CN113683966A - Silicate inorganic adhesive and preparation method and use method thereof - Google Patents
Silicate inorganic adhesive and preparation method and use method thereof Download PDFInfo
- Publication number
- CN113683966A CN113683966A CN202111140148.1A CN202111140148A CN113683966A CN 113683966 A CN113683966 A CN 113683966A CN 202111140148 A CN202111140148 A CN 202111140148A CN 113683966 A CN113683966 A CN 113683966A
- Authority
- CN
- China
- Prior art keywords
- component
- parts
- silicate
- inorganic adhesive
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 55
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 55
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 58
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 30
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 25
- 239000001923 methylcellulose Substances 0.000 claims abstract description 25
- 235000010981 methylcellulose Nutrition 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000440 bentonite Substances 0.000 claims abstract description 18
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 18
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000012153 distilled water Substances 0.000 claims abstract description 17
- 239000000919 ceramic Substances 0.000 claims abstract description 16
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 15
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 13
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 13
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004005 microsphere Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 239000003292 glue Substances 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 4
- 230000003020 moisturizing effect Effects 0.000 abstract description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 21
- 235000011187 glycerol Nutrition 0.000 description 16
- 235000012216 bentonite Nutrition 0.000 description 15
- 229910000831 Steel Inorganic materials 0.000 description 12
- 239000010959 steel Substances 0.000 description 12
- 239000004111 Potassium silicate Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 9
- 235000019353 potassium silicate Nutrition 0.000 description 9
- 229910052913 potassium silicate Inorganic materials 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 150000004706 metal oxides Chemical group 0.000 description 6
- 238000011049 filling Methods 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000395 magnesium oxide Substances 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000011398 Portland cement Substances 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 125000005456 glyceride group Chemical group 0.000 description 3
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000011325 microbead Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical group N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000008030 superplasticizer Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
- C09J1/02—Adhesives based on inorganic constituents containing water-soluble alkali silicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to an adhesive and a preparation method thereof, in particular to a silicate inorganic adhesive and a preparation method and a use method thereof, and provides the silicate inorganic adhesive which comprises a component A, a component B and 2-50 parts of sodium silicate; 10-200 parts of distilled water; 1-10 parts of sodium hydroxide; 0.5-5 parts of methyl cellulose; 1-10 parts of glycerol; the component B comprises the following components in parts by weight: 10-20 parts of zirconium dioxide; 20-40 parts of aluminum oxide; 5-20 parts of ceramic microspheres; 5-10 parts of bentonite. The adhesive provided by the invention has good moisturizing effect on the component A glue solution due to the addition of the glycerol and the methyl cellulose, and prevents the glue solution from volatilizing and solidifying at room temperature. And the surface gloss of the inorganic adhesive is well improved after the inorganic adhesive is cured in use. The component B has compact structure and fine powder.
Description
The application is a divisional application with the application date of 2016, 10, 27 and the application number of 201610955112.1, and the name of the invention is 'a silicate inorganic adhesive and a preparation method thereof'.
Technical Field
The invention relates to an adhesive and a preparation method thereof, in particular to a high-temperature-resistant silicate inorganic adhesive and a preparation method and a use method thereof.
Background
The inorganic adhesive is a novel adhesive, can resist high temperature and low temperature, has low cost, is not easy to age, has simple structure and high bonding degree, is widely used for bonding materials, particularly for bonding materials in a high-temperature environment, and achieves the purposes of saving materials, saving energy, simplifying the process and the like; sealing and filling; infiltration plugging; heat resistant fire resistant or insulating coatings, and the like. The inorganic adhesive is mainly phosphate adhesive and silicate adhesive in application, wherein the silicate inorganic adhesive can be used for bonding various materials such as metal, ceramic, glass, mica, stone and the like, and is used for assembling refractory materials, heating electric appliances, petrochemical equipment flaming parts, ignition plugs and other high-temperature resistant parts. Searching for domestic patents and patents with related inorganic adhesives, for example, the following are listed:
1. the invention patent with the patent application number of CN200810032289.X and the name of 'novel wood adhesive and preparation method thereof' discloses a novel wood adhesive, which comprises the following components: water: 100 parts by weight; protein-containing feedstock: 3-45 parts by weight; acidity regulator: 0.01 to 15 parts by weight; aromatic compound (c): 0.01 to 15 parts by weight; curing agent: 0.01 to 15 parts by weight; preservative: 0.01 to 15 parts by weight; viscosity modifier: 0 to 15 parts by weight; filling: 0 to 10 parts by weight; a drier: 0 to 15 parts by weight. The curing agent is selected from sodium fluosilicate, sodium silicate and the like, the viscosity regulator is selected from rosin glyceride, hydrogenated rosin glyceride, rosin modified maleic glyceride, carboxymethyl cellulose, sodium carboxymethyl cellulose and the like, and the filler is selected from diatomite, kaolin, bentonite, talcum powder and the like. Meanwhile, a preparation method of the adhesive is disclosed, which comprises the following steps: adding 3-45 parts by weight of a protein-containing raw material, 0.01-15 parts by weight of an acidity regulator, 0.01-15 parts by weight of an aromatic compound, 0.01-15 parts by weight of a curing agent, 0.01-15 parts by weight of a preservative, 0-15 parts by weight of a viscosity regulator, 0-10 parts by weight of a filler and 0-15 parts by weight of a drier into water at room temperature while stirring to prepare the novel wood adhesive.
2. The patent application No. CN201310414408.9, entitled "sticking joint-filling waterproof three-in-one mosaic adhesive" discloses a sticking joint-filling waterproof three-in-one mosaic adhesive which is a two-component material, wherein the component A comprises cement, quartz powder, redispersible emulsion powder, cellulose ether, superplasticizer, water repellent, lignin fiber, defoamer, and pigment is added according to needs, and the component B comprises emulsion, water, defoamer and preservative. Wherein the cement is one of portland cement or ordinary portland cement or white portland cement, the strength grade requirement is 42.5 or 42.5R or 52.5, and the cellulose ether is hydroxyethyl methyl cellulose ether or hydroxypropyl methyl cellulose ether with the viscosity of 500-100000 Pa-s. The adhesive can reduce the leakage of the outer wall caused by the fact that a waterproof layer is not made or the waterproof material is not good, improve the binding power of the binding material and the compatibility of the binding material and the waterproof layer, improve the flexibility and the quality of the binding material, reduce the phenomena of hollowing and falling of mosaics, water seepage and cracking of the outer wall and the like, can be used for quick spraying by adopting an airless sprayer, realize the integrated construction of sticking, filling and waterproofing, simplify the working procedure, shorten the construction period and reduce the construction difficulty.
3. The invention patent with patent application number CN201410478272.2 and name of 'an environment-friendly adhesive silicate adhesive' discloses an environment-friendly silicate adhesive with excellent performance, which comprises the following components by weight: 100-500 g of silicate, 1-5 g of butyl acrylate, 0.5-3 g of polyacrylamide, 6-30 g of silane coupling agent, 0.1-2 g of tackifier, 0.1-1 g of plasticizer, 0.1-1 g of waterproof agent and 0.1-0.5 g of preservative, wherein the tackifier is hydroxymethyl cellulose. On the premise of not adding any inorganic filler, the invention takes a plurality of organic matters as modifiers, and the prepared silicate adhesive has the characteristics of higher bonding strength, better water resistance, excellent heat resistance, lower curing temperature, better anticorrosion protection effect and the like, does not contain harmful components such as formaldehyde and the like, has low cost, and belongs to environment-friendly adhesives.
From the above search and analysis, it can be seen that the existing AB inorganic adhesive lacks the simultaneous addition of glycerin and methylcellulose, which results in poor curing effect and surface smoothness of the binder, and meanwhile, the existing AB inorganic adhesive has a non-dense metal oxide structure, which results in poor mixing effect, poor high temperature resistance and poor heat insulation effect, and therefore needs to be further improved.
Disclosure of Invention
The invention aims to provide a silicate inorganic adhesive which is not easy to cure at room temperature, is environment-friendly, has high bonding strength and resists high temperature.
The invention provides a silicate inorganic adhesive, which comprises a component A and a component B, wherein the component A comprises the following components in parts by weight: 2-50 parts of sodium silicate; 10-200 parts of distilled water; 1-10 parts of sodium hydroxide; 0.5-5 parts of methyl cellulose; 1-10 parts of glycerol;
the component B comprises the following components in parts by weight: 10-20 parts of zirconium dioxide; 20-40 parts of aluminum oxide; 5-20 parts of ceramic microspheres; 5-10 parts of bentonite;
the invention also provides a preparation method of the silicate inorganic adhesive in the technical scheme, which comprises the steps of preparing the component A and preparing the component B;
the preparation of the component A comprises the following steps:
dissolving sodium silicate in distilled water to obtain a sodium silicate solution;
heating the sodium silicate solution to 80-90 ℃, adding sodium hydroxide under the stirring condition, and adjusting the solution into a solution with the modulus of 1.8-3.2;
under the condition of stirring, adding methyl cellulose into the solution with the modulus of 1.8-3.2 for dissolving, and then dropwise adding glycerol for mixing to obtain a component A;
the preparation of the component B comprises the following steps:
mixing zirconium dioxide, aluminum oxide and bentonite, and sequentially calcining, cooling, grinding and sieving the obtained mixed material to obtain a primary component B;
mixing the primary component B with ceramic microspheres to obtain a component B;
the calcining temperature is 1100-1200 ℃, and the calcining time is 1 h.
Preferably, the mesh number of the sieve is 325 meshes.
The invention also provides a use method of the silicate inorganic adhesive in the technical scheme, which is characterized in that the component A and the component B are mixed when in use;
the mass ratio of the component A to the component B is 1: 1;
the curing temperature is 100 ℃, and the curing time is 2 hours.
The invention has the beneficial effects that:
1. the silicate inorganic adhesive has good moisturizing and thickening effects on the component A glue solution due to the addition of the glycerol and the methyl cellulose, and prevents the glue solution from volatilizing and solidifying at room temperature. And the surface gloss of the inorganic adhesive is well improved after the inorganic adhesive is cured in use.
2. The silicate inorganic adhesive enables the structure of metal oxide to be more compact after being calcined in preparation, and metal oxide powder after being ground and sieved is more exquisite.
3. The silicate inorganic adhesive is prepared by separately preparing the component A and the component B, and is mixed when in use, so that the silicate inorganic adhesive is convenient to store, and the quality guarantee period of the silicate inorganic adhesive is prolonged.
4. The silicate inorganic adhesive has good high temperature resistance and heat insulation effects, general temperature resistance can reach 1200 ℃, and the silicate inorganic adhesive is flame-retardant and fireproof, and can play a good role in protecting metal from high-temperature oxidation. The ceramic sealing material can be used as an anti-oxidation ceramic protective layer of metal, can be used for bonding and positioning metal, ceramic and the like, and is also suitable for sealing high-temperature flanges, pipe threads and the like.
Detailed Description
Example one
Taking the following raw materials in proportion: a high-temperature-resistant silicate inorganic adhesive comprises a component A and a component B, wherein the component A comprises sodium silicate, distilled water, methyl cellulose and glycerol, and the component B comprises zirconium dioxide, aluminum oxide, ceramic microspheres and bentonite.
The component A comprises: sodium silicate: 2-50 parts of sodium hydroxide: 1-10 parts of distilled water: 10-200 parts of glycerol: 1-10 parts of methyl cellulose: 0.5-5 parts. And B component: zirconium dioxide: 10-20 parts of alumina: 20-40 parts of ceramic microspheres: 5-20 parts of bentonite: 5-10 parts.
Preparing a component A: adding sodium silicate into distilled water, stirring uniformly, preparing a sodium silicate solution, heating to 80-90 ℃, stirring, adding sodium hydroxide, adjusting to a solution with a modulus of 1.8-3.2, stirring, adding methyl cellulose to dissolve the methyl cellulose in the hot solution, and then dropwise adding glycerol to obtain the component A.
Preparing a component B: the preparation method comprises the following steps of fully mixing zirconium dioxide, aluminum oxide and bentonite, calcining for 1 hour at the high temperature of 1100-1200 ℃, cooling, grinding, sieving with a 325-mesh sieve, and adding ceramic microspheres to obtain the component B.
When in use, the component A and the component B are mixed according to the mass ratio of 1:1 proportion, after curing for 2 hours at 100 ℃, the lap joint shear strength of the steel and the steel is 3.5MPa, and the sleeving strength of the steel and the steel is 22.0 MPa.
Example two:
taking the following raw materials in proportion: a high-temperature-resistant silicate inorganic adhesive comprises a component A and a component B, wherein the component A comprises potassium silicate, distilled water, methyl cellulose and glycerol, and the component B comprises zirconium dioxide, aluminum oxide, titanium dioxide, ceramic microbeads and bentonite.
The component A comprises: potassium silicate: 2-50 parts of potassium hydroxide: 1-10 parts of distilled water: 10-200 parts of glycerol: 1-10 parts of methyl cellulose: 0.5-5 parts. And B component: zirconium dioxide: 10-20 parts of alumina: 20-40 parts of titanium dioxide: 5-20 parts of bentonite: 5-10 parts.
Preparing a component A: adding potassium silicate into distilled water, stirring uniformly, preparing a potassium silicate solution, heating to 80-90 ℃, stirring, adding potassium hydroxide, adjusting to a solution with a modulus of 1.8-3.2, stirring, adding methyl cellulose to dissolve the methyl cellulose in the hot solution, and then dropwise adding glycerol to obtain the component A. Preparing a component B: the component B is prepared by fully mixing zirconium dioxide, aluminum oxide, titanium dioxide and bentonite, calcining at the high temperature of 1100-1200 ℃ for 1 hour, cooling, grinding and sieving with a 325-mesh sieve.
When in use, the component A and the component B are mixed according to the mass ratio of 1:1 proportion, after curing for 2 hours at 100 ℃, the lap joint shear strength of the steel and the steel is 3.7MPa, and the sleeving strength of the steel and the steel is 25.5 MPa.
Example three:
taking the following raw materials in proportion: a high-temperature-resistant silicate inorganic adhesive comprises a component A and a component B, wherein the component A comprises potassium silicate, distilled water, methyl cellulose and glycerol, and the component B comprises zinc dioxide, silicon dioxide, magnesium oxide, ceramic microbeads and bentonite.
The component A comprises: potassium silicate: 2-50 parts of potassium hydroxide: 1-10 parts of distilled water: 10-200 parts of glycerol: 1-10 parts of methyl cellulose: 0.5-5 parts. And B component: zinc dioxide: 10-20 parts of silicon dioxide: 20-40 parts of magnesium oxide: 1-10 parts of bentonite: 5-10 parts.
Preparing a component A: adding potassium silicate into distilled water under stirring, preparing a potassium silicate solution, heating to 80-90 ℃, adding potassium hydroxide under stirring, adjusting the solution to a modulus of 1.8-3.2, adding methyl cellulose under stirring to dissolve the methyl cellulose in the hot solution, and then dropwise adding glycerol to obtain the component A.
Preparing a component B: the component B is prepared by fully mixing zirconium dioxide, silicon oxide, magnesium oxide and bentonite, calcining at the high temperature of 1100-1200 ℃ for 1 hour, cooling, grinding, and sieving with a 325-mesh sieve.
When in use, the component A and the component B are mixed according to the mass ratio of 1:1 proportion, after curing for 2 hours at 100 ℃, the lap joint shear strength of the steel and the steel is 3.2MPa, and the sleeving strength of the steel and the steel is 23.4 MPa.
As can be seen from the above examples, the present invention provides a high temperature resistant silicate inorganic adhesive, comprising a component A and a component B, wherein the component A comprises silicate, distilled water, methyl cellulose and glycerol, and the component B comprises metal oxide, ceramic beads and bentonite.
Further, the silicate is sodium silicate or potassium silicate, and the modulus is adjusted by sodium hydroxide or potassium hydroxide correspondingly; adding the silicate into distilled water in the using process, uniformly stirring to prepare a silicate solution, heating to 80-90 ℃, stirring and adding sodium hydroxide or potassium hydroxide, and adjusting to a solution with the modulus of 1.8-3.2; after the methyl cellulose is prepared with silicate solution, the temperature is raised to 80-90 ℃, the methyl cellulose is stirred and added, so that the methyl cellulose is dissolved in hot solution, and then glycerin is dripped.
Further, the metal oxide is one or more of magnesium oxide, copper oxide, zirconium dioxide, aluminum oxide, titanium dioxide, zinc dioxide, silicon dioxide and boron oxide, and is calcined at the high temperature of 1100-1200 ℃ for 1 hour, cooled, ground and sieved by a 325-mesh sieve.
Further, the component A comprises the following components in parts by weight: silicate salt: 2-50 parts of distilled water: 10-200 parts of sodium hydroxide or potassium hydroxide: 1-10 parts of methyl cellulose: 0.5-5 parts of glycerol: 1-10 parts.
Further, the component B comprises the following components in parts by weight: metal oxide(s): 30-80 parts of bentonite, 5-10 parts of bentonite.
Further, when the adhesive has a heat insulation requirement, ceramic beads are added into the component B, and the adding amount is 5-20 parts of the component B.
Further, when the inorganic adhesive is used, the using amount of the component A and the component B is 1:1 by mass ratio.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (3)
1. A silicate inorganic adhesive is characterized in that: the adhesive comprises a component A and a component B, wherein the component A comprises the following components in parts by weight: 2-50 parts of sodium silicate; 10-200 parts of distilled water; 1-10 parts of sodium hydroxide; 0.5-5 parts of methyl cellulose; 1-10 parts of glycerol;
the component B comprises the following components in parts by weight: 10-20 parts of zirconium dioxide; 20-40 parts of aluminum oxide; 5-20 parts of ceramic microspheres; 5-10 parts of bentonite.
2. A method for preparing the silicate inorganic adhesive according to claim 1, wherein the method comprises the following steps: the preparation method comprises the steps of preparing a component A and preparing a component B;
the preparation of the component A comprises the following steps:
dissolving sodium silicate in distilled water to obtain a sodium silicate solution;
heating the sodium silicate solution to 80-90 ℃, adding sodium hydroxide under the stirring condition, and adjusting the solution into a solution with the modulus of 1.8-3.2;
under the condition of stirring, adding methyl cellulose into the solution with the modulus of 1.8-3.2 for dissolving, and then dropwise adding glycerol for mixing to obtain a component A;
the preparation of the component B comprises the following steps:
mixing zirconium dioxide, aluminum oxide and bentonite, and sequentially calcining, cooling, grinding and sieving the obtained mixed material with a 325-mesh sieve to obtain a primary component B;
mixing the primary component B with ceramic microspheres to obtain a component B;
the calcining temperature is 1100-1200 ℃, and the calcining time is 1 h.
3. The use method of the silicate inorganic adhesive according to claim 1, characterized in that, in use, the A component and the B component are mixed and then cured; the mass ratio of the component A to the component B is 1: 1; the curing temperature is 100 ℃, and the curing time is 2 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111140148.1A CN113683966A (en) | 2016-10-27 | 2016-10-27 | Silicate inorganic adhesive and preparation method and use method thereof |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610955112.1A CN106519993A (en) | 2016-10-27 | 2016-10-27 | Silicate inorganic adhesive and preparation method thereof |
| CN202111140148.1A CN113683966A (en) | 2016-10-27 | 2016-10-27 | Silicate inorganic adhesive and preparation method and use method thereof |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610955112.1A Division CN106519993A (en) | 2016-10-27 | 2016-10-27 | Silicate inorganic adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113683966A true CN113683966A (en) | 2021-11-23 |
Family
ID=58326819
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111140148.1A Pending CN113683966A (en) | 2016-10-27 | 2016-10-27 | Silicate inorganic adhesive and preparation method and use method thereof |
| CN201610955112.1A Pending CN106519993A (en) | 2016-10-27 | 2016-10-27 | Silicate inorganic adhesive and preparation method thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610955112.1A Pending CN106519993A (en) | 2016-10-27 | 2016-10-27 | Silicate inorganic adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN113683966A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115572575A (en) * | 2022-10-26 | 2023-01-06 | 合肥科天水性科技有限责任公司 | Environment-friendly water-based wood adhesive and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108191379A (en) * | 2018-01-24 | 2018-06-22 | 广东猛人高科技防火保温材料有限公司 | A kind of antiacid glue of fire prevention |
| CN112898904B (en) * | 2021-01-25 | 2022-08-16 | 株洲世林聚合物有限公司 | High-temperature-resistant inorganic adhesive and preparation method thereof |
| CN113979772A (en) * | 2021-11-05 | 2022-01-28 | 广东省科学院新材料研究所 | Porous ceramic, binder thereof, preparation method and application thereof |
| CN115353809A (en) * | 2022-09-21 | 2022-11-18 | 重庆华裕胜久材料科技有限公司 | High-temperature-resistant inorganic adhesive and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4018616A (en) * | 1974-09-13 | 1977-04-19 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Water glass composition |
| CN1153802A (en) * | 1995-12-06 | 1997-07-09 | 姜洪江 | Prodn of high-strength construction glue |
| WO2005071033A2 (en) * | 2004-01-23 | 2005-08-04 | R-Amtech International, Inc. | Method of production of polysilicate binder for adhesives and coatings, polysilicate binder, adhesive composition for adhesives and coating on its basis |
| CN104099028A (en) * | 2014-08-04 | 2014-10-15 | 公安部四川消防研究所 | Fire-proof adhesive and application thereof |
| CN105295741A (en) * | 2015-11-18 | 2016-02-03 | 中国建筑材料科学研究总院 | Fire-proof glue of fire-proof glass, preparation method thereof and composite fire-proof glass |
| CN105623532A (en) * | 2016-03-17 | 2016-06-01 | 淄博市新材料研究所 | High-temperature-resistant inorganic composite adhesive and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62132982A (en) * | 1985-12-04 | 1987-06-16 | Matsushita Electric Works Ltd | Heat-resistant adhesive |
| CN1067666A (en) * | 1988-01-25 | 1993-01-06 | 戴元宁 | The purification treating method of fleut |
| CN1253156A (en) * | 1998-10-30 | 2000-05-17 | 中国科学院生态环境研究中心 | Adhesive for ceramics |
| CN101050341B (en) * | 2007-05-21 | 2011-06-22 | 张焰峰 | Cement based adhesive, and preparation method |
| CN104140771A (en) * | 2014-08-06 | 2014-11-12 | 张建斌 | Aldehyde-free anti-static adhesive and preparation method thereof |
| US10703879B2 (en) * | 2014-12-30 | 2020-07-07 | The Boeing Company | Process and formulation to join ceramic forms while maintaining structural and physical characteristics across the bond surface |
-
2016
- 2016-10-27 CN CN202111140148.1A patent/CN113683966A/en active Pending
- 2016-10-27 CN CN201610955112.1A patent/CN106519993A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4018616A (en) * | 1974-09-13 | 1977-04-19 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Water glass composition |
| CN1153802A (en) * | 1995-12-06 | 1997-07-09 | 姜洪江 | Prodn of high-strength construction glue |
| WO2005071033A2 (en) * | 2004-01-23 | 2005-08-04 | R-Amtech International, Inc. | Method of production of polysilicate binder for adhesives and coatings, polysilicate binder, adhesive composition for adhesives and coating on its basis |
| CN104099028A (en) * | 2014-08-04 | 2014-10-15 | 公安部四川消防研究所 | Fire-proof adhesive and application thereof |
| CN105295741A (en) * | 2015-11-18 | 2016-02-03 | 中国建筑材料科学研究总院 | Fire-proof glue of fire-proof glass, preparation method thereof and composite fire-proof glass |
| CN105623532A (en) * | 2016-03-17 | 2016-06-01 | 淄博市新材料研究所 | High-temperature-resistant inorganic composite adhesive and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115572575A (en) * | 2022-10-26 | 2023-01-06 | 合肥科天水性科技有限责任公司 | Environment-friendly water-based wood adhesive and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106519993A (en) | 2017-03-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113683966A (en) | Silicate inorganic adhesive and preparation method and use method thereof | |
| CN103172330B (en) | Environment-friendly colorful tile joint mixture and preparation method thereof | |
| CN104945997A (en) | External wall flexible waterproof putty powder and preparation method thereof | |
| CN101544856B (en) | External wall putty | |
| CN103058607B (en) | Binder for installation of thermal insulation decorative plate | |
| CN110791242A (en) | Bi-component epoxy seam beautifying agent and preparation method thereof | |
| CN106145827A (en) | A kind of ceramic tile bond | |
| CN106497203A (en) | Heat insulating inner wall putty powder and its production technology | |
| CN106830994A (en) | A kind of solar heat reflecting and heat insulating thermal coating structure and preparation method thereof | |
| CN103275565B (en) | A kind of for exterior wall heat-reflecting heat-insulating thermal-insulating waterproof latex coating | |
| CN105419447A (en) | Interior wall putty and preparation method thereof | |
| CN109111883A (en) | A kind of architectural engineering AB glue binder and its preparation process | |
| CN104844078A (en) | Polymer repairing mortar and preparation method thereof | |
| WO2015035840A1 (en) | Three-in-one mosaic adhesive for pasting, seam-filling and water-resisting | |
| CN101381546A (en) | Microhollow super-fibre heat insulation coatings for building insulation and method of use thereof | |
| CN106554743A (en) | Acoustic mastic and preparation method thereof is built in a kind of high one-component epoxy resin capital construction of corrosion resistance adhesion strength | |
| CN108531026A (en) | A kind of polymer eakleite cementitious composite water-proof heat-insulating paint | |
| CN104845531A (en) | Waterproof crack-resistant external wall thermal insulation coating and preparation method thereof | |
| CN109336488B (en) | High-temperature-resistant waterproof tile joint mixture and preparation process thereof | |
| CN106554745A (en) | Acoustic mastic and preparation method thereof is built in a kind of environment-friendly type anophelifuge one-component epoxy resin capital construction | |
| CN110423507A (en) | A kind of thermal insulative anti-crack powder of lacquer putty for use on and preparation method thereof | |
| CN106064917A (en) | Bonding mortar for bonding Light trabs Yu warming plate | |
| CN104860610A (en) | High viscosity building wall repair material | |
| CN108658529A (en) | A kind of building inorganic sealant and preparation method thereof | |
| CN113502091A (en) | Waterproof plugging material for civil building materials and processing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211123 |
|
| RJ01 | Rejection of invention patent application after publication |