CN113754282A - Metal enamel glaze with milky glaze and preparation method thereof - Google Patents
Metal enamel glaze with milky glaze and preparation method thereof Download PDFInfo
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- CN113754282A CN113754282A CN202111191763.5A CN202111191763A CN113754282A CN 113754282 A CN113754282 A CN 113754282A CN 202111191763 A CN202111191763 A CN 202111191763A CN 113754282 A CN113754282 A CN 113754282A
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- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 34
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 24
- 239000002184 metal Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000000227 grinding Methods 0.000 claims abstract description 20
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 16
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010431 corundum Substances 0.000 claims abstract description 13
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 13
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 10
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010453 quartz Substances 0.000 claims abstract description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract description 9
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 9
- 229910000423 chromium oxide Inorganic materials 0.000 claims abstract description 9
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 9
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010436 fluorite Substances 0.000 claims abstract description 9
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 9
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims abstract description 9
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052582 BN Inorganic materials 0.000 claims abstract description 8
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 8
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005751 Copper oxide Substances 0.000 claims abstract description 8
- 235000019738 Limestone Nutrition 0.000 claims abstract description 8
- 229910052656 albite Inorganic materials 0.000 claims abstract description 8
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000010428 baryte Substances 0.000 claims abstract description 8
- 229910052601 baryte Inorganic materials 0.000 claims abstract description 8
- 229910021538 borax Inorganic materials 0.000 claims abstract description 8
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 8
- 239000006028 limestone Substances 0.000 claims abstract description 8
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 8
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 8
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 8
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 8
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 229910052573 porcelain Inorganic materials 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 235000012239 silicon dioxide Nutrition 0.000 claims description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- 238000000498 ball milling Methods 0.000 claims description 5
- 239000004570 mortar (masonry) Substances 0.000 claims description 5
- 238000010791 quenching Methods 0.000 claims description 5
- 230000000171 quenching effect Effects 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- RCMWGBKVFBTLCW-UHFFFAOYSA-N barium(2+);dioxido(dioxo)molybdenum Chemical compound [Ba+2].[O-][Mo]([O-])(=O)=O RCMWGBKVFBTLCW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052810 boron oxide Inorganic materials 0.000 claims description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000004907 flux Effects 0.000 claims 2
- 239000000454 talc Substances 0.000 claims 2
- 229910052623 talc Inorganic materials 0.000 claims 2
- 239000000919 ceramic Substances 0.000 abstract description 2
- 238000005299 abrasion Methods 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 14
- 239000002253 acid Substances 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000002320 enamel (paints) Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/04—Opaque glass, glaze or enamel
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2205/00—Compositions applicable for the manufacture of vitreous enamels or glazes
- C03C2205/02—Compositions applicable for the manufacture of vitreous enamels or glazes for opaque enamels or glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to the technical field of ceramic preparation, in particular to a metal enamel glaze with milky overglaze and a preparation method thereof, wherein the glaze comprises overglaze and ground glaze, and the overglaze comprises the following materials in parts by weight: 16-24 parts of quartz, 22-28 parts of albite, 12-18 parts of fluorite, 6-12 parts of barite, 5-15 parts of calcite, 15-20 parts of limestone, 5-8 parts of borax, 6-10 parts of soda ash, 4-8 parts of sodium nitrate, 2-6 parts of sodium fluosilicate, 4-10 parts of titanium oxide, 2-5 parts of cobalt oxide, 4-8 parts of nickel oxide, 2-4 parts of copper oxide, 3-8 parts of chromium oxide, 8-12 parts of zirconium dioxide, 12-15 parts of corundum particles, 16-18 parts of fluxing agent and 10-20 parts of grinding material; wherein the abrasive comprises silicon carbide and boron nitride. The metal enamel glaze prepared by the invention has good mechanical properties, and can resist abrasion, high temperature and corrosion.
Description
Technical Field
The invention relates to the technical field of ceramic preparation, in particular to a metal enamel glaze with milky overglaze and a preparation method thereof.
Background
Enamels originate from decorations, also known as enamels. Due to the limitation of the materials used, the method is limited to the manufacture of artware for a long time. Until the 18 th century, cast iron enamels appeared, and then rapid development of such commodities was achieved. The main components and structure of the enamel are consistent with those of glass, the disordered silicon-oxygen network structure of the enamel determines that the strain tolerance and fracture toughness of the enamel are low, the enamel is highly sensitive to cracks, and the enamel is easy to crack and peel due to the accumulation of thermal stress in the thermal cycle process, which is one of the main restriction factors of the enamel coating applied under the condition of high-temperature thermal shock. In addition, the glass phase in the enamel does not have a fixed melting point, when the temperature is higher than the glass transition point, the coating slowly changes from a solid state (glass state) to a liquid state (high elastic state or even molten state), and the barrier effect of the softened enamel coating on corrosive media (such as oxygen, sulfur, chlorine, molten metal, deposited salt and the like) is obviously reduced, so that the protection effect is lost, and the quality and the service life of the product are seriously reduced.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a metal enamel glaze with milky overglaze and a preparation method thereof.
The purpose of the invention is realized by the following technical scheme:
a metal enamel glaze with a milky glaze comprises a glaze and a ground glaze, wherein the glaze comprises the following materials in parts by weight: 16-24 parts of quartz, 22-28 parts of albite, 12-18 parts of fluorite, 6-12 parts of barite, 5-15 parts of calcite, 15-20 parts of limestone, 5-8 parts of borax, 6-10 parts of soda ash, 4-8 parts of sodium nitrate, 2-6 parts of sodium fluosilicate, 4-10 parts of titanium oxide, 2-5 parts of cobalt oxide, 4-8 parts of nickel oxide, 2-4 parts of copper oxide, 3-8 parts of chromium oxide, 8-12 parts of zirconium dioxide, 12-15 parts of corundum particles, 16-18 parts of fluxing agent and 10-20 parts of grinding material; wherein the abrasive comprises silicon carbide and boron nitride.
Further, the overglaze comprises the following materials in parts by weight: 18 parts of quartz, 26 parts of albite, 15 parts of fluorite, 10 parts of barite, 12 parts of calcite, 18 parts of limestone, 6 parts of borax, 8 parts of soda ash, 6 parts of sodium nitrate, 5 parts of sodium fluosilicate, 7 parts of titanium oxide, 3 parts of cobalt oxide, 6 parts of nickel oxide, 3 parts of copper oxide, 6 parts of chromium oxide, 10 parts of zirconium dioxide, 14 parts of corundum particles, 17 parts of fluxing agent and 15 parts of grinding material.
Further, the abrasive is composed of silicon carbide and boron nitride in a weight ratio of 4: 1.
Further, the fluxing agent is composed of calcium carbonate, talcum powder and silicon dioxide.
Further, the fluxing agent is composed of calcium carbonate, talcum powder and silicon dioxide according to the weight ratio of 3:5: 2.
Further, the particle size of the corundum particles is 10-18 μm.
Further, the ground glaze comprises the following raw materials in parts by weight: 14-20 parts of silicon dioxide, 19-24 parts of quartz, 6-10 parts of barium molybdate and 4-8 parts of boron oxide.
Further, the preparation method comprises the following steps: weighing the raw materials in parts by weight, grinding the raw materials uniformly in a mortar at the temperature of 1100-1200 ℃, sieving the ground raw materials with a 60-mesh sieve, putting the ground raw materials into a small crucible, preserving the heat for 1.2-1.5h to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold water for quenching, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a 100 ℃ drying box for drying for 1h, putting the dried porcelain glaze into a ball milling tank, adding the grinding material, adding 50% of water, grinding for 14min, and pouring the ground slurry out of the 40-mesh sieve.
The invention has the beneficial effects that:
(1) the corundum particles are added, the corundum particles can enhance the network structure and physical impedance capability of the glaze to improve the high-temperature protection capability of the enamel glaze, and can control the type and size of crystals and adjust the thermal physical performance of the glaze by changing the crystallization behavior of enamel.
(2) The added chromium oxide and zirconium dioxide can remarkably improve the acid and alkali resistance of the glaze, and the excellent high-temperature performance of the zirconium dioxide can also improve the thermal shock resistance of the glaze; the cobalt oxide and the nickel oxide are used as the adhesive in the glaze, so that the adhesive force of the glaze on the metal surface can be effectively improved, and the high-temperature resistance of the glaze can be improved; titanium oxide, fluorite and sodium fluosilicate are used as coloring agents in the glaze, the milky color of the glaze is improved, and the function of beautifying the appearance is achieved.
Detailed Description
The technical solution of the present invention is further described in detail with reference to the following specific examples, but the scope of the present invention is not limited to the following.
Example 1
A method for preparing the metal enamel glaze with milky overglaze, comprising the steps of: weighing 16 parts of quartz, 22 parts of albite, 12 parts of fluorite, 6 parts of barite, 5 parts of calcite, 15 parts of limestone, 5 parts of borax, 6 parts of soda ash, 4 parts of sodium nitrate, 2 parts of sodium fluosilicate, 4 parts of titanium oxide, 2 parts of cobalt oxide, 4 parts of nickel oxide, 2 parts of copper oxide, 3 parts of chromium oxide, 8 parts of zirconium dioxide, 12 parts of corundum particles, 4 parts of calcium carbonate, 9 parts of talcum powder, 3 parts of silicon dioxide, 8 parts of silicon carbide and 2 parts of boron nitride according to parts by weight, putting the mixture into a mortar at the temperature of 1100 ℃, grinding the mixture uniformly, sieving the mixture through a 60-mesh sieve, putting the mixture into a small crucible, preserving the temperature for 1.2 to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold water for quenching, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a drying oven at the temperature of 100 ℃, putting into a ball milling tank, adding the grinding materials, adding 50% of water, grinding for 14min, pouring the ground slurry out of 40 meshes, obtaining the metal enamel glaze with the milky overglaze.
Example 2
A method for preparing the metal enamel glaze with milky overglaze, comprising the steps of: weighing 18 parts of quartz, 26 parts of albite, 15 parts of fluorite, 10 parts of barite, 12 parts of calcite, 18 parts of limestone, 6 parts of borax, 8 parts of soda ash, 6 parts of sodium nitrate, 5 parts of sodium fluosilicate, 7 parts of titanium oxide, 3 parts of cobalt oxide, 6 parts of nickel oxide, 3 parts of copper oxide, 6 parts of chromium oxide, 10 parts of zirconium dioxide, 14 parts of corundum particles, 4 parts of calcium carbonate, 10 parts of talcum powder, 3 parts of silicon dioxide, 12 parts of silicon carbide and 3 parts of boron nitride according to parts by weight, putting the mixture into a mortar at the temperature of 1150 ℃, grinding the mixture uniformly, sieving the mixture through a 60-mesh sieve, putting the mixture into a small crucible, preserving the temperature for 1.3 hours to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold quenching water for crushing, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a drying box at the temperature of 100 ℃, drying the mixture for 1 hour, putting the mixture into a ball milling tank, adding the grinding materials, adding 50 percent of water, grinding for 14 minutes, pouring the ground slurry out of 40-mesh sieve, obtaining the metal enamel glaze with the milky overglaze.
Example 3
A method for preparing the metal enamel glaze with milky overglaze, comprising the steps of: weighing 24 parts of quartz, 28 parts of albite, 18 parts of fluorite, 12 parts of barite, 15 parts of calcite, 20 parts of limestone, 8 parts of borax, 10 parts of soda ash, 8 parts of sodium nitrate, 6 parts of sodium fluosilicate, 10 parts of titanium oxide, 5 parts of cobalt oxide, 8 parts of nickel oxide, 4 parts of copper oxide, 8 parts of chromium oxide, 12 parts of zirconium dioxide, 15 parts of corundum particles, 5 parts of calcium carbonate, 11 parts of talcum powder, 2 parts of silicon dioxide, 16 parts of silicon carbide and 4 parts of boron nitride according to parts by weight, putting the mixture into a mortar at 1200 ℃, grinding the mixture uniformly, sieving the mixture through a 60-mesh sieve, putting the mixture into a small crucible, preserving the temperature for 1.5 hours to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold water for quenching, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a drying oven at 100 ℃ for drying for 1 hour, putting into a ball milling tank, adding the grinding materials, adding 50% of water, grinding for 14 minutes, pouring the ground slurry out of 40 meshes, obtaining the metal enamel glaze with the milky overglaze.
Comparative example
The raw materials and preparation methods of this comparative example and example 2 are substantially the same, except that this comparative example does not contain corundum particles.
The metal enamel frits manufactured in examples 1 to 3 and comparative example were tested for heat resistance and acid resistance, and the results are shown in the following table 1:
test results
TABLE 1
The heat resistance test method comprises the following steps: GB11418-89 test method for enamel heat resistance;
the test method of the acid resistance comprises the following steps: the method comprises the steps of adding 10g of citric acid into 100mL of distilled water to prepare a 10% citric acid solution, overlapping three pieces of filter paper on a test board, dripping the citric acid solution by using a dropper to moisten the filter paper, standing for 15min at normal temperature, removing the filter paper, cleaning the glaze surface on the filter paper by using water, wiping the glaze surface with dry cloth, and then drawing three lines at the position by using a 3B pencil, wherein the dry cloth can wipe off the trace of the pencil and has the acid resistance AA; the dry cloth cannot be used, but the wet cloth can wipe off the pencil marks and resist the acid A level; the pencil marks can not be wiped off by dry and wet cloth, and the reagent is resistant to the acid B (AA: the best acid resistance; A: the moderate acid resistance; B: the poor acid resistance).
From table 1 above, it can be seen that the data of example 2 is better and is the most preferred example, and that the addition of rigid particles has a greater effect on both the heat resistance and the acid resistance of the glaze.
The foregoing is illustrative of the preferred embodiments of this invention, and it is to be understood that the invention is not limited to the precise form disclosed herein and that various other combinations, modifications, and environments may be resorted to, falling within the scope of the concept as disclosed herein, either as described above or as apparent to those skilled in the relevant art. And that modifications and variations may be effected by those skilled in the art without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (8)
1. The metal enamel glaze with the milky glaze comprises a glaze layer and a ground glaze, and is characterized in that the glaze layer comprises the following materials in parts by weight: 16-24 parts of quartz, 22-28 parts of albite, 12-18 parts of fluorite, 6-12 parts of barite, 5-15 parts of calcite, 15-20 parts of limestone, 5-8 parts of borax, 6-10 parts of soda ash, 4-8 parts of sodium nitrate, 2-6 parts of sodium fluosilicate, 4-10 parts of titanium oxide, 2-5 parts of cobalt oxide, 4-8 parts of nickel oxide, 2-4 parts of copper oxide, 3-8 parts of chromium oxide, 8-12 parts of zirconium dioxide, 12-15 parts of corundum particles, 16-18 parts of fluxing agent and 10-20 parts of grinding material; wherein the abrasive comprises silicon carbide and boron nitride.
2. The metal enamel glaze with milky glaze according to claim 1, wherein the glaze comprises the following materials in parts by weight: 18 parts of quartz, 26 parts of albite, 15 parts of fluorite, 10 parts of barite, 12 parts of calcite, 18 parts of limestone, 6 parts of borax, 8 parts of soda ash, 6 parts of sodium nitrate, 5 parts of sodium fluosilicate, 7 parts of titanium oxide, 3 parts of cobalt oxide, 6 parts of nickel oxide, 3 parts of copper oxide, 6 parts of chromium oxide, 10 parts of zirconium dioxide, 14 parts of corundum particles, 17 parts of fluxing agent and 15 parts of grinding material.
3. The metal enamel glaze with milky overglaze according to claim 1 or 2, wherein the abrasive consists of silicon carbide and boron nitride in a weight ratio of 4: 1.
4. The metal enamel glaze with opalescent overglaze according to claim 1, wherein the flux is composed of calcium carbonate, talc and silica.
5. The metal enamel glaze with milky overglaze according to claim 4, wherein the flux is composed of calcium carbonate, talc and silica in a weight ratio of 3:5: 2.
6. The metal enamel frit with an opalescent glaze according to claim 1, wherein the corundum particles have a particle size of 10 to 18 μm.
7. The metal enamel glaze with the milky overglaze according to claim 1, wherein the ground glaze comprises the following raw materials in parts by weight: 14-20 parts of silicon dioxide, 19-24 parts of quartz, 6-10 parts of barium molybdate and 4-8 parts of boron oxide.
8. A process for preparing the metal enamel frit with opalescent overglaze according to claim 1, characterized in that it comprises the steps of: weighing the raw materials in parts by weight, grinding the raw materials uniformly in a mortar at the temperature of 1100-1200 ℃, sieving the ground raw materials with a 60-mesh sieve, putting the ground raw materials into a small crucible, preserving the heat for 1.2-1.5h to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold water for quenching, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a 100 ℃ drying box for drying for 1h, putting the dried porcelain glaze into a ball milling tank, adding the grinding material, adding 50% of water, grinding for 14min, and pouring the ground slurry out of the 40-mesh sieve.
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Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB545190A (en) * | 1940-08-13 | 1942-05-14 | Titanium Alloy Mfg Co | Enameling compositions and the like and method of making the same |
CN103145335A (en) * | 2012-12-27 | 2013-06-12 | 龙门协成新材料有限公司 | Metal porcelain glaze with high adherence |
CN103693852A (en) * | 2013-12-09 | 2014-04-02 | 常熟市永达化工设备厂 | Metal enamel glaze with strong adherence |
CN104743880A (en) * | 2015-03-08 | 2015-07-01 | 李宏亮 | High-temperature porcelain glaze |
CN105948500A (en) * | 2016-04-28 | 2016-09-21 | 攀枝花学院 | Enamel glaze material, enamel slurry, and preparation method and application thereof |
CN106006652A (en) * | 2016-05-10 | 2016-10-12 | 攀枝花学院 | Silicon sodium titanate, enamel glaze, enamel slurry and micro-crystalline enamel and preparation method thereof |
WO2017074185A1 (en) * | 2015-10-28 | 2017-05-04 | Remeha B.V. | Enamel powder and enamel slurry for producing an enamel coating on a metallic substrate, method for manufacturing an enamel slurry and use of the enamel coating for heat exchangers |
CN108726883A (en) * | 2018-07-11 | 2018-11-02 | 潮州市潮安区皓强瓷业有限公司 | A kind of preparation method of high abrasion domestic ceramics glaze |
CN110790510A (en) * | 2019-12-16 | 2020-02-14 | 黄奕雯 | Wear-resistant high-hardness ceramic glaze and preparation method thereof |
CN111517824A (en) * | 2020-04-24 | 2020-08-11 | 佛山科学技术学院 | Wear-resistant corrosion-resistant ceramic glaze as well as preparation method and application thereof |
CN112342544A (en) * | 2020-10-19 | 2021-02-09 | 青岛裕晋精搪涂层有限公司 | Low-temperature acid and alkali resistant cast iron enamel processing technology and coating formula |
-
2021
- 2021-10-13 CN CN202111191763.5A patent/CN113754282A/en active Pending
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB545190A (en) * | 1940-08-13 | 1942-05-14 | Titanium Alloy Mfg Co | Enameling compositions and the like and method of making the same |
CN103145335A (en) * | 2012-12-27 | 2013-06-12 | 龙门协成新材料有限公司 | Metal porcelain glaze with high adherence |
CN103693852A (en) * | 2013-12-09 | 2014-04-02 | 常熟市永达化工设备厂 | Metal enamel glaze with strong adherence |
CN104743880A (en) * | 2015-03-08 | 2015-07-01 | 李宏亮 | High-temperature porcelain glaze |
WO2017074185A1 (en) * | 2015-10-28 | 2017-05-04 | Remeha B.V. | Enamel powder and enamel slurry for producing an enamel coating on a metallic substrate, method for manufacturing an enamel slurry and use of the enamel coating for heat exchangers |
CN105948500A (en) * | 2016-04-28 | 2016-09-21 | 攀枝花学院 | Enamel glaze material, enamel slurry, and preparation method and application thereof |
CN106006652A (en) * | 2016-05-10 | 2016-10-12 | 攀枝花学院 | Silicon sodium titanate, enamel glaze, enamel slurry and micro-crystalline enamel and preparation method thereof |
CN108726883A (en) * | 2018-07-11 | 2018-11-02 | 潮州市潮安区皓强瓷业有限公司 | A kind of preparation method of high abrasion domestic ceramics glaze |
CN110790510A (en) * | 2019-12-16 | 2020-02-14 | 黄奕雯 | Wear-resistant high-hardness ceramic glaze and preparation method thereof |
CN111517824A (en) * | 2020-04-24 | 2020-08-11 | 佛山科学技术学院 | Wear-resistant corrosion-resistant ceramic glaze as well as preparation method and application thereof |
CN112342544A (en) * | 2020-10-19 | 2021-02-09 | 青岛裕晋精搪涂层有限公司 | Low-temperature acid and alkali resistant cast iron enamel processing technology and coating formula |
Non-Patent Citations (1)
Title |
---|
白世贞等: "《工业品商品学》", 30 June 2014, 中国财富出版社 * |
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