts, and the active carbon is 30-50 parts.
4. The semi-coke combustion improver as set forth in claim 3, wherein: the potassium permanganate is 3 parts, the ammonium nitrate is 5 parts, the calcium chloride is 9 parts, the sodium dodecyl benzene sulfonate is 5 parts, the basic copper carbonate is 10 parts, and the active carbon is 30-50 parts.
5. The semi-coke combustion improver as set forth in claim 4, wherein: the potassium permanganate is 3 parts, the ammonium nitrate is 5 parts, the calcium chloride is 9 parts, the sodium dodecyl benzene sulfonate is 5 parts, the basic copper carbonate is 10 parts, and the active carbon is 30 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110960049.1A CN113755224A (en) | 2021-08-20 | 2021-08-20 | Semi-coke combustion improver |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110960049.1A CN113755224A (en) | 2021-08-20 | 2021-08-20 | Semi-coke combustion improver |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113755224A true CN113755224A (en) | 2021-12-07 |
Family
ID=78790538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110960049.1A Pending CN113755224A (en) | 2021-08-20 | 2021-08-20 | Semi-coke combustion improver |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113755224A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998038266A1 (en) * | 1997-02-26 | 1998-09-03 | Coalcorp Pty. Ltd. | Coal additive |
| CN101265429A (en) * | 2008-05-05 | 2008-09-17 | 陈汉明 | Fire coal energy-saving additive |
| CN102061212A (en) * | 2009-11-16 | 2011-05-18 | 中冶建筑研究总院有限公司 | Fire coal efficient catalysis combustion-supporting agent and preparation method and use method thereof |
| CN102876423A (en) * | 2012-09-13 | 2013-01-16 | 马春萍 | Novel coal-saving combustion improver |
-
2021
- 2021-08-20 CN CN202110960049.1A patent/CN113755224A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998038266A1 (en) * | 1997-02-26 | 1998-09-03 | Coalcorp Pty. Ltd. | Coal additive |
| CN101265429A (en) * | 2008-05-05 | 2008-09-17 | 陈汉明 | Fire coal energy-saving additive |
| CN102061212A (en) * | 2009-11-16 | 2011-05-18 | 中冶建筑研究总院有限公司 | Fire coal efficient catalysis combustion-supporting agent and preparation method and use method thereof |
| CN102876423A (en) * | 2012-09-13 | 2013-01-16 | 马春萍 | Novel coal-saving combustion improver |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102115688A (en) | High-efficiency energy-saving emission-reduction additive for burning coal | |
| CN102199466B (en) | Coal-saving combustion-supporting additive | |
| CN102796583B (en) | Efficient clean briquette coal and preparation method thereof | |
| CN101658757A (en) | High-efficiency environmental-friendly coal-saving sulphur-fixing antismoke agent and production technology thereof | |
| CN101372642B (en) | Efficient coal combustion energy-saving combustion adjuvant and preparation thereof | |
| CN104028306A (en) | Coal combustion composite catalyst | |
| CN103173260A (en) | Combustion improver and fuel made of same as well as fuel production method and application | |
| CN101921645A (en) | New application of calcium peroxide and fire coal combustion-supporting solid sulfide additive | |
| CN102618348B (en) | Coal-saving denitration combustion improver for cement industry | |
| CN1193042A (en) | High-energy sweetening coal-saving agent | |
| Peng et al. | Combustion Characteristics and NO Emissions during Co-Combustion of Coal Gangue and Coal Slime in O2/CO2 Atmospheres | |
| CN113755224A (en) | Semi-coke combustion improver | |
| CN1274793C (en) | Clean coal burning catalyst | |
| CN114410362B (en) | Biomass-based fire coal additive and application thereof | |
| CN101225343A (en) | Coal-saving combustion-supporting additive | |
| CN102585968B (en) | Nanometer composite coal-economizing agent for power plant boiler | |
| CN1420159A (en) | High-efficiency coal-fired additive | |
| CN101434885A (en) | Multiple-effect coal fines additive and efficient clean fire coal powder prepared thereby | |
| Tian et al. | Enhancing combustion efficiency and reducing nitrogen oxide emissions from ammonia combustion: A comprehensive review | |
| CN104293411B (en) | Preparation method of coal combustion catalyst | |
| CN114479981B (en) | Low-dosage high-efficiency coal-saving agent and preparation method thereof | |
| CN102643705A (en) | Coal combustion-supporting hydrogel as well as preparation method and application thereof | |
| CN103194293B (en) | Method for improving combustion speed of coal | |
| CN112662447B (en) | Nano coal additive and preparation method thereof | |
| CN115537246A (en) | Accelerant for thermal power generation, smelting and thermal power plant processes of raw coal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211207 |
|
| RJ01 | Rejection of invention patent application after publication |