CN113690345A - Efficient MWT component packaging method - Google Patents

Efficient MWT component packaging method Download PDF

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Publication number
CN113690345A
CN113690345A CN202111239217.4A CN202111239217A CN113690345A CN 113690345 A CN113690345 A CN 113690345A CN 202111239217 A CN202111239217 A CN 202111239217A CN 113690345 A CN113690345 A CN 113690345A
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curing
time
laminating
thickness
mwt
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Inventor
孙影
逯好峰
吴仕梁
张凤鸣
梁东海
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Nanjing Rituo Photovoltaic New Energy Co ltd
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Nanjing Rituo Photovoltaic New Energy Co ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The invention provides a high-efficiency packaging method of an MWT (metal wrap through) component, which comprises the steps of firstly coating polyurethane resin on a conductive metal foil, and volatilizing a solvent and initially curing the solvent after passing through a drying tunnel; then spraying epoxy acrylic resin on the surface layer of the polyurethane resin, and irradiating the epoxy acrylic resin on the surface layer by ultraviolet light for curing; after laser drilling is carried out on the insulating layer, arranging the battery piece; and finally, laying other materials for producing the assembly, and then entering a laminating machine for secondary laminating and curing. The packaging surface obtained by the method has certain strength and hardness, avoids layering caused by insufficient bonding strength in the long-term outdoor use process, further causes uneven current, improves the lamination hidden crack ratio and the glue hole blocking ratio in the lamination process, and can adjust the lamination time beat, improve the power and improve the hot spots.

Description

Efficient MWT component packaging method
Technical Field
The invention relates to the field of photovoltaic modules, in particular to a high-efficiency MWT module packaging method.
Background
In the conventional MWT photovoltaic component, because the positive electrode and the negative electrode of a component battery are arranged on the back of a battery piece, an electrode point is bonded with a conductive core board by using conductive adhesive, and the current of the positive electrode and the negative electrode is collected by the conductive core board.
The isolation layer between the back plate and the conductive core plate of the existing MWT component packaging structure is mostly of a whole structure, for example, an EPE or a whole coated insulating glue layer is used, then the insulation layer is punched to bond a positive electrode point, a negative electrode point and a conductive metal foil, the laying mode is adopted, the process is complex, the requirement on the hole site alignment precision is high, the field operation is difficult, the production cost is high, the raw material cost can be saved by adopting a gluing process, but the lamination process is easy to generate black strings, the interval between the strings is poor, the power is obviously reduced, and the current is uneven after a hot spot test.
Disclosure of Invention
The invention provides an efficient MWT component packaging method for solving the problems in the prior art, the packaging surface has certain strength and hardness, the phenomenon that layering occurs due to insufficient bonding strength in the long-term outdoor use process and further causes uneven current is avoided, the lamination hidden crack ratio and the glue hole blocking ratio in the lamination process are improved, the lamination time beat can be adjusted, the power is improved, and hot spots are improved.
The invention provides a high-efficiency MWT component packaging method, which comprises the following steps:
1) firstly coating polyurethane resin on a conductive metal foil, and volatilizing a solvent and initially curing after passing through a drying tunnel;
2) spraying epoxy acrylic resin on the surface layer of the polyurethane resin, and irradiating the epoxy acrylic resin on the surface layer by ultraviolet light for curing;
3) after laser drilling is carried out on the insulating layer, arranging the battery piece;
4) and laying a packaging adhesive film, glass and a back plate for producing the assembly, and then entering a laminating machine for secondary laminating and curing.
Further improvement, the temperature of the drying tunnel in the step 1) is 80 ℃, and the time is 1-2 min.
Further improvement, the thickness ratio of the polyurethane resin and the epoxy acrylic resin in the step 2) is 1-5: 1, the total thickness of the glue layer is 30-50 mm, and the ultraviolet illumination time is 30-50 s. The optimal solution method comprises the following steps: the thickness of the polyurethane resin is 25mm, the thickness of the epoxy acrylic resin is 15mm, and the ultraviolet irradiation time is 40 s.
Further improvement, in the secondary laminating and curing in the step 4), the heating temperature of one cavity is 133-138 ℃, the heating time is 7-9 min, the heating temperature of two cavities is 141-144 ℃, and the heating time is 7-9 min. The optimal method comprises the following steps: the heating temperature of one cavity is 136 deg.C, the heating temperature of two cavities is 144 deg.C, and the heating time of two cavities is 8 min.
Further improved, the coating process in the step 1) is a half coating mode, the negative electrode point is full coating, and the positive electrode point is directly contacted with the aluminum back field of the battery piece.
The invention has the beneficial effects that:
1. the preparation method comprises the steps of selecting epoxy acrylic resin and polyurethane, mutually matching, firstly coating the polyurethane resin on a conductive metal foil, volatilizing a drying tunnel solvent and initially curing, spraying the epoxy acrylic resin on the surface layer, and irradiating the epoxy acrylic resin on the surface layer by ultraviolet light for curing to ensure that the surface of the conductive metal foil has certain strength and hardness, so that the problems of uneven thickness, poor inter-sheet distance and the like caused by overlarge glue fluidity in the subsequent secondary high-temperature laminating process are solved.
2. Epoxy group in the epoxy acrylic resin and isocyanic acid group in the polyurethane can take place crosslinking reaction at high temperature lamination in-process, through the secondary high temperature lamination solidification back, increase the curing degree of depth, increase bonding strength, avoid long-term outdoor use in-process because of bonding strength is not enough, the layering appears, and then causes the electric current inequality.
3. The total thickness and the thickness proportion of the epoxy acrylic resin and the polyurethane resin are adjusted, and the lamination subfissure proportion and the glue hole blocking proportion in the lamination process are improved.
4. Adjusting the lamination time tact: the polyurethane curing agent and the epoxy acrylic resin are cured in the laminating machine again after passing through the drying tunnel in the earlier stage, so that the laminating curing time of the adhesive layer can be shortened by adopting higher laminating temperature, and the normal production beat of the component is met.
5. And (3) power boosting: conventional subassembly only carries out battery piece current collection through the position of punching, and the used glue film thickness of this scheme reduces than ordinary insulating layer thickness by a wide margin, can realize near positive pole point metal forming direct contact battery aluminium back of the body field, realizes the conduction of battery piece and metal forming current, and greatly increased current collection way reduces the internal loss, realizes power promotion effect.
6. And (3) hot spot improvement: due to the increase of the current transmission path and the contact area of the anode point, the heat generated by overlarge resistance in the working process of the component can be effectively reduced, the temperature of the electrode point when the component works is reduced, and the risk of hot spot failure is reduced.
Drawings
Fig. 1 is a MWT cell back side structure.
Fig. 2 is a plan view of a conventional insulating layer.
FIG. 3 is a plan view of a half-coating mode.
Fig. 4 is a design drawing of the whole core plate.
FIG. 5 shows a cross-sectional structure of the conductive metal foil and the adhesive layer.
Detailed Description
The invention will be further explained with reference to the drawings.
The invention provides a high-efficiency MWT component packaging method, which comprises the following steps:
1) firstly coating polyurethane resin on a conductive metal foil, and volatilizing a solvent and initially curing after passing through a drying tunnel;
2) spraying epoxy acrylic resin on the surface layer of the polyurethane resin, and irradiating the epoxy acrylic resin on the surface layer by ultraviolet light for curing;
3) after laser drilling is carried out on the insulating layer, arranging the battery piece;
4) and laying a packaging adhesive film, glass and a back plate for producing the assembly, and then entering a laminating machine for secondary laminating and curing.
Further improvement, the temperature of the drying tunnel in the step 1) is 80 ℃, and the time is 1-2 min.
Further improvement, the thickness ratio of the polyurethane resin and the epoxy acrylic resin in the step 2) is 1-5: 1, the total thickness of the glue layer is 30-50 mm, and the ultraviolet illumination time is 30-50 s. The optimal solution method comprises the following steps: the thickness of the polyurethane resin is 25mm, the thickness of the epoxy acrylic resin is 15mm, and the ultraviolet irradiation time is 40 s.
Further improvement, in the secondary laminating and curing in the step 4), the heating temperature of one cavity is 133-138 ℃, the heating time is 7-9 min, the heating temperature of two cavities is 141-144 ℃, and the heating time is 7-9 min. The optimal method comprises the following steps: the heating temperature of one cavity is 136 deg.C, the heating temperature of two cavities is 144 deg.C, and the heating time of two cavities is 8 min.
Fig. 1 shows a back structure of an MWT battery, in which a positive electrode 1 and a negative electrode 2 are arranged as shown in fig. 1, and fig. 2 shows a planar structure of a conventional separator, in which the positive electrode 1 and the negative electrode 2 are separated from each other by punching holes in a plane. Fig. 3 is a plan view of a half-coating mode, the coating process is a half-coating mode, full coating is performed at a negative electrode point, and a positive electrode point is directly contacted with an aluminum back field of a battery piece. Fig. 4 is a design diagram of the whole core board, and the bilateral symmetry design is adopted to ensure the current collection consistency of all parts of the whole core board. Fig. 5 is a cross-sectional view of the core board and the insulating layer structure, which sequentially comprises the following structures from top to bottom: epoxy acrylic acid 5, polyurethane 4 and conductive metal foil 3.
The specific implementation process of the invention is as follows:
conductive metal foil
Figure DEST_PATH_IMAGE001
Polyurethane coating
Figure 777310DEST_PATH_IMAGE001
Heating in drying tunnel
Figure 163292DEST_PATH_IMAGE001
Epoxy acrylic acid spray coating
Figure 270925DEST_PATH_IMAGE001
Ultraviolet light curing
Figure 541500DEST_PATH_IMAGE002
Laser drilling
Figure 900413DEST_PATH_IMAGE002
Printing of conductive paste
Figure 785192DEST_PATH_IMAGE001
Battery piece pendulum piece
Figure 458750DEST_PATH_IMAGE002
EVA laying
Figure 860913DEST_PATH_IMAGE002
Glass loading
Figure 342841DEST_PATH_IMAGE001
Fixing of battery piece
Figure 960640DEST_PATH_IMAGE002
Inverting before lamination
Figure 918232DEST_PATH_IMAGE002
Lamination of
Figure 750184DEST_PATH_IMAGE002
Chamfered edge
Figure 473902DEST_PATH_IMAGE002
Lead wire
Figure 920058DEST_PATH_IMAGE002
Dress frame
Figure 489579DEST_PATH_IMAGE002
Junction box welding
Figure 905648DEST_PATH_IMAGE002
Curing
Figure 627748DEST_PATH_IMAGE002
Name plate and bar code paste
Figure 166176DEST_PATH_IMAGE002
And (5) grading and packaging.
The specific embodiment of the invention is as follows:
example 1:
the thickness of polyurethane is 25mm, the temperature of a drying tunnel is 80 ℃, the drying tunnel time is 2min, the thickness of epoxy acrylic acid is 5mm, the ultraviolet illumination time is 30S, the total thickness of an adhesive layer is 30mm, the laminating temperature of a first cavity is 138 ℃, the laminating time of a first cavity is 7min, the laminating temperature of a second cavity is 142 ℃, and the laminating time of a first cavity is 7 min.
Example 2:
the thickness of polyurethane is 20mm, the temperature of a drying tunnel is 80 ℃, the drying tunnel time is 1min, the thickness of epoxy acrylic acid is 10mm, the ultraviolet illumination time is 35S, the total thickness of an adhesive layer is 30mm, the laminating temperature of a first cavity is 138 ℃, the laminating time of a first cavity is 7min, the laminating temperature of a second cavity is 142 ℃, and the laminating time of a first cavity is 7 min.
Example 3:
the thickness of polyurethane is 20mm, the temperature of a drying tunnel is 80 ℃, the drying tunnel time is 1min, the thickness of epoxy acrylic acid is 15mm, the ultraviolet irradiation time is 40S, the total thickness of an adhesive layer is 30mm, the laminating temperature of a first cavity is 138 ℃, the laminating time of a first cavity is 7min, the laminating temperature of a second cavity is 142 ℃, and the laminating time of a first cavity is 7 min.
Example 4:
the thickness of polyurethane is 30mm, the temperature of a drying tunnel is 80 ℃, the drying tunnel time is 2min, the thickness of epoxy acrylic acid is 10mm, the ultraviolet illumination time is 35S, the total thickness of an adhesive layer is 40mm, the laminating temperature of a cavity is 136 ℃, the laminating time of a cavity is 8min, the laminating temperature of two cavities is 144 ℃, and the laminating time of a cavity is 8 min.
Example 5:
the thickness of polyurethane is 25mm, the drying tunnel temperature is 80 ℃, the drying tunnel time is 2min, the thickness of epoxy acrylic acid is 15mm, the ultraviolet irradiation time is 40S, the total thickness of the glue layer is 40mm, the laminating temperature of a cavity is 136 ℃, the laminating time of a cavity is 8min, the laminating temperature of a cavity is 144 ℃, and the laminating time of a cavity is 8 min.
Example 6:
the thickness of polyurethane is 20mm, the temperature of a drying tunnel is 80 ℃, the drying tunnel time is 2min, the thickness of epoxy acrylic acid is 20mm, the ultraviolet irradiation time is 45S, the total thickness of an adhesive layer is 40mm, the laminating temperature of a first cavity is 136 ℃, the laminating time of a first cavity is 8min, the laminating temperature of a second cavity is 144 ℃, and the laminating time of a first cavity is 8 min.
Example 7:
the thickness of polyurethane is 35mm, the temperature of a drying tunnel is 80 ℃, the drying tunnel time is 3min, the thickness of epoxy acrylic acid is 15mm, the ultraviolet irradiation time is 40S, the total thickness of an adhesive layer is 50mm, the laminating temperature of a first cavity is 133 ℃, the laminating time of a first cavity is 9min, the laminating temperature of a second cavity is 141 ℃, and the laminating time of a first cavity is 9 min.
Example 8:
the thickness of polyurethane is 30mm, the temperature of a drying tunnel is 80 ℃, the drying tunnel time is 2min, the thickness of epoxy acrylic acid is 20mm, the ultraviolet illumination time is 40S, the total thickness of an adhesive layer is 50mm, the laminating temperature of a first cavity is 133 ℃, the laminating time of a first cavity is 9min, the laminating temperature of a second cavity is 141 ℃, and the laminating time of a first cavity is 9 min.
Example 9:
the thickness of polyurethane is 25mm, the temperature of a drying tunnel is 80 ℃, the drying tunnel time is 2min, the thickness of epoxy acrylic acid is 25mm, the ultraviolet illumination time is 50S, the total thickness of a glue layer is 50mm, the laminating temperature of a first cavity is 133 ℃, the laminating time of a first cavity is 9min, the laminating temperature of a second cavity is 141 ℃, and the laminating time of a first cavity is 9 min.
The performance indicators for the above examples are as follows:
example 1:
the proportion of uneven current caused by blocking of the rubber holes is 5%, the proportion of hidden cracks in lamination is 0%, the proportion of poor string black is 3%, the proportion of uneven string black is 7%, and the proportion of uneven current caused by hot spot experiment is 10%.
Example 2:
the proportion of uneven current caused by blocking the rubber holes is 4%, the lamination hidden crack proportion is 2%, the film string is poor and black, the lamination thickness is uneven and black is 5%, and the hot spot experiment current is uneven and 9%.
Example 3:
the proportion of uneven current caused by blocking the rubber holes is 0%, the lamination hidden crack proportion is 0%, the film string is poor and black, the lamination thickness is uneven and black is 0%, and the hot spot experiment current is uneven and 7%.
Example 4:
the proportion of current unevenness caused by blocking the rubber holes is 7%, the proportion of lamination hidden cracks is 0%, the film string is poor and has black color 5%, the lamination thickness is uneven and has black color 2%, and the current unevenness caused by hot spot experiment is 3%.
Example 5:
the proportion of uneven current caused by blocking the rubber holes is 0%, the lamination hidden crack proportion is 0%, the film string is poor and black, the lamination thickness is uneven and black is 0%, and the hot spot experiment current is uneven and 0%.
Example 6:
the proportion of uneven current caused by blocking the rubber holes is 0%, the lamination hidden crack proportion is 3%, the film string is poor and black, the lamination thickness is uneven and black is 0%, and the hot spot experiment current is uneven and 6%.
Example 7:
the proportion of current unevenness caused by blocking the rubber holes is 8%, the lamination hidden crack proportion is 0%, the film string is poor and has black color 3%, the lamination thickness is uneven and has black color 1%, and the current unevenness caused by hot spot experiment is 0%.
Example 8:
the proportion of uneven current caused by blocking the rubber holes is 10%, the lamination hidden crack proportion is 5%, the string defect string is 5%, the lamination thickness is 0%, and the hot spot experiment current is 2%.
Example 9:
the proportion of uneven current caused by blocking the rubber holes is 10%, the lamination hidden crack proportion is 7%, the piece string is poor and black is 7%, the lamination thickness is uneven and black is 0%, and the hot spot experiment current is uneven and 5%.
The best solution of example 5 can be obtained by comparing the performance indexes.
While the invention has been described in terms of its preferred embodiments, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention.

Claims (7)

1. An efficient MWT component packaging method is characterized by comprising the following steps:
1) firstly coating polyurethane resin on a conductive metal foil, and volatilizing a solvent and initially curing after passing through a drying tunnel;
2) spraying epoxy acrylic resin on the surface layer of the polyurethane resin, and irradiating the epoxy acrylic resin on the surface layer by ultraviolet light for curing;
3) after laser drilling is carried out on the insulating layer, arranging the battery piece;
4) and laying a packaging adhesive film, glass and a back plate for producing the assembly, and then entering a laminating machine for secondary laminating and curing.
2. The method for efficient encapsulation of MWT components according to claim 1, characterized by: the temperature of the drying tunnel in the step 1) is 80 ℃, and the time is 1-2 min.
3. The method for efficient encapsulation of MWT components according to claim 1, characterized by: the thickness ratio of the polyurethane resin to the epoxy acrylic resin in the step 2) is 1-5: 1, the total thickness of the glue layer is 30-50 mm, and the ultraviolet illumination time is 30-50 s.
4. The method for efficiently encapsulating MWT module as claimed in claim 3, wherein: the thickness of the polyurethane resin is 25mm, the thickness of the epoxy acrylic resin is 15mm, and the ultraviolet irradiation time is 40 s.
5. The method for efficient encapsulation of MWT components according to claim 1, characterized by: in the secondary laminating and curing in the step 4), the heating temperature of one cavity is 133-138 ℃, the heating time is 7-9 min, the heating temperature of two cavities is 141-144 ℃, and the heating time is 7-9 min.
6. The method for efficient encapsulation of MWT components according to claim 5, characterized in that: the heating temperature of one cavity is 136 deg.C, the heating temperature of two cavities is 144 deg.C, and the heating time of two cavities is 8 min.
7. The method for efficient encapsulation of MWT components according to claim 1, characterized by: the coating process in the step 1) is a half coating mode, the negative pole point is full coated, and the positive pole point is directly contacted with the aluminum back surface field of the battery piece.
CN202111239217.4A 2021-10-25 2021-10-25 Efficient MWT component packaging method Pending CN113690345A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103522658A (en) * 2013-09-18 2014-01-22 芜湖群跃电子科技有限公司 Backboard for metal perforation type solar battery and preparation method of backboard
US20150144180A1 (en) * 2012-06-05 2015-05-28 Ebfoil S.R.L. Encapsulating layer adapted to be applied to back-sheets for photovoltaic modules including back-contact cells
JP2016500569A (en) * 2012-10-30 2016-01-14 バイエル・マテリアルサイエンス・リミテッド・ライアビリティ・カンパニーBayer MaterialScience LLC Processes for coating substrates and substrates formed therefrom
US20170133537A1 (en) * 2014-03-21 2017-05-11 E I Du Pont De Nemours And Company Integrated back-sheets for back-contact solar cell modules

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150144180A1 (en) * 2012-06-05 2015-05-28 Ebfoil S.R.L. Encapsulating layer adapted to be applied to back-sheets for photovoltaic modules including back-contact cells
JP2016500569A (en) * 2012-10-30 2016-01-14 バイエル・マテリアルサイエンス・リミテッド・ライアビリティ・カンパニーBayer MaterialScience LLC Processes for coating substrates and substrates formed therefrom
CN103522658A (en) * 2013-09-18 2014-01-22 芜湖群跃电子科技有限公司 Backboard for metal perforation type solar battery and preparation method of backboard
US20170133537A1 (en) * 2014-03-21 2017-05-11 E I Du Pont De Nemours And Company Integrated back-sheets for back-contact solar cell modules

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
庄彩虹 等: "环氧丙烯酸酯树脂的制备及其聚氨酯改性", 《中南大学学报》 *

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