CN113754282A - Metal enamel glaze with milky glaze and preparation method thereof - Google Patents
Metal enamel glaze with milky glaze and preparation method thereof Download PDFInfo
- Publication number
- CN113754282A CN113754282A CN202111191763.5A CN202111191763A CN113754282A CN 113754282 A CN113754282 A CN 113754282A CN 202111191763 A CN202111191763 A CN 202111191763A CN 113754282 A CN113754282 A CN 113754282A
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- oxide
- milky
- metal enamel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/04—Opaque glass, glaze or enamel
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2205/00—Compositions applicable for the manufacture of vitreous enamels or glazes
- C03C2205/02—Compositions applicable for the manufacture of vitreous enamels or glazes for opaque enamels or glazes
Abstract
The invention relates to the technical field of ceramic preparation, in particular to a metal enamel glaze with milky overglaze and a preparation method thereof, wherein the glaze comprises overglaze and ground glaze, and the overglaze comprises the following materials in parts by weight: 16-24 parts of quartz, 22-28 parts of albite, 12-18 parts of fluorite, 6-12 parts of barite, 5-15 parts of calcite, 15-20 parts of limestone, 5-8 parts of borax, 6-10 parts of soda ash, 4-8 parts of sodium nitrate, 2-6 parts of sodium fluosilicate, 4-10 parts of titanium oxide, 2-5 parts of cobalt oxide, 4-8 parts of nickel oxide, 2-4 parts of copper oxide, 3-8 parts of chromium oxide, 8-12 parts of zirconium dioxide, 12-15 parts of corundum particles, 16-18 parts of fluxing agent and 10-20 parts of grinding material; wherein the abrasive comprises silicon carbide and boron nitride. The metal enamel glaze prepared by the invention has good mechanical properties, and can resist abrasion, high temperature and corrosion.
Description
Technical Field
The invention relates to the technical field of ceramic preparation, in particular to a metal enamel glaze with milky overglaze and a preparation method thereof.
Background
Enamels originate from decorations, also known as enamels. Due to the limitation of the materials used, the method is limited to the manufacture of artware for a long time. Until the 18 th century, cast iron enamels appeared, and then rapid development of such commodities was achieved. The main components and structure of the enamel are consistent with those of glass, the disordered silicon-oxygen network structure of the enamel determines that the strain tolerance and fracture toughness of the enamel are low, the enamel is highly sensitive to cracks, and the enamel is easy to crack and peel due to the accumulation of thermal stress in the thermal cycle process, which is one of the main restriction factors of the enamel coating applied under the condition of high-temperature thermal shock. In addition, the glass phase in the enamel does not have a fixed melting point, when the temperature is higher than the glass transition point, the coating slowly changes from a solid state (glass state) to a liquid state (high elastic state or even molten state), and the barrier effect of the softened enamel coating on corrosive media (such as oxygen, sulfur, chlorine, molten metal, deposited salt and the like) is obviously reduced, so that the protection effect is lost, and the quality and the service life of the product are seriously reduced.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a metal enamel glaze with milky overglaze and a preparation method thereof.
The purpose of the invention is realized by the following technical scheme:
a metal enamel glaze with a milky glaze comprises a glaze and a ground glaze, wherein the glaze comprises the following materials in parts by weight: 16-24 parts of quartz, 22-28 parts of albite, 12-18 parts of fluorite, 6-12 parts of barite, 5-15 parts of calcite, 15-20 parts of limestone, 5-8 parts of borax, 6-10 parts of soda ash, 4-8 parts of sodium nitrate, 2-6 parts of sodium fluosilicate, 4-10 parts of titanium oxide, 2-5 parts of cobalt oxide, 4-8 parts of nickel oxide, 2-4 parts of copper oxide, 3-8 parts of chromium oxide, 8-12 parts of zirconium dioxide, 12-15 parts of corundum particles, 16-18 parts of fluxing agent and 10-20 parts of grinding material; wherein the abrasive comprises silicon carbide and boron nitride.
Further, the overglaze comprises the following materials in parts by weight: 18 parts of quartz, 26 parts of albite, 15 parts of fluorite, 10 parts of barite, 12 parts of calcite, 18 parts of limestone, 6 parts of borax, 8 parts of soda ash, 6 parts of sodium nitrate, 5 parts of sodium fluosilicate, 7 parts of titanium oxide, 3 parts of cobalt oxide, 6 parts of nickel oxide, 3 parts of copper oxide, 6 parts of chromium oxide, 10 parts of zirconium dioxide, 14 parts of corundum particles, 17 parts of fluxing agent and 15 parts of grinding material.
Further, the abrasive is composed of silicon carbide and boron nitride in a weight ratio of 4: 1.
Further, the fluxing agent is composed of calcium carbonate, talcum powder and silicon dioxide.
Further, the fluxing agent is composed of calcium carbonate, talcum powder and silicon dioxide according to the weight ratio of 3:5: 2.
Further, the particle size of the corundum particles is 10-18 μm.
Further, the ground glaze comprises the following raw materials in parts by weight: 14-20 parts of silicon dioxide, 19-24 parts of quartz, 6-10 parts of barium molybdate and 4-8 parts of boron oxide.
Further, the preparation method comprises the following steps: weighing the raw materials in parts by weight, grinding the raw materials uniformly in a mortar at the temperature of 1100-1200 ℃, sieving the ground raw materials with a 60-mesh sieve, putting the ground raw materials into a small crucible, preserving the heat for 1.2-1.5h to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold water for quenching, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a 100 ℃ drying box for drying for 1h, putting the dried porcelain glaze into a ball milling tank, adding the grinding material, adding 50% of water, grinding for 14min, and pouring the ground slurry out of the 40-mesh sieve.
The invention has the beneficial effects that:
(1) the corundum particles are added, the corundum particles can enhance the network structure and physical impedance capability of the glaze to improve the high-temperature protection capability of the enamel glaze, and can control the type and size of crystals and adjust the thermal physical performance of the glaze by changing the crystallization behavior of enamel.
(2) The added chromium oxide and zirconium dioxide can remarkably improve the acid and alkali resistance of the glaze, and the excellent high-temperature performance of the zirconium dioxide can also improve the thermal shock resistance of the glaze; the cobalt oxide and the nickel oxide are used as the adhesive in the glaze, so that the adhesive force of the glaze on the metal surface can be effectively improved, and the high-temperature resistance of the glaze can be improved; titanium oxide, fluorite and sodium fluosilicate are used as coloring agents in the glaze, the milky color of the glaze is improved, and the function of beautifying the appearance is achieved.
Detailed Description
The technical solution of the present invention is further described in detail with reference to the following specific examples, but the scope of the present invention is not limited to the following.
Example 1
A method for preparing the metal enamel glaze with milky overglaze, comprising the steps of: weighing 16 parts of quartz, 22 parts of albite, 12 parts of fluorite, 6 parts of barite, 5 parts of calcite, 15 parts of limestone, 5 parts of borax, 6 parts of soda ash, 4 parts of sodium nitrate, 2 parts of sodium fluosilicate, 4 parts of titanium oxide, 2 parts of cobalt oxide, 4 parts of nickel oxide, 2 parts of copper oxide, 3 parts of chromium oxide, 8 parts of zirconium dioxide, 12 parts of corundum particles, 4 parts of calcium carbonate, 9 parts of talcum powder, 3 parts of silicon dioxide, 8 parts of silicon carbide and 2 parts of boron nitride according to parts by weight, putting the mixture into a mortar at the temperature of 1100 ℃, grinding the mixture uniformly, sieving the mixture through a 60-mesh sieve, putting the mixture into a small crucible, preserving the temperature for 1.2 to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold water for quenching, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a drying oven at the temperature of 100 ℃, putting into a ball milling tank, adding the grinding materials, adding 50% of water, grinding for 14min, pouring the ground slurry out of 40 meshes, obtaining the metal enamel glaze with the milky overglaze.
Example 2
A method for preparing the metal enamel glaze with milky overglaze, comprising the steps of: weighing 18 parts of quartz, 26 parts of albite, 15 parts of fluorite, 10 parts of barite, 12 parts of calcite, 18 parts of limestone, 6 parts of borax, 8 parts of soda ash, 6 parts of sodium nitrate, 5 parts of sodium fluosilicate, 7 parts of titanium oxide, 3 parts of cobalt oxide, 6 parts of nickel oxide, 3 parts of copper oxide, 6 parts of chromium oxide, 10 parts of zirconium dioxide, 14 parts of corundum particles, 4 parts of calcium carbonate, 10 parts of talcum powder, 3 parts of silicon dioxide, 12 parts of silicon carbide and 3 parts of boron nitride according to parts by weight, putting the mixture into a mortar at the temperature of 1150 ℃, grinding the mixture uniformly, sieving the mixture through a 60-mesh sieve, putting the mixture into a small crucible, preserving the temperature for 1.3 hours to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold quenching water for crushing, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a drying box at the temperature of 100 ℃, drying the mixture for 1 hour, putting the mixture into a ball milling tank, adding the grinding materials, adding 50 percent of water, grinding for 14 minutes, pouring the ground slurry out of 40-mesh sieve, obtaining the metal enamel glaze with the milky overglaze.
Example 3
A method for preparing the metal enamel glaze with milky overglaze, comprising the steps of: weighing 24 parts of quartz, 28 parts of albite, 18 parts of fluorite, 12 parts of barite, 15 parts of calcite, 20 parts of limestone, 8 parts of borax, 10 parts of soda ash, 8 parts of sodium nitrate, 6 parts of sodium fluosilicate, 10 parts of titanium oxide, 5 parts of cobalt oxide, 8 parts of nickel oxide, 4 parts of copper oxide, 8 parts of chromium oxide, 12 parts of zirconium dioxide, 15 parts of corundum particles, 5 parts of calcium carbonate, 11 parts of talcum powder, 2 parts of silicon dioxide, 16 parts of silicon carbide and 4 parts of boron nitride according to parts by weight, putting the mixture into a mortar at 1200 ℃, grinding the mixture uniformly, sieving the mixture through a 60-mesh sieve, putting the mixture into a small crucible, preserving the temperature for 1.5 hours to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold water for quenching, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a drying oven at 100 ℃ for drying for 1 hour, putting into a ball milling tank, adding the grinding materials, adding 50% of water, grinding for 14 minutes, pouring the ground slurry out of 40 meshes, obtaining the metal enamel glaze with the milky overglaze.
Comparative example
The raw materials and preparation methods of this comparative example and example 2 are substantially the same, except that this comparative example does not contain corundum particles.
The metal enamel frits manufactured in examples 1 to 3 and comparative example were tested for heat resistance and acid resistance, and the results are shown in the following table 1:
test results
TABLE 1
The heat resistance test method comprises the following steps: GB11418-89 test method for enamel heat resistance;
the test method of the acid resistance comprises the following steps: the method comprises the steps of adding 10g of citric acid into 100mL of distilled water to prepare a 10% citric acid solution, overlapping three pieces of filter paper on a test board, dripping the citric acid solution by using a dropper to moisten the filter paper, standing for 15min at normal temperature, removing the filter paper, cleaning the glaze surface on the filter paper by using water, wiping the glaze surface with dry cloth, and then drawing three lines at the position by using a 3B pencil, wherein the dry cloth can wipe off the trace of the pencil and has the acid resistance AA; the dry cloth cannot be used, but the wet cloth can wipe off the pencil marks and resist the acid A level; the pencil marks can not be wiped off by dry and wet cloth, and the reagent is resistant to the acid B (AA: the best acid resistance; A: the moderate acid resistance; B: the poor acid resistance).
From table 1 above, it can be seen that the data of example 2 is better and is the most preferred example, and that the addition of rigid particles has a greater effect on both the heat resistance and the acid resistance of the glaze.
The foregoing is illustrative of the preferred embodiments of this invention, and it is to be understood that the invention is not limited to the precise form disclosed herein and that various other combinations, modifications, and environments may be resorted to, falling within the scope of the concept as disclosed herein, either as described above or as apparent to those skilled in the relevant art. And that modifications and variations may be effected by those skilled in the art without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (8)
1. The metal enamel glaze with the milky glaze comprises a glaze layer and a ground glaze, and is characterized in that the glaze layer comprises the following materials in parts by weight: 16-24 parts of quartz, 22-28 parts of albite, 12-18 parts of fluorite, 6-12 parts of barite, 5-15 parts of calcite, 15-20 parts of limestone, 5-8 parts of borax, 6-10 parts of soda ash, 4-8 parts of sodium nitrate, 2-6 parts of sodium fluosilicate, 4-10 parts of titanium oxide, 2-5 parts of cobalt oxide, 4-8 parts of nickel oxide, 2-4 parts of copper oxide, 3-8 parts of chromium oxide, 8-12 parts of zirconium dioxide, 12-15 parts of corundum particles, 16-18 parts of fluxing agent and 10-20 parts of grinding material; wherein the abrasive comprises silicon carbide and boron nitride.
2. The metal enamel glaze with milky glaze according to claim 1, wherein the glaze comprises the following materials in parts by weight: 18 parts of quartz, 26 parts of albite, 15 parts of fluorite, 10 parts of barite, 12 parts of calcite, 18 parts of limestone, 6 parts of borax, 8 parts of soda ash, 6 parts of sodium nitrate, 5 parts of sodium fluosilicate, 7 parts of titanium oxide, 3 parts of cobalt oxide, 6 parts of nickel oxide, 3 parts of copper oxide, 6 parts of chromium oxide, 10 parts of zirconium dioxide, 14 parts of corundum particles, 17 parts of fluxing agent and 15 parts of grinding material.
3. The metal enamel glaze with milky overglaze according to claim 1 or 2, wherein the abrasive consists of silicon carbide and boron nitride in a weight ratio of 4: 1.
4. The metal enamel glaze with opalescent overglaze according to claim 1, wherein the flux is composed of calcium carbonate, talc and silica.
5. The metal enamel glaze with milky overglaze according to claim 4, wherein the flux is composed of calcium carbonate, talc and silica in a weight ratio of 3:5: 2.
6. The metal enamel frit with an opalescent glaze according to claim 1, wherein the corundum particles have a particle size of 10 to 18 μm.
7. The metal enamel glaze with the milky overglaze according to claim 1, wherein the ground glaze comprises the following raw materials in parts by weight: 14-20 parts of silicon dioxide, 19-24 parts of quartz, 6-10 parts of barium molybdate and 4-8 parts of boron oxide.
8. A process for preparing the metal enamel frit with opalescent overglaze according to claim 1, characterized in that it comprises the steps of: weighing the raw materials in parts by weight, grinding the raw materials uniformly in a mortar at the temperature of 1100-1200 ℃, sieving the ground raw materials with a 60-mesh sieve, putting the ground raw materials into a small crucible, preserving the heat for 1.2-1.5h to obtain uniform fused porcelain glaze, immediately pouring the fused porcelain glaze into cold water for quenching, finally taking out the porcelain glaze from the water, putting the porcelain glaze into a 100 ℃ drying box for drying for 1h, putting the dried porcelain glaze into a ball milling tank, adding the grinding material, adding 50% of water, grinding for 14min, and pouring the ground slurry out of the 40-mesh sieve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111191763.5A CN113754282A (en) | 2021-10-13 | 2021-10-13 | Metal enamel glaze with milky glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111191763.5A CN113754282A (en) | 2021-10-13 | 2021-10-13 | Metal enamel glaze with milky glaze and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113754282A true CN113754282A (en) | 2021-12-07 |
Family
ID=78799369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111191763.5A Pending CN113754282A (en) | 2021-10-13 | 2021-10-13 | Metal enamel glaze with milky glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113754282A (en) |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB545190A (en) * | 1940-08-13 | 1942-05-14 | Titanium Alloy Mfg Co | Enameling compositions and the like and method of making the same |
| CN103145335A (en) * | 2012-12-27 | 2013-06-12 | 龙门协成新材料有限公司 | Metal porcelain glaze with high adherence |
| CN103693852A (en) * | 2013-12-09 | 2014-04-02 | 常熟市永达化工设备厂 | Metal enamel glaze with strong adherence |
| CN104743880A (en) * | 2015-03-08 | 2015-07-01 | 李宏亮 | High-temperature porcelain glaze |
| CN105948500A (en) * | 2016-04-28 | 2016-09-21 | 攀枝花学院 | Enamel glaze material, enamel slurry, and preparation method and application thereof |
| CN106006652A (en) * | 2016-05-10 | 2016-10-12 | 攀枝花学院 | Silicon sodium titanate, enamel glaze, enamel slurry and micro-crystalline enamel and preparation method thereof |
| WO2017074185A1 (en) * | 2015-10-28 | 2017-05-04 | Remeha B.V. | Enamel powder and enamel slurry for producing an enamel coating on a metallic substrate, method for manufacturing an enamel slurry and use of the enamel coating for heat exchangers |
| CN108726883A (en) * | 2018-07-11 | 2018-11-02 | 潮州市潮安区皓强瓷业有限公司 | A kind of preparation method of high abrasion domestic ceramics glaze |
| CN110790510A (en) * | 2019-12-16 | 2020-02-14 | 黄奕雯 | Wear-resistant high-hardness ceramic glaze and preparation method thereof |
| CN111517824A (en) * | 2020-04-24 | 2020-08-11 | 佛山科学技术学院 | Wear-resistant corrosion-resistant ceramic glaze as well as preparation method and application thereof |
| CN112342544A (en) * | 2020-10-19 | 2021-02-09 | 青岛裕晋精搪涂层有限公司 | Low-temperature acid and alkali resistant cast iron enamel processing technology and coating formula |
-
2021
- 2021-10-13 CN CN202111191763.5A patent/CN113754282A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB545190A (en) * | 1940-08-13 | 1942-05-14 | Titanium Alloy Mfg Co | Enameling compositions and the like and method of making the same |
| CN103145335A (en) * | 2012-12-27 | 2013-06-12 | 龙门协成新材料有限公司 | Metal porcelain glaze with high adherence |
| CN103693852A (en) * | 2013-12-09 | 2014-04-02 | 常熟市永达化工设备厂 | Metal enamel glaze with strong adherence |
| CN104743880A (en) * | 2015-03-08 | 2015-07-01 | 李宏亮 | High-temperature porcelain glaze |
| WO2017074185A1 (en) * | 2015-10-28 | 2017-05-04 | Remeha B.V. | Enamel powder and enamel slurry for producing an enamel coating on a metallic substrate, method for manufacturing an enamel slurry and use of the enamel coating for heat exchangers |
| CN105948500A (en) * | 2016-04-28 | 2016-09-21 | 攀枝花学院 | Enamel glaze material, enamel slurry, and preparation method and application thereof |
| CN106006652A (en) * | 2016-05-10 | 2016-10-12 | 攀枝花学院 | Silicon sodium titanate, enamel glaze, enamel slurry and micro-crystalline enamel and preparation method thereof |
| CN108726883A (en) * | 2018-07-11 | 2018-11-02 | 潮州市潮安区皓强瓷业有限公司 | A kind of preparation method of high abrasion domestic ceramics glaze |
| CN110790510A (en) * | 2019-12-16 | 2020-02-14 | 黄奕雯 | Wear-resistant high-hardness ceramic glaze and preparation method thereof |
| CN111517824A (en) * | 2020-04-24 | 2020-08-11 | 佛山科学技术学院 | Wear-resistant corrosion-resistant ceramic glaze as well as preparation method and application thereof |
| CN112342544A (en) * | 2020-10-19 | 2021-02-09 | 青岛裕晋精搪涂层有限公司 | Low-temperature acid and alkali resistant cast iron enamel processing technology and coating formula |
Non-Patent Citations (1)
| Title |
|---|
| 白世贞等: "《工业品商品学》", 30 June 2014, 中国财富出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111333328B (en) | High-wear-resistance glaze material with polished glaze and preparation method thereof | |
| JP7288973B2 (en) | Dry grain ceramic tile by wet pouring method and its manufacturing method | |
| CN110683767B (en) | High-performance wear-resistant glaze and preparation method thereof | |
| CN108328927B (en) | Ultra-smooth white glaze and preparation method thereof | |
| US4196004A (en) | Corrosion resistant glasses that contain chemical additives for application over metal substrates | |
| CN112794645B (en) | High-transparency wear-resistant glaze material and preparation method thereof | |
| CN111732340B (en) | Wear-resistant glaze for glazed brick and preparation method thereof | |
| US5447891A (en) | Lead-free glaze or enamel for use on ceramic bodies | |
| CN109279780A (en) | A kind of ceramic glaze and preparation method thereof of resistance to alkali corrosion | |
| CN114292131B (en) | Glazed tile with bright star effect on surface and preparation method thereof | |
| CN113429130B (en) | Flash super-wear-resistant diamond glaze, ceramic tile and preparation method thereof | |
| CN113264680B (en) | Dry particle suspension glaze, preparation method and application in preparation of high-transparency ceramic tile | |
| CN113336444B (en) | High-viscosity middle-layer glaze capable of eliminating polishing glaze pinholes and polishing glazed rock plate using same | |
| CN108129029B (en) | Snowflake glaze material and related preparation method and overglaze formula adjustment method | |
| CN110510876A (en) | A kind of matting glaze and preparation method thereof | |
| CN112299884A (en) | Glaze material of sanitary ceramic easy to clean, sanitary ceramic and preparation method | |
| CN111423124B (en) | Wear-resistant transparent glaze, wear-resistant polished glazed brick and preparation method thereof | |
| CN115010367B (en) | Low-temperature quick-firing full-polished crystal glaze, artistic rock plate containing full-polished crystal glaze and preparation method | |
| CN102352143B (en) | Glass coating and film technology for reducing platinum rhodium alloy bushing plate loss | |
| CN114573233A (en) | Preparation method of wear-resistant color-assisting frit for wear-resistant glaze, super wear-resistant glaze and ceramic tile | |
| CN114292026A (en) | Satin glaze suitable for quick firing and having special crystallization effect and preparation method thereof | |
| CN113998893A (en) | Wear-resistant microcrystal dry particles with soft light effect, preparation method thereof and ceramic tile | |
| CN106380189A (en) | Natural surface tile and preparation method of blank material of natural surface tile | |
| CN113754282A (en) | Metal enamel glaze with milky glaze and preparation method thereof | |
| CN112592208B (en) | Silk glaze ceramic tile and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |