CN102199466B - Coal-saving combustion-supporting additive - Google Patents

Coal-saving combustion-supporting additive Download PDF

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Publication number
CN102199466B
CN102199466B CN 201110100217 CN201110100217A CN102199466B CN 102199466 B CN102199466 B CN 102199466B CN 201110100217 CN201110100217 CN 201110100217 CN 201110100217 A CN201110100217 A CN 201110100217A CN 102199466 B CN102199466 B CN 102199466B
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coal
powder
additive
saving
burning
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CN 201110100217
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CN102199466A (en
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徐福明
邱瑜铭
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Jiangsu Feng Tai Tools Co., ltd
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Jiangsu Fengtai Diamond Tool Manufacture Co Ltd
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Abstract

The invention provides a coal-saving combustion-supporting additive which is composed of the following components: 12-18wt% of combustion supporting agent, 35-58wt% of oxidant, 8-22wt% of fluxing agent, 8-20wt% of dispersant, 3-8wt% of sulfur fixing agent and 2-5wt% of carbon fixing agent. The addition of the coal-saving combustion-supporting additive can save coal by 12-18wt% and greatly reduce the discharge of sulfides and carbides.

Description

Coal-saving burning additive
Technical field
The present invention relates to a kind of fuel combustion additive, more particularly, relate to a kind of coal combustion additive.
Background technology
China's energy up to now, can account for the share more than 70% take coal as main in primary energy source consists of.Along with being on the rise of global energy shortage and environmental pollution, energy-conservation, reduction of discharging has become one of difficult problem that must face in development of all countries economy.The coal of China forms because of extra large land alternating deposit mostly, and sulphur content is generally higher, and after burning, major pollutants discharged have sulfurous gas, soot dust granule thing, oxynitride and carbon monoxide in the atmospheric environment.According to statistics, for a long time, due to coal burn incompletely in various boilers, both caused a large amount of wastings of resources, again serious pollution environment, approximately 90% sulfurous gas and approximately 96% flue dust all directly from coal combustion.As everyone knows, the ultimate analysis of coal shows, the flammable and non-flammable complex material that coal is comprised of multiple elements such as carbon, hydrogen, oxygen, nitrogen, sulphur, phosphorus, and burning of coal is these complex compounds, the physics of mixture complexity, chemical reaction process.When people utilize coal to obtain heat energy in the past, can only be extensive make it at combustion synthesis in air, still can not reasonably utilize with the burning of science, be to cause not only to waste coal resources, but also one of the reason of major polluting atmosphere environment.For this reason, preventing coal-smoke pollution, is the most urgent task of environment protection, and its prevention emphasis is sulfurous gas and the soot dust granule thing in atmosphere; And improve the burning of coal performance, be realize in coal burning energy-conservation, one of major way of reduction of discharging.
It is reported, 2010 national SO 2Quantity discharged is up to more than 2,500 ten thousand tons, NO XQuantity discharged is estimated as more than 2,000 ten thousand tons, CO, CO 2Quantity discharged is up to more than 5,000 ten thousand tons, and the annual whole nation is because of acid rain, SO 2With CO, CO 2On the financial loss that pollution causes 100,000,000,000 yuan, to acid rain, SO 2, NO XWith CO, CO 2The control of polluting, the out of stock decarburization technique of desulfurization of countries in the world exploitation at present has into more than hundred kinds of methods, but can be applied to the less than 10% of business, and some is that investment is large, and function is low, and removal effect is poor, and some is to be difficult to exploitation on using.Along with the development of Chinese national economy, the demand of electricity is increased significantly, greatly increased the consumption of coal, discharged a large amount of CO, CO in combustion processes due to coal 2And SO 2, NO XDeng pollutent, therefore, the cleanburning technology of coal has become the development priority of industry.
The present inventor has developed at a kind of environmentally friendly program additive based on for many years experience and long-term experimental study, and it has also significantly reduced the quantity discharged of sulfide and oxynitride when improving coal combustion efficient.
Summary of the invention
The objective of the invention is for a kind of environmentally friendly coal-saving burning additive is provided, the 12-18wt% that can economize on coal after coal-saving burning additive of the present invention joins in fire coal, and can significantly reduce the discharging of sulfide and carbide.
In order to achieve the above object, the invention provides a kind of coal-saving burning additive, the composition of coal-saving burning additive and proportioning are: ignition dope: 12-18wt%; Oxygenant: 35-58wt%; Fusing assistant: 8-22wt%; Dispersion agent: 8-20wt%; Sulphur-fixing agent: 3-8wt%; Charcoal consolidating agent: 2-5wt%; Wherein, described ignition dope selects in the group of free wood chip, gac, aluminium powder or magnesium powder composition; Described oxygenant selects in the group that the nitrate of free Manganse Dioxide, hypochlorite, permanganate or alkaline-earth metal forms; Described fusing assistant selects in the group of free iron powder, ferrosilicon powder, ferromanganese powder or titanium-iron powder composition; Described dispersion agent selects in the group of free sodium-chlor, Repone K, perlite or slag powders composition; Described sulphur-fixing agent selects in the group that free manganese, zinc, barium or calcium chloride forms; Described charcoal consolidating agent selects in the group that the hydroxides of free alkaline-earth metal forms.
Preferably, ignition dope wherein is gac and aluminium powder, selects the composite burning-point that can further reduce fire coal both.
Preferably, oxygenant wherein is the nitrate of Manganse Dioxide and permanganate or alkaline-earth metal, selection contains the composite process that can further improve oxidizing reaction of Manganse Dioxide, by the katalysis of Manganse Dioxide, can significantly improve the thermo-efficiency of fired coal combustion.
Preferably, fusing assistant wherein is ferromanganese powder or ferrosilicon powder, and the degree of oxidation that fusing assistant wherein can oxidation reinforced dose promotes the abundant burning of the combustiblematerials in fire coal.
Preferably, dispersion agent wherein is sodium-chlor and Repone K, perhaps perlite and slag powders.
Preferably, wherein sulphur-fixing agent is barium and calcium chloride.
Preferably, wherein charcoal consolidating agent is calcium hydroxide and magnesium hydroxide.
Concrete, the composition of coal-saving burning additive of the present invention and proportioning are: gac: the nitrate of 3-12wt%, aluminium powder: 3-9wt%, Manganse Dioxide: 5-12wt%, potassium permanganate: 8-15wt%, alkaline-earth metal: 8-45wt%, iron powder or ferrosilicon powder powder or ferromanganese powder or titanium-iron powder: 8-22wt%, perlite: 3-12wt%, 5-15wt%, barium powder or zinc powder: 2-5wt%, calcium chloride: 1-5wt%, calcium hydroxide: 1-3wt%, magnesium hydroxide: 1-3wt%.
Preferably, the composition of coal-saving burning additive of the present invention and proportioning are: gac: 8wt%, aluminium powder: 4wt%, Manganse Dioxide: 6wt%, potassium permanganate: 10wt%, nitrocalcite: 42wt%, ferromanganese powder: 12wt%, perlite: 6wt%, slag powders: 6wt%, barium powder: 2wt%, calcium chloride: 2wt%, calcium hydroxide: 1wt%, magnesium hydroxide: 1wt%.
Preferably, the composition of coal-saving burning additive of the present invention and proportioning are: gac: 8wt%, aluminium powder: 4wt%, Manganse Dioxide: 6wt%, potassium permanganate: 12wt%, nitrocalcite: 40wt%, ferrosilicon powder: 10wt%, perlite: 8wt%, slag powders: 4wt%, barium powder: 3wt%, calcium chloride: 1wt%, calcium hydroxide: 3wt%, magnesium hydroxide: 1wt%.
Coal-saving burning additive of the present invention can be milled to by the raw material ball of above-mentioned substance the 80-120 order, and then mixing and stirring obtains.
Ignition dope in coal-saving burning additive of the present invention, especially can significantly reduce coal-fired burning-point adding of gac and aluminium powder, the burning of gac and aluminium powder is violent and abundant, thereby has ignited the burning of combustiblematerials in coal, improve efficiency of combustion, also reduced the generation of black smoke.
Oxygenant in coal-saving burning additive of the present invention and fusing assistant, can react under the period in different temperature, by these strong oxidizers, the mixing effect that comprises fusing assistant, make coal-fired after entering burner hearth, be among strong cartalytic decomposition effect, the combustiblematerials sufficient combustion in fire coal, thus reach the purpose that improves efficiency of combustion, saves fire coal.
Dispersion agent in coal-saving burning additive of the present invention, play stabilization in the manufacturing of this product, can suppress the reaction between strong oxidizer, guaranteed the safety in production, transportation, storage and use, and can play bulk effect after entering boiler with coal in the coal seam, make the oxygen in the coal seam supply with abundance, avoided burning because oxygen is not enough insufficient.
Sulphur-fixing agent in coal-saving burning additive of the present invention, generate precipitation with former should reacting with cigarette expellant gas sulfide, particularly adopt the composite of barium powder and calcium chloride, it can react with various gaseous sulfides, thereby has greatly reduced sulphur dioxide emission.
Charcoal consolidating agent in coal-saving burning additive of the present invention, can with CO or CO 2The Formed hydrochlorate that reacts, thus can realize reducing the purpose of carbon emission.
Mix the coal-saving burning additive of 0.2-0.8wt% during use in fire coal.reduced coal-fired point of ignition after adding coal-saving burning additive of the present invention, accelerated burning of coal speed, improve fire box temperature, through test, thermo-efficiency has generally improved 2-5%, and strengthened heat transfer process, impel coal at the boiler furnace stratified combustion, obviously improve the burning subenvironment, strengthened the oxygenizement of coal, emit nascent state oxygen in intensification heat-processed, inflammable gas in the after-flame flue gas and toner suspension have been played keying action, thereby consumption and the oke exhaust blackness of coal have been reduced, ignition dope of the present invention at high temperature decomposes, gasification and generation microexplosion, stir the gas in coal seam and coal seam, make the coal seam of hardening loose, ventilation improves, oxygen is evenly distributed in the coal seam, in liberal supply, it is easy to make coal to disperse, surfactivity increases, increase with the contact area of oxygen, be beneficial to the abundant burning of coal dust, through test, add ignition dope of the present invention in fire coal, can save the fire coal of 12-18%.
Embodiment
Below in conjunction with specific embodiment, the present invention is further elaborated.
Embodiment 1
The composition of coal-saving burning additive of the present invention and proportioning are: gac: 8wt%, magnesium powder: 4wt%, clorox: 6wt%, potassium permanganate: 10wt%, nitrocalcite: 42wt%, iron powder: 12wt%, perlite: 6wt%, slag powders: 6wt%, barium powder: 2wt%, calcium chloride: 2wt%, calcium hydroxide: 1wt%, magnesium hydroxide: 1wt%.
Embodiment 2
The composition of coal-saving burning additive of the present invention and proportioning are: wood chip: 6wt%, magnesium powder: 6wt%, clorox: 10wt%, potassium permanganate: 12wt%, nitrocalcite: 36wt%, iron powder: 12wt%, perlite: 6wt%, slag powders: 6wt%, zinc powder: 1wt%, calcium chloride: 1wt%, calcium hydroxide: 2wt%, magnesium hydroxide: 2wt%.
Embodiment 3
The composition of coal-saving burning additive of the present invention and proportioning are: wood chip: 8wt%, magnesium powder: 4wt%, clorox: 10wt%, potassium permanganate: 12wt%, nitrocalcite: 36wt%, iron powder: 12wt%, sodium-chlor: 6wt%, Repone K: 6wt%, manganese powder: 4wt%, calcium hydroxide: 2wt%.
Embodiment 4
The composition of coal-saving burning additive of the present invention and proportioning are: wood chip: 5wt%, magnesium powder: 7wt%, clorox: 10wt%, potassium permanganate: 10wt%, nitrocalcite: 38wt%, titanium-iron powder: 12wt%, sodium-chlor: 8wt%, Repone K: 4wt%, manganese powder: 3wt%, magnesium hydroxide: 3wt%.
Embodiment 5
The composition of coal-saving burning additive of the present invention and proportioning are: gac: 8wt%, aluminium powder: 4wt%, Manganse Dioxide: 6wt%, potassium permanganate: 10wt%, nitrocalcite: 42wt%, ferromanganese powder: 12wt%, perlite: 6wt%, slag powders: 6wt%, barium powder: 2wt%, calcium chloride: 2wt%, calcium hydroxide: 1wt%, magnesium hydroxide: 1wt%.
Embodiment 6
The composition of coal-saving burning additive of the present invention and proportioning are: gac: 8wt%, aluminium powder: 4wt%, Manganse Dioxide: 6wt%, potassium permanganate: 12wt%, nitrocalcite: 40wt%, ferrosilicon powder: 10wt%, perlite: 8wt%, slag powders: 4wt%, barium powder: 3wt%, calcium chloride: 1wt%, calcium hydroxide: 3wt%, magnesium hydroxide: 1wt%.
The described coal-saving burning additive of embodiment 1-6 is mixed in fire coal in the ratio of the 0.2-0.8wt% of coal consumption, first with after 5-15 water dilution dissolving doubly, then mixes in coal and stir during use, coal-fired need with how many these additives namely dilute dissolving what; How many water ratio of visual coal regulates moisture in coal, and as the higher water consumption that can reduce in right amount the dilution solubilising additive of water ratio of coal, after generally this additive infiltrates, the water ratio of coal remains on about 8-10wt% best; Also can directly mix described coal-saving burning additive in coal and stir use.
With the coal-saving burning additive that above embodiment obtains, the burning contrast test by coal firing boiler can draw following result:
(1) thermal efficiency ratio that is added with coal-saving burning additive has improved 8.2-15wt% than the thermo-efficiency that adds, and particularly preferred embodiment 5-6, improved 13-15wt%.
(2) be added with the coal combustion of coal-saving burning additive abundant, the combustiblematerials after burning in the ash quarrel is lower than the combustiblematerials in the ash quarrel of the fire coal that does not add additive.
(3) coal that is added with coal-saving burning additive is than raw coal unit consumption descended 7-15wt%, particularly preferred embodiment 5-6, and 13-15wt% has descended.
(4) coal that is added with coal-saving burning additive has reduced 30-60wt% than the gas vulcanization compound of raw coal, preferred embodiment 5-6 particularly, and 50-60wt% has descended.
(5) more than the coal that is added with coal-saving burning additive has reduced 75wt% than the soot dust granule thing of raw coal.

Claims (2)

1. a coal-saving burning additive, is characterized in that the composition of described coal-saving burning additive and proportioning are: gac: 8wt%, aluminium powder: 4wt%, Manganse Dioxide: 6wt%, potassium permanganate: 10wt%, nitrocalcite: 42wt%, ferromanganese powder: 12wt%, perlite: 6wt%, slag powders: 6wt%, barium powder: 2wt%, calcium chloride: 2wt%, calcium hydroxide: 1wt%, magnesium hydroxide: 1wt%.
2. a coal-saving burning additive, is characterized in that the composition of described coal-saving burning additive and proportioning are: gac: 8wt%, aluminium powder: 4wt%, Manganse Dioxide: 6wt%, potassium permanganate: 12wt%, nitrocalcite: 40wt%, ferrosilicon powder: 10wt%, perlite: 8wt%, slag powders: 4wt%, barium powder: 3wt%, calcium chloride: 1wt%, calcium hydroxide: 3wt%, magnesium hydroxide: 1wt%.
CN 201110100217 2011-04-21 2011-04-21 Coal-saving combustion-supporting additive Expired - Fee Related CN102199466B (en)

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CN102517120B (en) * 2011-12-27 2014-07-02 长春市奥地特科技有限公司 Fuel coal additive
CN103320195B (en) * 2013-05-29 2016-02-10 上海绿达节能科技有限公司 A kind of coal additive
CN103436323B (en) * 2013-08-15 2015-04-15 广州高成环保科技有限公司 Coal-saving combustion improver
CN103468344B (en) * 2013-08-27 2015-01-28 广州高成环保科技有限公司 Oxygen producer for increasing coal burn-off rate
CN103555390B (en) * 2013-10-11 2015-08-12 沈阳建筑大学 A kind ofly improve additive of domestic garbage derived fuel calorific value and preparation method thereof
CN104651012B (en) * 2013-11-18 2017-11-10 广西桂晟新能源科技有限公司 A kind of fire coal energy-saving emission-reducing additive
CN103666632A (en) * 2013-12-26 2014-03-26 常熟市第二热电有限公司 Solid coal combustion improver and preparation method thereof
CN104087692B (en) * 2014-07-21 2016-05-18 武钢集团昆明钢铁股份有限公司 A kind of blast-furnace coal-injection combustion improver and using method thereof
CN105238495B (en) * 2015-10-30 2017-11-07 湖南和易环保科技有限公司 Eliminate the additive and its production technology and technique for applying of dioxin in waste incineration
CN105969447A (en) * 2016-03-22 2016-09-28 安徽徽明建设集团有限公司 Biomass briquette with cornstalk as base material and manufacturing method thereof
CN105755300B (en) * 2016-04-26 2018-04-24 沧州东盛金属添加剂制造有限公司 A kind of aluminium alloy chrome additive
CN107740113A (en) * 2017-11-10 2018-02-27 威海翔泽新材料科技有限公司 Boiler fire side corrosion inhibitor
CN111530265A (en) * 2020-05-08 2020-08-14 福建道远节能环保科技有限公司 Sintering tail gas carbon monoxide emission reduction additive, preparation method and addition method thereof
CN111996052A (en) * 2020-07-10 2020-11-27 广西夏阳环保科技有限公司 Special briquette for water treatment lime and preparation method thereof

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