CN103172330B - Environment-friendly colorful tile joint mixture and preparation method thereof - Google Patents

Environment-friendly colorful tile joint mixture and preparation method thereof Download PDF

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CN103172330B
CN103172330B CN 201310079858 CN201310079858A CN103172330B CN 103172330 B CN103172330 B CN 103172330B CN 201310079858 CN201310079858 CN 201310079858 CN 201310079858 A CN201310079858 A CN 201310079858A CN 103172330 B CN103172330 B CN 103172330B
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powder
waste
vinyl acetate
tile grout
water
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CN103172330A (en
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李明利
杨顺荣
林丽霞
肖尾俭
廖毅坚
张彬腾
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厦门路桥翔通股份有限公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/90Reuse, recycling or recovery technologies cross-cutting to different types of waste
    • Y02W30/91Use of waste materials as fillers for mortars or concrete
    • Y02W30/95Use of waste materials as fillers for mortars or concrete from building or ceramic industry

Abstract

本发明公开一种环保型彩色瓷砖填缝剂,其特征在于,以重量百分比计,包括如下组分:白水泥35-40%;废瓷粉40.73-47.75%;石英粉0-15%;钛白粉0-10%;可再分散性乳胶粉1-1.5%;憎水剂0.1%;保水剂0.15%;木质素纤维0.4%;减水剂0.1-0.25%;颜料0-2%。 The present invention discloses an environmentally friendly colored tile grout, characterized in that, in weight percent, comprising the following components: 35-40% of white cement; waste ceramic powder 40.73-47.75%; 0-15% quartz powder; titanium white powder 0-10%; re-dispersible emulsion powder 1-1.5%; 0.1% hydrophobic agent; aquasorb 0.15%; 0.4% lignin fiber; superplasticizer 0.1-0.25%; 0-2% pigment. 同时公开了该环保型彩色瓷砖填缝剂的制备方法,通过使用废瓷粉作为填缝剂填料,减少了石英砂和重钙粉的消耗,通过白水泥的早强作用,提高填缝剂早期强度,满足施工工序要求。 Also discloses a method for preparing the color tile grout environmentally friendly by using the waste ceramic powder as a filler grout, quartz sand and reducing the consumption of heavy calcium, by the white cement early strength, improve early caulks strength, to meet the requirements of the construction process. 废瓷粉经过高温烧结,物理化学性能稳定,体积稳定,与瓷砖膨胀收缩系数接近,采用同样膨胀收缩系数的材料作为填料,可以进一步减少瓷砖填缝剂产生裂缝的可能性。 Waste after high temperature sintering ceramic powder, stable physical and chemical properties, volume-stable, coefficient of expansion and contraction close to the tiles, using a material the same coefficient of expansion and contraction as a filler, it may further reduce the possibility of cracks in the tile grout.

Description

一种环保型彩色瓷砖填缝剂及其制备方法 An eco-friendly method of preparation and color tile grout

技术领域 FIELD

[0001] 本发明涉及一种用于建筑工程的瓷砖填缝剂,尤其涉及一种环保型彩色瓷砖填缝剂及其制备方法。 [0001] The present invention relates to a tile grout for building works, in particular, relates to an eco-friendly method of preparation and color tile grout.

背景技术 Background technique

[0002] 在现代的建筑物中瓷砖已成为主要的建筑材料广泛地用于建筑物的内外墙壁及地面的装饰装修,为避免瓷砖与之间由于热胀冷缩而产生空鼓,瓷砖与瓷砖之间需预留一定的缝隙,该缝隙需要瓷砖填缝剂来填充。 [0002] In modern buildings ceramic tile decoration has become the main construction material widely used in internal and external walls and floors of the building, in order to avoid thermal expansion and contraction and hollowing tiles, tile and ceramic tile and between between the need to set aside a certain gap which needs to tile grout to fill. 瓷砖填缝剂应具有与瓷砖接近的膨胀系数和一定的柔性,可以随瓷砖一同膨胀收缩,以避免产生裂缝。 Tile grout should have a coefficient of expansion close to ceramic tiles and a certain flexibility, it can be tiled together with expansion and contraction, in order to avoid cracks. 瓷砖填缝剂的主要组份为胶凝材料、填料和添加剂,胶凝材料赋予填缝剂粘接力,添加剂赋予填缝剂良好的施工性、柔性和其他功能性,而填料对填缝剂的体积稳定性和最终的膨胀收缩系数有很大的影响。 The main parts of tile grout group gelling materials, fillers and additives, gelling sealant adhesion imparting materials, caulks additive imparts good workability, flexibility and other functional, caulks and fillers on the final expanded volume stability and shrinkage factor has a great influence. 采用同样膨胀收缩系数的材料作为填料,可以进一步减少瓷砖填缝剂产生裂缝的可能性。 Using a material the same coefficient of expansion and contraction as a filler, it may further reduce the possibility of cracks in the tile grout.

[0003] 同时,废瓷粉作为一种工业垃圾很难分解,堆放占用耕地,已经严重的污染环境。 [0003] At the same time, waste ceramic powder as an industrial waste is difficult to break down, piling farmland, it has been seriously polluted the environment. 将废瓷粉作为建筑材料大量使用,可以使资源得到综合利用,环保利废。 Waste ceramic powder widely used as a building material, it can make comprehensive utilization of resources, environmental protection and waste utilization. 废瓷粉经过高温烧结,物理化学性能稳定,其本身具有一定颜色,通过加入少量氧化铁颜料,可以使填缝剂颜色稳定,色差减小,不影响填缝剂的品质。 Waste after high temperature sintering ceramic powder, stable physical and chemical properties, which itself has a certain color, by adding a small amount of iron oxide pigments, color stability can sealant, reduced color, does not affect the quality of the caulk.

[0004] 中国专利公开号CN101948285A和CN101337806的发明专利申请,虽然公开了利用废瓷粉制备瓷釉和硅酸钙材料的组分及方法,但是制备瓷砖填缝剂要解决的技术问题与制备瓷釉和硅酸钙材料各不相同,利用废瓷粉制备瓷砖填缝剂的技术关键在于组合物的组分和含量的选择。 [0004] Chinese Patent Publication No. CN101337806 CN101948285A and invention patent applications, while disclosing the use of waste enamel and porcelain powder components and preparation method of calcium silicate materials, tile grouts prepared but technical problems to be solved by the preparation of enamel and calcium silicate material vary, waste ceramic powder prepared using the tile grout in the art that the selection key components and contents of the composition.

发明内容 SUMMARY

[0005] 本发明的目的在于提供一种适用于建筑外墙和内墙家装的用废瓷粉作填料的环保彩色瓷砖填缝剂。 [0005] The object of the present invention is to provide a suitable and interior decoration of the building exterior ceramic powder as a filler with waste green colored tile grout.

[0006] 为了实现上述发明目的,本发明采用的技术方案为: [0006] In order to achieve the above object, the technical solution adopted by the invention is:

[0007] 一种环保型彩色瓷砖填缝剂,以重量百分比计,包括如下组分: [0007] A colored tile grout environmentally friendly, in weight percent, comprising the following components:

[0008]白水泥35-40% ; [0008] 35-40% of white cement;

[0009]废瓷粉40. 73-47. 75% ; [0009] 40. A waste ceramic powder 73-4775%;

[0010]石英粉0-15%; [0010] 0-15% quartz powder;

[0011]钛白粉0-10%; [0011] 0-10% titanium dioxide;

[0012] 可再分散性乳胶粉1-1. 5% ; [0012] The re-dispersible emulsion powder 1-15%;

[0013]憎水剂0.1%; [0013] 0.1% hydrophobic agent;

[0014]保水剂0.15%; [0014] 0.15% water retaining agent;

[0015] 木质素纤维0.4%; [0015] 0.4% vegetable fiber;

[0016]减水剂0. 1-0. 25% ; . [0016] 1-025 superplasticizer 0.5%;

[0017]颜料0-2% ; [0017] 0-2% pigment;

[0018] 所述废瓷粉为从陶瓷生产工艺中直接获得或将废陶瓷进行破碎、球磨制粉而得。 [0018] The ceramic powder is crushed waste is obtained directly from the ceramic or ceramic waste production processes, ball milling derived.

[0019] 其中,所述废瓷粉的粒径小于0. 81mm。 [0019] wherein said ceramic powder is a waste particle size less than 0. 81mm.

[0020] 其中,所述白水泥为42. 5号白色快硬硫铝酸盐水泥或氧化铝含量在70%以上的白色招酸盐水泥。 [0020] wherein, the white cement is a rapid hardening No. 42.5 white sulphoaluminate cement or alumina content of 70% or more strokes white Portland cement.

[0021] 其中,所述石英粉为重钙粉,所述重钙粉和钛白粉的粒径在100目-400目之间。 [0021] wherein the silica powder is a heavy calcium, heavy calcium powder and the titanium dioxide particle size between 100 mesh -400 mesh.

[0022] 其中,所述可再分散性乳胶粉为醋酸乙烯酯与乙烯共聚胶粉、乙烯与氯乙烯及月硅酸乙烯酯三元共聚胶粉、醋酸乙烯酯与乙烯及高级脂肪酸乙烯酯三元共聚胶粉、醋酸乙烯酯与高级脂肪酸乙烯酯共聚胶粉、丙烯酸酯与苯乙烯共聚胶粉、醋酸乙烯酯与丙烯酸酯及高级脂肪酸乙烯酯三元共聚胶粉、醋酸乙烯酯均聚胶粉、苯乙烯与丁二烯共聚胶粉、丙烯酸均聚胶粉中的一种或两种以上混合物。 [0022] wherein, the re-dispersible emulsion powder of vinyl acetate and ethylene copolymer powder, vinyl chloride and of ethylene and vinyl acetate terpolymer months silicate powder, of vinyl acetate with ethylene and vinyl esters of higher fatty three membered copolymer powder, vinyl acetate and a higher fatty acid vinyl acetate copolymer powder, methacrylate powder copolymerized with styrene, vinyl acetate and acrylic acid ester and a higher fatty acid vinyl acetate terpolymer powder, powder of vinyl acetate homo- styrene and butadiene copolymer powder, methacrylate powder homopolymerization of one or a mixture of two or more.

[0023] 其中,所述憎水剂为粉末有机硅憎水剂。 [0023] wherein the water-repellent agent is a silicone hydrophobic agent powder.

[0024] 其中,所述保水剂为羟丙基甲基纤维素醚,且其粘度在10000-40000mPa. s之间。 [0024] wherein said water retaining agent is hydroxypropyl methyl cellulose ether, and a viscosity 10000-40000mPa. Between s.

[0025] 其中,所述减水剂为聚羧酸粉剂减水剂,减水率> 20%,含水率< 3%,氯离子含量^ 0. lwt%。 [0025] wherein the water reducing agent is a polycarboxylate superplasticizer powders, water reduction of> 20%, water content <3%, chloride ion content ^ 0. lwt%.

[0026] 为了实现上述发明目的,本发明采用的又一技术方案为: [0026] In order to achieve the above object, another aspect of the present invention is used are:

[0027] 一种环保型彩色瓷砖填缝剂的制备方法,包括以下步骤: [0027] environmentally friendly method for producing a colored tile grout, comprising the steps of:

[0028] 1)按重量百分比称取以下组分: [0028] 1) weight percent weighed the following components:

[0029]白水泥35-40% ; [0029] 35-40% of white cement;

[0030]废瓷粉40. 73-47. 75% ; [0030] 40. A waste ceramic powder 73-4775%;

[0031]石英粉0-15%; [0031] 0-15% quartz powder;

[0032]钛白粉0-10%; [0032] 0-10% titanium dioxide;

[0033] 可再分散性乳胶粉1-1. 5% ; [0033] The re-dispersible emulsion powder 1-15%;

[0034]憎水剂0. 1% ; [0034] 0.1% hydrophobic agent;

[0035]保水剂0. 15% ; [0035] The water retaining agent 0.15%;

[0036] 木质素纤维0. 4% ; [0036] 0.4% vegetable fiber;

[0037]减水剂0. 1-0. 25% ; [0037] superplasticizer 1-0 0. 25%;

[0038]颜料0-2% ; [0038] 0-2% pigment;

[0039] 将各组分充分混合,搅拌均匀; [0039] The components are thoroughly mixed, stir;

[0040] 2)按与上述组合物1 :0. 7-1. 0比例称取水,一边搅拌一边添加上述混合粉料,搅拌成腻子状后,静置熟化8-15分钟,再机械搅拌20-60S,即为填缝剂。 [0040] 2) according to the above-described composition 1: 07-10 ratio of said water, was added with stirring the above mixed powder, putty into a stirred, allowed to stand for 8-15 minutes aging, mechanical stirring and then 20 -60S, namely sealant.

[0041] 其中,所述石英粉为重钙粉,所述重钙粉和钛白粉的粒径在100目-400目之间。 [0041] wherein the silica powder is a heavy calcium, heavy calcium powder and the titanium dioxide particle size between 100 mesh -400 mesh.

[0042] 本发明的有益效果为:通过使用废瓷粉作为填缝剂填料,减少了石英砂和重钙粉的消耗,通过白水泥的早强作用,提高填缝剂早期强度,满足施工工序要求。 [0042] Advantageous effects of the present invention are: ceramic powder as a waste by using a filler grout, quartz sand and reducing the consumption of heavy calcium, by the white cement early strength, improve the early strength grouts, to meet the construction step Claim. 废瓷粉经过高温烧结,物理化学性能稳定,体积稳定,与瓷砖膨胀收缩系数接近,采用同样膨胀收缩系数的材料作为填料,可以进一步减少瓷砖填缝剂产生裂缝的可能性。 Waste after high temperature sintering ceramic powder, stable physical and chemical properties, volume-stable, coefficient of expansion and contraction close to the tiles, using a material the same coefficient of expansion and contraction as a filler, it may further reduce the possibility of cracks in the tile grout.

[0043] 与现有技术相比,本发明具有以下独特的性能和优点: [0043] Compared with the prior art, the present invention has the following unique features and advantages:

[0044] (1)采用同样膨胀收缩系数的材料作为填料,可以减少瓷砖填缝剂产生裂缝的可能性。 [0044] (1) The coefficient of expansion and contraction of the same material as a filler, tile grouts possibility of cracks can be reduced.

[0045] (2)将废瓷粉作为建筑材料大量使用,可以使资源得到综合利用,环保利废。 [0045] (2) the extensive use of waste ceramic powder as a building material, allows utilization of resources, environmental waste utilization.

[0046] (3)应用聚羧酸粉剂减水剂,改善填缝剂的工作性、提高填缝剂的早后期强度、以及减少填缝剂固化后期收缩开裂,提高水泥基砂浆体系的和易性、施工性和温度适应性。 [0046] (3) Application of polycarboxylate superplasticizer powder, improve the workability of the sealant, caulk improved early and late strength and to reduce the post-curing sealant shrinkage cracking, improve the workability of the cement-based mortar systems property, construction and temperature adaptability.

具体实施方式 Detailed ways

[0047] 为详细说明本发明的技术内容、构造特征、所实现目的及效果,以下结合实施方式详予说明。 [0047] To illustrate the technical details of the present invention, the structural features, the objects and effects achieved, in conjunction with the following embodiments to be described in detail.

[0048] 废瓷粉:所述废瓷粉为从陶瓷生产工艺中直接获得或将废陶瓷进行破碎、球磨制粉而得,废瓷粉的化学组成Si02含量65%---70%之间,A1203含量在19%23%之间,K 20、 Na20含量在3%5%之间,化学组成中Si02、Al203含量与长石接近,K 20、Na20比长石低。 [0048] Waste ceramic powder: the ceramic powder as waste directly from the production process of ceramic or ceramic waste crushing, ball milling to give, Si02 content of the waste between the chemical composition of ceramic powder 70% 65% --- , A1203 content is between 19% 23%, K 20, Na20 content is between 3% and 5%, the chemical composition Si02, Al203 content close feldspar, K 20, Na20 lower than feldspar. 以下实施例中废瓷粉的粒径小于0. 81mm,因为废瓷粉粒径过大影响填缝剂工作性能,需要的是粉状材料,而废瓷粉中含有的瓷片等杂质颗粒应剔除,所以规定一个最大粒径。 The following example is waste ceramic powder particle size less than 0. 81mm, waste ceramic powder as particle size is too large impact performance caulks, powdery material is required, while tiles and other ceramic powder contained in the waste foreign particles should removed, so specify a maximum particle size.

[0049] 白水泥:白色硅酸盐水泥的简称,以适当成分的生料烧至部分熔融,所得以硅酸钙为主要成分,铁质含量少的熟料加入适量的石膏,磨细制成的白色水硬性胶凝材料。 [0049] White cement: Portland White Cement referred to an appropriate raw material component part till melted, the resulting calcium silicate as a main component, a small iron content of the clinker adding an appropriate amount of gypsum, ground made white hydraulic binder. 磨制水泥时,允许加入不超过水泥重量5%的石灰石。 When the grinding of cement, cement allowing addition of not more than 5% by weight of limestone. 本发明采用的白水泥为42. 5号白色快硬硫铝酸盐水泥或氧化铝含量在70%以上的白色铝酸盐水泥,这两种白水泥都具有快速硬化性能,适合填缝剂的使用要求,快速硬化以便进行其他装修操作。 White cement is employed in the present invention No. 42.5 white sulphoaluminate cement or rapid hardening white alumina content above 70% aluminate cement, and white cement have both rapid hardening properties, for the caulk requirements, rapid hardening for other renovation operations.

[0050]可再分散性乳胶粉:所述可再分散性乳胶粉为醋酸乙烯酯与乙烯共聚胶粉、乙烯与氯乙烯及月硅酸乙烯酯三元共聚胶粉、醋酸乙烯酯与乙烯及高级脂肪酸乙烯酯三元共聚胶粉、醋酸乙烯酯与高级脂肪酸乙烯酯共聚胶粉、丙烯酸酯与苯乙烯共聚胶粉、醋酸乙烯酯与丙烯酸酯及高级脂肪酸乙烯酯三元共聚胶粉、醋酸乙烯酯均聚胶粉、苯乙烯与丁二烯共聚胶粉、丙烯酸均聚胶粉中的一种或两种以上混合物。 [0050] redispersible latex powders: The re-dispersible emulsion powder of vinyl acetate and ethylene copolymer powder, vinyl chloride and of ethylene and vinyl acetate terpolymer months silicate powder, with ethylene and vinyl acetate higher fatty acid vinyl acetate terpolymer powder, vinyl acetate and a higher fatty acid vinyl acetate copolymer powder, methacrylate powder copolymerized with styrene, vinyl acetate and acrylic acid ester and a higher fatty acid vinyl acetate terpolymer powder, vinyl acetate ester homopolymerization powder, copolymer powder of styrene and butadiene, acrylic powder homopolymerization of one or a mixture of two or more.

[0051] 减水剂:所述减水剂为聚羧酸粉剂减水剂,减水率> 20%,含水率< 3%,氯离子含量< 0. lwt%,聚羧酸粉剂减水剂是一种新型的高性能减水剂,应用于水泥基干粉材料中,对于改善填缝剂的工作性、提高填缝剂的早后期强度、以及减少填缝剂固化后期收缩开裂有很大的帮助,并且能提高水泥基砂浆体系的和易性、施工性和温度适应性。 [0051] The water-reducing agent: The water-reducing agent is a polycarboxylate superplasticizer powders, water reduction of> 20%, water content <3%, chloride ion content <0. lwt%, powders polycarboxylate superplasticizer is a new type of superplasticizer used in the cement based dry materials for improving the workability of the sealant, caulk improved early and late strength and to reduce the post-cured sealant has a great shrinkage cracking help, and the workability can be improved, and workability of cementitious mortars temperature system adaptability. 具有掺量低、减水率闻、早强闻强、闻耐久、绿色环保等优点。 Having a low dosage, the smell water rates, early strength strong smell, the smell durability, environmental protection and so on.

[0052] 本发明环保型彩色瓷砖填缝剂具体制备步骤如下:按以下各实施例重量百分比称取各组分,搅拌均匀。 [0052] The present invention is environmentally friendly colored tile grout concrete preparation steps are as follows: in the following percentages by weight in each Example the components were weighed, stirred uniformly. 按与上述组合物1 :0. 7-1. 0比例称取水,一边搅拌一边添加上述混合粉料,搅拌成腻子状后,静置熟化8-15分钟,再机械搅拌20-60S,即为填缝剂。 According to the above-described composition 1: 07-10 ratio of said water, was added with stirring the above mixed powder, putty into a stirred, allowed to stand aged 8-15 minutes, and then mechanical stirring 20-60S, namely caulks. 一次搅拌,建议在30分钟内用完。 Stirring once, run over 30 minutes is recommended.

[0053] 实施例1 [0053] Example 1

[0054] 用废瓷粉的环保型彩色瓷砖填缝剂的各组分配比: [0054] The ceramic powder with waste environmentally friendly color tile grout distribution ratio for each group:

[0055]白水泥35% ; [0055] 35% of white cement;

[0056]废瓷粉47. 75% ; [0056] Waste ceramic powder 47.75%;

[0057] 重钙粉5% ; [0057] 5% of heavy calcium;

[0058]钛白粉10%; [0058] 10% of titanium dioxide;

[0059] 可再分散性乳胶粉1. 5% ; [0059] The re-dispersible emulsion powder 1.5%;

[0060]憎水剂0. 1% ; [0060] 0.1% hydrophobic agent;

[0061]保水剂0.15%; [0061] 0.15% water retaining agent;

[0062] 木质素纤维0. 4% ; [0062] 0.4% vegetable fiber;

[0063]减水剂0. 1% ; [0063] 0.1% water reducing agent;

[0064]颜料0%。 [0064] Pigment 0%.

[0065] 实施例2 [0065] Example 2

[0066] 用废瓷粉的环保型彩色瓷砖填缝剂的各组分配比: [0066] The ceramic powder with waste environmentally friendly color tile grout distribution ratio for each group:

[0067]白水泥37. 5% [0067] The white cement 37.5%

[0068]废瓷粉45· 45% [0068] Waste porcelain powder 45 · 45%

[0069] 重钙粉10% [0069] 10% of heavy calcium

[0070] 钛白粉5%; [0070] 5% of titanium dioxide;

[0071] 可再分散性乳胶粉1. 25% [0071] The re-dispersible emulsion powder 1.25%

[0072]憎水剂0. 1% ; [0072] 0.1% hydrophobic agent;

[0073]保水剂0. 15% ; [0073] 0.15% water retaining agent;

[0074] 木质素纤维0. 4% ; [0074] 0.4% vegetable fiber;

[0075]减水剂0. 15% ; [0075] 0.15% water reducing agent;

[0076]颜料0%。 [0076] Pigment 0%.

[0077] 实施例3 [0077] Example 3

[0078] 用废瓷粉的环保型彩色瓷砖填缝剂的各组分配比: [0078] The ceramic powder with waste environmentally friendly color tile grout distribution ratio for each group:

[0079]白水泥40%; [0079] 40% of white cement;

[0080]废瓷粉41. 1% ; [0080] Waste ceramic powder 41.1%;

[0081]重钙粉15%; [0081] 15% of heavy calcium;

[0082] 钛白粉0%; [0082] 0% of titanium dioxide;

[0083] 可再分散性乳胶粉1% ; [0083] The re-dispersible emulsion powder 1%;

[0084]憎水剂0. 1% ; [0084] 0.1% hydrophobic agent;

[0085]保水剂0. 15% ; [0085] 0.15% water retaining agent;

[0086] 木质素纤维0. 4% ; [0086] 0.4% vegetable fiber;

[0087]减水剂0. 25% ; [0087] 0.25% water reducing agent;

[0088]颜料2%。 [0088] 2% pigment.

[0089] 实施例4 [0089] Example 4

[0090] 用废瓷粉的环保型彩色瓷砖填缝剂的各组分配比: [0090] The ceramic powder with waste environmentally friendly color tile grout distribution ratio for each group:

[0091]白水泥40%; [0091] 40% of white cement;

[0092]废瓷粉40. 73% ; [0092] Waste ceramic powder 40.73%;

[0093]重钙粉15% ; [0093] 15% of heavy calcium;

[0094] 钛白粉0%; [0094] 0% of titanium dioxide;

[0095] 可再分散性乳胶粉1. 5% ; [0095] The re-dispersible emulsion powder 1.5%;

[0096]憎水剂0. 1% ; [0096] 0.1% hydrophobic agent;

[0097]保水剂0. 15% ; [0097] 0.15% water retaining agent;

[0098] 木质素纤维0. 4% ; [0098] 0.4% vegetable fiber;

[0099]减水剂0. 12% ; [0099] 0.12% water reducing agent;

[0100]颜料2%。 [0100] 2% pigment.

Claims (8)

1. 一种环保型彩色瓷砖填缝剂,其特征在于,以重量百分比计,包括如下组分: 白水泥35-40% ; 废瓷粉40. 73-47. 75% ; 重钙粉0-15% ; 钛白粉0-10%; 可再分散性乳胶粉1-1. 5% ; 憎水剂0. 1% ; 保水剂0. 15% ; 木质素纤维0. 4% ; 减水剂0. 1-0. 25% ; 颜料0-2% ; 所述废瓷粉为从陶瓷生产工艺中直接获得或将废陶瓷进行破碎、球磨制粉而得; 所述重钙粉和钛白粉的粒径在100目-400目之间。 An environmentally friendly colored tile grout, characterized in that, in weight percent, comprising the following components: 35-40% of white cement; 40. Waste 73-4775% ceramic powder; heavy calcium 0- 15%; 0-10% titanium dioxide;. 1-15% polymer powders redispersible; 0.1% hydrophobic agent; aquasorb 0.15%; 0.4% lignin fiber; superplasticizer 0 . 1-025%; 0-2% pigment; ceramic powder as the waste obtained directly from the production process of ceramic or ceramic waste crushing, ball milling derived; the titanium dioxide particles and heavy calcium diameter between 100 mesh -400 mesh.
2.根据权利要求1所述的环保型彩色瓷砖填缝剂,其特征在于,所述废瓷粉的粒径小于0. 81mm η The environmentally friendly color tile grout according to claim 1, wherein said ceramic powder is a waste particle size less than 0. 81mm η
3.根据权利要求1所述的环保型彩色瓷砖填缝剂,其特征在于,所述白水泥为42. 5号白色快硬硫招酸盐水泥或氧化招含量在70%以上的白色招酸盐水泥。 According to claim environmental type color tile grout of claim 1, wherein the white cement is a rapid hardening No. 42.5 white cement or a sulfur oxide salt strokes move the content of more than 70% of the white strokes acid salts of cement.
4.根据权利要求1所述的环保型彩色瓷砖填缝剂,其特征在于,所述可再分散性乳胶粉为醋酸乙烯酯与乙烯共聚胶粉、乙烯与氯乙烯及月桂酸乙烯酯三元共聚胶粉、醋酸乙烯酯与乙烯及高级脂肪酸乙烯酯三元共聚胶粉、醋酸乙烯酯与高级脂肪酸乙烯酯共聚胶粉、 丙烯酸酯与苯乙烯共聚胶粉、醋酸乙烯酯与丙烯酸酯及高级脂肪酸乙烯酯三元共聚胶粉、 醋酸乙烯酯均聚胶粉、苯乙烯与丁二烯共聚胶粉、丙烯酸均聚胶粉中的一种或两种以上混合物。 According to claim environmental type color tile grout of claim 1, wherein the re-dispersible emulsion powder of vinyl acetate and ethylene copolymer powder, vinyl chloride and vinyl laurate, vinyl acetate terpolymer copolymer powder, vinyl acetate and a higher fatty acid with ethylene vinyl acetate terpolymer powder, vinyl acetate and a higher fatty acid vinyl acetate copolymer powder, methacrylate powder copolymerized with styrene, vinyl acetate and acrylic acid ester and a higher fatty acid vinyl acetate terpolymer powder, polyethylene powder are vinyl acetate, styrene and butadiene copolymer powder, methacrylate powder homopolymerization of one or a mixture of two or more.
5.根据权利要求1所述的环保型彩色瓷砖填缝剂,其特征在于,所述憎水剂为粉末有机娃憎水剂。 The environmentally friendly color tile grout according to claim 1, wherein the hydrophobic agent is an organic baby powder hydrophobic agent.
6.根据权利要求1所述的环保型彩色瓷砖填缝剂,其特征在于,所述保水剂为羟丙基甲基纤维素醚,且其粘度在10000-40000mPa. s之间。 According to claim environmental type color tile grout of claim 1, wherein said water retaining agent is hydroxypropyl methyl cellulose ether, and a viscosity 10000-40000mPa. Between s.
7.根据权利要求1所述的环保型彩色瓷砖填缝剂,其特征在于,所述减水剂为聚羧酸粉剂减水剂,减水率彡20%,含水率< 3%,氯离子含量< 0. lwt%。 According to claim environmental type color tile grout of claim 1, wherein the water reducing agent is a polycarboxylate superplasticizer powders, water rates San 20% water content <3% chloride ion content <0. lwt%.
8. 一种环保型彩色瓷砖填缝剂的制备方法,其特征在于,包括以下步骤: 1)按重量百分比称取以下组分: 白水泥35-40% ; 废瓷粉40. 73-47. 75% ; 重钙粉0-15% ; 钛白粉0-10% ; 可再分散性乳胶粉1-1. 5% ; 憎水剂0. 1% ; 保水剂0. 15% ; 木质素纤维0. 4% ; 减水剂0. lo. 25% ; 颜料0-2% ; 将各组分充分混合,搅拌均匀; 2)按与上述组合物1 :0. 7-1. 0比例称取水,一边搅拌一边添加上述混合粉料,搅拌成腻子状后,静置熟化8-15分钟,再机械搅拌20-60S,即为填缝剂; 所述重钙粉和钛白粉的粒径在100目-400目之间。 8. A method of preparing an environmentally friendly color tile grout, which is characterized in that it comprises the following steps: 1) by weighing the following components in weight percent: 35-40% of white cement; waste ceramic powder 40. 73-47. 75%; heavy calcium 0-15%; 0-10% titanium dioxide; re-dispersible emulsion powder 1-15%;. repellent agent 0.1%; 0.15% water-retaining agent; lignin fiber 0 4%; superplasticizer 0. lo 25%; 0-2% pigment; the ingredients are well mixed and kneaded; 2) according to the above-described composition 1:... 07-10 the ratio of said water, was added with stirring the above mixed powder, putty into a stirred, allowed to stand aged 8-15 minutes, and then mechanical stirring 20-60S, caulk that is; the heavy calcium and titanium dioxide in a particle size of 100 mesh between -400 mesh.
CN 201310079858 2013-03-13 2013-03-13 Environment-friendly colorful tile joint mixture and preparation method thereof CN103172330B (en)

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