CN106145827A - A kind of ceramic tile bond - Google Patents

A kind of ceramic tile bond Download PDF

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Publication number
CN106145827A
CN106145827A CN201610542127.5A CN201610542127A CN106145827A CN 106145827 A CN106145827 A CN 106145827A CN 201610542127 A CN201610542127 A CN 201610542127A CN 106145827 A CN106145827 A CN 106145827A
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CN
China
Prior art keywords
parts
ceramic tile
quartz sand
polyvinyl alcohol
latex powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610542127.5A
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Chinese (zh)
Inventor
王兴文
徐荣平
汤萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU LANQUAN NEW MATERIAL CO Ltd
Original Assignee
JIANGSU LANQUAN NEW MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU LANQUAN NEW MATERIAL CO Ltd filed Critical JIANGSU LANQUAN NEW MATERIAL CO Ltd
Priority to CN201610542127.5A priority Critical patent/CN106145827A/en
Publication of CN106145827A publication Critical patent/CN106145827A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/10Mortars, concrete or artificial stone characterised by specific physical values for the viscosity
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of ceramic tile bond, component including following weight proportion: Portland cement 300 400 parts, triple superphosphate 50 100 parts, 40 70 mesh quartz sand 200 250 parts, 70 100 mesh quartz sand 350 400 parts, redispersable latex powder 10 20 parts, organosilicon moisture repellent 48 parts, cellulose 2 3.5 parts, lignocellulose 1 1.5 parts, polyvinyl alcohol 12 parts.Ceramic tile bond cohesive force of the present invention is strong, plasticity is less, has good workability, ageing-resistant.

Description

A kind of ceramic tile bond
Technical field
The invention belongs to building material technical field, be specifically related to a kind of binding agent for ceramic tile.
Background technology
Tile decorative surface system is one of decorative encasing the most frequently used in China's architectural engineering;There is strong shock resistance, resistance to The features such as long good, the easy cleaning of property;But also it is often accompanied with infiltration, hollowing, the puzzlement of several big persistent ailments such as come off.The most domestic make porcelain Bonding, pointing that brick facing is conventional have: neat slurry, cement mortar, ceramic tile bond and silica gel etc..In these materials pure Cement, cement mortar rigidity are big, and water absorption rate is big, can produce powerful thermal expansion internal stress and the winter of severe cold in hot heat System freezes after absorbing water and also can produce powerful swelling internal stress.Owing to cement is hydraulic material, formed with hydrate Behavior of Hardened Cement Paste, typically needs to can be only achieved for 28 days design strength, premature dehydration, and aquation stops, and intensity the most no longer rises, cement material Being the plastic material of blunging, volume shrinks along with the evaporation of moisture, in contraction process, if cement material does not also have Intensity or intensity are the lowest, and shrinkage stress is more than the tension stress of material, and amount of contraction will show as comparing the large fracture of concentration, and Exist due to variations in temperature cause expand, shrink and produce the problem in crack, these internal stress destroy combination interface cause hollowing, Come off.Return home is expensive, the most aging, and is difficult to control flatness in work progress.
In developed countries such as America and Europes, almost all of tile paste engineering all uses conformance with standard JC/T547 " pottery wall ground Brick adhesive " serial adhesive.JC/T547 standard has been carried out more than 20 year in China, but in the patch block engineering that China is actual, The glue for tile meeting this mark does not obtain substantial amounts of universal use.It is reported, China still adopts close to the patch block engineering of 90% Constructing with Site cement sand (or scene adds some building glues), not only labor intensity is big, construction environment is poor, and And final stickup potential safety hazard is greatly, the most in recent years, large scale, low water absorption vitrified tile were pasted engineering hollow drum, were taken off The quality problems such as fall get more and more;And, although the patch block engineering that there are about about 10% have employed Ceramic Tiles adhesive, but still deposits Some due to material do not mate with ceramic tile, the series of problems such as early strength is low, open assembly time is short, sliding, and when construction Easily trickling destruction facing flatness, efficiency of construction and stickup safety do not obtain the raising of reality.
Summary of the invention
The invention aims to solve defect present in prior art, it is provided that a kind of cohesive force is strong, plasticity relatively Little, have good workability, ageing-resistant binding agent.
In order to achieve the above object, the invention provides a kind of ceramic tile bond, including the component of following weight proportion: general Logical portland cement 300-400 part, triple superphosphate 50-100 part, 40-70 mesh quartz sand 200-250 part, 70-100 mesh quartz sand 350- 400 parts, redispersable latex powder 10-20 part, organosilicon moisture repellent 4-8 part, cellulose 2-3.5 part, lignocellulose 1-1.5 Part, polyvinyl alcohol 1-2 part.
Wherein, redispersable latex powder is prepared by following raw material: polyvinyl acetate-vac emulsion 40%, acrylic emulsion 30%, Ammonium persulfate. 1%, cellulose ether 3%, polyvinyl alcohol 15%, calcite in powder 10% and tributyl phosphate 1%.By the following method Preparation: polyvinyl acetate-vac emulsion and acrylic emulsion are added after stirring in reactor, after being heated to 80 DEG C, depend on Secondary addition Ammonium persulfate., cellulose ether, polyvinyl alcohol, calcite in powder, tributyl phosphate and water, be warming up to 110 DEG C of reactions 4 little Time, after reaction terminates, carry out atomization drying, obtain described redispersable latex powder;The addition of water is redispersable latex powder The 4%-15% of raw material gross weight.
The best composition weight proportion of binding agent of the present invention is: Portland cement 380 parts, triple superphosphate 60 parts, 40-70 mesh Quartz sand 230 parts, 70-100 mesh quartz sand 370 parts, redispersable latex powder 12 parts, organosilicon moisture repellent 5 parts, cellulose 3 parts, Lignocellulose 1 part, polyvinyl alcohol 1 part.
The present invention has the advantage that compared to existing technology and utilizes polyvinyl alcohol, is sticked together with cement and sand, significantly Add the adhesive force of ceramic tile and basic unit, dramatically increase the early strength of ceramic tile bond simultaneously, improve mortar cohesiveness, thus Improve the anti-slipping property of ceramic tile adhesive, adhesive property, after solving caducous technical problem and the tile paste of ceramic tile Slippage, make construction more quick neat.Use the redispersable latex powder of ternary polymerization, there is the resistance to water of former latex The feature that good and elasticity is high, environmental protection, cohesive force is strong, water resistance good, pliability is high and ageing-resistant.Simultaneously by redispersible breast Rubber powder and organosilicon moisture repellent compound, and utilize both hydrolysis film forming to be wrapped in around inorganic coagulation material, after material solidifies Form plasticity ligament between inorganic gel granule, the pliability of binding agent can be increased, improve shock resistance, anti-folding, stretch-proof, contraction Etc. adaptability to changes, hinder the brittle break such as temperature stress or the impact of other external force generation, expansion or shrinkage, make binding agent simultaneously There is the strongest impervious, waterproof ability.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
The preparation of redispersable latex powder:
Raw material weight proportioning: polyvinyl acetate-vac emulsion 40 parts, acrylic emulsion 30 parts, Ammonium persulfate. 1 part, cellulose ether 3 Part, polyvinyl alcohol 15 parts, calcite in powder 10 parts and tributyl phosphate 1 part, 10 parts of water.
Preparation process: polyvinyl acetate-vac emulsion and acrylic emulsion are added after stirring in reactor, heating After 80 DEG C, it is sequentially added into Ammonium persulfate., cellulose ether, polyvinyl alcohol, calcite in powder, tributyl phosphate and water, is warming up to 110 DEG C reaction 4 hours, reaction terminate after, carry out atomization drying, cool down and get final product.
Binder component weight proportion: Portland cement (po42.5) 300 parts, triple superphosphate 50 parts, 40-70 mesh quartz sand 200 parts, 70-100 mesh quartz sand 350 parts, redispersable latex powder 10 parts, organosilicon moisture repellent 4 parts, cellulose 2 parts, wooden fibre Dimension element 1 part, polyvinyl alcohol 1 part.
The adhesive strength prepared is 1.0MPa, and immersion intensity is 0.8MPa, and hanging rear intensity is 0.75MPa, heat Aging intensity is 0.85MPa, and freeze-thawing resistant intensity is 0.7MPa.
Embodiment 2
The preparation of redispersable latex powder is with embodiment 1.
Binder component weight proportion: Portland cement (po42.5) 400 parts, triple superphosphate 100 parts, 40-70 mesh quartz 250 parts of sand, 70-100 mesh quartz sand 400 parts, redispersable latex powder 20 parts, organosilicon moisture repellent 8 parts, cellulose 3.5 parts, wood Matter cellulose 1.5 parts, polyvinyl alcohol 2 parts.
The adhesive strength prepared is 1.0MPa, and immersion intensity is 0.85MPa, and hanging rear intensity is 0.8MPa, heat Aging intensity is 0.8MPa, and freeze-thawing resistant intensity is 0.7MPa.
Embodiment 3
The preparation of redispersable latex powder is with embodiment 1.
Binder component weight proportion: Portland cement (po42.5) 380 parts, triple superphosphate 60 parts, 40-70 mesh quartz sand 230 parts, 70-100 mesh quartz sand 370 parts, redispersable latex powder 12 parts, organosilicon moisture repellent 5 parts, cellulose 3 parts, wooden fibre Dimension element 1 part, polyvinyl alcohol 1 part.
The adhesive strength prepared is 1.1MPa, and immersion intensity is 0.85MPa, and hanging rear intensity is 0.75MPa, heat Aging intensity is 0.95MPa, and freeze-thawing resistant intensity is 0.75MPa.

Claims (4)

1. a ceramic tile bond, it is characterised in that include the component of following weight proportion: Portland cement 300-400 Part, triple superphosphate 50-100 part, 40-70 mesh quartz sand 200-250 part, 70-100 mesh quartz sand 350-400 part, redispersable latex powder 10-20 part, organosilicon moisture repellent 4-8 part, cellulose 2-3.5 part, lignocellulose 1-1.5 part, polyvinyl alcohol 1-2 part.
Ceramic tile bond the most according to claim 1, it is characterised in that described redispersable latex powder passes through following raw material Preparation: polyvinyl acetate-vac emulsion 40%, acrylic emulsion 30%, Ammonium persulfate. 1%, cellulose ether 3%, polyvinyl alcohol 15%, Calcite in powder 10% and tributyl phosphate 1%.
Ceramic tile bond the most according to claim 2, it is characterised in that described redispersable latex powder is by the following method Preparation: polyvinyl acetate-vac emulsion and acrylic emulsion are added after stirring in reactor, after being heated to 80 DEG C, depend on Secondary addition Ammonium persulfate., cellulose ether, polyvinyl alcohol, calcite in powder, tributyl phosphate and water, be warming up to 110 DEG C of reactions 4 little Time, after reaction terminates, carry out atomization drying, obtain described redispersable latex powder;The addition of described water is redispersible breast The 4%-15% of rubber powder raw material gross weight.
Ceramic tile bond the most according to claim 3, it is characterised in that described binding agent includes the group of following weight proportion Point: Portland cement 380 parts, triple superphosphate 60 parts, 40-70 mesh quartz sand 230 parts, 70-100 mesh quartz sand 370 parts, can divide again Dissipate latex powder 12 parts, organosilicon moisture repellent 5 parts, cellulose 3 parts, lignocellulose 1 part, polyvinyl alcohol 1 part.
CN201610542127.5A 2016-07-12 2016-07-12 A kind of ceramic tile bond Pending CN106145827A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610542127.5A CN106145827A (en) 2016-07-12 2016-07-12 A kind of ceramic tile bond

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610542127.5A CN106145827A (en) 2016-07-12 2016-07-12 A kind of ceramic tile bond

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630826A (en) * 2016-12-15 2017-05-10 苏州市世好建材新技术工程有限公司 High-performance mortar for ceramic tile
CN106746949A (en) * 2016-11-24 2017-05-31 安庆市凯瑞建材有限公司 A kind of ceramic tile bond and preparation method thereof
CN107129242A (en) * 2017-06-06 2017-09-05 肥西县碧涛建材有限公司 A kind of ceramic tile adhesive and preparation method thereof
CN107880848A (en) * 2017-10-25 2018-04-06 刘彦麟 A kind of floor tile decontamination antilubricant and floor tile decontaminate anti-skidding method
CN108382011A (en) * 2018-04-16 2018-08-10 广东金意陶陶瓷集团有限公司 A kind of film decorative porcelain plank and preparation method thereof
CN108396929A (en) * 2018-04-16 2018-08-14 广东金意陶陶瓷集团有限公司 A kind of composite ceramics plank and preparation method thereof
CN108396924A (en) * 2018-04-16 2018-08-14 广东金意陶陶瓷集团有限公司 A kind of porous ceramics dalle
CN108554752A (en) * 2018-04-16 2018-09-21 广东金意陶陶瓷集团有限公司 A kind of porous ceramics dalle and preparation method thereof with lacquer
CN108585684A (en) * 2018-05-17 2018-09-28 北京宝辰联合科技股份有限公司 A kind of cement base Ceramic Tiles adhesive
CN108863249A (en) * 2018-07-28 2018-11-23 河南强耐新材股份有限公司 A kind of floor tile, which is splashed, flows glue and its construction method
CN109678431A (en) * 2019-02-15 2019-04-26 衢州市逸宏建材有限公司 A kind of the viscose glue mud and its preparation process of high intensity
WO2020048603A1 (en) * 2018-09-06 2020-03-12 Wacker Chemie Ag Polymer powder compositions which can be redispersed in water

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220250A (en) * 2007-12-28 2008-07-16 烟建集团有限公司 Environment protection type multifunction architecture adhesion agent and method for producing the same
CN101830675A (en) * 2010-05-14 2010-09-15 山西元立科技开发有限公司 Tile adhesive
CN101880512A (en) * 2010-07-14 2010-11-10 浙江德尚化工科技有限公司 Aqueous binding agent and preparation method thereof
CN104193257A (en) * 2014-08-06 2014-12-10 南京市苏宝节能科技有限公司 Dry material applied to adhering exterior wall tiles
US9169382B2 (en) * 2012-03-09 2015-10-27 Dow Global Technologies Llc Carboxyl group containing acrylic RDP and dry mix cement formulations containing them

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220250A (en) * 2007-12-28 2008-07-16 烟建集团有限公司 Environment protection type multifunction architecture adhesion agent and method for producing the same
CN101830675A (en) * 2010-05-14 2010-09-15 山西元立科技开发有限公司 Tile adhesive
CN101880512A (en) * 2010-07-14 2010-11-10 浙江德尚化工科技有限公司 Aqueous binding agent and preparation method thereof
US9169382B2 (en) * 2012-03-09 2015-10-27 Dow Global Technologies Llc Carboxyl group containing acrylic RDP and dry mix cement formulations containing them
CN104193257A (en) * 2014-08-06 2014-12-10 南京市苏宝节能科技有限公司 Dry material applied to adhering exterior wall tiles

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106746949A (en) * 2016-11-24 2017-05-31 安庆市凯瑞建材有限公司 A kind of ceramic tile bond and preparation method thereof
CN106630826A (en) * 2016-12-15 2017-05-10 苏州市世好建材新技术工程有限公司 High-performance mortar for ceramic tile
CN107129242A (en) * 2017-06-06 2017-09-05 肥西县碧涛建材有限公司 A kind of ceramic tile adhesive and preparation method thereof
CN107880848A (en) * 2017-10-25 2018-04-06 刘彦麟 A kind of floor tile decontamination antilubricant and floor tile decontaminate anti-skidding method
CN108396924A (en) * 2018-04-16 2018-08-14 广东金意陶陶瓷集团有限公司 A kind of porous ceramics dalle
CN108396929A (en) * 2018-04-16 2018-08-14 广东金意陶陶瓷集团有限公司 A kind of composite ceramics plank and preparation method thereof
CN108382011A (en) * 2018-04-16 2018-08-10 广东金意陶陶瓷集团有限公司 A kind of film decorative porcelain plank and preparation method thereof
CN108554752A (en) * 2018-04-16 2018-09-21 广东金意陶陶瓷集团有限公司 A kind of porous ceramics dalle and preparation method thereof with lacquer
CN108396929B (en) * 2018-04-16 2023-09-29 广东金意陶陶瓷集团有限公司 Composite ceramic plate and preparation method thereof
CN108585684A (en) * 2018-05-17 2018-09-28 北京宝辰联合科技股份有限公司 A kind of cement base Ceramic Tiles adhesive
CN108863249A (en) * 2018-07-28 2018-11-23 河南强耐新材股份有限公司 A kind of floor tile, which is splashed, flows glue and its construction method
WO2020048603A1 (en) * 2018-09-06 2020-03-12 Wacker Chemie Ag Polymer powder compositions which can be redispersed in water
CN112601785A (en) * 2018-09-06 2021-04-02 瓦克化学股份公司 Polymer powder composition redispersible in water
CN109678431A (en) * 2019-02-15 2019-04-26 衢州市逸宏建材有限公司 A kind of the viscose glue mud and its preparation process of high intensity

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